• Journal of Korean Society of Environmental Engineers
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• v.35 no.2
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• pp.109-114
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• 2013

Polyhydroxyalkanoates (PHAs) are synthesized by numerous bacteria as carbon and energy storage compounds and are raw materials for biocompatible plastics. In this paper, the effect of $CO_2$ concentrations on the growth of C. necator and the accumulation of Poly(3-hydroxybutyrate) (P(3HB)) are investigated by increasing the $CO_2$ concentration in the substrate gas mixture. During 6 d cultivation in a nitrogen-present mineral medium, the $CO_2$ concentration did not affect the growth of the cells, while the Poly(3- hydroxybutyrate) (P(3HB)) content decreased with increasing $CO_2$ concentrations from 1% to 20%. During 4 d cultivation in the nitrogen-limited medium, the P(3HB) accumulation was the greatest at 3% $CO_2$; however, the total amount of accumulated P(3HB) was the greatest at 1% $CO_2$, which decreased with increasing $CO_2$ concentrations. The results indicate that the gas mixture with 1% $CO_2$ is the most effective in both growing the cells and accumulating P(3HB) under our experimental conditions.

• Journal of the Korean Society for Marine Environment & Energy
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• v.10 no.2
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• pp.118-124
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• 2007

The oceans could absorb almost all the anthropogenic carbon dioxide the mankind has been producing eventually, but in the nature the air-sea $CO_2$ exchange occurs very slowly and to lower the atmospheric $CO_2$ concentration substantially $CO_2$ must be injected to the interior of the ocean directly. If we inject $CO_2$ collected at the major $CO_2$ sources into the international waters in the Philippine Sea or east of Japan, we could store the $CO_2$ in the oceans effectively for a few hundred years. When $CO_2$ is dissolved into the water, PH drops. The creatures adapted to the deep oceans where environment is very stable could be affected by even a small change in pH significantly. If, therefore, we are to inject $CO_2$ into the oceans, we must assess the effect of $CO_2$ injection in the marine ecosystem beforehand. Only when the damage to the marine ecosystem is smaller than the benefit from the $CO_2$ injection, $CO_2$ injection is effective.

• Korean Journal of Food Science and Technology
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• v.35 no.6
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• pp.1104-1109
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• 2003

Response surface methodology (RSM) was used to investigate the effects of the processing parameters on supercritical $CO_2\;(SC-CO_2)$. extraction of total carotenoids and ${\beta}$-cyptoxanthin from Citrus unshiu press cake. The parameters tested were $SC-CO_2$ pressure, dynamic extraction time, and concentration of ethanol added as the modifier to $CO_2$. Experimental data correlated well with the processing parameters (p<0.01), and there was a high statistically significant multiple regression relationship for the extraction of total carotenoids and ${\beta}-cyrptoxanthin$ ($R^2=0.9789$ and 0.9796, respectively). The optimal processing conditions were extraction pressure 33.4 and 37.3 MPa, extraction time 39.6 and 41.0 min, ethanol concentration 18.6 and 17.0% for total carotenoids and ${\beta}-cryptozanthin$, respectively. Maximum extraction yields predicted by RSM were 61.1 and 95.8% ppm, respectively. The extraction yield of total carotenoids increased asymptotically with the increase of the extraction pressure. It increased in proportion to extraction time and concentration of the cosolvent. The extraction yield of ${\beta}-cryptoxanthin$ increased with extraction pressure, extraction time, and concentration of the cosolvent. The extraction time and the concentration of the cosolvent, and the interaction between extraction time and the concentration of the cosolvent significantly affected the extraction yields of carotenoids from C. unshiu press cake.

• Applied Chemistry for Engineering
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• v.7 no.6
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• pp.1156-1163
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• 1996

This study is related to the investigation of the characteristics of quaternary ammonium salt catalyst on the addition reaction of carbon dioxide and glycidyl methacrylate(GMA) to form(2-oxo-1,3-dioxolane-4-yl)methacrylate(DOMA). Among the salts tested, the ones with higher alkyl chain length and with more nucleophilic counter anion showed a higher catalytic activity. Mixed catalysts of NaI and 18-crown-6 showed a good yield of DOMA, but when they are used alone, they showed no catalytic activity. The DOMA monomer was obtained in low polar solvents, while poly(DOMA) could be directly synthesized in aprotic dipolar solvents. Kinetic studies carried out by measuring $CO_2$ pressure in a high pressure batch reactor showed that the reaction rate was first order to the concentration of GMA and $CO_2$ respectively. The rate constant(k) was 0.56L/mol hr and Henry's constant(H') of $CO_2$ in diglyme at $80^{\circ}C$ was $6.5{\times}10^{-4}mol/L{\cdot}kPa$.

• Journal of the Korean Society of Safety
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• v.36 no.1
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• pp.86-94
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• 2021

Lecture rooms are crowded with many attendees. Moreover, they rely significantly on the natural ventilation through windows for removing and controlling indoor contaminants such as CO₂. With the aim of broadening the understanding of the characteristics of natural ventilation phenomena in lecture rooms, the average individual CO₂ release rates of attendees were measured during the course of a lecture and compared with previously reported CO₂ release rates. In addition, the effects of natural ventilation through windows on the time-variant CO₂ concentrations in the center of the lecture room were measured and analyzed. Moreover, details about the overall and regional CO₂ concentrations, as well as the air flows in the lecture room, were simulated and analyzed with computational fluid dynamics software, Fluent 2020 R2. It was found that the average individual CO₂ release rates were slightly slower than previously reported rates. The local CO₂ concentrations in the lecture room for regions with a high density of attendees increased over a short period of time, although the natural ventilation was already started by opening the windows. The overall CO₂ concentration in the lecture room rapidly decreased in the early stage of ventilation, but declined very slowly after a longer period of ventilation time. Therefore, in order to enhance the efficiency of a lecture room's natural ventilation, it is recommended to homogeneously distribute the attendees in the lecture room, and to frequently open the windows for short periods of time.

• Clean Technology
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• v.18 no.4
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• pp.347-354
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• 2012

In this study, simulation works have been performed for the $CO_2$ removal process contained in the DME production process using NMP (N-methyl-2-pyrrolidone) as a solvent. PRO/II with PROVISION release 9.1 at Invensys was used as a chemical process simulator and NRTL activity coefficient model with Henry's law option and Soave-Redlich-Kwong equation of state were used for thermodynamic models. For the determination of the binary interaction parameters in NRTL model, regression works have been performed to match the experimental thermodynamic data. Optimal feed tray location which minimizes the reboiler heat duty was determined.

• The Korean Journal of Ecology
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• v.24 no.6
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• pp.335-339
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• 2001

The dynamic model was developed to simulate the photosynthetic rate of Phragmites communis stands in coastal ecosystem. The model was composed of the compartments of both climatic and biological variables. The former were photosynthetic photon flux density(PPFD), daily maximum- and minimum-temperature. The latter were combinations of the specific physiological responses of plant organs with the biomass of each organs. The PPFD and air temperature were calculated and using those values, gas exchange rate of each plant organ was calculated at every hour. The carbon budget was constructed using the modelled predictions. Analysis of annual productivity and fluxes showed that yearly gross population productivity, yearly population respiration and yearly net population productivity were 33.4, 21.3 and 12.1 $CO_2ton{\cdot}ha^{-2}{\cdot}yr^{-1}$, respectively. The final result was tested over two stands, produced promising predictions with regards to the levels of production attained. The model can be used to determine production potential under given climatic conditions and could even be applied to plant canopies with analogous biological characteristics.

• Journal of Hydrogen and New Energy
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• v.25 no.6
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• pp.586-593
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• 2014

Limited sources of fossil fuels and also global climate changes caused by $CO_2$ emissions are currently discussed around the world. As a renewable, carbon neutral and widely available energy source, biogas is regarded as a promising alternative to fossil fuels. In this study, a plasma dump reformer was proposed to produce $H_2$-rich synthesis gas by a model biogas. The three-phase gliding arc plasma and dump combustor were combined. Screening studies were carried out with the parameter of a dump injector flow rate, water feeding flow rate, air ratio, biogas component ratio and input power. As the results, methane conversion rate, carbon dioxide conversion rate, hydrogen selectivity, carbon monoxide yield at the optimum conditions were achieved to 98%, 69%, 42%, 24.7%, respectively.

• The Journal of the Korea institute of electronic communication sciences
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• v.10 no.8
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• pp.907-914
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• 2015

Due to the global warming, the restriction for emitting the green-house gas is strengthened and a main ingredient of the green-house gas is carbon dioxide ($CO_2$). In order to reduce the amount of $CO_2$, the low-carbon and long-life of the construction and the construction materials management system based on the radio frequency identification (RFID) technique have been actively studied in the construction field. The conventional construction management system based on RFID only focuses on the study and experiment for managing the used amount and location of the construction materials in the construction stage, but it does not consider the study for the status management system for the recycling materials in the construction stage or the building deactivation. In this paper, we propose the effective RFID system for managing the status of the construction materials during the construction stage or the building deactivation. Employing RFID with the frequency of 900MHz, the proposed system consists of the reader unit, communication unit, and memory unit, and its tags are attached in the surface or inside of the construction materials.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.36 no.2
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• pp.137-143
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• 2012

Currently, in order to meet the reinforced emissions regulations for harmful exhaust gas including carbon dioxide ($CO_2$) as a greenhouse gas, technologies for reducing $CO_2$ emission and fuel consumption are being developed. Gasoline direct injection (GDI) systems have the advantage of improved fuel economy and higher power output than port fuel injection gasoline engine systems. The aim of this study is to examine the performance and emission characteristics of a lean burn GDI engine equipped with spray-guided-type combustion system. Stable lean combustion was achieved with a late fuel injection strategy under a constant operating condition. Further improvement in specific fuel consumption is possible with the introduction of multiple fuel injection strategies, which also increases hydrocarbon (HC) and nitrogen oxide ($NO_x$) emissions and decreases carbon monoxide (CO) emission.