• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1331-1335
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• 2010

A novel spherical carbon composite material, in which nanosized disordered carbons are dispersed in a soft carbon matrix, has been prepared and investigated for use as a potential anode material for lithium ion batteries. Disordered carbons were synthesized by ball milling natural graphite in air. The composite was prepared by mixing the ball-milled graphite with petroleum pitch powder, pelletizing the mixture, and pyrolyzing the pellets at $1200^{\circ}C$ in an argon flow. The ballmilled graphite consists of distorted nanocrystallites and amorphous phases. In the composite particle, nanosized flakes are uniformly distributed in a soft carbon matrix, as revealed by X-ray diffractometer (XRD) and transmission electron microscopy (TEM) experiments. The composite is compatible with a pure propylene carbonate (PC) electrolyte and shows high rate capability and excellent cycling performance. The electrochemical properties are comparable to those of hard carbon.

• Transactions on Electrical and Electronic Materials
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• v.15 no.4
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• pp.193-197
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• 2014

Si-carbon composites as anode materials for lithium rechargeable batteries were prepared simply by mixing Si nanoparticles with carbon black and/or graphite through a solution process. Si nanoparticles were well dispersed and deposited on the surface of the carbon in a tetrahydrofuran solution. Si-carbon composites showed more than 700 mAh/g of initial capacity under less than 20% loading of Si nanoparticle in the composites. While the electrode with only Si nanoparticles showed fast capacity fading during continuous cycling, Si-carbon composite electrodes showed higher capacities. The cycle performances of Si nanoparticles in composites containing graphite were improved due to the role of the graphite as a matrix.

• Journal of Ecology and Environment
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• v.42 no.2
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• pp.60-69
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• 2018

Background: This study was conducted from March 2011 to February 2013 in order to evaluate the ecosystem value by examining the organic carbon distribution and cycling in the Quercus glauca forest, evergreen oak community at Seonheul-Gotjawal, Jeju Island. Results: The amount of organic carbon distribution was $124.5ton\;C\;ha^{-1}$ in 2011 and $132.63ton\;C\;ha^{-1}$ in 2012 for aboveground biomass. And it was $31.13ton\;C\;ha^{-1}$ in 2011 and $33.16ton\;C\;ha^{-1}$ in 2012 for belowground biomass. In total, the amount of organic carbon distribution in plants was 155.63 and $165.79ton\;C\;ha^{-1}$ in 2011 and 2012, respectively. In 2011 and 2012 respectively, the amount of organic carbon distribution was 3.61 and $6.39ton\;C\;ha^{-1}$ in the forest floor and it was 78.89 and $100.71ton\;C\;ha^{-1}$ in the soil. As shown, most carbon was distributed in plants. Overall, the amount of organic carbon distribution of the Q. glauca forest was $238.13ton\;C\;ha^{-1}$ in 2011 and $272.89ton\;C\;ha^{-1}$ in 2012. In 2011, the amount of organic carbon fixed in plants through photosynthesis (NPP) was $14.22ton\;C\;ha^{-1}\;year^{-1}$ and the amount of carbon emission of soil respiration was $16.77ton\;C\;ha^{-1}\;year^{-1}$. The net ecosystem production (NEP) absorbed by the Q. glauca forest from the atmosphere was $5ton\;C\;ha^{-1}\;year^{-1}$. Conclusions: The carbon storage value based on such organic carbon distribution was estimated about $23.81mil\;won\;ha^{-1}$ in 2011 and $27.29mil\;won\;ha^{-1}$ in 2012, showing an annual increment of carbon storage value by $3.48mil\;won\;ha^{-1}$. The carbon absorption value based on such NEP was estimated about $500,000won\;ha^{-1}\;year^{-1}$.

• Journal of Industrial and Engineering Chemistry
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• v.68
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• pp.140-145
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• 2018

Bulky carbon layer uniformly distributed with nanoscale $Fe_2O_3$ was prepared via a direct carbonation of $Fe^{3+}$-polyacrylonitrile complexes at $700^{\circ}C$ under $N_2$ flow. The iron oxide carbon composites exhibited an excellent cycling performance for lithium storage with a reversible capacity of ${\sim}810mAh\;g^{-1}$ after 250 cycles at a current rate of $100mA\;g^{-1}$. The enhancement was mainly attributed to dual functions of bulky carbon layer which facilitated the lithium-ion diffusion and accommodated the volume changes of active $Fe_2O_3$ during charge/discharge process. Our novel chemical strategy is quite effective for scalable fabrication of high capacity lithium-storage materials.

• Journal of Wetlands Research
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• v.16 no.3
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• pp.315-325
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• 2014

Valuation of ecosystem services through organic carbon distribution and cycling in the Quercus mongolica forest at Mt. Worak national park were investigated from May 2012 through April 2013. The amount of carbon allocated to above and below ground biomass was 81.94 and 20.53 ton C/ha. Amount of organic carbon in litter layer was 6.49 ton C/ha. Amount of organic carbon within 50 soil depth was 141.23 ton C $ha^{-1}$ $50cm-depth^{-1}$. Total amount of organic carbon in this Quercus mongolica forest was estimated to 250.19 ton C $ha^{-1}$. The estimated amount of won in this Quercus mongolica forest in terms of total organic carbon was about 5.27 million won $ha^{-1}$. The amount of carbon evolved through soil respiration was 7.31 ton C $ha^{-1}yr^{-1}$. The amount of carbon evolved through microbial respiration and root respiration was 3.58 and 3.73 ton C $ha^{-1}yr^{-1}$, respectively. The amount of organic carbon absorbed from the atmosphere of this Quercus mongolica forest was 1.61 ton C $ha^{-1}yr^{-1}$ when estimated from the difference between net primary production and microbial respiration. This amount will come to about 33,000 won $ha^{-1}yr^{-1}$ in Korean currency.

• Journal of Wetlands Research
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• v.17 no.4
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• pp.332-338
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• 2015

Valuation of ecosystem services through organic carbon distribution and cycling in the Pinus densiflora forest at Mt. Worak National Park were investigated from January 2013 through December 2013. The amount of carbon allocated to above and below ground biomass was 32.17 and 8.04 ton C $ha^{-1}$. Amount of organic carbon in litter layer was 5.55 ton C $ha^{-1}$. Amount of organic carbon within 50cm soil depth was 58.62 ton C $ha^{-1}$ 50cm-$depth^{-1}$. Total amount of organic carbon in this Pinus densiflora forest was estimated to 104.38 ton C $ha^{-1}$. The estimated amount of won in this Pinus densiflora forest in terms of total organic carbon was about 10.44 million won $ha^{-1}$. The amount of carbon evolved through soil respiration was 4.44 ton C $ha^{-1}yr^{-1}$. The amount of carbon evolved through microbial respiration and root respiration was 2.18 and 2.27 ton C $ha^{-1}yr^{-1}$, respectively. The amount of organic carbon absorbed from the atmosphere of this Pinus densiflora forest was 0.44 ton C $ha^{-1}yr^{-1}$ when estimated from the difference between net primary production and microbial respiration. This amount will come to about 44,000 won $ha^{-1}$ in Korean currency.

• Journal of Korean Society of Forest Science
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• v.110 no.4
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• pp.569-576
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• 2021

This study developed an estimation model for litterfall input using the stand parameters (basal area, stand density, mean DBH, and carbon stocks of the aboveground tree biomass) collected from the Korean red pine (Pinus densiflora S. et Z.) stands of seven regions in Gyeongsangnam-do. The mean annual litterfall was 2,779 kg ha^-1 year^-1 for needles, 883 kg ha^-1 year^-1 for miscellaneous, 611 kg ha^-1 year^-1 for broadleaved, 513 kg ha^-1 year^-1 for branches, and 340 kg ha^-1 year^-1 for bark litter. The mean annual total litterfall was 5,051 kg ha^-1 year^-1. Litterfall components were significantly correlated with stand parameters, except for broadleaved litter. A stronger correlation was observed between the carbon stock of the aboveground tree biomass and all the litterfall components compared with the other stand variables. The allometric equations for all the litterfall components were significant (P < 0.05), with the stand parameters accounting for 5%-43% and 8%-42% of the variation in the needle litter and total litterfall, respectively. The results indicated that the annual litterfall inputs of the Korean red pine stands on a regional scale can be effectively estimated by allometric equations using the basal area and carbon stocks of the aboveground tree biomass.

• Journal of Electrochemical Science and Technology
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• v.2 no.3
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• pp.157-162
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• 2011

We report a simple route for synthesizing multi-dimensional structured silicon anode materials from commercially available bulk silicon powders via metal-assisted chemical etching process. In the first step, silver catalyst was deposited onto the surface of bulk silicon via a galvanic displacement reaction. Next, the silver-decorated silicon particles were chemically etched in a mixture of hydrofluoric acid and hydrogen peroxide to make multi-dimensional silicon consisting of one-dimensional silicon nanowires and micro-scale silicon cores. As-synthesized silicon particles were coated with a carbon via thermal decomposition of acetylene gas. The carbon-coated multi-dimensional silicon anodes exhibited excellent electrochemical properties, including a high specific capacity (1800 mAh/g), a stable cycling retention (cycling retention of 89% after 20 cycles), and a high rate capability (71% at 3 C rate, compared to 0.1 C rate). This process is a simple and mass-productive (yield of 40-50%), thus opens up an effective route to make a high-performance silicon anode materials for lithiumion batteries.

• Journal of Environmental Science International
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• v.5 no.4
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• pp.429-440
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• 1996

A global carbon cycle model (GCCM), that incorporates interaction among the terrestrial biosphere, ocean, and atmosphere, was developed to study the carbon cycling aid global carbon budget, especially due to anthropogenic $CO_2$ emission. The model that is based on C, 13C and 14C mass balance, was calibrated with the observed $CO_2$ concentration, $\delta$13C and $\Delta$14C in the atmosphere, Δ14C in the soil, and $\Delta$14C in the ocean. Also, GCCM was constrained by the literature values of oceanic carbon uptake and CO, emissions from deforestation. Inputs (forcing functions in the model) were the C, 13C and 14C as $CO_2$ emissions from fossil fuel use, and 14C injection into the stratosphere by bomb-tests. The simulated annual carbon budget of 1980s due to anthropoRenic $CO_2$ shows that the global sources were 5.43 Gt-C/yr from fossil fuel use and 0.91 Gt-C/yr from deforestation, and the sinks were 3.29 Gt-C/yr in the atmosphere, 0.90 Gt-C/yr in the terrestrial biosphere and 2.15 Gt-C/yr in the ocean. The terrestrial biosphere is currently at zero net exchange with the atmosphere, but carbon is lost cia organic carbon runoff to the ocean. The model could be utilized for a variety of studies in $CO_2$ policy and management, climate modeling, $CO_2$ impacts, and crop models.

• ETRI Journal
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• v.38 no.2
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• pp.252-259
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• 2016

Di(1-aminopyrene)quinone (DAQ) as a quinone-containing conducting additive is synthesized from a solution reaction of 1-aminopyrene and hydroquinone. To utilize the conductive property of DAQ and its compatibility with activated carbon, a composite electrode for a supercapacitor is also prepared by blending activated carbon and DAQ (3:1 w/w), and its supercapacitive properties are characterized based on the cyclic voltammetry and galvanostatic charge/discharge. As a result, the composite electrode adopting DAQ exhibits superior electrochemical properties, such as a higher specific capacitance of up to $160F{\cdot}g^{-1}$ at $100mV{\cdot}s^{-1}$, an excellent high-rate capability of up to $1,000mV{\cdot}s^{-1}$, and a higher cycling stability with a capacitance retention ratio of 82% for the 1,000th cycle.