• 제목/요약/키워드: Carbon dioxide (CO2)

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초임계 추출 Lard를 이용한 Maillard 반응생성물 유래 육류향미제의 향기패턴 및 관능적 특성 (Flavor Pattern and Sensory Properties of Meat Flavor Based on Maillard Reaction Products with Supercritical Fluid Extracted Lard Fractions)

  • 문지혜;최인욱;최희돈;김윤숙
    • 한국축산식품학회지
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    • 제32권5호
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    • pp.644-651
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    • 2012
  • MRP유래 육류 향미제의 향미 증강을 위하여 리보오스와 저 Glu 소맥글루텐 산 가수분해물을 기본 기질로 한 향미 조성물에 온도와 압력 조건별로 추출한 lard SC-$CO_2$ 분획을 첨가하여 향미제를 제조하였다. 이렇게 제조된 육류 향미제의 SMart nose를 이용한 향기패턴과 관능적 특성을 비교분석하여 향 특성이 우수한 육류 향미제를 개발하고자 하였다. Lard SC-$CO_2$분획 추출시 $40^{\circ}C$ 이상의 온도에서는 추출 수율이 증가하지 않았으며, 추출온도를 $40^{\circ}C$로 고정하여 30-60 MPa의 압력에서 추출하였을 때 40 MPa 이상에서 추출효율이 크게 증가하였다. 추출된 lard SC-$CO_2$ 분획들의 SMart nose를 이용한 향기패턴 분석을 실시한 결과, $40^{\circ}C$에서 원료 lard와 30 MPa에서 추출한 lard SC-$CO_2$ 분획의 향기패턴은 40 MPa 이상의 압력에서 추출한 분획들과 구별되었으나 40 MPa 이상의 압력에서 추출한 분획들은 서로 유사한 향기패턴을 나타내었다. 그러나 40 MPa 이상 압력 추출 lard SC-$CO_2$ 분획은 다른 flavor전구체와 반응시켰을 때 다른 전구체들과의 상호반응을 통해 뚜렷한 향기패턴의 차이를 나타내었다. 관능검사 결과 MRP based 육류향미제의 전체적 기호도는 $40^{\circ}C$, 50 MPa에서 추출한 lard SC-$CO_2$ 분획을 첨가한 MRP based meat flavor과 $40^{\circ}C$, 60 MPa에서 추출한 lard SC-$CO_2$ 분획첨가 MRP based meat flavor가 가장 높게 나타났다. 따라서 육류 향 증강 MRP based meat flavor의 전구체로 lard를 초임계 추출하기 위한 최적 조건은 $40^{\circ}C$에서 압력을 50 및 60 MPa로 이 조건에서 추출시 높은 경제성과 관능적 우수성이 확보된 육류 향미제 생산이 가능하다고 판단된다.

Datong탄에 대한 Bench Scale Unit급 분류층 석탄가스화 연구 (Gasification Study of Datong Coal in a Bench Scale Unit of Entrained Flow Gasifier)

  • Ryu, Si-Ok;Kim, Jae-Ho;Lee, Hyo-Jin;Lee, Jae-Goo;Park, Tae-Jun;An, Dal-Hong;Park, Ho-Young
    • 에너지공학
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    • 제6권1호
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    • pp.96-103
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    • 1997
  • 0.5~1.0톤/일 용량의 BSU급 분류층 가스화기에서 중국산 Datong탄에 대한 석탄가스화 특성실험을 하였다. 가스화기의 반응온도는 1300~155$0^{\circ}C$를 유지하였으며, 실험에 사용된 슬러리농도는 62.5wt% ($H_2O$/Coal=0.6)였다. 산소 및 슬러리는 버너에 주입되기전 예일을 실시하였으며 $O_2$/Coal의 공급비는 0.8~l.2를 유지하였다. 또한 슬러리의 점도를 낮추고 유동성을 향상시키기 위하여 첨가제로서 CWM 1002와 NaOH를 각각 0.3%와 0.05% 추가하였다. 석탄가스화 실험에서 측정된 생성기체는 주로 수소, 일산화탄소 및 이산화탄소로 구성되어 있으며 미량의 메탄도 생성되었다. 생성된 가스는 반응온도가 증가함에 따라 H$_2$와 CO의 생성량은 증가하는 반면 $CO_2$의 양은 감소하였다. 산소의 공급량이 증가함에 따라 $CO_2$의 생성량은 지속적으로 증가하고 CO 및 H$_2$의 생성량은 $O_2$/Coal의 비가 약 0.9에서 최대치를 나타낸 후 감소하였으며, 생성가스 발열량은 1700~2400 kcal/N㎥을 나타내었다.

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플라즈마-축열버너 부분산화 개질장치 (Partial Oxidation Reformer in a Plasma-Recuperative Burner)

  • 안준;전영남
    • 한국수소및신에너지학회논문집
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    • 제32권1호
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    • pp.68-76
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    • 2021
  • Climate change problems occur during the use of fossil fuel and the process of biogas production. Research continues to convert carbon dioxide and methane, the major causes of climate change, into high-quality energy sources. in order to present the performance potential for the novel plasma-recuperative burner reformer, the reforming characteristics for each variable were indentified. The optimal operating condition of was an O2/C ratio of 1.0 and a total gas supply of 20 L/min. At this time, CH4 conversion was 64%, H2 selectivity was 39%, and H2/CO ratio was 1.13, which were the results applicable to the solid oxide fuel cell fuel stack for RPG, or Residential Power Generator. Recirculation of reformed gas increases the amount of H2 and CO, which are combustible gases, especially the amount of H2. As a result, the H2 selectivity is improved, and high-quality gas can be produced.

광역지자체의 산림지 온실가스 인벤토리 시범 산정 (Estimation of the Greenhouse Gas Inventory on Forest Land at Provincial Level)

  • 김경남;이선정;김래현;손영모
    • 한국농림기상학회지
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    • 제16권4호
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    • pp.336-342
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    • 2014
  • 본 연구는 우리나라의 광역지자체의 산림지 온실가스 배출량을 시범산정하기 위해 수행되었다. 온실가스 배출량은 국가 온실가스 인벤토리 산정 지침에 따라 산정하였으며, 이를 위해 임업통계연보 및 산림관련 활동 자료 및 배출계수를 이용하였다. 그 결과 산림지의 2011년 총 배출량은 -58,711Gg $CO_2eq.$, 벌채, 연료재 수집, 산불에 의한 배출량은 19,896Gg $CO_2eq.$로 나타났다. 2011년을 기준으로 산림지에서는 온실가스를 흡수하는 것으로 나타났고, 순 배출량은 -38,815Gg $CO_2eq.$로 나타났다. 광역지자체 별로는 강원도에서 온실가스를 가장 많이 흡수하는 것으로 나타났다. 본 연구의 산정결과는 현재 중복산정을 최대한 배제하고자 많은 통계를 활용하지 않은 것으로, 향후 활동자료 및 배출계수 등을 보완하여 산정할 필요가 있을 것으로 사료된다.

동맥혈 및 뇨 $P_CO_2}, P{O_2}$ 의 산-염기 균형 및 뇨량과의 관계 (Relationships between arterial and urinary $P_CO_2}, P{O_2}$ and acid-base balances)

  • 김용진;이영균
    • Journal of Chest Surgery
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    • 제16권2호
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    • pp.213-220
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    • 1983
  • Pulmonary function is the determinant of blood gas tension. However, Acid-Base disturbances can also alter partial pressures of oxygen and carbon dioxide in arterial blood. During respiratory acidosis $PO_2$ will be lowered and reverse changes will be produced during respiratory alkalosis. On the other hand, in metabolic acidosis $PO_2$ will be elevated and $PCO_2$ will be lowered by the respiratory compensation, and reverse response will be induced in metabolic alkalosis. Urinary gas tension has many influencing factors than arterial blood and difficult to estimate the tendency of its alterations. Urinary $PO_2$ and $PCO_2$ are not always identical level as venous blood. It is to be altered by blood gas tension, flow rate of urine, metabolic rate of kidney, and Acid-Base status of blood. Particularly countercurrent exchange of oxygen and carbon dioxide in the renal medulla will make larger alteration of gas tension than venous blood. After induction of Acid-Base disturbances [disturbances] arterial and urinary $PCO_2$, $PO_2$, urinary volume, and osmolarity were determined in dogs, and the relationships between arterial and urinary $PCO_2$ , $PO_2$ Acid-Base disturbances, urinary volume, and osmolarity were investigated. 1. During the acute Metabolic and Respiratory disturbances urinary pH did not respond on respiratory origin. However, there were immediate urinary response in pH on metabolic origin. 2. Urinary $PO_2$, $PCO_2$, did not always follow arterial or venous gas tension and Acid-Base disturbance. Urinary $PCO_2$, correlate well with the urinary volume. The larger the urinary volume, $PCO_2$ lowered to the venous level. The smaller the urinary volume, urinary $PCO_2$ tends to be higher. However urinary $PO_2$ did not have any particular correlation with urinary volume. 3. Correlation between urinary $PCO_2$ and $PO_2$ were inversely proportional to arterial blood. Differences of $PCO_2$ between arterial blood and urine also did not have any particular correlation with urinary volume. This may suggest that changes on blood gas tensions can influence on urinary $PCO_2$. 4. There were eminent clear inverse correlation between urinary $PCO_2$ and osmolar concentrations of urine. Above results strongly suggest that partial pressure of gas in urine primarily depend upon counter-current exchanges in renal medullary tissues.

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초임계추출의 천연물 시트러스계의 항산화효과와 향기성분 연구 (On study antioxidant effect and aroma component of natural citrus by SC-$CO_2$ Extraction)

  • 임덕점;전병수;오대희
    • 한국응용과학기술학회지
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    • 제31권2호
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    • pp.285-295
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    • 2014
  • Citrus essential oil were extracted from citron peel of cultivated in Gohong (CCP) using environmentally friendly supercritical carbon dioxide method. Antioxidant activity and aroma composition of the essential oils extracted by the SC-$CO_2$ method were evaluated by comparing with those extracted by organic solvent method. Fatty acid composition, DPPH scavenging, and antioxidant activity of the oils obtained by different extraction condition of SC-$CO_2$ method were investigated and their antioxidant activities were compared with commercially available lavender, eucalyptus and tea tree oils. As the results, linoleic acid was most abundantly found from CCP oil extracted by the SC-$CO_2$ method and cis-11,144-eicosadienoic acids was second abundantly found. Radical scavenging ability of DPPH was 98% when the concentration of CCP oil was 50 mg/mL. This scavenging ability increased with the increase of oil concentration. On the other hand, flavonoids content (84 mg/100g) of the CCP oil extracted by the SC-$CO_2$ method was slightly higher than that (75 mg/100g) by hexane extraction. The results, obtained from CCP oil by GC-MS, indicated that, among 66 components, the content of terpenes was 55.8% and limonene was 27.3%.

세관내 이산화탄소의 증발 열전달 및 압력강화 (Evaporation Heat Transfer and Pressure Drop of $CO_2$ in a Small diameter Tube)

  • 장승일;최선묵;김대희;박기원;오후규
    • 한국마린엔지니어링학회:학술대회논문집
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    • 한국마린엔지니어링학회 2005년도 전기학술대회논문집
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    • pp.189-194
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    • 2005
  • The evaporation heat transfer and pressure drop of $CO_2$ in a small diameter tube was investigated experimentally. The experiments were conducted without oil in a closed refrigerant loop which was driven by a magnetic gear pump. The main components of the refrigerant loop are a receiver, a variable-speed pump, a mass flow meter, a pre-heater and evaporator(test section). The test section was made of a horizontal stainless steel tube with the inner diameter of 4.57 mm, and length of 4 m. The experiments were conducted at mass flux of 200 to 700 $kg/m^2s$, saturation temperature of $0^{\circ}C$ to $20^{\circ}C$, and heat flux of 10 to 20 $kW/m^2$ . The test results showed the evaporation heat transfer of $CO_2$ has great effect on more nucleate boiling than convective boiling. The evaporation heat transfer coefficients of $CO_2$ are highly dependent on the vapor quality, heat flux and saturation temperature. The evaporation pressure drop of C02 are highly dependent on the mass flux. In comparison with test results and existing correlations, correlations failed to predict the evaporation heat transfer coefficient and pressure drop of $CO_2$, therefore, it is necessary to develop reliable and accurate predictions determining the evaporation heat transfer coefficient and friction pressure drop of $CO_2$ in a horizontal tube.

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입체 장애 알카놀아민 혼합 수용액에서 중탄산칼륨 결정의 냉각 반용매 결정화 (Cooling and Antisolvent Crystallization of Potassium Bicarbonate in the Presence of Sterically Hindered Alkanolamines)

  • 조창신;정태성;윤형철;김종남;이영우
    • 청정기술
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    • 제20권4호
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    • pp.383-389
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    • 2014
  • 이산화탄소 흡수공정은 대규모의 이산화탄소를 처리하는데 유리하지만, 다량의 흡수액을 재생하는데 필요한 현열과 증발열로 인한 에너지 비용 상승이 단점으로 지적되고 있다. 이를 극복하기 위해 이산화탄소를 흡수한 탄산칼륨 흡수액을 냉각 결정화시켜, 다량의 물로부터 이산화탄소가 많이 포함된 중탄산칼륨 결정을 선택적으로 분리할 수 있다. 본 연구에서는 이산화탄소 분리효율을 높이기 위해 입체 장애 알카놀아민 첨가제를 도입하여, 이들이 중탄산칼륨 연속식 결정화에 미치는 영향에 대해 살펴보았다. 결정의 석출량은 2-아미노-2-메틸-1-프로판올(2-amino-2-methyl-1-propanol, AMP), 2-아미노-2-메틸-1,3-프로판디올(2-amino-2-methyl-1,3-propanediol, AMPD), 2-아미노-2-히드록시메틸-1,3-프로판디올(2-amino-2-hydroxymethyl-1,3-propanediol, AHPD)의 순서로 증가하였으며, 반용매로 작용하는 첨가제들의 히드록실기 개수와 관계가 있는 것으로 나타났다. 탄소 핵자기공명분광 분석 결과, 첨가제들은 입체 장애 효과에 의해 중탄산 이온의 생성을 유도하고 과포화도를 상승시킨 것으로 나타났다. 또한, 첨가제들은 과포화도 상승을 통해 평균 입도와 결정 성장 속도를 증가시키는 것으로 나타났다. 입체 장애 알카놀아민 첨가제는 중탄산칼륨 결정화를 촉진함으로써, 물로부터 이산화탄소의 분리효율을 향상시키고 재생에너지를 저감시킬 수 있을 것으로 기대된다.

Anaerobic digestion and agricultural application of organic wastes

  • Suanu, Leh-Togi Zobeashia S.;Abiodun, Aransiola S.;Josiah, Ijah U.J.;Peter, Abioye O.
    • Advances in environmental research
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    • 제7권2호
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    • pp.73-85
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    • 2018
  • The anaerobically digestion and agricultural application of organic wastes was conducted using food wastes and cow dung. Twenty kilograms each of the feed stocks was added into two 30 liters-capacity batch digesters. The anaerobic digestion was carried out within a temperature range of $25-31^{\circ}C$ for a retention time of 51 days. The results showed a cumulative gas yield of 5.0 bars for food waste and no gas production for cow dung within the retention time. Bacteria such as Escherichia coli, Staphylococcus aureus, Pseudomonas aeruginosa, Proteus vulgaris and Clostridium sp were isolated. Fungi isolated included Aspergillus niger, Aspergillus nidulan, Trichophyton rubrum and Epidermophyton flocossum. The non-dispersive infrared (NDIR) analysis of the biogas produced confirmed that the gas consisted of $CH_4$, $CO_2$ and $H_2$. Statistical analysis revealed there was no significant correlation between temperature and biogas produced from the organic wastes (r= 0.177, p = 0.483).The organic wastes from the biogas production process stimulated maize growth when compared to control (soil without organic waste) and indicated maximum height. The study therefore reveals that food waste as potential substrates for biogas production has a moderate bio-fertilizer potential for improving plant growth and yield when added to soil.

외피 친환경 성능평가 II: 광선반, RetroLux (Performance Assessment of Building Envelopes II: LightShlef, RetroLux)

  • 김덕우;박철수
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2009년도 춘계학술발표대회 논문집
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    • pp.83-90
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    • 2009
  • As a series of 'Performance Assessment of Building Envelopes I: Double Skin Facade', three types (interior, exterior, mixed (int.&ext.)) of lightshelves and RetroLux were examined in terms of $CO_2$ emissions. It is shown that the exterior lightshelf could achieve the most energy savings (9.6-38.7%) in general office buildings due to blocking solar radiation before entering the indoor space. However, the interior lightshelf is the worst (1.4-5.2%) among three of them. The RetroLux has two components: (1) sun-reflector (first louver component), (2) light shelf for improving daylight induction (second louver component). Due to these two components, solar radiation from windows is filtered depending on seasonal variation (solar altitude). Therefore, the RetroLux can reduce 18.0-27.9% of annual energy consumption (both cooling and heating), and $552-3,290Won/m^2{\cdot}yr$ of operation cost is saved.

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