• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09b
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• pp.980-981
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• 2006

In this study, bottom-up type powder processing and top-down type SPD (severe plastic deformation) approaches were combined in order to achieve full density of Carbon nanotube (CNT)/metal matrix composites with superior mechanical properties by improved particle bonding and least grain growth, which were considered as a bottle neck of the bottom-up method using the conventional powder metallurgy of compaction and sintering. ECAP (equal channel angular pressing), the most promising method in SPD, was used for the CNT/Cu powder consolidation. The powder ECAP processing with 1, 2, 4 and 8 route C passes was conducted at room temperature.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.366-367
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• 2006

Carbon nanotubes (CNTs) have attracted remarkable attention as reinforcement for composites owing to their outstanding mechanical properties. The CNT/Cu nanocomposite is fabricated by a novel fabrication process named molecular level process. The novel process for fabricating CNT/Cu composite powders involves suspending CNTs in a solvent by surface functionalization, mixing Cu ions with CNT suspension, drying, calcination and reduction. The molecular level process produces CNT/Cu composite powders whereby the CNTs are homogeneously implanted within Cu powders. The mechanical properties of CNT/Cu nanocomposite, consolidated by spark plasma sintering of CNT/Cu composite powders, shows about 3 times higher strength and 2 times higher Young's modulus than those of Cu matrix.

• Composites Research
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• v.29 no.3
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• pp.104-110
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• 2016

This paper reports a novel method for simultaneous exfoliation of graphene and dispersion of carbon nanotube by using intercalation method. In common, graphene flake and carbon nanotubes can be produced through individual exfoliation or debundling process, but the process require significant amount of time. Here, potassium sodium tartrate was thermally intercalated into graphite and carbon nanotube bundle for simultaneous exfoliation and dispersion of graphene and carbon nanotubes. We confirmed expansion of interlayer distance via XRD, and also found that oxidation level of the exfoliated materials were significantly low (below 8.3 at%). The produced materials are fabricated in to conductive composite film via vacuum filtration and spray deposition to show enhancement of conductive properties.

• Composites Research
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• v.24 no.6
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• pp.25-30
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• 2011

This paper presents an experimental study on the enhancement of electromagnetic shielding (EMI) properties of glass fiber, carbon fiber, and glass-carbon fiber composites by adding layers of multi-walled carbon nanotubes (MWCNTs). In the case of glass-fiber composites, spraying 0.1~0.2 g of MWCNT over a fiber area of $200mm{\times}200mm$ (1.8~3.6 ${\mu}m$ in thickness) resulted in significant improvement in EMI shielding effectiveness (SE). Also, when applying multiple MWCNT layers, it was more effective to place the layers concentrated near the center of the composite rather than spreading them out. On the contrary, inherently conductive carbon fiber and glass-carbon fiber composites did not show appreciable improvement with the addition of MWCNT layers. In order to maximize the effectiveness of carbon nanomaterials as EMI shielding fillers, it is imperative to understand the effect of these materials on various EMI shielding mechanisms and their interactions.

• Smart Structures and Systems
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• v.29 no.2
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• pp.351-359
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• 2022

The present study investigated the synergistic effects of carbon nanotube (CNT) and carbon black (CB) inclusions on the piezoresistive sensing behaviors of cementitious composites. Four different CNT and CB combinations were considered to form different conductive networks in the binder material composed of Portland cement and fly ash. The cement was substituted with fly ash at levels of 0 or 50% by the mass of binder. The specimens were cured up to 100 days to observe the variations of the electrical characteristics with hydration progress, and the piezoresistive sensing behaviors of the specimens were measured under cyclic loading tests. The fabricated specimens were additionally evaluated with flowability, resistivity and cyclic loading tests, and morphological analysis. The scanning electron microscopy and energy disperse X-ray spectroscopy test results indicated that CNT and CB inclusion induced synergistic formations of electrically conductive networks, which led to an improvement of piezoresistive sensing behaviors. Moreover, the incorporation of fly ash having Fe³⁺ components decreased the electrical resistivity, improving both the linearity of fractional changes in the electrical resistivity and reproducibility expressed as R² under cyclic loading conditions.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.36 no.6
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• pp.415-421
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• 2023

In this study, the piezoresistive properties of cementitious composites enhanced with carbon nanotubes for improved electrical conductivity were analyzed using a deep learning-based transformer algorithm. Experimental execution was performed in parallel for acquisition of training data. Previous studies on mixture design, specimen fabrication, chemical composition analysis, and piezoresistive performance testing are also reviewed in this paper. Notably, specimens in which fly ash substituted 50% of the binder material were fabricated and evaluated in this study, in addition to carbon nanotube-infused specimens, thereby exploring the potential enhancement of piezoresistive characteristics in conductive cementitious materials. The experimental results showed more stable piezoresistive responses in specimens with fly-ash substituted binder. The transformer model was trained using 80% of the gathered data, with the remaining 20% employed for validation. The analytical outcomes were generally consistent with empirical measurements, yielding an average absolute error and root mean square error between 0.069 to 0.074 and 0.124 to 0.132, respectively.

• Journal of Adhesion and Interface
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• v.11 no.4
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• pp.149-154
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• 2010

Interfacial evaluation was investigated for single-carbon fiber/phenolic and carbon nanotube (CNT)-phenolic composites by micromechanical technique and electrical resistance measurement combined with wettability test. Compressive strength of pure phenol and CNT-phenolic composites were compared using Broutman specimen. The contact resistance of CNT-phenolic composites was obtained using a gradient specimen by two and four-point methods. Surface energies and wettability by dynamic contact angle measurement were measured using Wilhelmy plate technique. Since hydrophobic domains are formed as heterogeneous microstructure of CNT in the surface, the dynamic contact angle exhibited more than $90^{\circ}$. CNT-phenolic composites exhibited a higher apparent modulus than neat phenolic case due to better stress transferring effect. Work of adhesion, $W_a$ between single-carbon fiber and CNT-phenolic composites exhibited higher than neat phenolic resin due to the enhanced viscosity by CNT addition. It was consistent with micro-failure patterns in microdroplet test.

• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.16-21
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• 2016

Silicon/Carbon/CNT composites as anode materials for lithium-ion batteries were synthesized to overcome the large volume change during lithium alloying-de alloying process and low electrical conductivity. Silicon/Carbon/CNT composites were prepared by the fabrication processes including the synthesis of SBA-15, magnesiothermic reduction of SBA-15 to obtain Si/MgO by ball milling, carbonization of phenolic resin with CNT and HCl etching. The prepared Silicon/Carbon/CNT composites were analysed by XRD, SEM, BET and EDS. In this study, the electrochemical effect of CNT content to improve the capacity and cycle performance was investigated by charge/discharge, cycle, cyclic voltammetry and impedance tests. The coin cell using Silicon/Carbon/CNT composite (Si:CNT=93:7 in weight) in the electrolyte of $LiPF_6$ dissolved in organic solvents (EC:DMC:EMC=1:1:1 vol%) has better capacity (1718 mAh/g) than those of other composition coin cells. The cycle performance of coin cell was improved as CNT content was increased. It is found that the coin cell (Si:CNT=89:11 in weight) has best capacity retension (83%) after 2nd cycle.

• Proceedings of the Korean Vacuum Society Conference
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• 2005.08a
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• pp.84-84
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• 2005

• Smart Structures and Systems
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• v.18 no.2
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• pp.217-231
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• 2016

The present work aims to develop piezoresistive sensors of excellent piezoresistive response attributable to change in nanoscale structures of multi-wall carbon nanotube (MWNT) embedded in cement. MWNT was distributed in a cement matrix by means of polymer wrapping method in tandem with the ultrasonication process. DC conductivity of the prepared samples exhibited the electrical percolation behavior and therefore the dispersion method adopted in this study was deemed effective. The integrity of piezoresistive response of the sensors was assessed in terms of stability, the maximum electrical resistance change rate, and sensitivity. A composite sensor with MWNT 0.2 wt.% showed the lowest stability and sensitivity, while the maximum electrical resistance change rate exhibited by this sample was the highest (96 %) among others and even higher than those found in the literature. This observation was presumably attributed by the percolation threshold and the tunneling effect. As a result of the MWNT content (0.2 wt.%) of the sensor being near the percolation threshold (0.25 wt.%), MWNTs were close to each other to trigger tunneling in response of external loading. The sensor with MWNT 0.2 wt.% was able to maintain the repeatable sensing capability while sustaining a vehicular loading on road, demonstrating the feasibility in traffic flow sensing application.