• Title/Summary/Keyword: Carbon equivalent

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Determination of Preheating Temperature for Box Girder Welding (강교용 박스거더의 용접예열 온도 선정에 관한 연구)

  • Cho, Jae-Hun;Moon, Seung-Jae;Yoo, Hoseon
    • Plant Journal
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    • v.7 no.1
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    • pp.49-55
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    • 2011
  • This study analyzed causes and status of cracks to suggest preventives for welding cracks generated on fillet welding zone of atmosphere corrosion resisting steel box girder. Penetrant testing, a sort of non-destructive testing, was conducted for inspection of crack status on welding zone. As a result of test, welding cracks were found on the point of start, center and end to fillet welding zone of 32 mm-thickness. The result of carbon equivalent composition of materials was 0.452%. According to welding specification, to preheat prevent welding crack, preheat temperature of $100{\sim}200^{\circ}C$ should be kept before welding execution. It was failed to keep preheat temperature because it had been executed on winter season and the structure of box girder had wide heat transfer area. As a result of examination of time varying preheating temperature of 32mm-thickness material, it was understood that preheat temperature of above $230^{\circ}C$ on both 130mm-long sides of welded joint can prevent welding crack.

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Effects of Processing and Designing Variables on Formation of Shrinkage Cavities in GC150 Gray Cast Iron (GC150 회주철의 수축결함생성에 미치는 주조 및 설계공정인자들의 영향)

  • Yu, Sung-Kon;Shin, Sang-Woo
    • Korean Journal of Materials Research
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    • v.12 no.7
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    • pp.580-586
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    • 2002
  • The effect of processing and designing variables such as pouring temperature(1400 or $1500^{\circ}C$), inoculation and risering design(T and H type) on the formation of defects such as external depression, primary and secondary shrinkage cavities in GC150 gray cast iron was investigated. In T type risering design, external depression or primary shrinkage cavity due to liquid contraction was formed in all of the eight cases. Regardless of its modulus value, the riser could not function properly in T type risering design because directional solidification was not promoted toward the riser. On the other hand, the four cases of H type risering design in which thermal sleeves were set onto the risers produced defect-free castings. In both types of the risering designs, secondary shrinkage cavity caused by solidification contraction was not observed in the casting because of the expansion pressure due to graphite precipitation and the application of rigid pep-set mold. The degree of external depression or primary shrinkage cavity was reduced with lowered pouring temperature. The effect of inoculation was diminished because of the high carbon equivalent of GC 150 gray cast iron.

Electrochemical Performance of Activated Carbon Electrode Materials with Various Post Treatments for EDLC (활성탄의 후 처리에 의한 EDLC 전극재의 전기화학 성능 개선)

  • Lee, Eunji;Kwon, Soon Hyung;Choi, Pooreum;Jung, Ji Chul;Kim, Myung-Soo
    • Korean Journal of Materials Research
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    • v.24 no.6
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    • pp.285-292
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    • 2014
  • Commercial activated-carbon used as the electrode material of an electric double-layer capacitor (EDLC) was posttreated with various acids and alkalis to increase its capacitance. The carbon samples prepared were then heat-treated in order to control the amount of acidic functional groups formed by the acid treatments. Coin-type EDLC cells with two symmetric carbon electrodes were assembled using the prepared carbon materials and an organic electrolyte. The electrochemical performance of the EDLC was measured by galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy. Among the various activated carbons, the carbon electrodes (CSsb800) prepared by the treatments of coconutshell-based carbon activated with NaOH and $H_3BO_5$, and then heat treated at $800^{\circ}C$ under a flow of nitrogen gas, showed relatively good electrochemical performance. Although the specific-surface-area of the carbon-electrode material ($1,096m^2/g$) was less than that of pristine activated-carbon ($1,122m^2/g$), the meso-pore volume increased after the combined chemical and heat treatments. The specific capacitance of the EDLC increased from 59.6 to 74.8 F/g (26%) after those post treatments. The equivalent series resistance of EDLC using CSsb800 as electrode was much lower than that of EDLC using pristine activated carbon. Therefore, CSsb800 exhibited superior electrochemical performance at high scan rates due to its low internal resistance.

Rhodium-Catalyzed Reductive Decyanation of Nitriles Using Hydrosilane as a Reducing Agent: Scope, Mechanism and Synthetic Application

  • Tobisu, Mamoru;Nakamura, Ryo;Kita, Yusuke;Chatani, Naoto
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.582-587
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    • 2010
  • A rhodium-catalyzed reductive cleavage reaction of carbon-cyano bonds is developed using hydrosilane as a mild reducing agent. A wide range of nitriles, including aryl, benzyl, and $\beta$-hydrogen containing alkyl cyanides are applicable to this decyanation reaction. The method is also applicable to organic synthesis, in which benzyl cyanide is used as a benzyl anion equivalent and a cyano group functions as a removable ortho-directing group.

Prediction of the Carbon Dioxide Emission Change Resulting from the Changes in Bovine Meat Consumption Behavior in Korea (우리나라 쇠고기 소비 행태 변화에 의한 이산화탄소 배출 변화량 예측)

  • Yeo, Min Ju;Kim, Yong Pyo
    • Journal of Korean Society for Atmospheric Environment
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    • v.31 no.4
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    • pp.356-367
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    • 2015
  • A consumption based study on the carbon dioxide ($CO_2$) emission change due to the changes in the bovine meat consumption behavior in Korea was carried out. It was found that if the consumption of bovine meat be reduced by half, the reduction amount of $CO_2$ emissions be over 0.8 $MtCO_2e$ in all senarios in 2023. This amount is equivalent to over 50% of the greenhouse gases (GHGs) emission reduction target in agriculture and forestry, and fishery, a significant reduction. It was also found that the $CO_2$ emission reduction amount in consumption-based approach was the largest when the consumption of the imported bovine meat be reduced, though the difference was not that large.

Fabrication and Electrical Properties of Highly Organized Single-Walled Carbon Nanotube Networks for Electronic Device Applications

  • Kim, Young Lae
    • Journal of the Korean Ceramic Society
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    • v.54 no.1
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    • pp.66-69
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    • 2017
  • In this study, the fabrication and electrical properties of aligned single-walled carbon nanotube (SWCNT) networks using a template-based fluidic assembly process are presented. This complementary metal-oxide-semiconductor (CMOS)-friendly process allows the formation of highly aligned lateral nanotube networks on $SiO_2/Si$ substrates, which can be easily integrated onto existing Si-based structures. To measure outstanding electrical properties of organized SWCNT devices, interfacial contact resistance between organized SWCNT devices and Ti/Au electrodes needs to be improved since conventional lithographic cleaning procedures are insufficient for the complete removal of lithographic residues in SWCNT network devices. Using optimized purification steps and controlled developing time, the interfacial contact resistance between SWCNTs and contact electrodes of Ti/Au is reached below 2% of the overall resistance in two-probe SWCNT platform. This structure can withstand current densities ${\sim}10^7A{\cdot}cm^{-2}$, equivalent to copper at similar dimensions. Also failure current density improves with decreasing network width.

A Study on the Application of District Heating System using Sewage Source (하수열원을 이용한 지역난방 적용성 검토)

  • Kim, Sang-Hun;Kim, Dong-Jin;Choi, Dong-Kyoo
    • Proceedings of the SAREK Conference
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    • 2009.06a
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    • pp.928-933
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    • 2009
  • The purpose of this study is to examine the energy consumption, carbon dioxide emission & energy cost of district heating using sewage source. The annual TOE of heat pump using sewage source save 37.1 percent than city gas boiler. And annual carbon dioxide emission of heat pump cut down 41.3 percent than city gas boiler. If it charges the rate schedule for district heating to apartment resident, collected amount are 3,127,170 thousand won. As energy cost of heat pump & circulation pump are 1,378,072 thousand won. the profits are 1,749,098 thousand won. As payback period is 8.97years, applicability is low level. However, it has advantages in energy consumption, carbon dioxide emission & energy cost. Therefore, it needs to proceed through government assistance.

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A Study on Engine Performance and Exhaust Emission Characteristics of Gasoline Engine using Bio-ethanol Blended Fuel (가솔린 엔진(3.8L)에서 바이오에탄올 혼합연료의 성능 및 배출특성에 관한 연구)

  • Lee, Chi-Woo
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.4
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    • pp.131-137
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    • 2012
  • This article is about using the fuel mixed with 10% and 20% bio-ethanol to gasoline for the engine as a way to reduce carbon emission before commercializing future automobiles like fuel cell cars. The fuel mixed with 10% and 20% bio-ethanol showed output equivalent to that of the previous gasoline fuel. CO and $CO_2$ emission was somewhat reduced, but the difference was not significant. And the consumption of the fuel increased slightly. However, bio-ethanol is produced from bio mass growing with the absorption of carbon dioxide, so the total amount of carbon dioxide did not increase according to the result. In NOx, as the use of ethanol increases, the effect of reduction gets greater, and the emission of oxygen showed almost no change compared with gasoline.

Computational continuum modelling to analysis the dynamic and static stability of a cantilever nano-scale system

  • Jiangjiang Li
    • Advances in Computational Design
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    • v.8 no.1
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    • pp.77-96
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    • 2023
  • Calculating size-dependent mechanical properties of the nano-scale materials usually involves cumbersome numerical and theoretical works. In this paper, we aim to present a closed-form relation to calculate the length-dependent Young's modulus of carbon nanotubes (CNTs) based on nonlocal elasticity theory. In this regard, a single wall carbon nanotube (SWCNT) is considered as a rod structure and the governing nonlocal equations are developed under uniaxial tensile load. The equations are solved using analytical methods and strain distribution, total displacement and the size-dependent equivalent Young's modulus are obtained. Further, the results are compared with the molecular dynamics results from the literature. The outcome indicates that the calculated relations are coincident with the molecular dynamics results.

Carbon Reduction Services of Evergreen Broadleaved Landscape Trees for Ilex rotunda and Machilus thunbergii in Southern Korea

  • Jo, Hyun-Kil;Kim, Jin-Young;Park, Hye-Mi
    • Journal of Forest and Environmental Science
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    • v.35 no.4
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    • pp.240-247
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    • 2019
  • This study quantified carbon reduction services through direct harvesting of Ilex rotunda and Machilus thunbergii, which are the typical urban landscape tree species in southern Korea. A total of 20 open-grown tree specimens (10 specimens for each species) were selected reflecting various sizes of stem diameter at breast height of 1.2 m (DBH) at a regular interval. The study measured biomass for each part of the tree specimens including roots to compute total carbon storage per tree. Annual carbon uptake per tree was also calculated analyzing the DBH growth rate of stem disk specimens. Quantitative models were developed using DBH as an independent variable to easily estimate storage and annual uptake of carbon by tree growth for each species. All the models had a high goodness-of-fit with R2=0.95-0.99. The difference in carbon reduction services between DBH sizes increased with increasing DBH. The storage and annual uptake of carbon from a tree with DBH of 10 cm were 13.5 kg and 2.4 kg/yr for I. rotunda, and 19.1 kg and 3.6 kg/yr for M. thunbergii, respectively. The tree of this size stored the amount of carbon equivalent to that emitted from a gasoline use of approximately 24 L for I. rotunda and 34 L for M. thunbergii, respectively. The study provides actual measurement data to quantify carbon reduction services of urban open-grown landscape trees for the warm-temperate species that have been little known until now.