• Journal of the Korea institute for structural maintenance and inspection
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• v.22 no.6
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• pp.182-188
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• 2018

Recently, various researches on the utilization of carbon nanotube(CNT) with superior electrical conductivity and large surface areas into concrete have been actively conducted. Thus, mechanical and thermal properties of cement-flyash composites were evaluated concerning the CNT replacements. Based on the low binder-to-water ratio, the cement composites were produced with 0.2 % and 0.5 % of CNT solids. The compressive strengths with various ages, isothermal calorimetry measurement, SEM analysis, thermal conductivity of cement composites and thermal gravimetry analysis were implemented. As the amount of CNT addition was increased, the thermal conductivity of cement composites were also increased. Also, there was no significant mechanical property differences between mixtures with and without CNTs.

• Applied Chemistry for Engineering
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• v.19 no.2
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• pp.161-167
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• 2008

Multi-walled carbon nanotubes (MWCNT)-reinforced poly(ethylene-co-ethyl acrylate) (EEA) nanocomposites were prepared by both melt and solution mixing methods. The mechanical, thermal, and electrical properties were investigated as a function of type and loading of CNT. The tensile strength and modulus increased, while elongation at break decreased with increasing MWCNT content. The hollow-type MWCNT showed an improved tensile strength and elongation at break compared with a conventional MWCNT. The thermal degradation temperature was increased by around $40^{\circ}C$ with increasing the amount of MWCNT. The melt-mixed composites showed the highest volume resistivity. In the case of solution-mixed composites, the conventional MWCNT was estimated to show much lower volume resistivity than that of hollow MWCNT. The number and length of extruded CNT onto the fractured surface increased by both increasing the content of CNT and employing the tensile strain to the sample. The melt-mixed specimens showed much smaller number and shorter length of extruded CNT.

• Korean Chemical Engineering Research
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• v.60 no.3
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• pp.327-333
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• 2022

In this study, silicon/carbon nanotube/carbon (Si/CNT/C) composites for anode were prepared to improve the volume expansion of silicon used as a high-capacity anode material. Si/CNT were prepared by electrostatic attraction of the positively charged Si and negatively charged CNT and then hydrothermal synthesis was performed to obtain the spherical Si/CNT/C composites. Poly(vinylidene fluoride) (PVDF), polyacrylic acid (PAA), and styrene butadiene rubber (SBR) were used as binders for electrode preparation, and coin cell was assembled using 1.0 M LiPF₆ (EC:DMC:EMC = 1:1:1 vol%) electrolyte and fluoroethylene carbonate (FEC) additive. The physical properties of Si/CNT/C anode materials were analyzed using SEM, EDS, XRD and TGA, and the electrochemical performances of lithium-ion batteries were investigated by charge-discharge cycle, rate performance, dQ/dV and electrochemical impedance spectroscopy tests. Also, it was confirmed that both capacity and rate performance were significantly improved using the PAA/SBR binder and 10 wt% FEC-added electrolyte. It is found that Si/CNT/C have the reversible capacity of 914 mAh/g, the capacity retention ratio of 83% during 50 cycles and the rate performance of 70% in 2 C/0.1 C.

• Composites Research
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• v.34 no.6
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• pp.387-393
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• 2021

This paper investigated the electrical properties of multiwall carbon nanotube reinforced polydimethylsiloxane (CNT-PDMS) strain sensors with copper electrodes on the wet-etched surface. MWCNT-PDMS strain sensors were fabricated according to the wt% of MWCNT. Surfaces on the electrode area were wet-etched with various etching duration and silver epoxy adhesives were spread on the wet-etched surface. Finally, we attached the copper electrodes to the MWCNT-PMDS strain sensors. We checked the electric conductivities by the two-probe method and sensing characteristics under the cyclic loading. We observed the electric conductivity of MWCNT-PDMS strain sensors increased sharply and the scattering of the measured data decreased when the surface of the electrode area was wet-etched. Initial resistances of MWCNT-PDMS strain sensors were inversely proportion to wt% of MWCNT and the etching duration. However, the resistance changing rates under 30% strain increased as wt% of MWCNT and the etching duration increased. Decreasing rate of the electric resistance change after 100 repetitions was smaller when wt% of MWCNT was larger and the etching duration was short. This was due to the low initial resistance of the MWCNT-PMDS strain sensors by the wet-etching.

• Advances in nano research
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• v.16 no.5
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• pp.509-519
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• 2024

In this study, the static analysis of carbon nanotube-reinforced composites (CNTRC) beams resting on a Winkler-Pasternak elastic foundation is presented. The developed theories account for higher-order variation of transverse shear strain through the depth of the beam and satisfy the stress-free boundary conditions on the top and bottom surfaces of the beam. To study the effect of carbon nanotubes distribution in functionally graded (FG-CNT), we introduce in the equation of CNT volume fraction a new exponent equation. The SWCNTs are assumed to be aligned and distributed in the polymeric matrix with different patterns of reinforcement. The rule of mixture is used to describe the material properties of the CNTRC beams. The governing equations were derived by employing Hamilton's principle. The models presented in this work are numerically provided to verify the accuracy of the present theory. The analytical solutions are presented, and the obtained results are compared with the existing solutions to verify the validity of the developed theories. Many parameters are investigated, such as the Pasternak shear modulus parameter, the Winkler modulus parameter, the volume fraction, and the order of the exponent in the volume fraction equation. New results obtained from bending and stresses are presented and discussed in detail. From the obtained results, it became clear the influence of the exponential CNTs distribution and Winkler-Pasternak model improved the mechanical properties of the CNTRC beams.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.36 no.5
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• pp.525-530
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• 2023

Stretchable piezoelectric energy harvester (S-PEHs) based on composite materials are considered one of the potential candidates for realizing wearable self-powered devices for smart clothing and electronic skin. However, low energy conversion performance and expensive stretchable electrodes are major bottlenecks hindering the development and application of S-PEHs. Here, we fabricated the S-PEH by adopting the piezoelectric composites with enhanced stress transfer properties and kirigami-patterned textile electrodes. The optimum contents of piezoelectric BaTiO₃ nanoparticles inside the carbon nanotube/ecoflex composite were selected as 30 wt% considering the trade-off between stretchability and energy harvesting performance of the device. The final S-PEH shows an output voltage and mechanical stability of ~5 V and ~3,000 cycles under repeated 150% of tensile strain, respectively. This work presents a cost-effective and scalable way to fabricate stretchable piezoelectric devices for self-powered wearable electronic systems.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2023.05a
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• pp.95-96
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• 2023

In this study, the table flow of fiber reinforced cement composites mixed with CNTs dispersed differently according to the dispersion method was evaluated. The mixture was composed of plain mixture according to the presence or absence of ultrasonic dispersion and PCE-based dispersants A and B of 0.5% and 1.0%, respectively, CNT was mixed with 0.03% of cement weight and fiber was mixed with 1.5% of total volume. As a result of the experiment, NC-A0.5 showed a fluidity similar to that of P without CNT. The fluidity of NC-A0.5 and P-N showed a similar tendency, which is considered to be due to the distribution of evenly dispersed CNT particles without agglomeration between cement particles due to the dispersant. NC-B0.5 showed a similar level of firmness to P-U, but after hitting 250 mm, B Agent seems to have a significant effect on liquidity improvement.Both NC-A1.0 and NC-B1.0 seem to have increased flow due to excessive dispersion.

• Applied Chemistry for Engineering
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• v.27 no.5
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• pp.502-507
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• 2016

This study was conducted to develop novel antimicrobial nano-composites, with the aim of fully utilizing antimicrobial properties of multi-walled carbon nanotubes (MWCNTs), nickel (Ni) and zinc oxide (ZnO). Ni coated-MWCNTs (Ni-CNT) were prepared and evaluated for their potential application as an antimicrobial material for inactivating bacteria. Field emission scanning electron microscopy (FE-SEM), and X-ray energy dispersive spectroscopy (EDS) were used to characterize the Ni coating and morphology of Ni-CNT. Staphylococcus aureus (S. aureus) and Escherichia coil (E. coil) were employed as the target bacterium on antimicrobial activities. Comparing with the nitric acid treated MWCNTs and Ni-CNT which have been previously reported to possess antimicrobial activity towards S. aureus and E. coil, Ni-CNT/ZnO exhibited a stronger antimicrobial ability. The nickel coating was confirmed to play an important role in the bactericidal action of Ni-CNTs/ZnO composites. Also, the addition of ZnO to the developed nanocomposite is suggested to improve the antimicrobial property.

• Composites Research
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• v.26 no.4
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• pp.254-258
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• 2013

Polypropylene films reinforced with multi-walled carbon nanotubes and exfoliated graphite nanoplatelets were fabricated by extrusion, and the effects of filler type and take-up speed on the mechanical properties and microstructure of composite films were investigated. Differential scanning calorimetry revealed that the addition of carbon nanomaterials resulted in increased degree of crystallinity. However, increasing the take-up speed reduced the degree of crystallinity, which indicates that tension-induced orientations of polymer chains and carbon nanomaterials and the loss of degree of crystallinity due to rapid cooling at high take-up speeds act as competing mechanisms. These observations were in good agreement with tensile properties, which are governed by the degree of crystallinity, where the C-grade exfoliated graphite nanoplatelet with a surface area of $750m^2/g$ showed the greatest reinforcing effect among all types of carbon nanomaterials used. Scanning electron microscopy was employed to observe the carbon nanomaterial dispersion and orientation, respectively.

• Korean Chemical Engineering Research
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• v.54 no.4
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• pp.574-581
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• 2016

In this study, CNT functionalized with pyrrolidine ring via 1,3-dipolar cycloaddition reaction with various amino acid and aldehyde was synthesized. Metallocene was subsequently immobilized on the functionalized CNT and CNT/polyethylene composite was prepared via in-situ ethylene polymerization. The polymerization activities of metallocene supported on CNT functionalized with glycine and benzaldehyde (Gly+BA-CNT) were similar to those of metallocene supported on CNT functionalized with N-benzyloxycarbonylglycine and paraformaldehyde (Z-Gly+PFA-CNT) although its Zr content was lower than that of Z-Gly+PFA-CNT. In the case of metallocene supported on Z-Gly+PFA-CNT, the even distribution of active sites hindered the diffusion of ethylene monomer and cocatalyst MAO due to steric hindrance during ethylene polymerization. Compared to polyethylene produced from homogeneous metallocene catalysts, CNT/PE composites had a higher initial degradation temperature ($T_{onset}$) and maximum mass loss temperature ($T_{max}$). It suggests that pyrrolidine functionalized CNT is uniformly dispersed and strongly interacted with the PE matrix, enhancing the thermal stability of PE.