• Proceedings of the Korean Society of Marine Engineers Conference
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• 2011.10a
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• pp.88-89
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• 2011

The study on synthesis of carbon nanomaterials by H2 mixing in counterflow methane diffusion flames has been experimentally conducted. We have also investigated on effect of catalyst and temperature in flame. The counterflow flame was formed by many kind of gas (fuel side using $CH_4-H_2-N_2$ and oxidizer side $N_2-O_2$) and nitrogen shields discharge on each other side to cut off oxidizer of the atmosphere. Ferrocene was used as a metal catalyst for CNTs synthesis. substrate was used to deposit carbon nanomaterials and these were analyzed by FE-SEM. We could find that carbon nanotubes and many kind of carbon nano materials were formed in Cu wire substrate, through this experiment.

• Journal of the Microelectronics and Packaging Society
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• v.17 no.1
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• pp.75-80
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• 2010

Electroless nickel plating on porous carbon substrate was investigated. The pore sizes of carbon substrates were 16-20 ${\mu}m$ and over 20 ${\mu}m$. The carbon surface was changed from hydrophobic to hydrophilic after immersing the substrate in an ammonia solution for 40 min at $60^{\circ}C$. The contact angle of water was decreased from $85^{\circ}$ to less than $20^{\circ}$ after ammonia pretreatment. The content of phosphorous in nickel deposit was decreased with increasing pH and then deposits became crystallized. The thickness of nickel deposit was increased with increasing pH. The minimum concentration of $PdCl_2$ for the electroless nickel plating was 5 ppm and the thickness of nickel was not significantly affected by the concentration of $PdCl_2$.

• Carbon letters
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• v.11 no.3
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• pp.184-191
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• 2010

Carbon nanotubes are unique tubular structures of nanometer diameter and large length/diameter ratio. The nanotubes may consist of one up to tens and hundreds of concentric shells of carbons with adjacent shells separation of ~0.34 nm. Multiwalled carbon nanotubes were synthesized by arc-discharge technique. MWCNTs were formed at the cathode deposit along with other carbonaceous materials like amorphous carbon, graphite etc. However, to get the best advantage of carbon nanotubes in various advanced applications, these undesired carbonaceous materials to be removed which is a challenging task. In the present study, various techniques were tried out for purifying MWCNTs such as physical filtration, chemical treatment and thermal annealing. SEM, FTIR, TGA and BET techniques were used to characterize the CNTs at various stages. Results shows that suitable chemical treatment followed by thermal annealing under controlled flow of oxygen gives the better route for purification of carbon nanotubes.

• Journal of the Korean Society for Precision Engineering
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• v.23 no.12 s.189
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• pp.122-127
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• 2006

This paper reports on the development of carbon nanotube tip modified with focused ion beam(FIB). We used an electric field which causes dielectrophoresis, to align and deposit CNTs on a metal-coated canning Probe Microscope (SPM) tip. Using the CNT attached SPM tip, we have obtained an enhanced resolution and wear property compared to that from the bare silicon tip through the scanning of the surface of the bio materials. The carbon nanotube tip was aligned toward the source of the ion beam allowing their orientation to be changed at precise angles. By this technique, metal coated carbon nanotube tips that are several micrometer in length are prepared for SPM.

• Journal of Environmental Science International
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• v.17 no.11
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• pp.1235-1241
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• 2008

Membrane separation is extensively used for water/wastewater treatment because of its efficiency separation processes. However, particles in the feed water can deposit and accumulate on the membrane surface to created cake layer. As a consequence, the selectivity of the membrane and flux through the membrane are decreased, which is called fouling/blocking phenomenon. In order to solve fouling problem, we developed a novel membrane named Carbon Whisker Membrane (CWM) which contains vapor-grown carbon fibers/whiskers on the surface of the membrane and a layer of carbon film coated on the ceramic substrate. We firstly employed polymethyl methacrylate (PMMA) as a testing material to investigate the fouling mechanism. The results suggested that Carbon Whiskers on the surface of the membrane can prevent the directly contact between the membrane body and particles so that the fouling/blocking could not occurred easily compared to the membrane without carbon whiskers. We also researched the relationship with the diameter, density of carbon whisker on the membrane surface and total flux of solutions. Finally, we will be able to control the diameter and density of carbon whiskers on the membrane and existence of carbon whiskers on the membrane, it is important factor, might be prevent fouling/blocking in the water treatment.

• 한국신재생에너지학회:학술대회논문집
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• 2008.10a
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• pp.188-191
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• 2008

There have been many methods for producing natural gas from gas hydrate reservoirs in permafrost and sea floor sediments. It is well knownthat the depressurization should be a best option for Class 1 gas hydrate deposit, which is composed of tow layers: hydrate bearing layer and an underlying free gas. However many of gas hydrate reservoirs in sea floor sediments are classified as Class 2 that is composed of gas hydrate layer and mobile water, and Class 3 that is a single gas hydrate layer. The most appropriate production methods among the present methods such as thermal stimulation, inhibitor injection, and controlled oxidation are still under development with considering the gas hydrate reservoir characteristics. In East Sea of Korea, it is presumed that the thick fractured shale deposits could be Class 2 or 3, which is similar to the gas hydrate discovered offshore India. Therefore it is needed to evaluate the possible production methods for economic production of natural gas from gas hydrate reservoir. Here we would like to present the production of natural gas from gas hydrate deposit in East Sea with industrial flue gases from steel company, refineries, and other sources. The existing industrial complex in Gyeongbuk province is not far from gas hydrate reservoir of East Sea, thus the carbon dioxide in flue gas could be used to replace methane in gas hydrate. This approach is attractive due to the suggestion of natural gas productionby use of industrial flue gas, which contribute to the reduction of carbon dioxide emission in industrial complex. As a feasibility study, we did the NMR experiments to study the replacement reaction of carbon dioxide with methane in gas hydrate cages. The in-situ NMR measurement suggeststhat 42% of methane in hydrate cages have been replaced by carbon dioxide and nitrogen in preliminary test. Further studies are presented to evaluate the replacement ratio of methane hydrate at corresponding flue gas concentration.

• Journal of the korean Society of Automotive Engineers
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• v.10 no.5
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• pp.61-68
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• 1988

This paper reports the basic performance of a naturally aspirated DI diesel engine which is used widely in industry and agriculture when vegetable oils are used as fuel substitutes. In this paper, the properties of vegetable oils as diesel fuel were investigated and the load-performance of diesel engine when vegetable oils were used, as tested compared against diesel fuel. The general objective of this investigation is to realize an efficient, clean, and low carbon deposit combustion of the vegetable oils in diesel engines, showing their feasibility as diesel fuel substitutes. The results of this experiment were as follows; (1) Compared with diesel fuel, the droplet size of vegetable oil is very large. (2) Compared with diesel fuel, rapeseed oil, palm oil, and their blend fuels offered lower smoke, lower NOx, ower engine noise, and high thermal efficiency in a D.I. diesel engine However, there were carbon deposit and piston ring sticking problems with long-term operation. (3) For ethanol-rapeseed oil blends, a 10-20% of ethanol content is recommended to enable lower BSHC and less smoke without a remarkable increase in engine noise compared with pure rapeseed oil. (4) A 10% oxygen content in the vegetable oils is contributed to reduced smoke emission.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.1
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• pp.1-7
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• 2007

Electrorefining experiments were successfully carried out in LiCl-KCl eutectic molten salt with a graphite cathode. It was found that the formation of Uranium-Graphite intercalation compound(U-GIC) helped the self-scraping mechanism of the uranium dendrite and the efficiency of the electrorefiner increased due to an elimination of the stripping step. The contaminations of the uranium deposit by rare earth elements was negligible while about 300 ppm of carbon was observed. The carbon contamination is believed to be eliminated by further purification by yttrium reaction. The morphology characteristics of the recovered U deposit was compared to that of steel cathode. These are only qualitative preliminary experimental results, but we believe that further research on this type of activity change the direction of the electrorefining research on spent nuclear fuel.

• Economic and Environmental Geology
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• v.38 no.4 s.173
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• pp.421-434
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• 2005

Abstract Based onthe characteristics of Carlin-type gold deposit in Nevada district, a potential in Korea is evaluated to the Yemi area where is structurally controlled by folds and trust fault. The fault of high angles are combined with a more permeable rocks such as the Yemi breccia and laminated silty limestone. The pattern of enrichment factors for Tl, Sb, As, Ag, Pb, Zn, Cu, Mo and W of limestones in the southern area are geochemically similar with those reported from the Carlin-type Bold deposit. Moreover, the oxygen and carbon isotopes show a hydrothermal alteration is widely developed in this area. According to the result of geophysical interpretation, stable isotope, alteration mineralogy, geochemical study, and geological structure, this mineralized zone may be extended to the M direction, so a detailed systematic exploration is required to identify this alteration zone.

• Korean Journal of Soil Science and Fertilizer
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• v.27 no.4
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• pp.315-320
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• 1994

This survey report introduced briefly peat deposits in SAKHALIN island of eastern SIBERIA continent. Peat industry was promoted as leading resources for development in this island by national control economic plan of central government before CIS. But development of deposit was left suspension of operation due to investment now. In southern area, about 10km from Yuzunosakhalinsk, two deposits of peat field were explored. One of them (Troisk) was suspended at begining stage of peat harvest from 300ha field and the other(Missilop) was producing the compact peat through drying and pulverizing from 350ha peat field which showed long run harvest activities. There are plenty of peat deposits near the Polonai Reika (river) in the central area of this island, At Zbaikaritz, 40km nothern area from Polonaisk, 135ha of peat field was developed. This field was left without working but established field preparation and could be able to be harvested any time if machines and utlities were settled. At southern suburb 10km from Polonaisk, about 40ha field of virgin deposit has been established planning for development. The plan involved estimated amount of peat, deposit depth, water level, drainage and leading road. The most of peat deposits accumulated from sphagnum moss. Texture is coarse but it contains more than 95% of organic carbon near to 0.5% of total nitrogen and acidity showed pH4-5.