• Journal of the Korean Electrochemical Society
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• v.12 no.2
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• pp.155-161
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• 2009

Lithium secondary batteries have been widely used in the portable electric devices as power source. Recently it is expected that the realm of its applications expands to the markets such as energy storage medium of hybrid electric vehicle(HEV), electric vehicle(EV). Cathode active material is crucial in terms of performance, durability, capacity of lithium secondary batteries. It is urgent to develope the technology for mass production of cathode material to cope with the markets' demands in the near future. In this study, a calcination furnace running in real production line is modelled in 3D, and the thermal flow and gas flow after chemical reaction in the furnace is analyzed through numerical computations. Based on the results, it is shown that large volume of $CO_2$ gas is generated from chemical reaction. High concentration of $CO_2$ gas and it's stagnation is clearly found from the reactant containers in which the reaction occur to the bottom area of the furnace. It is also studied that 15% or more $CO_2$ mol fraction could affect to proper formation of $LiCoO_2$ through TGA-DSC analysis. The solutions to evacuate carbon dioxide from the furnace are suggested through the change of furnace design and operating condition as well.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.9 no.3
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• pp.574-579
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• 2008

The evaporation heat transfer coefficient of $CO_2$ (R-744) in a horizontal tube was investigated experimentally. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator (test section). The test section consists of a smooth, horizontal stainless steel tube of inner diameter of 4.57mm. The experiments were conducted at mass flux of 400 to $900kg/m^2s$, saturation temperature of 5 to $20^{\circ}C$, and heat flux of 10 to $40kW/m^2$. The test results showed the heat transfer of $CO_2$ has a greater effect on nucleate boiling more than convective boiling. Mass flux of $CO_2$ does not affect nucleate boiling too much. In comparison with test results and existing correlations, All of the existing correlations for the heat transfer coefficient underestimated the experimental data. However Jung et al.'s correlation showed a good agreement with the experimental data. Therefore, it is necessary to develope accurate predictions determining the evaporation heat transfer coefficient of $CO_2$ in horizontal tubes.

• Korean Journal of Agricultural and Forest Meteorology
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• v.12 no.1
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• pp.11-22
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• 2010

According to IPCC 4th Assessment Report, concentration of carbon dioxide has been increasing by 30% since Industrial Revolution. Most of IPCC $CO_2$ emission scenarios estimate that the concentration will reach up to double of its present level within 100-year if the current tendency continues. The global warming has resulted in the agro-climate change over the Korean Peninsula as well. Accordingly, it is necessary to understand the future agro-climate induced by the increase of greenhouse gases in terms of the agro-climatic indices in the Korean peninsula. In this study, the future climate is simulated by an atmosphere/ocean/land surface/sea ice coupled general circulation climate model, Pusan National University Coupled General Circulation Model(hereafter, PNU CGCM), and by a regional weather prediction model, Weather Research and Forecasting Model(hereafter, WRF) for the purpose of a dynamical downscaling. The changes of the vegetable period and the crop growth period, defined as the total number of days of a year exceeding daily mean temperature of 5 and 10, respectively, have been analyzed. Our results estimate that the beginning date of vegetable and crop growth periods get earlier by 3.7 and 17 days, respectively, in spring under the $CO_2$-doubled climate. In most of the Korean peninsula, the predicted frost days in spring decrease by 10 days. Climatic production index (CPI), which closely represent the productivity of rice, tends to increase in the double $CO_2$ climate. Thus, it is suggested that the future $CO_2$ doubled climate might be favorable for crops due to the decrease of frost days in spring, and increased temperature and insolation during the heading date as we expect from the increased CPI.

• Korean Journal of Agricultural and Forest Meteorology
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• v.16 no.3
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• pp.199-212
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• 2014

The physiological responses of three common temperate species, Pinus densiflora, Fraxinus rhynchophylla, Sorbus alnifolia to elevated $CO_2$ was investigated using open top chambers with different $CO_2$ concentrations. Morphological (stomatal size, density and area) and physiological characteristics (maximum rates of photosynthesis, carboxylation and electron transport) were compared among trees grown under ambient, ambient ${\times}1.4$ (~550 ppm) and ambient ${\times}1.8$ (~700 ppm) $CO_2$ concentrations for last four years. Morphological responses were different among species. F. rhynchophyllar increased their stomatal size and S. alnifolia had higher stomatal density under elevated $CO_2$ than ambient. Stomatal area decreased in P. densiflora, whereas it increased in S. alnifolia. However, the maximum photosynthesis rate increased in all species up to 43.5% by S. alnifolia under elevated $CO_2$ and the enhancement increased with time. Even with four years of exposure to elevated $CO_2$, there was no sign of acclimation in the maximum carboxylation rate and the maximum electron transport rates in all species. Especially, S. alnifolia even showed the temporary increase of photosynthetic capacities in spring, when leaf nitrogen concentration was high with new leaf development. There was no significant differences in diameter growth rate in any species due to high variation in their tree sizes, however accumulated diameter and biomass for four years showed significantly increment in all species under elevated $CO_2$. For example, S. alnifolia showed 59% increase in diameter at the ambient ${\times}1.8$ (~700 ppm) compared to ambient.

• Korean Journal of Remote Sensing
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• v.31 no.6
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• pp.549-560
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• 2015

With the global scale impact of atmospheric $CO_2$ in global warming and climate system, it is necessary to monitor the $CO_2$ concentration continuously on a global scale, where satellite remote sensing has played a significant role recently. In this study, global monthly $CO_2$ concentrations obtained by satellite remote sensing were compared with ground-based measurements at Anmyeon-do and Gosan Korean Global Atmosphere Watch Center. Atmospheric $CO_2$ concentration has increased from 371.87 ppm in January 1999 to 405.50 ppm in December 2013 at Anmyeon-do station (KMA, 2013). Comparison of the continuous measurements by flask air sampling at Anmyeon-do shows the same trend and seasonal variations with those of global monthly mean dataset. Nevertheless, the trends of $CO_2$ over Northeast Asia showed the higher than those of global and the trends also changes with different slope. $CO_2$ products derived from Greenhouse Gases Observing Satellite (GOSAT) and Atmospheric Infrared Sounder (AIRS) were compared with ground-based measurement at Anmyeon-do. The monthly mean values of GOSAT and AIRS data are systemically lower than those obtained at Anmyeon-do, however, the seasonal cycle of satellite products present the similar trend with values of global and Anmyeon-do. The accuracy of $CO_2$ products from GOSAT and AIRS were evaluated statistically for two years from January 2011 to December 2012. GOSAT showed good correlation with the correlation coefficient, RMSD and bias of 0.947, 5.610 and -5.280 to ground-based measurements respectively, while AIRS showed reasonable comparison with 0.737, 8.574 and -7.316 at Anmyeon-do station, respectively.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.6 no.1
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• pp.31-36
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• 2000

180g of fermented soy paste and 150g of red pepper paste were packaged in glass jars of 232 mL with different conditions of active packaging and then stored at $13^{\circ}C$ for about 170 and 128 days, respectively. During the storage, package atmosphere, surface color, pH, acidity and microbial flora were monitored to see the effect of packaging conditions. Test packaging conditions include package equipped with $Ca(OH)_2\;as\;CO_2$ absorber, package with pinhole and closed control one. Closed control packages of soypaste and red pepper paste showed the increased $CO_2$ partial pressure, the decreased $O_2$ partial pressure and the constant $N_2$ partial pressure to produce high pressure buildup with storage. The paste packages with $Ca(OH)_2$ maintained relatively low $CO_2$ partial pressure and thus the package pressure close to normal atmospheric pressure for initial storage period of 70 days. The packages with air pinhole channel had the partial pressures of $O_2\;and\;N_2$ decreased with storage time, while $CO_2$ partial pressure first increased to a maximum and then slowly decreased thereafter Without any pressure increase the packages with pinhole gave the lowest quality changes possibly due to the effect of package atmosphere, but it had problem of mold contamination and growth for soy paste after 120 days. There were no difference in microbial flora between the packages after about 70 day storage.

• Journal of Korean Society of Environmental Engineers
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• v.33 no.4
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• pp.267-274
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• 2011

The environmental impacts of 95% remediation of a total petroleum hydrocarbon-contaminated soil were evaluated using life cycle assessment (LCA). LCA of two remediation systems, soil vapor extraction (SVE) and biopile, were conducted by using imput materials and energy listed in a remedial system standardization report. Life cycle impact assessment (LCIA) results showed that the environmental impacts of SVE were all higher than those of biopile. Prominent four environmental impacts, human toxicity via soil, aquatic ecotoxicity, human toxicity via surface water and human toxicity via air, were apparently found from the LCIA results of the both remedial systems. Human toxicity via soil was the prominent impact of SVE, while aquatic ecotoxicity was the prominent impact of biopile. This study also showed that the operation stage and the activated carbon replacement stage contributed 60% and 36% of the environmental impacts of SVE system, respectively. The major input affecting the environmental impact of SVE was electricity. The operation stage of biopile resulted in the highest contribution to the entire environmental impact. The key input affecting the environmental impact of biopile was also electricity. This study suggested that electricity reduction strategies would be tried in the contaminated-soil remediation sites for archieving less environmental impacts. Remediation of contaminated soil normally takes long time and thus requires a great deal of material and energy. More extensive life cycle researches on remedial systems are required to meet recent national challenges toward carbon dioxide reduction and green growth. Furthermore, systematic information on electricity use of remedial systems should be collected for the reliable assessment of environmental impacts and carbon dioxide emissions during soil remediation.

• Korean Journal of Food Science and Technology
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• v.21 no.6
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• pp.869-875
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• 1989

For the evaluation of storage stability of kiwifruit, the conditions of CA storage were based on the following gas compositions; 2% oxygen and 2, 4, 6% carbon dioxide, respectively. The results obtained from the experiment were as follows; The flesh softening was considerably reduced at the storage atmospheres of 4% $CO_2$ plus 2% $O_2$, and fruit firmness of 3.0kg was marked in this CA condition after storage for 180 days. The concentration of $CO_2$ affected clearly on the respiration rate and organic acid compositions of kiwifruit during CA storage. The respiration rate at the storage condition of 6% $CO_2$ was lower than those at 2 and 4% $CO_2$. Quinic and succinic acid contents were obviously increased in the kiwifruit stored at all the CA conditions studied. In comparision of the developed amounts of off-flavor substances, ethanol and acetaldehyde, depended upon the concentration of $CO_2$ in the CA conditions, the larger amount were produced in the storage condition of higher concentration of $CO_3$. From the results mentioned above, it could be concluded that the optimum atmosphere combination for CA storage of kiwifruit was 4% $CO_2$ plus 2% $O_2$.

• Archives of Plastic Surgery
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• v.42 no.1
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• pp.52-58
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• 2015

Background The erbium:yttrium scandium gallium garnet (Er:YSGG) laser differs from other laser techniques by having a faster and higher cure rate. Since the Er:YSGG laser causes an appropriate proportion of ablation and coagulation, it has advantages over the conventional carbon dioxide ($CO_2$) laser and the erbium-doped yttrium aluminum garnet (Er:YAG) laser, including heating tendencies and explosive vaporization. This research was conducted to explore the effects and safety of the Er:YSGG laser. Methods Twenty patients participated in the pilot study of a resurfacing system using a 2,790-nm Er:YSGG laser. All patients received facial treatment by the 2,790-nm Er:YSGG laser system (Cutera) twice with a 4-week interval. Wrinkle reduction, reduction in pigment inhomogeneity, and improvement in tone and texture were measured. Results Study subjects included 15 women and five men. Re-epithelization occurred in all subjects 3 to 4 days after treatment, and wrinkle reduction, reduction in pigment inhomogeneity, and improvement in tone and texture within 6 months of treatment. Conclusions The 2,790-nm YSGG laser technique had fewer complications and was effective in the improvement of scars, pores, wrinkles, and skin tone and color with one or two treatments. We expect this method to be effective for people with acne scars, pore scars, deep wrinkles, and uneven skin texture and color.

• Advances in concrete construction
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• v.12 no.6
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• pp.499-505
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• 2021

Geopolymer binders fascinate the attention of researchers as a replacement to cement binder in conventional concrete. One-ton production of cement releases one ton of carbon-dioxide in the atmosphere. In the replacement of cement by geopolymer material, there are two advantages: one is the reduction of CO₂ in the atmosphere, second is the utilization of Fly ash and Ground granulated blast furnace slag (GGBFS) are by-products from coal and steel industries. This paper focuses on the mechanical properties of steel fiber reinforced geopolymer concrete. The framework considered in this research work is geopolymer source (Fly ash, GGBFS and crimped steel fibre) and alkaline activator which consists of NaOH and Na₂SiO₃ of molarity 8M. Here the Na₂SiO₃ / NaOH ratio was taken as 2.5. The variables considered in this experimental work include Binder content (360,420 and 450 kg/m³), the proportion of Fly ash and GGBS (70-30, 60-40 and 50-50) for three different grades of Geopolymer concrete (GPC) GPC 20, GPC 40 and GPC 60. The percentage of crimped steel fibres was varied as 0.1%, 0.2%, 0.3%, 0.4% and 0.5%. Generally, the inclusion of steel fibres increases the flexural and split tensile strength of Geopolymer concrete. The optimum dosage of steel fibres was found to be 0.4% (by volume fraction).