• Title/Summary/Keyword: Carbon Nanotube, CNT

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Characterization of Carbon Nanotube Cathodes with Surface Treatment by Polymer-Based Organic Materials

  • An, Young-Je;Lee, Ji-Eon;Kim, Kye-Sung;Cheon, Ko-Eun;Karim, Md. Anwarul;Cho, Young-Rae
    • 한국정보디스플레이학회:학술대회논문집
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    • 2006.08a
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    • pp.1210-1213
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    • 2006
  • The effect of surface treatment on CNT cathodes used in field emission displays was investigated. A liquid method using a polymer-based organic solution and a mechanical method were applied. The liquid method, using PVA(polyvinyl alcohol) showed high potential compared to the mechanical adhesive taping and rolling method used in the fabrication of CNT cathodes for large-sized field emission displays with high emission uniformity and a low cost.

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Electrochemical Properties of PPy/CNT Electrodes Prepared by Chemical Process for Ultracapacitor

  • Shin, Jeong-Gyun;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.141-144
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    • 2007
  • Polypyrrole(PPy) was composite with MWNT to attain cycle stable by chemical method. We have been considered PPy is the ideal material for high energy density electrochemical capacitor due to pseudo capacitor reaction. In this study we found that increase in cycle life due to composite MWNT. Also PPy/MWNT composite material have resulted larger capacitance and exhibits better electrochemical behavior. The structural feature was investigated by using SEM and TEM. The PPy/CNT composite is not only a promising ultracapacitor material for energy storages but also has a good possibility because of its great capacitive properties, simple preparation and low cost.

Nonlinear Dynamics at the Nanoscale (나노스케일에서의 비선형 동역학)

  • Lee, Soo-Il;Hong, Sang-Hyuk;Park, Jun-Hyung;Lee, Jang-Moo
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2004.11a
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    • pp.125-128
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    • 2004
  • AFM(Atomic Force Microscope) becomes a versatile tool in the nanoscale measurements and processes. Especially the tapping mode is a very useful mode in AFM operation to measure and process at the nanoscale. Although the tapping mode has a great potential for the novel techniques such as phase imaging, however, it is not clearly known the fundamental mechanics affected by complex tip-sample interactions. This paper shows the various nonlinear dynamic features in tapping mode AFM microcantilevers including hysteretic jumps and period doublings of the microcantilevers. Also it is discussed the complex dynamics of CNT(Carbon Nanotube) probes and the opportunities on the nanoscale nonlinear dynamics.

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Multiscale modeling approach for thermal buckling analysis of nanocomposite curved structure

  • Mehar, Kulmani;Panda, Subrata Kumar
    • Advances in nano research
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    • v.7 no.3
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    • pp.181-190
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    • 2019
  • The thermal buckling temperature values of the graded carbon nanotube reinforced composite shell structure is explored using higher-order mid-plane kinematics and multiscale constituent modeling under two different thermal fields. The critical values of buckling temperature including the effect of in-plane thermal loading are computed numerically by minimizing the final energy expression through a linear isoparametric finite element technique. The governing equation of the multiscale nanocomposite is derived via the variational principle including the geometrical distortion through Green-Lagrange strain. Additionally, the model includes different grading patterns of nanotube through the panel thickness to improve the structural strength. The reliability and accuracy of the developed finite element model are varified by comparison and convergence studies. Finally, the applicability of present developed model was highlight by enlighten several numerical examples for various type shell geometries and design parameters.

A Study on Performance Improvement of Glucose Sensor Adopting a Catalyst Using New Cross Liker (새로운 가교제를 적용한 촉매를 이용한 글루코스 센서의 성능향상 연구)

  • Chung, Yongjin;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.53 no.6
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    • pp.802-807
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    • 2015
  • In this study, we synthesized a new biocatalyst consisting of glucose oxidase (GOx), polyethyleneimine (PEI) and carbon nanotube (CNT) with addition of terephthalaldehyde (TPA) (TPA/GOx/PEI/CNT) for fabrication of glucose sensor that shows improved sensing ability and stability compared with that using other biocatalysts. Main bonding of the new TPA/GOx/PEI/CNT catalyst is formed by Aldol condensation reaction of functional end groups between GOx/PEI and TPA. Such formed bonding structure promotes oxidation reaction of glucose. Catalytic activity of TPA/GOx/PEI/CNT is evaluated quantitatively by electrochemical measurements. As a result of that, large sensitivity value of $41{\mu}Acm^{-2}mM^{-1}$ is gained. Regarding biosensor stability of TPA/GOx/PEI/CNT catalyst, covalent bonding formed between GOx/PEI and TPA prevents GOx molecules from becoming leaching-out and contributes improvement in biosensor stability. With estimation of the biosensor stability, it is found that the TPA/GOx/PEI/CNT catalyst keeps 94.6% of its initial activity even after three weeks.

A Study on the Formation of Detection Electrode for the IED Removal Robot by Using A Photosensitive CNT Paste (감광성 CNT 페이스트를 이용한 IED 폭발물 제거로봇 탐지전극 형성에 관한 연구)

  • Kwon, Hye Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.4
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    • pp.231-237
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    • 2018
  • In this study, two important requirements for the home production of a robot to detect and remove improvised explosive devices (IEDs) are presented in terms of the total cost for robot system development and the performance improvement of the mine detection technology. Firstly, cost analyses were performed in order to provide a reasonable solution following an engineering estimate method. As a result, the total cost for a mass production system without the mine detection system was estimated to be approximately 396 million won. For the case including the mine detection system, the total cost was estimated to be approximately 411 million won, in which labor costs and overhead charges were slightly increased and the material costs for the mine detection system were negligible. Secondly, a method for fabricating the carbon nanotube (CNT) based gas detection sensor was studied. The detection electrodes were formed by a photolithography process using a photosensitive CNT paste. As a result, this method was shown to be a scalable and expandable technology for producing excellent mine detection sensors. In particular, it was found that surface treatments by using adhesive taping or ion beam bombardment methods are effective for exposing the CNTs to the ambient air environment. Fowler-Nordheim (F-N) plots were obtained from the electron-emission characteristics of the surface treated CNT paste. The F-N plot suggests that sufficient electrons are available for transport between CNT surfaces and chemical molecules, which will make an effective chemiresistive sensor for the advanced IED detection system.

Effect of intermolecular interactions between CNTs and silane binders on the opto-electrical properties of SWNT/silane binder films (탄소나노튜브와 바인더의 상호작용이 탄소나노튜브/바인더 박막의 정전기적 특성에 미치는 영향)

  • Han, Joong-Tark;Kim, Sun-Young;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.04b
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    • pp.97-98
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    • 2009
  • Here, we describe a versatile strategy for precise control of the optoelectrical properties of the single walled carbon nanotube (SWNT)/silane binder hybrid films by noncovalent hybridization. Stable SWNT/silane binder solutions were prepared by direct mixing of high concentration CNT solutions and silane sol solutions. The critical binder content was determined by varying the amount of binder in the SWNT/binder solutions. A binder content of 50 wt% was used to prepare the other SWNT/binder solutions. This study demonstrates how the intermolecular interactions between the SWNTs and the silanes can affect the conductivity of the CNT/binder network films by characterizing the optoelectrical and Raman spectroscopic properties of the SWNT/silane films containing silane binders with various functional groups. The use of the PTMS binder with phenyl groups was found to be most effective in the fabrication of transparent and conductive films on glass substrates. Such a precise control of the optoelectrical properties of SWNT/binder films can be useful to fabricate the high performance conductive thin films, with ramifications for understanding the fundamental intermolecular interaction in carbon materials science.

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Development of CNT-dispersed Si3N4 Ceramics by Adding Lower Temperature Sintering Aids

  • Matsuoka, Mitsuaki;Yoshio, Sara;Tatami, Junichi;Wakihara, Toru;Komeya, Katsutoshi;Meguro, Takeshi
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.333-336
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    • 2012
  • The study to give electrical conductivity by dispersing carbon nanotubes (CNT) into silicon nitride ($Si_3N_4$) ceramics has been carried out in recent years. However, the density and the strength of $Si_3N_4$ ceramics were degraded and CNTs disappeared after firing at high temperatures because CNTs prevent $Si_3N_4$ from densification and there is a possibility that CNTs react with $Si_3N_4$ or $SiO_2$. In order to suppress the reaction and the disappearance of CNTs, lower temperature densification is needed. In this study, $HfO_2$ and $TiO_2$ was added to $Si_3N_4-Y_2O_3-Al_2O_3$-AlN system to fabricate CNT-dispersed $Si_3N_4$ ceramics at lower temperatures. $HfO_2$ promotes the densification of $Si_3N_4$ and prevents CNT from disappearance. As a result, the sample by adding $HfO_2$ and $TiO_2$ fired at lower temperatures showed higher electrical conductivity and higher bending strength. It was also shown that the mechanical and electrical properties depended on the quantity of the added CNTs.

A X-ray Tube Using Field Emitter Made by Multi-walled Carbon Nanotube Yarns

  • Kim, Hyun-Suk;Castro, Edward Joseph D.;Kwak, Seung-Im;Ju, Jin-Young;Hwang, Yong-Gyoo;Lee, Choong-Hun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.392-392
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    • 2011
  • Carbon nanotubes (CNT) emitter has widely become an attractive mechanism that draws growing interests for cold cathode field emission.$^{1,2}$ CNT yarns have demonstrated its potential as excellent field emitters.$^3$ Extensive simulations were carried out in designing a CNT yarn-based cathode assembly. The focal spot size dependence on the anode surface of the geometric parameters such as axial distance of the electrostatic focus lens from the cathode and the applied bias voltages at the cathode, grid mesh and electrostatic focus lens were studied. The detailed computer simulations using Opera 3D electromagnetic software$^4$ had revealed that a remarkable size of focal spot under a focusing lens triode type set-up design was achieved. The result of this optimization simulation would then be applied for the construction of the CNT yarn based micro-focus x-ray tube with its field emission characteristics evaluated.

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Free vibration analysis of a laminated trapezoidal plate with GrF-PMC core and wavy CNT-reinforced face sheets

  • Yingqun Zhang;Qian Zhao;Qi Han;N. Bohlooli
    • Steel and Composite Structures
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    • v.48 no.3
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    • pp.275-291
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    • 2023
  • This paper has focused on presenting vibration analysis of trapezoidal sandwich plates with 3D-graphene foam reinforced polymer matrix composites (GrF-PMC) core and FG wavy CNT-reinforced face sheets. The porous graphene foam possessing 3D scaffold structures has been introduced into polymers for enhancing the overall stiffness of the composite structure. Also, 3D graphene foams can distribute uniformly or non-uniformly in the plate thickness direction. The effective Young's modulus, mass density and Poisson's ratio are predicted by the rule of mixture. In this study, the classical theory concerning the mechanical efficiency of a matrix embedding finite length fibers has been modified by introducing the tube-to-tube random contact, which explicitly accounts for the progressive reduction of the tubes' effective aspect ratio as the filler content increases. The First-order shear deformation theory of plate is utilized to establish governing partial differential equations and boundary conditions for trapezoidal plate. The governing equations together with related boundary conditions are discretized using a mapping-generalized differential quadrature (GDQ) method in spatial domain. Then natural frequencies of the trapezoidal sandwich plates are obtained using GDQ method. Validity of the current study is evaluated by comparing its numerical results with those available in the literature. It is explicated that 3D-GrF skeleton type and weight fraction, carbon nanotubes (CNTs) waviness and CNT aspect ratio can significantly affect the vibrational behavior of the sandwich structure. The plate's normalized natural frequency decreased and the straight carbon nanotube (w=0) reached the highest frequency by increasing the values of the waviness index (w).