• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.798-803
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• 2018

In order to use Si as an anode material for lithium-ion battery, the particle size was controlled to less than $0.5{\mu}m$ and carbon was coated on the surface with the thickness less than 10 nm. The carbon fiber was grown on the Si surface with 50~150 wt%, and the carbon coating was carried out once again. The Si composite material was mixed with dissimilar metals to increase the conductivity, and graphite was mixed to improve cyclic life characteristics. The physical and electrochemical characteristics of composite materials were measured with XRD, SEM, TEM and coin cell. The discharge capacity of Si/PC/CNF/PC was lower than that of Si/PC (Pyrolytic Carbon)/CNF (Carbon Nano Fiber). However, the cyclic life of Si/PC/CNF/PC was higher. Initial discharge capacity of 1512 mA h g-1 at 0.2 C rate and initial efficiency of 78% were shown. It also showed a capacity retention of 94% in 10 cycles.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2009.10a
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• pp.190-191
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• 2009

• Structural Engineering and Mechanics
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• v.56 no.2
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• pp.157-167
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• 2015

The impact behavior of epoxy-based nanocomposites reinforced with carbon nano tube (CNT), carbon nano fiber (CNF) and mixed contents of these nanoparticles was investigated using Izod impact test. The results showed that while the impact strength of nanocomposites containing 1 wt% of CNT and 1 wt% of CNF increased 19% and 13% respectively, addition of mixed contents of these nanofillers (0.5-0.5 wt%) demonstrated higher improvement (21%) in the impact resistance. The trend of the results is explained on the basis of different fracture mechanisms of nanocomposites. Furthermore, the fracture surface of specimens and the dispersion state of nanoenhancers have been studied using scanning electron microscopy (SEM) photographs.

• Structural Engineering and Mechanics
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• v.87 no.4
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• pp.375-389
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• 2023

In many fiber concrete beams with Carbon Fiber Reinforced Polymer (CFRP), debonding occurs between the carbon sheets and the concrete due to the low strength of the bonding resin. A total of 42 fiber concrete beams with a cross-section of 10×10 cm with a span length of 50 cm are fabricated and retrofitted with CFRP and subjected to a 4-point bending test. Graphene Oxide (GO) at 1, 2, and 3 wt% of the resin is used to improve the mechanical properties of the bonding resins, and the effect of length, width, and the number of layers of CFRP and resin material are investigated. The crack pattern, failure mode, and stress-strain curve are analyzed and compared in each case. The results showed that adding GO to polyamine resin could improve the bonding between the resin and the fiber concrete beam. Furthermore, the optimum amount of nanomaterials is equal to 2% by the weight of the resin. Using 2% nanomaterials showed that by increasing the length, width, and number of layers, the bearing and stiffness of fiber concrete beams increased significantly.

• Composites Research
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• v.26 no.3
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• pp.160-164
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• 2013

In this study, the effect of phosphoric acid (PA) as a fiber spinning aid on the strength increase of polyacrylonitrile (PAN) nano-fibers by using modified mechano-electrospinning technologies has been analyzed. The medium carbonization temperature of $800^{\circ}C$ has been selected for the future economic production of these new materials. The concentration of PAN in dimethyl sulfoxide (DMSO) was fixed as 5 wt%. The weight fraction of PA was selected as being 2%, 4%, 6%, and 8% in comparison to PAN. These solutions have been used to make the nanofibers. The mechano-electrospinning apparatus installed in KRICT was made by our own design. By using this apparatus the continous and highly aligned precursor nano-fibers have been obtained. The bundle of 50 well aligned nano diameter continuous fibers with the diametr of 10 microns with 6 wt% phosphoric acid for addition showed maximum mechanical properties of 1.6 GPa as tensile strength and 300 GPa as Young's modulus. The weight of final product can be increased 19%, which can improve the economical benefits for the application of these new materials.

• Advances in nano research
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• v.14 no.5
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• pp.443-450
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• 2023

Carbon nanotubes (CNTs) have received increased interest in reinforcing research for polymer matrix composites due to their exceptional mechanical characteristics. Its high surface area/volume ratio and aspect ratio enable polymer-based composites to make the most of its features. This study focuses on the experimental tensile testing and fabrication of carbon nanotube reinforced composite (CNTRC) beams, exploring various micromechanical models. By examining the performance of these models alongside experimental results, the research aims to better understand and optimize the mechanical properties of CNTRC materials. Tensile properties of neat epoxy and 0.3%; 0.4% and 0.5% by CNT reinforced laminated single layer (0°/90°) carbon fiber composite beams were investigated. The composite plates were produced in accordance with ASTM D7264 standard. The tensile test was performed in order to see the mechanical properties of the composite beams. The results showed that the optimum amount of CNT was 0.3% based on the tensile capacity. The capacity was significantly reduced when 0.4% CNT was utilized. Moreover, the experimental results are compared with Finite Element Models using ABAQUS. Hashin Failure Criteria was utilized to predict the tensile capacity. Good conformance was observed between experimental and numerical models. More importantly is that Young' Moduli of the specimens is compared with the prediction Halpin-Tsai and Mixture-Rule. Although Halpin-Tsai can accurately predict the Young's Moduli of the specimens, the accuracy of Mixture-Rule was significantly low.

• Korean Journal of Metals and Materials
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• v.48 no.12
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• pp.1130-1135
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• 2010

Cu/carbon nano-particle hybrids were fabricated through the cathodic electrophoretic deposition (EPD) process. CNT and CNF nano-particles were modified to give positive charges by polyethyleneimine (PEI) treatment before depositing them on the substrate. Since a Cu plate was used as an anode in the EPD process, Cu particles were also deposited along with the carbon nano-particles. Experimental observation showed the nano-hybrids constructed a novel formicary-like nano-structure which is strong and highly conductive. Utilizing the hybrids, carbon fiber composites were manufactured, and their electrical conductivity and interlaminar shear strength were measured. In addition, the deposition morphology and failure surface were examined by SEM observations. Results demonstrated that the electrical conductivities in the through-the-thickness direction and the interlaminar shear strength significantly increased by 350~2100% and 14%, respectively.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.2
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• pp.94-101
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• 2017

Tow Prepreg is the intermediate material for filament winding process that has been "pre-impregnated fiber tow" with resin system. As "dry filament winding" process emerges as a reliable alternative to conventional filament winding (called "wet filament winding") process, interest in tow prepreg as a material for dry filament winding is rising as well. In this article, we have reviewed the recent research trends in carbon fiber tow prepreg for high-performance rocket motor cases, fuel tanks for hydrogen vehicles and other high-quality commercial pressure vessels.

• Korean Chemical Engineering Research
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• v.46 no.6
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• pp.1142-1147
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• 2008

Nano-structured porous carbon fiber(PCF) for the catalyst supports of the direct methanol fuel cell (DMFC) were prepared from the mesophase pitch by using the nano-MgO powders. Specific surface area of the PCFs was $8{\sim}58m^2/g$ and surface pore structures had almost meso pore diameter of 10~20 nm which were depending on the amount of MgO spheres. Aqueous reduction method was used to load 60 wt% PtRu on the prepared PCF supports. The electro-oxidation activity and single cell performance of the 60 wt% Pt-Ru catalysts were measured by cyclic voltammetry and unit cell test. The performances of these catalysts increased by 5~10% compared with one of commercial catalyst.

• Journal of Korean Society for Atmospheric Environment
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• v.25 no.2
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• pp.122-132
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• 2009

Adsorption of toluene by activated carbon fiber (ACF) coated with dielectric heating element and desorption by applying microwave were investigated. In order to prepare adsorbent so that VOC can be desorbed by microwave heating, fine dielectric heating element with nano size was coated on the surface of the ACF using hybrid binder. Eight adsorbents (ACF-DHE, Activated Carbon Fiber coated with Dielectric Heating Element) were prepared with different amount of dielectric heating element, kinds of hybrid binder, and solvent. In order to investigate adsorption characteristics, BET surface area, pore volume, and average pore size were measured for each adsorbent including ACF. Breakthrough experiments with toluene concentration, flow rate, bed length using fixed bed reactor were performed to investigate adsorbality of adsorbent, and results were compared with that of the ACF. Desorption reactor was constructed with modified microwave oven to investigate heating effect on ACF-DHE by applying microwave power. Each adsorbent saturated with toluene were put into desorption reactor. Composition of desorbed gas generated by applying controlled microwave power to reactor was measured. Up to now, hot air desorption method has been used. Experimental results showed that desorption method with new adsorbent prepared by coating dielectric heating element on ACF can be used for industrial application.