• Korean Journal of Materials Research
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• v.28 no.1
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• pp.6-11
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• 2018

There are various manufacturing processes for pure $SiO_2$ that is used as abrasives, chemicals, filters, and glasses, and in metallurgy and optical industries. In the optical fiber industry, to produce $SiO_2$ preform, $SiCl_4$ is utilized as a raw material. However, the combustion reaction of $SiCl_4$ has caused critical environmental issues, such as ozone deficiency by chlorine compounds, the greenhouse effect by carbon dioxide and corrosive gas such as hydrochloric acid. Thus, finding an alternative source that does not have those environmental issues is important for the future. Octamethylcyclotetrasiloxane (OMCTS or D4) as a chlorine free source is recently promising candidate for the $SiO_2$ preform formation. In this study, we first conducted a vaporizer design to vaporize the OMCTS. The vaporizer for the OMCTS vaporization was produced on the basis of the results of the vaporizer design. The size of the primary particle of the $SiO_2$ formed by OMCTS was less than 100 nm. X-ray diffraction patterns of the $SiO_2$ indicated an amorphous phase. Fourier-transform infrared spectroscopy analysis revealed the Si-O-Si bond without the -OH group.

• Tunnel and Underground Space
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• v.29 no.3
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• pp.157-171
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• 2019

The fracturing by liquid carbon dioxide ($LCO_2$) as a fracking fluid has been an alternative to mitigate the environmental issues often caused by the conventional hydraulic fracking since it facilitates the fluid permeation owing to its low viscosity. This study presents how $LCO_2$ injection influences the breakdown pressure, acoustic emission, and fracture morphology. Three fracturing fluids such as $LCO_2$, water, and oil are injected with different pressurization rate to the synthetic and porous mortar specimens. Also, the shale which has been a major target formation in conventional fracking practices is also tested to examine the failure characteristics. The results show that $LCO_2$ injection induces more tortuous and undulated fractures, and particularly the larger fractures are developed in cases of shale specimen. On the other hand, the relationship between the fracturing fluids and the breakdown pressure shows opposite tendency in the tests of mortar and shale specimens.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.26 no.2
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• pp.294-305
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• 2022

Recently, drones have been widely used to solve environmental problems such as environmental protection and natural disaster monitoring. This study focuses on the problem of the search altitude of drones when using drones to search for air pollution in order to maintain the urban air environment. In particular, when exploring air pollution in cities using drones, various experiments are conducted to determine the appropriate search altitude for each air pollution source and each communication module. Through the experiment, the maximum measurable altitude for the most common air pollutants, such as CO (carbon monoxide), NO₂ (nitrogen dioxide), O₃ (ozone), and P10, P2.5 (fine dust), was identified, and the effective search altitude for each air pollution source was determined. As a result of the experiment, three types of drone search altitudes including legally measurable altitudes were suggested. The communication module measurable altitude was 60m to 120m depending on the communication module, and the effective measurable altitude was analyzed from 10m to 100m.

• Journal of Energy Engineering
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• v.18 no.3
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• pp.191-202
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• 2009

South Korea, ranks 10th largest emitter of carbon dioxide in the world, will probably be under the obligation to reduce GHG emission from 2013. It is very important to reduce the electrical energy consumption since 30% of GHG emission in South Korea is made during electricity generation. In this study, based on "the 1st national energy master plan", the GHG emission reduction potential and the feasibility of the scenario in the electricity generation have been analyzed using LEAP(Long-range Energy Alternative Planning system). The scenario of the mater plan contains the 41% expansion of nuclear power plant facilities and the 11% diffusion of renewable energy until 2030. In result, total $CO_2$ emission reduction rate is 28.8% in 2030. Also $CO_2$ emission of unit electricity generation of bituminous coal power plant is $0.85kgCO_2/kWh$ and its LNG power plant is $0.51kgCO_2/kWh$ in BAU scenario. Therefore when existing facilities is exchanged for nuclear or renewable energy power plant, substitute of bituminous power plant is more effective than LNG power.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2011.06a
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• pp.277-277
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• 2011

본 논문은 $CO_2$ 히트펌프용 모세관의 기초 설계자료를 제공하기 위해서 모세관 길이 예측에 대해서 이론 및 실험적으로 조사하였다. 본 연구에서 고려된 작동변수로는 증발온도, 가스냉각기 냉각압력, 냉매유량, 모세관의 관경 등이다. 몇몇연구자들의 자료를 바탕으로 $CO_2$ 모세관 길이를 예측할 수 있는 수학적 모델식을 작성하였다. 그리고 단열 모세관 팽창장치내 $CO_2$의 증발온도, 냉매유량, 냉각압력 등에 대해서 실험한 결과, Fig. 1에 나타낸 것처럼, 모세관 길이가 증가할수록 증발온도는 감소하는 것을 알 수 있다. 그리고 증발온도에 대한 실험값과 예측값의 비교 결과, 실험값이 예측값보다 약간 높게 나타났다. $CO_2$냉매가 모세관내를 통과할 때 플래쉬 가스(flash gas)의 발생으로 인해 액상의 양보다 기상의 양이 많아지고 액상의 압력강하보다 기상의 압력강하가 휠씬 더 크기 때문이다. 또한 증발온도에 대한 실험값과 예측값은 6.5~9.9% 이내에서 좋은 일치를 보였다. Fig. 2에 나타낸 것처럼, 모세관 길이가 증가할수록 냉매유량은 감소하는 것을 알 수 있다. 이는 전술한 바와 같이 모세관 길이가 증가할수록 냉매 압력강하가 더욱더 증가하기 때문이다. 그리고 냉매유량에 대한 실험값과 예측값의 비교 결과, 실험값이 예측값보다 약간 높게 나타났다. 이는 전술한 증발온도와 동일한 이유로 실제 $CO_2$냉매가 모세관내를 통과할 때 플래쉬 가스의 발생량이 많아지기 때문이다. 또한 냉매유량에 대한 실험값과 예측값은 0.64~10.9% 이내에서 좋은 일치를 보였다. Fig. 3에 나타낸 것처럼, 모세관 길이가 증가할수록 냉각압력은 증가하는 것을 알 수 있다. 이는 증발온도가 일정한 경우 모세관 길이가 증가할수록 냉매유량이 감소하여 압축기 토출측 온도(압력)가 상승하기 때문이다. 그리고 냉각압력에 대한 실험값과 예측값의 비교 결과, 실험값이 예측값보다 약간 낮게 나타났으며 실험값과 예측값은 1.04~3.7% 이내에서 좋은 일치를 보였다. 따라서 본 연구에서는 수송기계용 $CO_2$ 열펌프 단열 모세관에 대한 기초설계 자료로서, 냉각압력, 증발온도, 모세관 직경, 냉매유량 등의 조건으로부터 모세관 길이를 계산해낼 수 있는 예측 상관식을 제안하였다.

• Journal of the Korean Wood Science and Technology
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• v.44 no.5
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• pp.639-654
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• 2016

This study building materials by relates to human hazard assessment in accordance with the combustion gas SEM, the flame-retardant foam FTIR and cone calorimeter to configure the Forest products of MDF and preservative treated Lauan two kinds of Retardant styrofoam, Styrofoam, Urethane foam and gypsum board four kinds of plastics material by the combustion gas were each analyzed. MDF was burned to the structure of the wood and the glue evenly mixed combustion area preservative treated Lauan, kept constant even in the form of high heat to penetrate deep into the wood flame retardant agents. Retardant styrofoam is due to feed my Dropped dissolved inorganic flame retardant without the fire-stick and confirmed that the weak form of gypsum board, but keep the column. In MDF ammonia ($NH_3$), lethal concentration (750 ppm) compared to 795 ppm, preservative treated Lauan is carbon dioxide ($CO_2$) that was greater than 2.5 times the lethal concentration (100,000 ppm) to 256,965 ppm, the lethal concentration (500 ppm) of hydrogen chloride (HCl). The Urethane greater than 697 ppm, 434 ppm also greatly exceeding the nitrogen dioxide ($NO_2$) lethal concentration (250 ppm) in Retardant styrofoam and 398 ppm was released. It is confirmed that the human body is extremely harmful gas emitted from most of the materials to be utilized as basic data for evaluating the hazard-specific human future building material.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.5 no.2
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• pp.27-34
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• 1985

Pig manure mixed with straw, sawdust, packing paper and chaff was composted in a batch type enclosed composter without regular mixing for 1 week. The maximum decomposition was obtained in the temperature of $70^{\circ}C$ with an initial moisture content of 50 to 65 %, initial pH of 7 to 8, 0.7 to $2.0l/min{\cdot}kg$ per volatile matter of air supplied and C/N ratio of 60 to 70. The maximum carbon dioxide content in the produced gas was 65 to 85 mg/hr-vm at 45 to $53^{\circ}C$.

• Asian Journal of Atmospheric Environment
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• v.2 no.2
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• pp.102-108
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• 2008

In China, energy and environmental problems are becoming serious owing to rapid economic development. Coal is the most problematic energy source because it causes indoor and outdoor air pollution, acid rain, and global warming. One type of clean coal technology that has been developed is the coal-biomass briquette (or bio-briquette, BB) technique. BBs, which are produced from pulverized coal, biomass (typically, agricultural waste), and a sulfur fixation agent (slaked lime, $Ca(OH)_2$) under high pressure without any binder, have a high sulfur-fixation effect. In addition, BB combustion ash, that is, the waste material, can be used as a neutralization agent for acidic soil because of its high alkalinity, which originates from the added slaked lime. In this study, we evaluated the suitability of alternative biomass sources, namely, aquatic plants, as a BB constituent from the perspective of their use as a source of energy. We selected three types of aquatic plants for use in BB preparation and compared the fuel, handling, and environmental characteristics of the new BBs with those of conventional BBs. Our results showed that air-dried aquatic plants had a higher calorific value, which was in proportion to their carbon content, than agricultural waste biomass; the compressive strength of the new BBs, which depends on the lignin content of the biomass, was high enough to bear long-range intracontinental transport in China; and the new BBs had the same emission control capacity as the conventional BBs.

• Proceedings of the Korean Society of Crop Science Conference
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• 2022.10a
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• pp.145-145
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• 2022

South Korea greenhouse gas emissions have increased year by year, resulting in a total emission of 727.6 million tons of CO₂ eq in 2018, a 2.5% increase compared to 2017. Among them, the agricultural sector emitted 21.2 million tons of CO₂ eq., accounting for 2.9% of the total. Among the greenhouse gases emitted from the agricultural sector, a particularly problematic is methane gas emitted from rice paddies. Methane is one of the important greenhouse gases with a global warming potential (GWP) that is about 21 times higher than that of carbon dioxide due to its high infrared absorption capacity despite its relatively short remaining atmospheric period. Since the pattern of methane generation varies depending on the rice variety and ecological type, research related to this is necessary for accurate emission calculation and development of reduction technology. Accordingly, a study was conducted to find out the changes in greenhouse gas emission according to rice varieties and ecology types. As for the rice eco-type cultivar, early maturing cultivar (Haedamssal) and medium-late rice cultivar (Saeilmi) were used. Haedamssal was transplanted on May 25 and June 25, and Saeilmi was transplanted on June 10 and June 25. The amount of methane generated according to the growing day showed a tendency to increase as the planting period was earlier. The difference between varieties was that Haedamssal showed higher methane production than Saeilmi. The total CH₄ flux in the saeilmi was 18.7 kg·h^-1(Jun 10 transplanting), 12.4 kg·h^-1(Jun 25 transplanting) during rice cultivation. Lower methane emission was observed in Saeilmi than in Haedam rice. In addition, the earlier the planting period, the higher the methane emission. This study is the result of the first year of research, and it is planned to investigate the amount of greenhouse gas emission between double cropping and single cropping using wheat cultivation after harvest for each ecological type.

• Journal of the Korean Applied Science and Technology
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• v.29 no.3
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• pp.478-485
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• 2012

Polymers are widely used as membrane material for performing the separation of various gaseous mixtures due to their attractive permselective properties and high processability. The separation characteristics of $CH_4$ and $CO_2$ mixed gas using polyamide composite membrane has been studied in this work. The sample gas was prepared by mixing pure methane and carbon dioxide. Permeation tests were carried out at different operation conditions. Feed flow rates were varied between 800~1000 $cm^3/min$, and the stage cuts were varied between 50~60%. The gas inlet pressure and the temperature were varied as 6 bar and $30{\sim}70^{\circ}C$, respectively. The effects of the above mentioned parameters were investigated to estimate the permeability of $CH_4$ and $CO_2$, and the selectivity of $CO_2$ was also calculated for all conditions. The Arrhenius plots were also performed to obtaine the activation energies of $CH_4$ and $CO_2$ permeabilities.