• Title/Summary/Keyword: Carbon dioxide (CO2)

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Changes in the Quality of Astringent Persimmon during Removal of Astringency by Carbon Dioxide ($CO_2$탈삽과정 중 떫은감의 품질변화)

  • 변효숙;박석희;노영균;성전중
    • Food Science and Preservation
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    • v.6 no.4
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    • pp.392-397
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    • 1999
  • The quality changes during the removal of astringecy by CO$_2$gas at 2$^{\circ}C$ and 20$^{\circ}C$ of three varieties of persimmons named 'Tonewase', 'Chungdobanshi' and 'Sagokshi' were examined. Astringency index and tannin content showed rapid decrease at 20$^{\circ}C$ and gradual decrease at 2$^{\circ}C$. All was edible 2days from the removal of astringency at 20$^{\circ}C$, while 'Tonewase' and 'Sagokshi' were edible on 6days and 'Chungdobanshi' on 10days after treatment at 2$^{\circ}C$. Soluble solid contents was decreased a little(1∼3%) during the removal of astringency. Hardness was decreased slowly but, kept over 1.0kg/$\phi$5mm till edible period in all varieties at 2$^{\circ}C$ and 20$^{\circ}C$. The hardness of 'Chungdobanshi' was kept well after the removal of astringency at 2$^{\circ}C$. No noticeable color changes in all varieties during treatment. Injury fruits were noticeable in only 'Tonewase' after the removal of astringency treatment at 2$^{\circ}C$.

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Development of Carbon Dioxide Emission Factor from Resource Recovery Facility (폐기물자원회수시설의 이산화탄소 배출계수 개발)

  • Kim, Seungjin;Im, Gikyo;Yi, Chi-Yeong;Lee, Seehyung;Sa, Jae-Hwan;Jeon, Eui-Chan
    • Journal of Climate Change Research
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    • v.4 no.1
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    • pp.51-61
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    • 2013
  • To address the problems associated with climate change and energy shortage, Korea has been making efforts to turn waste materials into usable energy. Due to the ongoing efforts to convert waste materials into energy, waste incineration is expanding to utilize the heat generated, and the subsequent greenhouse gas emissions from these waste material incineration are expected to increase. In this study, a municipal waste incineration plant that generates heat and electricity through heat recovery was selected as a subject facility. Methods for estimating the greenhouse gas emissions in the municipal waste incineration plant that was selected as a subject plant were sought, and the greenhouse gas emissions and emission factor were estimated. The $CO_2$ concentrations in discharge gas from the subject facility were on average 6.99%, and the result from calculating this into greenhouse gas emissions showed that the total amount of emissions was $254.60ton\;CO_2/day$. The net emissions, excluding the amount of greenhouse gas emitted from biomass incineration, was shown to be $110.59ton\;CO_2/day$. In addition, after estimating the emissions by separating the heat and electricity generated in the incineration facility, greenhouse gas emission factors were calculated using the greenhouse gas emissions produced per each unit of output. The estimated emission factor for heat was found to be $0.047ton\;CO_2/GJ$ and the emission factor for electricity was found to be $0.652ton\;CO_2/MWh$. The estimated emission factor was shown to be about 17% lower than the $0.783ton\;CO_2/MWh$ emission factor for thermal power plants that use fossil fuels. Waste material types and fossil carbon contents were evaluated as being the factors that have major effects on the greenhouse gas emissions and emission factor.

Comparison of catalytic activity through gas-solid reaction models in CO2 gasification of lignite with alkali metal salts and iron sulfate (알칼리금속염과 철황산염을 촉매로 한 갈탄의 CO2 가스화반응에서 기체-고체 반응모델을 적용한 촉매활성의 비교)

  • Bungay, Vergel C.;Song, Byungho
    • Journal of Energy Engineering
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    • v.23 no.1
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    • pp.58-66
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    • 2014
  • Catalytic gasification of a low rank coal- Inner Mongolian lignite has been carried out with carbon dioxide. The gasification reactions were performed in a thermogravimetric analyzer at temperatures of $600^{\circ}C$ to $900^{\circ}C$. The kinetic parameters were evaluated using three different gas-solids reaction models and the prediction ability of each model were compared. Among the models evaluated, the modified volumetric model was found to correlate best both the non-catalytic and catalytic gasification reactions. The theoretical models, homogeneous and shrinking-core models, were found to satisfactorily correlate gasification reactions for the non-catalytic and $FeSO_4$-catalyzed reactions. In case of alkali metal catalysts, the catalytic activity was mostly pronounced at a low temperature of $600^{\circ}C$ and observed to decrease by 50% as the temperature was increased to $700^{\circ}C$, and it remained nearly constant at temperature over $800^{\circ}C$. The order of catalytic activity was found to be: $K_2CO_3$ > $Na_2CO_3$ > $K_2SO_4$ > $FeSO_4$.

Effects of Light Quality and Intensity on the Carbon Dioxide Exchange Rate, Growth, and Morphogenesis of Grafted Pepper Transplants during Healing and Acclimatization

  • Jang, Yoonah;Mun, Boheum;Seo, Taecheol;Lee, Jungu;Oh, Sangseok;Chun, Changhoo
    • Horticultural Science & Technology
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    • v.31 no.1
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    • pp.14-23
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    • 2013
  • This study evaluated the influence of light quality and intensity during healing and acclimatization on the $CO_2$ exchange rate, growth, and morphogenesis of grafted pepper (Capsicum annuum L.) transplants, using a system for the continuous measurement of the $CO_2$ exchange rate. C. annuum L. 'Nokkwang' and 'Tantan' were used as scions and rootstocks, respectively. Before grafting, the transplants were grown for four weeks in a growth chamber with artificial light, where the temperature was set at $25/18^{\circ}C$ (light/dark period) and the light period was 14 hours $d^{-1}$. The grafted pepper transplants were then healed and acclimatized under different light quality conditions using fluorescent lamps (control) and red, blue, and red + blue light-emitting diodes (LEDs). All the transplants were irradiated for 12 hours per day, for six days, at a photosynthetic photon flux (PPF) of 50, 100, or 180 ${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$. The higher PPF levels increased the $CO_2$ exchange rate during the healing and acclimatization. A smaller increase in the $CO_2$ exchange rates was observed in the transplants under red LEDs. At a PPF of 180 ${\mu}mol{\cdot}m^{-2}{\cdot}s^{-1}$, the $CO_2$ exchange rate of the transplants irradiated with red LEDs was lowest and it was 37% lower than those irradiated with fluorescent lamps. The $CO_2$ exchange rates of transplants irradiated with blue LEDs was the highest and 20% higher than those irradiated under fluorescent lamps. The graft take was not affected by the light quality. The grafted pepper transplants irradiated with red LEDs had a lower SPAD value, leaf dry weight, and dry matter content. The transplants irradiated with blue LEDs had longer shoot length and heavier stem fresh weight than those irradiated with the other treatments. Leaves irradiated with the red LED had the smallest leaf area and showed leaf epinasty. In addition, the palisade and spongy cells of the pepper leaves were dysplastic and exhibited hyperplasia. Grafted pepper transplants treated with red + blue LEDs showed similar growth and morphology to those transplants irradiated with fluorescent lamps. These results suggest that high-quality grafted pepper transplants can be obtained by healing and acclimatization under a combination of blue and red lights at a high PPF level.

Ce addition into Ni/$MgAl_2O_4$ catalysts in combined $H_2O$ and $CO_2$ reforming of $CH_4$ for improvement of coke resistance (수증기-이산화탄소 복합개질 반응에서 Ce가 증진된 Ni-Ce/$MgAl_2O_4$ 촉매의 탄소 침적저항성 향상에 관한 연구)

  • Lee, Sung-Hun;Koo, Kee-Young;Jung, Un-Ho;Roh, Hyun-Seog;Lee, Deuk-Ki;Yoon, Wang-Lai
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.226.1-226.1
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    • 2010
  • 본연구에서는 GTL(gas to liquids)공정의 합성가스 생산을 위해 수증기-이산화탄소 복합개질반응(Combined Steam and Carbon dioxide Reforming of Methane, CSCRM)을 수행하였다. CSCRM은 수증기와 이산화탄소의 공급비 조절을 통해 $H_2$/CO비를 2로 맞추기 용이한 장점을 지니고 있어 다른 단일 개질 반응과 달리 합성가스 생산 시 $H_2$/CO 비율을 조절하기 위한 부가적인 공정이 필요하지 않아 경제적인 공정이다. 일반적으로 사용되는 Ni개질촉매는 가격대비 우수한 성능을 보이지만 S/C비가 낮은 CSCRM의 경우 촉매표면의 탄소침적에 의한 비활성화가 야기되는 문제점이 있다. 따라서 본 연구에서는 산소저장능력과 산소전달능력이 우수한 $CeO_2$를 조촉매로 첨가하여 표면에 형성된 코크 제거가 용이하도록 하였다. Ni-Ce/$MgAl_2O_4$촉매는 동시함침법(co-impregnation)으로 제조하였으며, Ni의 함량을 10wt%로 고정한 상태에서 Ce의 함량을 조절하여 Ce/Ni 최적비를 찾고자 하였다. XRD, TPR, BET, $H_2$-Chemisorption과 같은 촉매의 특성분석을 통해 촉매의 비표면적, 환원특성과 Ni입자의 분산도 등을 확인하였다. Ce를 첨가함에 따라 Ce2.5wt%까지는 비표면적이 증가하다가 이후 점차 줄어드는 경향성을 보였다. 또한, $H_2$-Chemisorption 결과 역시 비표면적과 유사한 경향성을 보였는데, Ce5.0wt%까지 Ni 분산도가 증가 하다가 다시 감소하는 것을 확인할 수 있었다. 반응실험은 $H_2O:CO_2:CH_4:N_2$ = 0.8:0.4:1:1의 공급조건에서 수행하였으며, 질소와 수소 환원분위기로 $700^{\circ}C$에서 1시간 환원 후 $650^{\circ}C$에서 $550^{\circ}C$범위로 온도를 떨어뜨려가면서 반응을 수행하였다. Ce를 첨가함에 따라 $CH_4$ 전환율이 증가를 하다가 Ce2.5wt% 이후 감소하는 것을 확인할 수 있었다. 이러한 높은 촉매 활성은 Ce 첨가로 인해 환원특성이 좋아지고 Ni분산도가 증가하여 담체와 강한 상호작용(SMSI)을 형성함으로 탄소침적 저항성 강화에 기인한 것이다.

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A Study on the Fluid H in Automotive Air Conditioning System as an Alternative Refrigerant (자동차 공조용 대체 냉매로서의 H냉매에 대한 연구)

  • Choi, Jeong-Won;Nam, Soo-Byeong;Bang, Scott
    • Transactions of the Korean Society of Automotive Engineers
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    • v.15 no.6
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    • pp.170-176
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    • 2007
  • It is time to prepare the phaseout of R134a, the current refrigerant, in automotive air conditioning system because the EC deadline has been coming with new platform vehicles in 2011 and all vehicles by 2017. Until now a high-pressure carbon dioxide($CO_2$) system is the leading replacement of R134a in European auto-makers but there is no firm agreement in the world automotive market. Recently three new fluids have been announced as the possibilities from Honeywell, DuPont and INEOS Fluor. The new alternative refrigerant should meet the requirements like non flammable, non toxic, no ozone depletion effect and low GWP(under 150 to meet EC regulation). The objectives of this paper are to review the fluid H from Honeywell, the more possible alternative refrigerant in 3 new fluids, compare the properties of R134a & fluid H and see the possibility as a replacement of R134a. In this experimental paper we ran and reviewed the cooling performance data in the bench system, the vehicle and the field test. We found the possibility of fluid H system to meet the R134a system performance with some hardware modifications but agreed that it is still needed to study about the long term safety, environmental effects, material compatibilities and so on.

A simulation study on synthesis gas process optimization for FT(Fischer-Tropsh) synthesis (FT(Fischer-Tropsh) 합성유 제조를 위한 합성가스 공정 최적화 연구)

  • Kim, Yong-Heon;Lee, Won-Su;Lee, Heoung-Yeoun;Koo, Kee-Young;Song, In-Kyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.888-888
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    • 2009
  • A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

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Study on Feasibility Biomethane as a Transport Fuel in Korea (국내 바이오메탄의 차량 연료화 타당성 연구)

  • Kim, Jae-Kon;Lee, Donmin;Park, Chunkyu;Lim, Eui Soon;Jung, Choong-Sub;Kim, Ki-Dong;Oh, Youngsam
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.174.1-174.1
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    • 2011
  • Biogas production and utilisation is an emerging alternative energy technology. Biogas is produced from the biological breakdown of organic matter through anaerobic digestion. Biogas can be utilized for various energy services such as heating, electricity generation and vehicle fuel. Especially, to be utilized as vehicle fuel, raw biogas needs to be upgraded, that is, mainly the removal of carbon dioxide to increase the methane content, up to more than 95% in some cases, similar to the composition of fossil-based natural gas. Biogas fuelled vehicles can reduce $CO_2$ emission by between 75% and 200% compared with fossil fuels. Biomethane development is largely driven by national initiative and predominately by concerns for national air pollution and waste management. Recently, biogas projects for vehicle fuels by some companies are ongoing and Korea government also announced investment to develop biogas as a transport fuel. Therefore, the aim of this study is to examine the feasibility of biomethane as a transport fuel in Korea. In this study, we investigated quality characteristics, quality standard and upgrading technology to use vehicle fuel of transport sector in Korea.

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Quality Changes in Dried Persimmons Processed by Different Pretreatment and Drying Method (전처리 및 건조방법에 따른 곶감의 품질변화)

  • Moon, Kwang-Deok;Kim, Jong-Kuk;Sohn, Tae-Hwa
    • Journal of the Korean Society of Food Culture
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    • v.8 no.4
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    • pp.331-335
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    • 1993
  • This study was performed to improved the quality of dried persimmon. For this, the investigation of quality factor and processing experiments were performed. The moisture contents of dried persimmons were 30 to 36% and it was the most important component of the quality. Tannin contents were 0 to 20% and non-treated persimmon had higher tannin contents than treatment of carbon dioxide and alcohol. Total sugar contents were 55 to 60% and it was composed in glucose and fructose. Processing of dried persimmon by artificial-drying seemed to be useful when it needed to shorten the drying time or it continued rainy day during sun-drying. From the result of quality evaluation, sliced dried persimmon was better than whole dried persimmon in quality, so the sliced dried persimmon was expected that it has a little marketability.

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Exploration of Alternative Raw materials to Forest Biomass for Pellets (숲가꾸기 산물을 이용한 펠릿의 원료 적성 연구)

  • Kim, Seong-Ho;Kim, Cheol-Hwan;An, Byeong-Il;Lee, Ji-Yeong;Momin, Md.;Yeasmin, Shabina;Park, Hyeon-Jin;Gwak, Hye-Jeong;Kim, Gyeong-Cheol
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2011.04a
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    • pp.171-178
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    • 2011
  • During the last decades, global warming from the increased amount of greenhouse gases, mainly carbon dioxide has become a major political and scientific issue. Burning fossil fuels (natural gas, coal and oil) releases $CO_2$, which is also a major cause of global warming. Among the clean environment, wood pellets are considered as promising renewable fossil fuels because of clean burning characteristics, reduction of particulate and NOx emission from combustion. In Korea, more than 50% pellets have to be imported every year because of shortage of feedstocks. On the other hand, about 80% of wood pulps are greatly dependent upon overseas products due to limited forest resources. Under this situation, this study explored how efficiently we have to use forest biomass instead of total dependence on wood as raw materials for pellets.

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