• Title/Summary/Keyword: Carbon dioxide (CO2)

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Numerical Analysis on Depressurization of High Pressure Carbon Dioxide Pipeline (고압 이산화탄소 파이프라인의 감압거동 특성에 관한 수치해석적 연구)

  • Huh, Cheol;Cho, Meang Ik;Kang, Seong Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.1
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    • pp.52-61
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    • 2016
  • To inject huge amount of $CO_2$ for CCS application, high pressure pipeline transport is accompanied. Rapid depressurization of $CO_2$ pipeline is required in case of transient processes such as accident and maintenance. In this study, numerical analysis on the depressurization of high pressure $CO_2$ pipeline was carried out. The prediction capability of the numerical model was evaluated by comparing the benchmark experiments. The numerical models well predicted the liquid-vapor two-phase depressurization. On the other hands, there were some limitations in predicting the temperature behavior during the supercritical, liquid phase and gaseous phase expansions.

Analysis of Spatial and Vertical Variability of Environmental Parameters in a Greenhouse and Comparison of Carbon Dioxide Concentration in Two Different Types of Greenhouses (온실 환경요인의 공간적 및 수직적 특성 분석과 온실 종류에 따른 이산화탄소 농도 비교)

  • Jeong, Young Ae;Jang, Dong Cheol;Kwon, Jin Kyung;Kim, Dae Hyun;Choi, Eun Young
    • Journal of Bio-Environment Control
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    • v.31 no.3
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    • pp.221-229
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    • 2022
  • This study was aimed to investigate spatial and vertical characteristics of greenhouse environments according to the location of the environmental sensors, and to investigate the correlations between temperature, light intensity, and carbon dioxide (CO2) concentration according to the type of greenhouse. Temperature, relative humidity (RH), CO2, and light sensors were installed in the four-different vertical positions of the whole canopy as well as ground and roof space at the five spatial locations of the Venlo greenhouse. Also, correlations between temperature, light intensity, and CO2 concentration in Venlo and semi-closed greenhouses were analyzed using the Curve Expert Professional program. The deviations among the spatial locations were larger in the CO2 concentration than other environmental factors in the Venlo greenhouse. The average CO2 concentration ranged from 465 to 761 µmol·mol-1 with the highest value (646 µmol·mol-1) at the Middle End (4ME) close to the main pipe (50Ø) of the liquefied CO2 gas supply and lowest (436 µmol·mol-1) at the Left Middle (5LM). The deviation among the vertical positions was greater in temperature and relative humidity than other environments. The time zone with the largest deviation in average temperature was 2 p.m. with the highest temperature (26.51℃) at the Upper Air (UA) and the lowest temperature (25.62℃) at the Lower Canopy (LC). The time zone with the largest deviation in average RH was 1 p.m. with the highest RH (76.90%) at the LC and the lowest RH (71.74%) at the UA. The highest average CO2 concentration at each hour was Roof Air (RF) and Ground (GD). The coefficient of correlations between temperature, light intensity, and CO2 concentration were 0.07 for semi-closed greenhouse and 0.66 for Venlo greenhouse. All the results indicate that while the CO2 concentration in the greenhouse needs to be analyzed in the spatial locations, temperature and humidity needs to be analyzed in the vertical positions of canopy. The target CO2 fertilization concentration for the semi-closed greenhouse with low ventilation rate should be different from that of general greenhouses.

Experimental Study on N2 Impurity Effect in the Pressure Drop During CO2 Mixture Transportation (CO2 파이프라인 수송에서의 N2 불순물이 압력강하에 미치는 영향에 대한 실험적 연구)

  • Cho, Meang-Ik;Huh, Cheol;Jung, Jung-Yeul;Baek, Jong-Hwa;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.15 no.2
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    • pp.67-75
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    • 2012
  • Carbon-dioxide capture and storage (CCS) process is consisted by capturing carbon-dioxide from large point source such as power plant and steel works, transporting and sequestrating captured $CO_2$ in a stable geological structure. During CCS process, it is inevitable of introducing impurities from combustion, capture and purification process into $CO_2$ stream. Impurities such as $SO_2$, $H_2O$, CO, $N_2$, Ar, $O_2$, $H_2$, can influence on process efficiency, capital expenditure, operation expense of CCS process. In this study, experimental apparatus is built to simulate the behavior of $CO_2$ transport under various impurity composition and process pressure condition. With this apparatus, $N_2$ impurity effect on $CO_2$ mixture transportation was experimentally evaluated. The result showed that as $N_2$ ratio increased pressure drop per mass flow and specific volume of $CO_2-N_2$ mixture also increased. In 120 and 100 bar condition the mixture was in single phase supercritical condition, and as $N_2$ ratio increased gradient of specific volume change and pressure drop per mass flow did not change largely compared to low pressure condition. In 70 bar condition the mixture phase changed from single phase liquid to single phase vapor through liquid-vapor two phase region, and it showed that the gradient of specific volume change and pressure drop per mass flow varied in each phase.

The Assessment and Recognition on Indoor Air Quality at Schools in Korea (전국 일부 학교 건축물 내의 실내 공기 및 인식도 조사)

  • Sohn Jong-Ryeul;Yoon Seung-Uk;Kim Jong-Hyuk;Lee Yong-Sik;Choi Han-Young;Kim Young-Sung;Son Bu-Soon;Yang Won-Ho;Kim Min-Hoi
    • Journal of environmental and Sanitary engineering
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    • v.20 no.3 s.57
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    • pp.1-9
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    • 2005
  • Recently, indoor air quality (IAQ) in workplace, residential environments and schools has been concerned of people, scientists and related the public, and has recognized the healthy effectsrelated to IAQ, specially in schools in Korea. Therefore, objectives of this study in this study were to measure and compare the perception of TAQ of selected air pollutants in Seoul from April to September 2004. Measurement place measured 2 schools of Seoul and local 9 schools (by Kyonggi Province, Chungchong-bukdo Chungchong-namdo, Chollado-bukdo, Cholla-namdo, Kyongsang-bukdo, Kyongsang-namdo, Kwangju, schoolin Pusan each 1 place). Temperature, humidity, illumination, carbon monoxide, carbon dioxide, TBC (total bacteria count), noise, PM10, TVOC(total volatile organic compounds), HCHO (formaldehyde) were measured simultaneously. Also, we Performed a questionnaire survey of 250 students and 50 teachers about their awareness for the importance of IAQ in their schools. Among this article, we handled noise, carbon monoxide, carbon dioxide, TBC, TVOC, HCHO, PM 10 in our conclusion. Major results were as follows ; Carbon monoxide (CO) was lower than indoor air standard of Korea. Carbon dioxide $(CO_2)$ appeared that 4 schools among our sample target school exceeded in normal standard. 4 schools were almost similar with normal standard. TBC appeared that 7 schools among 11 schools were higher than standard. Noise measured school's mean value passed exceeded standard. And school which passed over standard appeared to 7 schools among 11 schools. HCHO was exceeded 4 schools by standard that excess and certainly interrelation between school's establishment year and facilities of construction was detected. PM10 was exposed all schools by fitness in standard. TVOC appeared that 9 schools among 11 measurement school was exceeded health effect standard of Japan.

Comparison of Model-simulated Atmospheric Carbon Dioxide with GOSAT Retrievals

  • Shim, Chang-Sub;Nassar, Ray;Kim, Jhoon
    • Asian Journal of Atmospheric Environment
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    • v.5 no.4
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    • pp.263-277
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    • 2011
  • Global atmospheric $CO_2$ distributions were simulated with a chemical transport model (GEOS-Chem) and compared with space-borne observations of $CO_2$ column density by GOSAT from April 2009 to January 2010. The GEOS-Chem model simulated 3-D global atmospheric $CO_2$ at $2^{\circ}{\times}2.5^{\circ}$ horizontal resolution using global $CO_2$ surface sources/sinks as well as 3-D emissions from aviation and the atmospheric oxidation of other carbon species. The seasonal cycle and spatial distribution of GEOS-Chem $CO_2$ columns were generally comparable with GOSAT columns over each continent with a systematic positive bias of ~1.0%. Data from the World Data Center for Greenhouse Gases (WDCGG) from twelve ground stations spanning $90^{\circ}S-82^{\circ}N$ were also compared with the modeled data for the period of 2004-2009 inclusive. The ground-based data show high correlations with the GEOS-Chem simulation ($0.66{\leq}R^2{\leq}0.99$) but the model data have a negative bias of ~1.0%, which is primarily due to the model initial conditions. Together these two comparisons can be used to infer that GOSAT $CO_2$ retrievals underestimate $CO_2$ column concentration by ~2.0%, as demonstrated in recent validation work using other methods. We further estimated individual source/sink contributions to the global atmospheric $CO_2$ budget and trends through 7 tagged $CO_2$ tracers (fossil fuels, ocean exchanges, biomass burning, biofuel burning, net terrestrial exchange, shipping, aviation, and CO oxidation) over 2004-2009. The global $CO_2$ trend over this period (2.1 ppmv/year) has been mainly driven by fossil fuel combustion and cement production (3.2 ppmv/year), reinforcing the fact that rigorous $CO_2$ reductions from human activities are necessary in order to stabilize atmospheric $CO_2$ levels.

Development of Pilot Injection Plant for CO2 Underground Storage (이산화탄소 지중저장용 파일럿 주입플랜트 개발)

  • Yoon, Seok-Ho;Kim, Young;Lee, Jun-Ho;Lee, Kong-Hoon
    • Plant Journal
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    • v.9 no.2
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    • pp.42-45
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    • 2013
  • The worldwide issue of greenhouse gas reduction has recently drawn great attention to carbon capture and storage(CCS). In this study, we developed a 10,000 ton/year pilot injection plant for geological storage of carbon dioxide. Major components of the pilot plant include a pressure pump, a booster pump, and an inline heater to bring liquid carbon dioxide into its supercritical state. The test results show that the pilot plant readily achieves the injection pressure and temperature, showing satisfactory control performance. The overall power consumption is 2,000 ~ 2,500 W, more than 75% of which consumed by the pressure pump. This study will facilitate varied research on greenhouse gas reduction as the only domestically developed system for geological injection.

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Effect of Weathering of Bottom Ash on Mitigation of Green House Gases Emission from Upland Soil (밭토양에서 저회의 풍화가 온실가스 배출 저감에 미치는 영향)

  • Heo, Do Young;Hong, Chang Oh
    • Korean Journal of Environmental Agriculture
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    • v.38 no.4
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    • pp.245-253
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    • 2019
  • BACKGROUND: Weathering of bottom ash (BA) might induce change of its surface texture and pH and affect physical and chemical properties of soil associated with greenhouse gas emission, when it is applied to the arable soil. This study was conducted to determine effect of weathering of BA in mitigating emission of greenhouse gases from upland soil. METHODS AND RESULTS: In a field experiment, methane (CH4), carbon dioxide (CO2), and nitrous oxide (N2O) emitted from the soil was periodically monitored using closed chamber. Three month-weathered BA and non-weathered BA were applied to an upland soil at the rates of 0, 200 Mg ha-1. Maize (Zea mays L.) was grown from July 1st to Oct 8th in 2018. Both BAs did not affect cumulative CH4 emission. Cumulative CO2 emission were 23.1, 19.8, and 18.8 Mg/ha/100days and cumulative N2O emission were 35.8, 20.9, and 17.7 kg/ha/100days for the control, non-weathered BA, and weathered BA, respectively. Weathering of BA did not decrease emission of greenhouse gases significantly, compared to the weathered BA in this study. In addition, both BAs did not decrease biomass yields of maize. CONCLUSION: BA might be a good soil amendment to mitigate emissions of CO2 and N2O from arable soil without adverse effect on crop productivity.

Calibration of δ13C values of CO2 gas with different concentrations in the analysis with Laser Absorption Spectrometry (레이저흡광분석기(Laser Absorption Spectrometry)를 이용한 CO2가스의 탄소안정동위원소비 보정식 산출)

  • Jeong, Taeyang;Woo, Nam C.;Shin, Woo-Jin;Bong, Yeon-Sik;Choi, Seunghyun;Kim, Youn-Tae
    • Economic and Environmental Geology
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    • v.50 no.6
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    • pp.537-544
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    • 2017
  • Stable carbon isotope ratio of carbon dioxide (${\delta}^{13}C_{CO2}$) is used as an important indicator in the researches for global climate change and carbon capture and sequestration technology. The ${\delta}^{13}C$ value has been usually analyzed with Isotope Ratio Mass Spectrometer (IRMS). Recently, the use of Laser Absorption Spectrometry (LAS) is increasing because of the cost efficiency and field applicability. The purpose of this study was to suggest practical procedures to prepare laboratory reference gases for ${\delta}^{13}C_{CO2}$ analysis using LAS. $CO_2$ gas was adjusted to have the concentrations within the analytical range. Then, the concentration of $CO_2$ was assessed in a lab approved by the Korea Laboratory Accreditation Scheme and the ${\delta}^{13}C_{CO2}$ value was measured by IRMS. When the instrument ran over 12 hours, the ${\delta}^{13}C$ values were drifted up to ${\pm}10$‰ if the concentration of $CO_2$ was shifted up to 1.0% of relative standard deviation. Therefore, periodical investigation of analytical suitability and correction should be conducted. Because ${\delta}^{13}C_{CO2}$ showed the dependency on $CO_2$ concentration, we suggested the equation for calibrating the concentration effect. After calibration, ${\delta}^{13}C_{CO2}$ was well matched with the result of IRMS within ${\pm}0.52$‰.

Optimal CO2 level for cultivation of Pleurotus eryngii (큰느타리버섯 재배의 최적 CO2 조건)

  • Ryu, Jae-San;Kim, Min-Keun;Cho, Sook-Hyun;Yun, Young-Chul;Seo, Won-Myung;Lee, Hyun-Sook
    • Journal of Mushroom
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    • v.3 no.3
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    • pp.95-99
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    • 2005
  • Carbon dioxide($CO_2$) promotes development of primordia and depress differentiation of sporophore and gill containing basidia, have an effect on quality. This experiments were conducted to elucidate optimal level of $CO_2$ for king oyster mushroom(Pleurotus eryngii). King oyster mushroom was cultivated under 1,600, 2,400, and 3,200ppm $CO_2$. Harvest ratio in normal plot were 98.6, 99.3, and 93.8% at 1,600, 2,400, 3,200ppm, respectively, so 2,400ppm is optimal. The yield per bottle was 102.5g at 2,400ppm, better than 99.7g at 1,600ppm, The $CO_2$ concentration of 2,400ppm was also the best condition for quality, 6.1 at 2,400ppm was 115% of 1,600ppm's. In thinning treatment plot, quality at 2,400ppm was 9.5 better than 1,600ppm whose quality was 9.4. The yields per bottle were 90.7, 98.2, 77.3g at 1,600, 2,400, 3,200ppm respectively. These results show that 2,400ppm was optimal $CO_2$ concentration for quantity of King Oyster mushroom as well as quality.

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The Mechanical properties of Mud Flat mortar mixed with Blast furnace slag (고로슬래그가 혼입된 갯벌 모르타르의 역학적 특성)

  • Kang, Yun Young;Kim, Hui Doo;Kang, Dae kyu;Yang, Seong Hwan
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.32-33
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    • 2015
  • Depending on the industrialization, construction market has grown buildings are based on concrete will continue to increase. But the problems of environmental pollution come to the fore with the indiscriminate use of concrete and rapid development. In addition, carbon dioxide(CO2) in the process of producing cement being emitted a large amount of has been caused a serious problem of environmental pollution. This trend is being actively conducted research to reduce the use of cement. In this study, eco-friendly materials, such as flats, Blast-furnace slag by mix and cement review the mechanical characteristics of the mudflats eco-friendly cement mortar to reduce the usability of the review were seen as a green building material.

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