• 제목/요약/키워드: Carbon material

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Ketjenblack 전도제 혼합량에 따른 EDLC용 탄소나노섬유 전극의 특성 (Characterization of Carbon Nanofiber Electrode with different Ketjenblack Conducting Material Mixing Amount Using EDLC)

  • 최원경
    • 한국수소및신에너지학회논문집
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    • 제19권2호
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    • pp.163-170
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    • 2008
  • Carbon nanofibers with nano-sized structures were evaluated as a active material using supercacitor electrode which could store electrochemical energy reversibly. A feasibility of EDLC electrode was estimated with specific surface area measurement by BET method and mesopore structure of carbon nanofiber surface could be explained electrochemical absorption-desorption in aqueous electrolyte. A capacitance of carbon nanofiber electrode was increased gradually, depending on the ratio of Ketjenblack as a conducting material. Ketjen Black $20{\sim}25\;wt.%$ ratio in electrode was observed a suitable amount of conducting material by cyclic voltametry results.

탄화된 페놀레진의 전기화학적 성질 (Electrochemical Properties of Carbonized Phenol Resin)

  • 김한주;박종은;홍지숙;류부형;박수길
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1999년도 추계학술대회 논문집
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    • pp.629-632
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    • 1999
  • For replacing Li metal ai Lithium ton Bakery(LIB) system. we used carbon powder material which prepared by pyrolysis of phenol resin as starting material. It became amorphous carbon by pyrolysis through it\`s self condensation by thermal treatment. Amorphous carbon can be doped with Li intercalation and deintercalation because it has wide interlayer. however it has a problem with structural destroy causing weak carbon-carbon bond. So. we used ZnCl$_2$ as the pore-forming agent. This inorganic salt used together with the resin serves not only as the pore-forming agent to form open pores, which grow Into a three-dimensional network structure in the cured material, foul also as the microstructure-controlling agent to form a loose structure dope with bulky dopants. We analyzed SEM in order to find to different of structure. and can calculate distance of interlayer. CV test showed oxidation and reduction

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Preparation and Characterization of Spherical Carbon Composite for Use as Anode Material for Lithium Ion Batteries

  • Ahn, Byoung-Hoon;Lee, Sung-Man
    • Bulletin of the Korean Chemical Society
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    • 제31권5호
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    • pp.1331-1335
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    • 2010
  • A novel spherical carbon composite material, in which nanosized disordered carbons are dispersed in a soft carbon matrix, has been prepared and investigated for use as a potential anode material for lithium ion batteries. Disordered carbons were synthesized by ball milling natural graphite in air. The composite was prepared by mixing the ball-milled graphite with petroleum pitch powder, pelletizing the mixture, and pyrolyzing the pellets at $1200^{\circ}C$ in an argon flow. The ballmilled graphite consists of distorted nanocrystallites and amorphous phases. In the composite particle, nanosized flakes are uniformly distributed in a soft carbon matrix, as revealed by X-ray diffractometer (XRD) and transmission electron microscopy (TEM) experiments. The composite is compatible with a pure propylene carbonate (PC) electrolyte and shows high rate capability and excellent cycling performance. The electrochemical properties are comparable to those of hard carbon.

탄소섬유그리드 보강 휨부재의 거동에 대한 실험적 연구 (An Experimental Study on the Behavior of Carbon Fiber Grid Reinforced Flexural Members)

  • 박제용;안동준;정상균;윤순종
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 1999년도 추계학술발표대회 논문집
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    • pp.154-159
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    • 1999
  • In this paper we present tile results of an experimental investigation on the physical and mechanical properties of carbon fiber grid, polymer mortar, and carbon fiber grid reinforced plain concrete flexural members. In order to repairing and reinforcing damaged and/or deteriorated existing concrete structural members, new materials have been developed and utilized in the construction industries. But the physical and mechanical behaviors of the material are not well understood. To use the material effectively various aspects of the material must be throughly investigated analytically as well as experimentally. In this investigation we found the physical and mechanical properties of carbon fiber grid and polymer mortar which are directly utilized in the repair and reinforcement design of damaged or deteriorated concrete structures. In addition, we also investigate the strengthening effect of carbon fiber grid on the plain concrete flexural test specimens. It was found that the material can be used to repair and strengthen the concrete structures effectively.

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Controlling the Hardness and Tribological Behaviour of Non-asbestos Brake Lining Materials for Automobiles

  • Mathur, R.B.;Thiyagarajan, P.;Dhami, T.L.
    • Carbon letters
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    • 제5권1호
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    • pp.6-11
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    • 2004
  • In spite of unparalleled combination of essential material properties for brake linings and clutch facings, replacement for asbestos is seriously called for since it is a health hazard. Once asbestos is replaced with other material then composition and properties of brake pad changes. In certain cases hardness of the material may be high enough to affect the rotor material. In this study, hardness of the brake pad has been controlled using suitable reinforcement materials like glass, carbon and Kevlar pulp. Brake pad formulations were made using CNSL (cashew net shell liquid) modified phenolic resin as a binder, graphite or cashew dust as a friction modifier and barium sulphate, talc and wollastonite as fillers. Influence of each component on the hardness value has been studied and a proper formulation has been arrived at to obtain hardness values around 35 on Scleroscopic scale. Friction and wear properties of the respective brake pad materials have been measured on a dynamometer and their performance was evaluated.

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싸이클로헥센 증기 공정에 의한 산소량이 적은 실리콘카바이드 섬유의 개발 (Development of Polymer-derived Silicon Carbide Fiber with Low Oxygen Content Using a Cyclohexene Vapor Process)

  • 윤병일;최우철;김명주;김재성;김정일;강홍구
    • 한국군사과학기술학회지
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    • 제20권5호
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    • pp.620-632
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    • 2017
  • A chemical vapor curing method(CVC) was developed to cure polycarbosilane(PCS) fibers by using cyclohexene vapour as a non-oxygen active reactant, instead of air in oder to prepare the silicon carbide(SiC) fiber with low oxygen content. A cross-linked PCS fibers by cyclohexene vapor showed a completely different variation in IR spectra in comparison to the air-cured PCS fiber. CVC method resulted in less than 3 wt% in oxygen content. In this experiment conditions, The average tensile strength and modulus of SiC fiber obtained by CVC had 1995 MPa and 183 GPa respectively, which is higher than that of SiC fiber prepared by air-curing process.

온도 변화에 따른 EBA/카본블랙 복합체의 점탄성 특성에 관한 연구 (Study on the viscoelasticity properties of EBA/Carbon Black composites by temperature changes)

  • 양종석;이경용;최용성;남종철;박동하;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.136-137
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    • 2005
  • To measure elastic properties of semiconducting materials in power cable, we have investigated modulus of EBA/carbon black composite showed by changing the content of carbon black. The specimen was primarily kneaded in material samples of pellet form for 5 minutes on rollers ranging between 70[$^{\circ}C$] and 100[$^{\circ}C$]. Then this was produced as sheets after pressing for 20 minutes at 180[$^{\circ}C$] with a pressure of 200[kg/cm]. The contents of conductive carbon black were 20, 30 and 40[wt%], respectively. The modulus experiment was measured by DMA 2980. The ranges of measurement temperature were from -50[$^{\circ}C$] to 100[$^{\circ}C$] and measurement frequency is 1 [Hz]. The modulus of specimens was increased according to an increment of carbon black content And modulus was rapidly decreased at the glass transition temperature. The tan$\delta$ of specimens was decreased according to an increment of carbon black content.

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신광원 적용을 위한 카본 박막의 특성 (Electrical Properties of Carbon film for Application of New Light Source)

  • 이상헌;최용성;박대희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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    • pp.346-347
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    • 2005
  • The carbon film was deposited by the electrolysis of methanol solution. From investigations of the Raman spectroscopy and the FTIR spectroscopy, the carbon film deposited by the electrolysis was identified the hydrogenated carbon film with the porous structure. The carbon film deposited by electrolysis of methanol was identified as the hydrogenated carbon film with porous structure.

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RF 열플라즈마를 이용한 이차전지 음극재용 탄소나노실리콘복합소재 합성 (Synthesis of Carbon Nano Silicon Composites for Secondary Battery Anode Materials Using RF Thermal Plasma)

  • 이순직;김대신;연정미;박원규;신명선;최선용;주성후
    • 한국재료학회지
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    • 제33권6호
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    • pp.257-264
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    • 2023
  • To develop a high capacity lithium secondary battery, a new approach to anode material synthesis is required, capable of producing an anode that exceeds the energy density limit of a carbon-based anode. This research synthesized carbon nano silicon composites as an anode material for a secondary battery using the RF thermal plasma method, which is an ecofriendly dry synthesis method. Prior to material synthesis, a silicon raw material was mixed at 10, 20, 30, 40, and 50 wt% based on the carbon raw material in a powder form, and the temperature change inside the reaction field depending on the applied plasma power was calculated. Information about the materials in the synthesized carbon nano silicon composites were confirmed through XRD analysis, showing carbon (86.7~52.6 %), silicon (7.2~36.2 %), and silicon carbide (6.1~11.2 %). Through FE-SEM analysis, it was confirmed that the silicon bonded to carbon was distributed at sizes of 100 nm or less. The bonding shape of the silicon nano particles bonded to carbon was observed through TEM analysis. The initial electrochemical charging/discharging test for the 40 wt% silicon mixture showed excellent electrical characteristics of 1,517 mAh/g (91.9 %) and an irreversible capacity of 133 mAh/g (8.1 %).