• Proceedings of the Korean Vacuum Society Conference
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• 2013.02a
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• pp.217-217
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• 2013

Carbon-fiber-supported NiO catalytic filters for oxidation of volatile organic compounds were prepared by electroless Ni-P plating and subsequent annealing processes. Surface structure and crystallinity of NiO film on carbon fiber could be modified by post-annealing at different temperatures (500 and $650^{\circ}C$. Catalytic thermal decompositions of toluene over these catalytic filters were investigated. $500^{\circ}C$ annealed sample showed a higher catalytic reactivity toward toluene decomposition than $650^{\circ}C$ annealed one under same conditions, despite of its lower surface area and toluene adsorption capacity. X-ray diffraction and X-ray photoelectron spectroscopy studies suggested that amorphous structures of NiO on $500^{\circ}C$ annealed catalyst caused the higher reactivity for oxidation of toluene than that of $650^{\circ}C$ annealed sample with a higher crystallinity.

• Bulletin of the Korean Chemical Society
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• v.33 no.4
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• pp.1199-1203
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• 2012

Catalytic filters consisting of Ni nanoparticle and carbon fiber with different oxidation states of Ni (either metallic or oxidic) were prepared using a chemical vapor deposition process and various post-annealing steps. CO oxidation reactivity of each sample was evaluated using a batch type quartz reactor with a gas mixture of CO (500 mtorr) and $O_2$ (3 torr) at $300^{\circ}C$. Metallic and oxidic Ni showed almost the same CO oxidation reactivity. Moreover, the CO oxidation reactivity of metallic sample remained unchanged in the subsequently performed second reaction experiment. We suggested that metallic Ni transformed into oxidic state at the initial stage of the exposure to the reactant gas mixture, and Ni-oxide was catalytically active species. In addition, we found that CO oxidation reactivity of Ni-oxide surface was enhanced by increase in the $H_2O$ impurity in the reactor.

• Composites Research
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• v.32 no.6
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• pp.342-348
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• 2019

Development of flame retarding polymer based materials has been studied actively due to the increase in use of polymers. The post treatment of manufactured fibers or the introduction of flame retardant into fibers is representative method for the way to improve the flame retardancy. Among the polymers, polyacrylonitrile (PAN), which is a precursor of carbon fiber, has been widely used for clothes. Due to low flame retardancy of PAN fiber (LOI value: 17~18%), the improvement of flame retardancy of PAN fiber is needed. In this review paper, we report preparation methods for the fabrication of post-treated (oxidization or chemical reaction) flame-retarding PAN fibers and composites composed of PAN and organic/inorganic materials (SiO₂, 2D materials or CNT).

• Structural Engineering and Mechanics
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• v.87 no.6
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• pp.585-599
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• 2023

Geopolymer concrete (GC) can be competently utilized as a practical replacement for cement to prevent a high carbon footprint and to give a direction toward sustainable concrete construction. Moreover, previous studies mostly focused on the axial response of glass fiber reinforced polymer (glass-FRP) concrete compressive elements without determining the effectiveness of repairing them after their partial damage. The goal of this study is to assess the structural effectiveness of partially damaged GC columns that have been restored using carbon fiber reinforced polymer (carbon-FRP). Bars made of glass-FRP and helix made of glass-FRP are used to reinforce these columns. For comparative study, six of the twelve circular specimens-each measuring 300 mm×1200 mm-are reinforced with steel bars, while the other four are axially strengthened using glass-FRP bars (referred to as GSG columns). The broken columns are repaired and strengthened using carbon-FRP sheets after the specimens have been subjected to concentric and eccentric compression until a 30% loss in axial strength is attained in the post-peak phase. The study investigates the effects of various variables on important response metrics like axial strength, axial deflection, load-deflection response, stiffness index, strength index, ductility index, and damage response. These variables include concentric and eccentric compression, helix pitch, steel bars, carbon-FRP wrapping, and glass-FRP bars. Both before and after the quick repair process, these metrics are evaluated. The results of the investigation show that the axial strengths of the reconstructed SSG and GSG columns are, respectively, 15.3% and 20.9% higher than those of their original counterparts. In addition, compared to their SSG counterparts, the repaired GSG samples exhibit an improvement in average ductility indices of 2.92% and a drop in average stiffness indices of 3.2%.

• Membrane Journal
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• v.23 no.5
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• pp.332-342
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• 2013

In the present study, carbon molecular sieve (CMS) hollow fiber membranes were prepared by carbonizing a methyl imide hollow fiber precursor, which was spun by non-solvent induced phase separation process. And effects of carbonization parameters such as pre-oxidation, pyrolysis, and post-oxidation on the gas permeation were systematically investigated. CMS membrane having the highest gas flux was obtained by carbonizing the precursor through a combined process of air pre-oxidation at $250^{\circ}C$ for 2h, nitrogen pyrolysis at $550^{\circ}C$ for 2h, and oxygen post-oxidation at $250^{\circ}C$ for 2h. The optimized membrane showed a considerable gas permeance : the $H_2$, He, $CO_2$ permeances were 69.72, 35.61, 31.01 GPU, respectively, and the $O_2$ and $N_2$ permeances were ignorable. Therefore, it was clear that the prepared CMS hollow fiber membrane was a promising membrane for recovering small gases such as hydrogen and hellium and carbon dioxide.

• Journal of the Korean Society for Advanced Composite Structures
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• v.4 no.2
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• pp.25-30
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• 2013

In this study a hybrid safety barrier system consisting of steel rail and carbon fiber reinforced polymer (CFRP) post is considered. W hile CFRP post is selected for impact energy reflection due to its high strength, steel rail is selected for impact energy absorption due to its high ductility. A numerical model considering the elastoplastic behavior of steel is formulated to simulate the dynamic responses of the hybrid system subject to an impact load. A hybrid roadside guard rail system of steel rail and CFRP post is proposed and analyzed with a case study. The numerical model for the hybrid roadside guard rail system is used to find optimized design of the proposed hybrid system.

• International Journal of Concrete Structures and Materials
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• v.6 no.3
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• pp.199-207
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• 2012

Concrete is an economical construction material and for that reason it is widely used in buildings and infrastructures. The use of deicing salts, expansion joint failure, and freeze-thaw cycles have led to concrete bridge girders experiencing corrosion of steel reinforcement and becoming unsafe for driving. The goal of this research is to assess the effectiveness of current and possible repair techniques for the end region of damaged prestressed concrete girders. To do this, three American Association of State Highway and Transportation prestressed concrete girders were tested to failure, repaired, and retested. Three different repair materials were tested including carbon fiber, glass fiber, and surface mounted rods. Each different repair material was also tested with and without injected epoxy. Comparisons were then made to determine if injecting epoxy had a positive effect on stiffness and strength recovery as well as which repair type regained the largest percentage of original strength.

• Proceedings of the Korea Concrete Institute Conference
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• 2000.04a
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• pp.639-644
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• 2000

Prestressing steels are susceptible to corrosion, which is considered the major reason in the deterioration of prestressed concrete structures. To solve this problem, many research have been made to utilize new type of tendons. FRP tendons have many advantages compared to steel tendons. However, FRP tendons have some disadvantages, such as no plastic behavior. This study focused on the flexural behavior of prestresssed concrete beams which is fabricated by post-tensioning method with CFRP (Carbon Fiber Reinforced Plastic) tendons. Th results drawn from the study, prestressed concrete beams with CFRP tendons have higher flexural cracking load, flexural yielding load, and flexural fracture load. While displacement at the fracture stage is lower compared to prestressed concrete beams with steel tendon. Excessive steel reinforcement lead lower ductility index. So, appropriate reinforcement guideline is needed. Further more, prestressed concrete beams with CFRP tendons can have sufficient ductility index when ruptured by crushing of concrete or used unbonded tendon. Therefore, the best design method for prestressed concrete beams with CFRP tendons is over-reinforcement, and use of unbonded tendon.

• Applied Chemistry for Engineering
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• v.10 no.6
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• pp.814-821
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• 1999

The specific capacitance characteristics of the electric double layer capacitors(ELDC) which were made of phenol based activated carbon fiber(ACF) electrodes. Also the effect of aqueous electrolytes on the cell performance has been investigated with respect to different specific surface areas of electrodes and different kinds of aqueous electrolytes. It has been shown that larger surface area and pore size, higher conductivity of electrodes, and higher ion mobility of electrolytes have better specific capacitances. It has been found that heat treatment at $1200^{\circ}C$ and $CO_2$ post-activation at $900^{\circ}C$ of the electrode are effective to improve the specific capacitance over 145F/g and 165F/g, respectively. The EDLC showed high efficiency and long cycle life over 30000 cycles.

• Journal of the Korean Society of Manufacturing Technology Engineers
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• v.6 no.4
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• pp.108-117
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• 1997

A continuum analysis has been performed for the application to the thermo-elasto-plastic behavior in a discontinuous metal matrix composite. an FEM (Finite Element Method) analysis was implemented to obtain the internal field quantities of composite as well as overall composite behavior and an experiment was demonstrated to compare with the numerical simulation . As the procedure, a reasonably optimized FE mesh generation, the appropriate imposition of boundary condition , and the relevant post processing such as elastoplastic thermomchanical analysis were taken into account. For the numerical illustration, an aligned axisymmetric single fiber model with temperature dependent material properties and precipitation hardening effect has been employed to assess field quantities. It was found that the residual stresses are induced substantially by the temperature drop during the thermal treatment and that the FEM results of the vertically and horizontally constrained model give a good agreement with experimental data.with non-woven carbon mat is about 24% higher than that of composite materials without non-woven carbon mat. Transverse tensile strength and torughness also increase by inserting non-woven carbon mat between layers.