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Development of a Plasma-Dump Reformer for Syngas Production

합성가스 생산을 위한 플라즈마-덤프 개질기 개발

  • Lim, Mun Sup (Department of Environmental Engineering. Chosun University) ;
  • Kim, Eun Hyuk (Department of Environmental Engineering. Chosun University) ;
  • Chun, Young Nam (Department of Environmental Engineering. Chosun University)
  • Received : 2014.11.18
  • Accepted : 2014.12.31
  • Published : 2014.12.30

Abstract

Limited sources of fossil fuels and also global climate changes caused by $CO_2$ emissions are currently discussed around the world. As a renewable, carbon neutral and widely available energy source, biogas is regarded as a promising alternative to fossil fuels. In this study, a plasma dump reformer was proposed to produce $H_2$-rich synthesis gas by a model biogas. The three-phase gliding arc plasma and dump combustor were combined. Screening studies were carried out with the parameter of a dump injector flow rate, water feeding flow rate, air ratio, biogas component ratio and input power. As the results, methane conversion rate, carbon dioxide conversion rate, hydrogen selectivity, carbon monoxide yield at the optimum conditions were achieved to 98%, 69%, 42%, 24.7%, respectively.

Keywords

References

  1. M. H. Rafiq, and J. E. Hustad, "Experimental and thermodynamic studies of the catalytic partial oxidation of model biogas using a plasma-assisted gliding arc reactor", Renewable Energy, Vol. 36, pp. 2878-2887, 2011. https://doi.org/10.1016/j.renene.2011.04.012
  2. A. Effendi, Z.-G. Zhang, K. Hellgardt, K. Honda, and T. Yoshida, "Steam reforming of a clean model biogas over Ni/$Al_2O_3$ influidized-andfixedbedreactors," Catalysis. Today, Vol. 77, 2002, pp. 181-189. https://doi.org/10.1016/S0920-5861(02)00244-4
  3. M. Ashrafi, T. Proll, C. Pfeifer, and H. Hofbauer, "Experimental study of model biogas catalytic steam reforming: 1. Thermodynamic optimization," Energy & Fuels, Vol. 22, No. 6, 2008, pp. 4182-4189. https://doi.org/10.1021/ef800081j
  4. S. Appari, V. M. Janardhanan, R. Bauri, and S. Jayanti, "Deactivation and regeneration of Ni catalyst during steam reforming of model biogas: An experimental investigation", International Journal of Hydrogen Energy, Vol. 39, 2014, pp. 297-304. https://doi.org/10.1016/j.ijhydene.2013.10.056
  5. W. Nimwattanakul, A. Luengnaruemitchai, and S. Jitkarnka, "Potential of Ni supported on clinoptilolite catalysts for carbon dioxide reforming of methane," International Journal of Hydrogen Energy, Vol. 31, No. 1, 2006, pp. 93-100. https://doi.org/10.1016/j.ijhydene.2005.02.005
  6. J. Zhua, D. Zhang, K. and D. King, "Reforming of CH4by partial oxidation : thermodynamic and kinetic analyses," Fuel, Vol. 80, 2001, pp. 899-905. https://doi.org/10.1016/S0016-2361(00)00165-4
  7. X. Tu, and J. C. Whitehead, "Plasma dry reforming of methane in an atmospheric pressure AC gliding arc discharge: Cogeneration of syngas and carbon nanomaterials", International Journal of Hydrogen Energy, Vol. 39, 2014, pp. 9658-9969. https://doi.org/10.1016/j.ijhydene.2014.04.073
  8. Y. N. Chun, Y. C. Yang, and K. Yoshikawa, "Hydrogen generation from biogas reforming using a gliding arc plasma-catalyst reformer", Catalysis Today, Vol. 148, 2009, pp. 283-289. https://doi.org/10.1016/j.cattod.2009.09.019
  9. B. Zhu, X.-S. Li, J.-L. Liu, and A.-M. Zhu, "Optimized mixed reforming of biogas with O2 addition in spark-discharge plasma", International Journal of Hydrogen Energy, Vol. 37, 2012, pp. 16916-16924. https://doi.org/10.1016/j.ijhydene.2012.08.091
  10. Y. N. Chun, S. C. Kim, and K. Yoshikawa, "Decomposition of Benzene as a Surrogate Tar in a Gliding Arc Plasma", Environmental Progress & Sustainable Energy, Vol. 32, No. 3, 2013, pp. 837-845. https://doi.org/10.1002/ep.11663
  11. O. A. Bereketidou, and M. A. Goula, "Biogas reforming for syngas production over nickel supported on ceria-alumina catalysts", Catalysis Today, Vol. 195, 2012, pp. 93-100. https://doi.org/10.1016/j.cattod.2012.07.006
  12. Y. Xu, Q. Wei, H. Long, X. Zhang, S. Shang, X. Dai, and Y. Yin, "CO reforming of $CH_4$ by synergies of binode thermal plasma and catalysts", International Journal of Hydrogen Energy, Vol. 38, 2013, pp. 1384-1390. https://doi.org/10.1016/j.ijhydene.2012.11.008
  13. V. Goujard, J.-M. Tatibouet, and C. Batiot-Dupeyrat, "Use of a non-thermal plasma for the production of synthesis gas from biogas", Applied Catalysis A: General, Vol. 253, 2009, pp. 228-235.