• Korean Chemical Engineering Research
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• v.43 no.3
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• pp.432-437
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• 2005

An electric swing adsorption (ESA) process for recovering highly pure $CO_2$ from the mixed gases was tested. In this study, activated carbon fibers were used as an adsorbent. The activated carbon fibers showed fast adsorption rate and the high adsorption capacity for $CO_2$ adsorption under the condition of the ambient pressure. Activated carbon fiber with higher specific surface area was suitable to repeated adsorption-desorption cycle process, showing consistent breakthrough curve. Especially, the regeneration method by vacuum combined with ESA improved the performance of desorption process by an additional 17％ regeneration efficiency compared to a vacuum only method, and showed the high regeneration efficiency at comparatively low 7-8 Wh energy.

• Journal of Korean Society for Atmospheric Environment
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• v.20 no.5
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• pp.655-662
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• 2004

An adsorption process to recover the pure $CH_4\;and\;CO_2$ from its mixture was examined. In this study, activated carbon fibers were used as a selective adsorbent. The activated carbon fibers has 78~94% micropore volume and 10.5~20.3${\AA}$ narrow pore size, and showed high adsorption rate and the good selectivity for $CO_2$ under the ambient pressure. The ACF with high surface area showed short mass transfer zone and long breakthrough time and, its adsorption capacity depended on the microporosity. Compared with single component adsorption, the amount adsorbed $CO_2$ on ACF increased by the roll-up of $CH_4$ in mixed gases. The adsorption selectivity increased as now rate and $CO_2$ concentration of mixed gases increased, showing 5.2 selectivity for 75% $CO_2$ concentration.

• Preventive Nutrition and Food Science
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• v.2 no.4
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• pp.316-320
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• 1997

Phenolic acids are regarded as harmful materials in food and environment science but recently, as useful materials, and thus adsorption is recommended as an effective separation technique to recover or remove phenolic acids from diluted solution. If the adsorbed phenolic compounds were useful materials, the materials should be recovered through desorption. Desorption using supercritical carbon dioxide(SC-$CO_2$) was tried to separate food-borne phenolic acids from charcoal in single solute system. In the comparisons of desorption amounts, gallic acid had the lowest lolubiligy to SC-$CO_2$. Gallic acid has more hydroxy functional groups than the other phenolic acids, which was immiscible with nonpolar SC-$CO_2$. Ferulic acid was yielded more than p-coumaric acid, because ferulic acid had much bigger molecular weight, which was affected more by van der Waas force. It was found that the most affecting factor on desorption amounts was the solubility of phenolic acids to SC-$CO_2$. The second affecting factor was van der Waals force. Response surface methodology(RSM) was conducted to read the trend of desorption. Increasing density of SC-$CO_2$ raised solubility of phenolic acids.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.4
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• pp.307-319
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• 2009

Carbon dioxide capture and storage (CCS) technology has been regarded as one of the most possible and practical option to reduce the emission of carbon dioxide ($CO_2$) and consequently to mitigate the climate change. Korean government also have started a 10-year R&D project on $CO_2$ storage in sea-bed geological structure including gas field and deep saline aquifer since 2005. Various relevant researches are carried out to cover the initial survey of suitable geological structure storage site, monitoring of the stored $CO_2$ behavior, basic design of $CO_2$ transport and storage process and the risk assessment and management related to $CO_2$ leakage from engineered and geological processes. Leakage of $CO_2$ to the marine environment can change the chemistry of seawater including the pH and carbonate composition and also influence adversely on the diverse living organisms in ecosystems. Recently, IMO (International Maritime Organization) have developed the risk assessment and management framework for the $CO_2$ sequestration in sub-seabed geological structures (CS-SSGS) and considered the sequestration as a waste management option to mitigate greenhouse gas emissions. This framework for CS-SSGS aims to provide generic guidance to the Contracting Parties to the London Convention and Protocol, in order to characterize the risks to the marine environment from CS-SSGS on a site-specific basis and also to collect the necessary information to develop a management strategy to address uncertainties and any residual risks. The environmental risk assessment (ERA) plan for $CO_2$ storage work should include site selection and characterization, exposure assessment with probable leak scenario, risk assessment from direct and in-direct impact to the living organisms and risk management strategy. Domestic trial of the $CO_2$ capture and sequestration in to the marine geologic formation also should be accomplished through risk management with specified ERA approaches based on the IMO framework. The risk assessment procedure for $CO_2$ marine storage should contain the following components; 1) prediction of leakage probabilities with the reliable leakage scenarios from both engineered and geological part, 2) understanding on physio-chemical fate of $CO_2$ in marine environment especially for the candidate sites, 3) exposure assessment methods for various receptors in marine environments, 4) database production on the toxic effect of $CO_2$ to the ecologically and economically important species, and finally 5) development of surveillance procedures on the environmental changes with adequate monitoring techniques.

• Proceedings of the SAREK Conference
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• 2009.06a
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• pp.928-933
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• 2009

The purpose of this study is to examine the energy consumption, carbon dioxide emission & energy cost of district heating using sewage source. The annual TOE of heat pump using sewage source save 37.1 percent than city gas boiler. And annual carbon dioxide emission of heat pump cut down 41.3 percent than city gas boiler. If it charges the rate schedule for district heating to apartment resident, collected amount are 3,127,170 thousand won. As energy cost of heat pump & circulation pump are 1,378,072 thousand won. the profits are 1,749,098 thousand won. As payback period is 8.97years, applicability is low level. However, it has advantages in energy consumption, carbon dioxide emission & energy cost. Therefore, it needs to proceed through government assistance.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2016.10a
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• pp.87-88
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• 2016

In the current construction market usage cement and aggregate is increasing continuously. This is progressing serious environmental pollution due to the carbon dioxide generated during cement production. Further, by using a large amount of aggregate, they tend to have even reduced natural resources. As a result, the reduction of carbon dioxide through the United Nations Framework Convention on Climate Change, the energy saving has been positioned as a global trend. Therefore, in this study, instead of fine aggregate fix the cement, by the use to increase the proportion of the tidal flats, to try to reduce the amount of cement and fine aggregate. Accordingly, according to increasing the proportion of the mud flat be analyzed for properties the compressive strength, tensile strength, flow, chloride test, workability of the mortar.

• Journal of Welding and Joining
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• v.11 no.1
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• pp.73-79
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• 1993

The phenomenon of metal transfer has been investigated for different transfer modes using a digital high speed motion analyzer and an arc shadow-graphing system based on a laser source and related optical system. It was observed that the pinch instability phenomenon did not occur for the globular transfer mode, since the liquid globule was then spherical rateher than a cylindrical liquid bar. On increasing the ratio of carbon dioxide to argon, the transition current from globular to spray transfer generally increased, but it is interesting that the transition was observed to occur at the lowest current in a 5% CO$_{2}$-95% argon gas mixture. For pure carbon dioxide and helium shielding gases, the drop frequency increased slowly with increasing current. At high currents or an argon based shielding gas, the length of liquid bar decreased as the carbon dioxide content increased. The acceleration of a droplet within the arc was determined using the gas drag force theory and was found to be greater than the experimental results.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.1
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• pp.72-78
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• 2014

The study has been designed to develop water vapor supply for semiconductor industry, industrial gas manufacturing, impurities analysis, and fuel cell. Water concentration in air reached $1019{\mu}mol/mol$ at dew temp ($-20^{\circ}C$) and water concentration in CO2 reached $127{\mu}mol/mol$ at dew temp ($-40^{\circ}C$. Carbon dioxide needs more wet gas than air because interaction potential of carbon dioxide shows more strong attraction than air.

• Proceedings of the Membrane Society of Korea Conference
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• 1995.09a
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• pp.73-85
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• 1995

The asymmetric hollow fiber membranes were prepared by the wet spining of polyetherimide dope solution and the effect of hollow fiber structures on the permeation characteristics of carbon dioxide and nitrogen gases through these membrane were investigated. As the concentration of the $\gamma$-butyrolactone (GBL) in dope solution, acting as a swelling agent was increased, the structure of hollow fiber was changed from the finger to sponge type. The permeabilities of gases (CO$_{2}$, N$_{2}$) through these membrane were measured over the wide range of pressure under different temperature. The effect of water vapor on the permeabilities of gases was also investigated. The measured permeabilities showed the different characteristics depending on the structure of membranes. It was found that the flow through the pores were dominant over the polymers matrix. Blocking effect by water vapor in the pores of skin layer greatly improved the ideal separation factor of carbon dioxide/nitrogen.

• Food Science and Biotechnology
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• v.14 no.1
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• pp.82-88
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• 2005

Ethnic Korean onggi earthenwares were fabricated using different clay formulations and glazing treatments. Their permeability properties against oxygen, carbon dioxide, and moisture were measured at $20^{\circ}C$ and examined from the aspect of food preservation. Onggi walls consisted of micropores that offered higher gas and moisture permeation rates when compared with other food packaging materials. Earthenware walls were unique in having $CO_2/O_2$ permeability ratios of 0.60-1.00. Gas and moisture permeabilities were lower, with wall structure having lower porosity and surface glazing. Results revealed onggi jar packages of grape fruits could attain wide range of $O_2$ and $CO_2$ concentrations. Onggi containers present good opportunity to obtain optimum packaging conditions for respiring or ripening products, depending on commodity type.