• Title/Summary/Keyword: Carbon ion

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Adsorption and Desorption Characteristics of Methyl iodide on Silver ion-Exchanged Synthetic Zeolite at High Temperature

  • Park, Geun-Il;Park, Byung-Sun;Cho, Il-Hoon;Kim, Joon-Hyung;Ryu, Seung-Kon
    • Nuclear Engineering and Technology
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    • v.32 no.5
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    • pp.504-513
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    • 2000
  • The adsorption characteristics of methyl iodide generated from the simulated off-gas stream on various adsorbents such as silver ion-exchanged zeolite (AgX), zeocarbon and activated carbon were investigated. An extensive evaluation was made on the optimal silver ion-exchanged level for the effective removal of methyl iodide at temperature up to 38$0^{\circ}C$. The degree of adsorption efficiency of methyl iodide on silver ion-exchanged zeolite is strongly dependent of silver ion-amount and process temperature. The influence of temperature, methyl iodide concentration and silver ion-exchanged level on the adsorption efficiency is closely related to the pore characteristics of adsorbents. It would be facts that the effective silver ion-exchanged level was about 10 wt%, based on the degree of silver utilization for the removal of methyl iodide.

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Synthesis and Characterization of Tin-Pyrolyzed Carbon Composites as Anode Material for Lithium Ion Secondary Batteries (리튬이온이차전지 음극활물질로써 주석을 첨가한 열분해탄소의 합성과 특성평가)

  • Hwang, Yun-Ju;Park, Sang-Ho;Kim, Ae-Rhan;Jisha, M.R.;Christy, Maria;Suh, Eun-Kyung;Nahm, Kee-Suk
    • Journal of Energy Engineering
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    • v.19 no.1
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    • pp.16-20
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    • 2010
  • In present work, tin-carbon mixtures by using carbon from pyrolyzed coffee seeds were synthesized. Synthesis methods includes simple mixing and chemical mixing. X-ray diffraction pattern indicated carbon and tin mixture peaks and scanning electron microscope images showed particles size of $12{\sim}85\;{\mu}m$ and shape. Charge discharge test were carried out. Tin-carbon mixture by chemical mixing indicated higher discharge capacity of 191 mAh/g than commercial carbon black(105 mAh/g) for 15cycles. Tin-carbon mixture by simple mixing indicated similar performance to carbon black.

Surface modification and induced ultra high surface hardness by nitrogen ion implantation of low alloy steel

  • Olofinjana, A.O.;Bell, J.M.;Chen, Z.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.157-158
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    • 2002
  • A surface hardenable low alloy carbon steel was implanted with medium energy (20 - 50KeV) $N_2^+$ ions to produced a modified hardened surface. The implantation conditions were varied and are given in several doses. The surface hardness of treated and untreated steels were measured using depth sensing ultra micro indentation system (UMIS). It is shown that the hardness of nitrogen ion implanted steels varied from 20 to 50GPa depending on the implantation conditions and the doses of implantation. The structure of the modified surfaces was examined by X-ray photoelectron spectroscopy (XPS). It was found that the high hardness on the implanted surfaces was as a result of formation of non-equilibrium nitrides. High-resolution XPS studies indicated that the nitride formers were essentially C and Si from the alloy steel. The result suggests that the ion implantation provided the conditions for a preferential formation of C and Si nitrides. The combination of evidences from nano-indentation and XPS, provided a strong evidence for the existence of $sp^3$ type of bonding in a suspected $(C,Si)_xN_y$ stoichiometry. The formation of ultra hard surface from relatively cheap low alloy steel has significant implication for wear resistance implanted low alloy steels.

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A Study on the Removal of Silver in Copper Electrolyte (황산동전해액(黃酸銅電解液) 중 은(銀(Ag)) 제거(除去)를 위한 연구(硏究))

  • So, Sun-Seob;Ahn, Jae-Woo
    • Resources Recycling
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    • v.17 no.5
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    • pp.60-65
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    • 2008
  • A study on the removal of silver(Ag) in copper electrolyte was carried out to produce high purity copper by using various method such as ion exchange resin, activated carbon adsorption, copper cementation with powder and wire, CuS precipitation. Parameters, such as reaction time, reaction temperature, addition amount etc. were investigated to determine the effective condition of silver removal. CuS precipitation and ion exchange using Lewatit TP214 was found to be effective. Especially, silver content in copper electrolyte was reduced from 10 ppm to less than 0.1 ppm by ion exchange with Lewatit TP214.

Corrosion resistance of a carbon-steel surface modified by three-dimensional ion implantation and electric arc.

  • Valbuena-Nino, E.D.;Gil, L.;Hernandez, L.;Sanabria, F.
    • Advances in materials Research
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    • v.9 no.1
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    • pp.1-14
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    • 2020
  • The hybrid method of three-dimensional ion implantation and electric arc is presented as a novel plasma-ion technique that allows by means of high voltage pulsed and electric arc discharges, the bombardment of non-metallic and metallic ions then implanting upon the surface of a solid surface, especially out of metallic nature. In this study AISI/SAE 4140 samples, a tool type steel broadly used in the industry due to its acceptable physicochemical properties, were metallographically prepared then surface modified by implanting titanium and simultaneously titanium and nitrogen particles during 5 min and 10 min. The effect of the ion implantation technique over the substrate surface was analysed by characterization and electrochemical techniques. From the results, the formation of Ti micro-droplets upon the surface after the implantation treatment were observed by micrographs obtained by scanning electron microscopy. The presence of doping particles on the implanted substrates were detected by elemental analysis. The linear polarization resistance, potentiodynamic polarization and total porosity analysis demonstrated that the samples whose implantation treatment with Ti ions for 10 min, offer a better protection against the corrosion compared with non-implanted substrates and implanted at the different conditions in this study.

Liquid Crystal Alignment Effects on Nitrogen-doped Diamond like Carbon Layer by Ion Beam Alignment Method

  • Han, Jeong-Min;Choi, Sung-Ho;Kim, Byoung-Yong;Han, Jin-Woo;Kim, Jong-Hwan;Kim, Young-Hwan;Hwang, Jeoung-Yeon;Lee, Sang-Keuk;Ok, Chul-Ho;Seo, Dae-Shik
    • Transactions on Electrical and Electronic Materials
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    • v.8 no.1
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    • pp.46-50
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    • 2007
  • We have studied the nematic liquid crystal (NLC) alignment effects on a nitrogen-doped diamond-like carbon (NDLC) thin film layer with ion beam irradiation. The pretilt angle for NLC on the NDLC surface with ion beam exposure was observed below 1 degree. Also, we had the good LC alignment characteristics on the NDLC thin films with ion beam exposure of 1800 eV. In thermal stability experiments, the alignment defect of the NLC on the NDLC surface with ion beam irradiation above annealing temperature of $250^{\circ}C$ can be observed. Therefore, the good thermal stability and LC alignment for NLC by ion beam aligned NDLC thin films can be achieved.

Investigation on Liquid Crystal Alignment Effects of SiNx Thin Film Irradiated by Ion Beam (이온 빔 조사된 SiNx 박막의 액정 배향 효과에 관한 연구)

  • Lee, Sang-Keuk;Kim, Young-Hwan;Kim, Byoung-Yong;Han, Jin-Woo;Kang, Dong-Hun;Kim, Jong-Hwan;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.398-398
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    • 2007
  • Most recently, the Liquid Crystal (LC) aligning capabilities achieved by ion beam exposure on the diamond-like carbon (DLC) thin film layer have been successfully studied. The DLC thin films have a high mechanical hardness, a high electrical resistance, optical transparency and chemical inertness. Nitrogen doped Diamond Like Carbon (NDLC) thin films exhibit properties similar to those of the DLC films and better thermal stability than the DLC films because C:N bonding in the NDLC film is stronger against thermal stress than C:H bonding in the DLC thin films. Moreover, our research group has already studied ion beam alignment method using the NDLC thin films. The nematic liquid crystal (NLC) alignment effects treated on the SiNx thin film layers using ion beam irradiation for three kinds of N rations was successfully studied for the first time. The SiNx thin film was deposited by plasma-enhanced chemical vapor deposition (PECVD) and used three kinds of N rations. In order to characterize the films, the atomic force microscopy (AFM) image was observed. The good LC aligning capabilities treated on the SiNx thin film with ion beam exposure for all N rations can be achieved. The low pretilt angles for a NLC treated on the SiNx thin film with ion beam irradiation were measure.

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Fabrication of micro carbon structures using laser-induced chemical vapor deposition and Raman spectroscopic analysis (레이저 국소증착에 의한 탄소 미세 구조물 제조 및 분광분석)

  • ;;J. Senthil Selvan
    • Laser Solutions
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    • v.5 no.2
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    • pp.17-22
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    • 2002
  • Characteristics of micro carbon structures fabricated with laser-induced chemical vapor deposition (LCVD) are investigated. An argon ion laser (λ=514.5nm) and ethylene gas were utilized as the energy source and precursor, respectively. The laser beam was focused onto a graphite substrate to produce carbon deposit through thermal decomposition of the precursor. Average growth rate of a carbon rod increased for increasing laser power and pressure. Micro carbon rods with good surface quality were obtained at near the threshold condition. Micro carbon rods with aspect ratio of about 100 and micro tubular structures were fabricated to demonstrate the possible application of this method to the fabrication of three-dimensional microstructures. Laser Raman spectroscopic analysis of the micro carbon structures revealed that the carbon rods are consisting of amorphous carbon.

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Anode Layer Linear Ion Source for Roll-to-Roll Process

  • Kim, Do-Geun;Lee, Seunghun;Kim, Jong-Kuk
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.128-128
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    • 2012
  • Korea institute of materials science (KIMS) has researched an anode layer linear ion source (ALIS) for various roll-to-roll treatment processes. The ALIS can be used to Ar ion beam (1~2 keV) treatment, and diamond-like carbon coating and so on. The treatment width of ALIS is 500 mm with a uniformity below 5 % (=(Max-min)/(Max+min)). We also demonstrate the status of development of ALIS in a roll-to-roll industry.

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