• 한국세라믹학회지
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• 제46권3호
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• pp.301-305
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• 2009

The novel carbon coating process for interlayer of fiber reinforced ceramic composites between fiber and matrix was performed by carbonizing phenolic resin solution that coated on fiber surface in $N_2$ atmosphere at $600^{\circ}C$ to improve the strength and fracture toughness of CMC(ceramic matrix composite). 160 nm carbon layer was coated on fiber surface with 5 vol% of phenolic resin solution. Since the process temperature ($600^{\circ}C$) is lower than chemical vapor deposition($900{\sim}1000^{\circ}C$), the strength and toughness could be preserved. Furthermore the coating thickness uniformity was improved to 8% of deviation along the stacking sequence. Therefore, prevention from fiber degradation during coating process and controlling coating thickness uniformity along the preform depth were achieved by coating with phenolic resin carbonizing method.

• Carbon letters
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• 제12권2호
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• pp.95-101
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• 2011

To investigate new applications for illite as an additive for carbon-based composites, the composites were prepared with and without illite at different heat-treatment temperatures. The effects of the heat-treatment temperature on the chemical structure, microstructure, and thermal oxidation properties of the resulting composites were studied. As the heat-treatment temperature was increased, silicon carbide SiC formation via carbothermal reduction increased until all the added illite was consumed in the case of the samples heat-treated at $2,300^{\circ}C$. This is attributed to the intimate contact between the $SiO_2$ in the illite and the phenol carbon precursor or the carbon fibers of the preform. Among composites prepared at all temperatures, those with illite addition exhibited fewer pores, voids, and interfacial cracks, resulting in larger bulk densities and lower porosities. A delay of oxidation was not observed in the illite-containing composites prepared at $2,300^{\circ}C$, suggesting that the illite itself absorbed energy for exfoliation or other physical changes. Therefore, if the illite-containing C/C composites can reach a density generally comparable to that of other C/C composites, illite may find application as a filler for C/C composites. However, in this study, the illite-containing C/C composites exhibited low density, even when prepared at a high heat-treatment temperature of $2300^{\circ}C$, although the thermal oxidation of the resulting composites was improved.

• Carbon letters
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• 제11권4호
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• pp.293-297
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• 2010

To investigate new potential application of a clay material for C/C composites, illite added C/C composites were prepared with various illite contents. The improvement of filler effect by illite size reduction was also investigated using wet ballmilling by evaluating illite/phenolic resin infiltration using bulk density and porosity measurements, chemical structural changes of the composites using XRD, and thermal oxidation stability in air of the composites using TGA. The size reduction of illite resulted in narrower particle size distribution and improved illite infiltration into carbon preform. And the resultant C/C composites prepared with illite had even more improved thermal oxidation stability in air, showing more increased IDTs up to $100^{\circ}C$, compared to those of the C/C composites with pristine illite, due to the SiC formation through carbothermal reduction between illite and carbon materials. The illite induced delay in oxidation of the illite-C/C composites was also observed and the delayed oxidation behavior was attributed to the layered structure of illite, which improved illite/phenol resin infiltration. Therefore, the potential use of illite as filler to improve oxidation stability of C/C composite can be promising. And the size reduction of illite can improve its effect on the desired properties of illite-C/C composites even more.

• Composites Research
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• 제12권3호
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• pp.8-16
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• 1999

탄소직포/탄소/SiC 복합재는 탄소직포/탄소 프로폼을 SiC의 유기전구체인 polycarbosilane에 다중함침 열처리하여 제조하였다. 더불어 탄소 섬유의 분율과 배열 형태가 다른 두 가지 종류의 저밀도 탄소/탄소 복합재 즉, 탄소직포($\thickapprox$55 vol%)/탄소 복합재와 chopped 탄소섬유($\thickapprox$40 vol%)/탄소 복합재를 $1700^{\circ}C$ 진공 분위기에서 용융 실리콘과 반응결합하여 고밀도의 탄소섬유/Si/SiC 복합재도 제조하였다. 이 반응 결합 공정 이전 각 밀도가 1.6g/$cm^3$인 탄소직포/탄소 복합재와 1.15g/$cm^3$인 chopped 탄소섬유/탄소 복합재는 반응결합 후 그 밀도가 각각 2.1g/$cm^3$로 증가하였다. 제조한 복합재는 전형적인 섬유강화 복합재의 파괴거동을 보였으며 반응결합 후 밀도와 stiffness 그리고 탄성 한계 강도 등은 모두 현저히 증가하였다. 3점 곡강도와 인장 시험으로 기계적 물성을 비교평가하였다. 탄소직포/탄소 복합재와 chopped 탄소섬유/탄소 복합재의 곡강도에 대한 인장 강도의 비는 약 1/3이었다. 탄소직포/Si/SiC 복합재의 밀도는 2.06g/$cm^3$, 최대 곡강도는 ~120 MPa, 탄성한계 응력은 ~80 MPa를 나타내었다.

• Tribology and Lubricants
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• 제24권4호
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• pp.163-169
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• 2008

Tribological properties of ceramic brake discs were investigated using a commercial friction material. The discs were manufactured by liquid silicon infiltration (LSI) into a C-C preform. The disc surface was modified by two different methods, producing sliding surfaces with chopped carbon fibers and carbon felt. In addition, the composition of the surface was also changed. Friction characteristics of the discs were examined using a 1/5 scale dynamometer. Results showed that the type and composition of the disc surface significantly affected the level of braking effectiveness and high temperature brake performance. The discs with felt surfaces showed higher friction levels than those with chopped fiber surfaces and SiC tended to increase the friction level while C lowered the friction coefficient. The ceramic disc was more sensitive to the deceleration rate than gray iron, showing high speed sensitivity.

• 반도체디스플레이기술학회지
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• 제14권2호
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• pp.61-65
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• 2015

SiC composite materials are usually used to very high temperature condition such as thermal protection system materials at space vehicles, combustion chambers or engine nozzles because they have high specific strength and good thermal properties at high temperature. One of the most widely used fabrication methods of SiC composites is the chemical vapor infiltration (CVI) process. During the process, chemical gases including Si are introduced into porous preform which is made by carbon fibers for infiltration. Since the processes take a very long time, it is important to reduce the process time in designing the reactors and processes. In this study, both the gas flow and heat transfer in the reactors during the processes are analyzed using a computational fluid dynamics method in order to design reactors and processes for uniform, high quality SiC composites. Effects of flow rate and heater temperature as process parameters to the infiltration process were examined.

• Composites Research
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• 제19권6호
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• pp.1-7
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• 2006

본 논문은 수지충전공정을 활용한 상업용 항공기의 복합재 윈도우 프레임을 개발하기 위한 선행 연구이다. 윈도우 프레임을 제작하기 위해 고려중인 2종류의 카본 섬유-triaxial overbraid 와 sleeving braider-에 대해서 VaRTM 공정을 활용한 시편을 제작하고, ASTM 시험법에 따라 물성치를 얻기 위해 물리적/기계적 성질 시험이 실시되었다. 이후 복합재 윈도우 프레임의 최소 플라이수와 무게를 얻기 위해 각각의 탄소 섬유에 대하여 유한요소해석이 수행되었다. 본 연구에서는 구조물의 안전성을 평가하기 위하여 Tsai-Wu 파손강도이론을 사용했다.

• Composites Research
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• 제31권6호
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• pp.293-298
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• 2018

본 논문에서는 항공기용 스트링거(Stringer)로 사용하기 위한 브레이드 복합재료(Braided composites)의 물성에 대해 연구하였다. 브레이드 프리폼(braid preform)을 $30^{\circ}$, $45^{\circ}$, $60^{\circ}$로 제작하기 위해 드럼 와인더 속도, 브레이드 속도, 멘드럴 직경과 같은 공정변수들을 정량화시켰고, 에폭시 수지 종류를 TGDDM, YD-128로 브레이드 프리폼에 다르게 적용하여 각도에 따른 브레이드 복합재료의 인장강도, 굽힘강도를 섬유부피분율에 따라 규명하였으며, TGA 분석으로 열적 특성과 에폭시 수지의 분해 온도를 조사하였다. 그 결과 브레이드 프리폼의 각도가 낮을수록 인장강도와 굽힘강도가 향상됨을 확인하였고, 분자량이 높은 에폭시 수지를 사용할 때 물리적 성질이 향상되었다.

• 한국표면공학회지
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• 제50권6호
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• pp.523-530
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• 2017

In this study, we developed the h-BN interphase for ceramic matrix composites (CMCs) through a wet chemical coating method, which has excellent price competitiveness and is a simple process as a departure from the existing high cost chemical vapor deposition method. The optimum condition for nitriding an h-BN interphase using boric acid and urea as precursors were derived, and the h-BN interphase coating through a wet method on a carbon preform of 2.5 D was conducted to apply the optimum conditions to the CMCs. In order to control the coating property via the wet coating method, four parameters were investigated such as dipping time of the specimen in the precursor solution, the ratio of boric acid and urea in the precursor, the concentration of solution where the precursor was dissolved, and the cycle of dipping and dry process. The CMCs was fabricated through polymer impregnation and pyrolysis (PIP) processes and a three-point flexural strength test was conducted to verify the role of the coated h-BN interphase.

• Composites Research
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• 제26권5호
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• pp.322-327
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• 2013

탄소섬유강화 SiC기지상 복합재는 우수한 산화저항성과 우수한 열충격저항성을 가진다. 그리고 이런 특성들은 탄소섬유강화복합재가 고온구조재로서 응용케하였다. 본 연구에서는 $C_f/SiC$ 복합재가 전구체 함침과 액상 함침이 동반된 열분해공정, Cyclohexene을 사용한 화학기상 경화공정을 통해 제조되었다. 최종 제조된 $C_f/SiC$ 복합재는 5회 함침을 통해 $0.43g/cm^3$ 밀도를 갖는 탄소섬유 프리폼에서 $1.76g/cm^3$의 밀도값을 나타내고 있다. 그리고 산화저항성 특성면에서 $C_f/SiC$ 복합재의 무게가 공기중 $1400^{\circ}C$에서 6시간 유지 후에 81%가 남았다. 결과적으로 Cyclohexene을 사용한 화학기상 경화공정은 효과적으로 높은 치밀화와 증가된 산화저항성을 보이고 있다.