• Proceedings of the Materials Research Society of Korea Conference
• /
• 2010.05a
• /
• pp.5.1-5.1
• /
• 2010

One of the most important environmental problems is global warming. Global warming is caused by increase in the amounts of water vapor, methane, carbon dioxide and other gases being released into the atmosphere as a result of the burning of fossil fuels. It has thus become important to reduce fossil fuel use. Environmentally friendly preparation of functional materials has, therefore, attracted much interest for environmental problems. Furthermore, nature mimetic processes are recently been of great interest as environmentally friendly one. There have been many studies on fabrication of various functional nanocrystals. Among various nanocrystal fabrication techniques, flux growth is an environmentally friendly, very convenient process and can produce functional nanocrystals at temperatures below the melting points of the solutes. Furthermore, this technique is suitable for the synthesis of crystals having an enhedral habit. In flux growth, the constituents of the materials to be crystallized are dissolved in a suitable flux (solvent) and crystal growth occurs as the solution becomes critically supersaturated. The supersaturation is attained by cooling the solution, by evaporation of the solvent or by a transport process in which the solute is made to flow from a hotter to a cooler region. Many kinds of oxide nanocrystals have been grown in our laboratory. For example, zero- (e.g., particle), one- (e.g., whisker and tube) and two-dimensional (e.g., sheet) nanocrystals were successfully grown by flux method. Our flux-growth technique has some industrial and ecological merits because the nanocrystal fabrication temperatures are far below their melting points and because the used reagents are less harmless to human being and the environment.

• Journal of Korea Water Resources Association
• /
• v.56 no.11
• /
• pp.721-728
• /
• 2023

Agricultural drought is triggered by a depletion of moisture content in the soil, which hinders photosynthesis and thus increases carbon dioxide (CO₂) concentrations in the atmosphere. The aim of this study is to analyze the relationship between soil moisture (SM) and vegetation activity toward quantifying CO₂ concentration in the atmosphere. To this end, the MODerate resolution imaging spectroradiometer (MODIS), an optical multispectral sensor, was used to evaluate two regions in South Korea for validation. Vegetation activity was analyzed through MOD13A1 vegetation indices products, and MODIS gross primary productivity (GPP) product was used to calculate the CO₂ flux based on its relationship with respiration. In the case of SM, it was calculated through the method of applying apparent thermal inertia (ATI) in combination with land surface temperature and albedo. To validate the SM and CO₂ flux, flux tower data was used which are the observed measurement values for the extreme drought period of 2014 and 2015 in South Korea. These two variables were analyzed for temporal variation on flux tower data as daily time scale, and the relationship with vegetation index (VI) was synthesized and analyzed on a monthly scale. The highest correlation between SM and VI (correlation coefficient (r) = 0.82) was observed at a time lag of one month, and that between VI and CO₂ (r = 0.81) at half month. This regional study suggests a potential capability of MODIS-based SM, VI, and CO₂ flux, which can be applied to an assessment of the global view of the agricultural drought by using available satellite remote sensing products.

• Membrane and Water Treatment
• /
• v.6 no.1
• /
• pp.1-13
• /
• 2015

The modification of ultrafiltration membranes with carbon nanotube (CNT) buckypaper on fouling control was investigated. Two types of commercially available flat-sheet membranes were used: PS35 and PES900C/D (PES) (the PS35 membranes were hydrophilic with a molecular weight cutoff of 20 kDa, and the PES membranes were hydrophobic with a molecular weight cutoff of 20 kDa). The CNT buckypaper modified ultrafiltration membranes were prepared by filtering a CNT suspension through the flat-sheet membrane in a dead-end ultrafiltration unit. After modification, the pure water flux of PES was significantly increased, while the pure water flux of PS35 was decreased. The properties of the CNT modified membranes were also investigated. Considering the antifouling properties, pure water flux of the modified membrane, and the stability of CNT buckypaper layer on the membrane surface, ethanol solution with a concentration of 50 wt.%, multi-walled carbon nanotubes (MWCNTs) with a larger diameter (30-50 nm), and the CNT loading with $7.5g/m^2$ was selected. The CNT buckypaper on the surface of ultrafiltration membranes can trap the pollutants in sewage effluent and prevent them reaching the surface of virgin membranes. Water quality analysis showed that the effluent quality of the modified membrane was obviously improved. The removal efficiency of humic acid and protein-like matters by the modified membrane was significant. These results indicate the potential application of the CNT buckypaper layer modified membranes in the field of wastewater reclaim.

• Progress in Superconductivity and Cryogenics
• /
• v.21 no.2
• /
• pp.36-39
• /
• 2019

Effects of the spherically shaped Ge and the rod-like carbon-coated Ge on the superconducting properties of $MgB_2$ were investigated. Pure Ge and carbon-coated Ge nano-powders were synthesized under the different amount of $CH_4$ (0 to 5 kPa) by using DC thermal plasma method. When the $CH_4$ was added ~100 nm sized Ge with a spherical shape changed to rod-like morphology with a diameter of ~30-70 nm and a length of ~400-500 nm. Also it was confirmed that thin carbon layers of a few nanometers were formed along the rod length and the agglomerated carbons were found on the edges of rods. Pure spherical Ge and Ge/C rods were mixed and milled with Mg & B precursor to form the doped $MgB_2$ bulk samples by the solid-state reaction method. Almost no change of $T_c$ was noticed for the pure Ge-added $MgB_2$, whereas $T_c$ was found to decrease with the Ge/C-added $MgB_2$ samples. It was found that the pure spherical Ge showed to have a negative effect on the flux pinning of $MgB_2$. However, Ge/C rods can enhance the flux pinning property of $J_c$ due to the coated carbon on Ge rods.

• The Korean Journal of Ecology
• /
• v.26 no.5
• /
• pp.289-296
• /
• 2003

The ecological process-based approach provides a detailed assessment of belowground compartment as one of the major compartment of carbon balance. Carbon net balance (NEP: net ecosystem production) in forest ecosystems by ecological process-based approach is determined by the balance between net primary production (NPP) of vegetation and heterotrophic respiration (HR) of soil (NEP=NPP-HR). Respiration due to soil heterotrophs is the difference between total soil respiration (SR) and root respiration (RR) (HR=SR-RR, NEP=NPP-(SR-RR)). If NEP is positive, it is a sink of carbon. This study assessed the forest carbon balance by ecological process-based approach included belowground compartment intensively. The case study in the Takayama Station, cool-temperate deciduous broad-leaved forest was reported. From the result, NEP was estimated approximately 1.2 t C $ha^{-1} yr^{-1}$ in 1996. Therefore, the study area as a whole was estimated to act as a sink of carbon. According to flux tower result, the net uptake rate of carbon was 1.1 t C $ha^{-1} yr^{-1}$.

• Atmosphere
• /
• v.34 no.1
• /
• pp.69-81
• /
• 2024

In this paper, Annual flux variations in the Boseong Tall Tower (BTT) from 2016 to 2020 were analyzed using data from three levels (2.5 m, 60 m, and 300 m). BTT was installed in Boseong-gun, Jeollanam-do in February 2014 and continued to conduct energy exchange observations such as CO2, sensible heat, and latent heat using the eddy covariance method until March 2023. The BTT was located in a very flat and uniform paddy field, and flux observations were conducted at four levels: 2.5 m, 60 m, 140 m, and 300 m above ground. Surface energy balance was confirmed from observed data of net radiation flux, soil heat flux, sensible heat flux, and latent heat flux. Additionally, 2.5 m height surface fluxes, which are most influenced by agricultural land, were compared with data from Local Data Assimilation and Prediction System (LDAPS) of the Korea Meteorological Administration to evaluate the accuracy of LDAPS flux data. The correlation coefficient between LDAPS flux data and observed values was 0.95 or higher. Excluding summer latent heat flux data, there was a general tendency for LDAPS data to be higher than observed values. The footprint areas estimated below 60 m height mainly covered agricultural land, and flux observations at 2.5 m and 60 m heights showed typical agricultural characteristics. In contrast, the footprint estimated at 300 m height did not show agricultural characteristics, indicating that observations at this height encompassed a wide range, including mountains, sea, and roads. The analysis results of long-term flux observations can contribute to understanding the energy and carbon dioxide fluxes in agricultural fields. Furthermore, these results can be utilized as essential data for validating and improving numerical models related to such fluxes.

• Journal of Microbiology and Biotechnology
• /
• v.12 no.2
• /
• pp.258-267
• /
• 2002

A flux determination methodology has been built which enables to develop constrained stoichiometric relationships and metabolic balances. The analysis differs from those developed for anaerobic growth conditions in that cell mass formation is a significant sink for carbon. When combined with experimental measurements, a determined system of equations results yielded tricarboxylic acid (TCA) cycle and glycolytic fluxes. The methodology was implemented to determine the fluxes of E. coli B/r and K12, and it was found that as the growth rate in a glucose minimal medium increased, the cells became increasing glycolytic and the TCA fluxes either leveled off or declined. The pattern identified for the TCA fluxes corresponded to ${\alpha}$-ketoglutarate dehydrogenase's induction-repression pattern, thereby suggesting that the induction-repression of the enzyme could result in significant flux changes. When the minimum flux solution was contrasted to the glycolytic and TCA fluxes determined, two observations were made. First, the minimum flux could provide the cell's biosynthetic ATP requirements. Second, at a high growth rate in a glucose medium, the excess glycolytic flux exceeded that of the TCA cycle, which appeared to more closely match the biosynthetic needs.

• Membrane and Water Treatment
• /
• v.12 no.2
• /
• pp.65-73
• /
• 2021

Sponge ball cleaning can generate an abrasion effect, which leads to an attractive increasing in both permeate flux and membrane rejection. The aim of this study was to investigate the influence of the daily sponge ball cleaning (SBC) on the performance of different UF cross-flow membrane modules integrated with a bioreactor. Two 1"-membrane modules and one 1/2"-membrane module were tested. The parameters measured and controlled are temperature, pH, viscosity, particle size, dissolved organic carbon (DOC), total suspended solids (TSS), and permeate flux. The permeate flux could be improved by 60%, for some modules, after 11 days of daily sponge ball cleaning at a transmembrane pressure of 350 kPa and a flow velocity of 4 m/s. Rejection values of all tested modules were improved by 10%. The highest permeate flux of 195 L/㎡.h was achieved using a 1"-membrane module with the aid of its negatively charged membrane material and the daily sponge ball cleaning. In addition, the enhancement in the permeate flux caused by daily sponge ball cleaning improved the energy specific demand for all tested modules. The negatively charged membrane showed the lowest energy specific demand of 1.31 kWh/㎥ in combination with the highest flux, which is a very competitive result.

• Korean Journal of Agricultural and Forest Meteorology
• /
• v.5 no.2
• /
• pp.116-127
• /
• 2003

The Tak flux measurement (TFM) site, one of the sites of Korean Flux Network (KoFlux) which is an infrastructure of AsiaFlux, is constructed at a northwest of Thailand. The eddy covariance technique is used for measuring energy, water and carbon dioxide ($CO_2$) fluxes, and a real time monitoring and simulation system (RTMASS) developed for data acquisition and processing. The RTMASS is the core structure of the KoFlux-data information system (KoFlux-DIS) and consisted of a remote and a local system. Data acquisition and transmission, and data storage, processing and publishing are functions of those systems, respectively. As primary results about the characteristics of mean flow and turbulence analysis, TFM is a proper site to measure and analyze the various fluxes and those budgets on tropical deciduous forest.

• Journal of environmental and Sanitary engineering
• /
• v.12 no.2
• /
• pp.65-74
• /
• 1997

The purpose of this study was to investigate the removal effect and variation of contaminated water by various water treatment processes using sediment filter, activated carbon, photocatalysis, reverse osmosis, ultra violet sterilizer and ultra filtration. The removal effect of chloride and trace metal was low by activated carbon and ultra filter but high in reverse osmosis. The removal effect of bacteria and E. coli was low by activated carbon and membrane filter system using activated carbon but high in impregnated activated carbon. The removal effect of TCE was low in sand and ultra filter system as compared with activated carbon. Ultra filtration process was effective for purify agricultural water without E.coli. Reverse osmosis was effective to remove heavy metal and activated carbon was effective to remove halogenated organic chemical compound. The flux and the removal effect of COD in spiral wound ultrafilter were higher than the hollow fiber ultrafilter.