• Title/Summary/Keyword: Carbon Nanotube, CNT

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Preparation of uniformly dispersed iron nanoparticles and growth of carbon nanotube

  • Kim, Do-Yoon;Yoo, Ji-Beom;Berdinsky, A.S.;Park, Chong-Yun;Han, In-Taek;Jung, Jae-Eun;Jin, Yong-Wan;Kim, Jong-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.462-464
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    • 2004
  • We studied the growth characteristics of carbon nanotubes which was grown from uniformly dispersed iron nanoparticles prepared from iron-acetate [Fe(II)$(CH_3COO)_2$]. The density of CNT was controlled from precursor concentrations. We also investigated the field emission properties of CNTs. We found that the optimization of CNT density is an important factor for field_emission properties.

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Structure dependence of carbon nanotube on the process parameters using microwave plasma chemical vapor deposition

  • Kim, Gwang-Bai;Lee, Soo-Myun;Uh, Hyung-Soo;Park, Sang-Sik;Cho, Euo-Sik;Kwon, Sang-Jik
    • 한국정보디스플레이학회:학술대회논문집
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    • 2002.08a
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    • pp.678-680
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    • 2002
  • Vertically aligned carbon nanotubes(CNTs) have been grown on Ni-coated TiN/Si substrate by microwave plasma chemical vapor deposition using $H_2/CH_4$ mixture gas. We have investigated the Effect of process parameters on the growth of CNT. During the growth, microwave power, pressure, and growth temperature were varied from 300 W to 700 W, 10 Torr to 30 Torr, and 300 $^{\circ}C$ to 700 $^{\circ}C$. respectively. Then we controlled the size of CNTs. The structure of CNT was sensitively dependent on the process parameters.

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Synthesis of Silica Coated Carbon Nanotubes by Sol-Gel Method (졸-겔 법에 의한 탄소나노튜브의 실리카 코팅)

  • Lee, Sang-Hun;Kang, Kuk-Hyoun;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.28 no.2
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    • pp.185-195
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    • 2011
  • Carbon nanotube(CNT) plays an essential role in various fields of nano based science and technology. Recently, silica coated CNT composites are interested because they are useful for the optical, magnetical, and catalytic applications. In this report, carboxyl groups were introduced on the MWCNT using nitric acid. In order to maximize the silica encapsulation efficiency, carboxyl groups of MWCNT reacted with a silane coupling agent were used to prepare silica coated MWCNT. Due to their strong interaction between modified MWCNT and TEOS. Silica layer with a controllable thickness was achieved. Silica coated MWCNT were further utilized as the template for the synthesis of hollow silica nanotubes after $800^{\circ}C$ calcination.

Field emission characteristics of CNT-FED using ink-jet printing (잉크젯 프린팅을 이용한 CNT-FED의 전계 방출 특성)

  • Song, Jin-Won;Yoon, Yeo-Hwan;Han, Chang-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.426-426
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    • 2007
  • We report the field emission characteristics of transparent single-walled carbon nanotube (SWNT) film printed using an inkjet. Pure SWNTs dispersed in dimethylformamide were printed in a transparent layer on indium-tin oxide-coated glass and annealed at $350^{\circ}C$. After taping treatment, SWNTs were oriented vertically on the substrate. The front and the back of the fabricated device produced simultaneous emissions of identical quality. In addition, inkjet printing directly achieved a patterned emission, without a secondary pattern process. This method allows simple fabrication using only SWNTs, without the use of other additives.

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Microstructure and Ablation Performance of CNT-phenolic Nanocomposites (삭마 효과에 대한 CNT-페놀 나노복합재료의 미세구조 분석)

  • Wang, Zuo-Jia;Kwon, Dong-Jun;Park, Jong-Kyoo;Lee, Woo-Il;Park, Joung-Man
    • Composites Research
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    • v.26 no.5
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    • pp.309-314
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    • 2013
  • Highly ablation resistant carbon nanotube (CNT)-phenolic composites were fabricated by the addition of low concentrations of CNT nanofiller. Tensile and compressive properties as well as ablative resistance were significantly improved by the addition of only 0.1 and 0.3 wt% of uniformly dispersed CNTs. An oxygen-kerosene-flame torch and a field emission scanning electron microscope (FE-SEM) were used to evaluate the ablative properties and microstructures of these CNT-phenolic composites. Thermal gravimetric analysis (TGA) revealed that the ablation rate was lower for the 0.3 wt% CNT-phenolic composites than for neat phenolic or the composite with 0.1 wt% CNT. Ablative mechanisms for all three materials were investigated using this TGA in conjunction with microstructural studies using a FE-SEM. The microstructural studies revealed that CNT acted as an ablation resistant phase at high temperatures, and that the uniformity of dispersion of the CNT played an important role in this resistance to ablation.

Comparative properties for serial-parallel connection of DSC with CNT and pt counter electrodes (CNT와 Pt 상대전극을 가지는 염료감응형 태양전지의 직렬 ${\cdot}$ 병렬 연결에 따른 특성비교)

  • Choi, Jin-Young;Hong, Ji-Tae;Kim, Mi-Jeong;Lee, Yong-Chul;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.335-338
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    • 2007
  • Cost effectiveness is an important parameter for producing DSSCs as compared to the widely used conventional silicon based solar cells. A fluorine-doped tin oxide (FTO) substrate coated with a catalytic amount of platinum is used as counter electrode in dye-sensitized solar cell. Carbonaceous materials are quite attractive to replace platinum due to their high electronic conductivity, corrosion resistance towards $I_{2}$, good catalytic effect and low cost. In this paper, the unit DSSCs with Pt and CNT as a counter electrode were connected in series-parallel externally, then the current-voltage curves were investigated to find out the connection characteristics of the DSSC with CNT counter electrode. The connection characteristics of the DSSC with CNT counter electrode is superior to that of the DSSC with Pt counter electrode. And a parallel connection of the DSSC with CNT counter electrode has higher efficiency than a series connection of that.

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Improvement of Piezoelectric Performance of the CNT/PVDF Composite Film by Enhancing Conductivity of the PEDOT:PSS Electrodes (PEDOT:PSS 전극의 전도도향상에 의한 CNT/PVDF 복합막의 압전성능 개선)

  • Lim, Young-Taek;Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.29 no.11
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    • pp.716-719
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    • 2016
  • In this paper, we fabricated flexible CNT/PVDF (carbon nanotube / polyvinylidene fluoride) piezoelectric composite device with flexible poly(3,4-ethylenedioxythiophene) : polystyrene sulfonate (PEDOT:PSS) conducting polymer electrode using spray coating method. We tried to improve the piezoelectric performance from the CNT/PVDF composite film by enhancing electrical conductivity of the PEDOT:PSS electrodes. Electrical conductivity of the PEDOT:PSS electrode was enhanced by dipping it into the EG (ethylene glycol) solvent. Changes of chemical composition of the PEDOT:PSS electrode were analyzed with the dipping time by XPS (x-ray photoelectron spectroscopy) in terms of oxygen (O1s). Finally, Piezoelectric performances such as output voltage and current were measured with the dipping time. We found that enhanced electrical conductivity of the PEDOT:PSS electrodes resulted in improvement of the piezoelectric performance of the CNT/PVDF films.

Evaluating Cadmium Ion Removal in Aqueous Solutions and Cytotoxicity Evaluation of Carbon, Synthesized Layered Double Hydroxide, and Multi-wall Carbon Nanotube (활성탄, 합성 층상이중층 수산화물, 카본나노튜브를 이용한 수용액상의 카드뮴의 제거와 흡착제 독성 연구)

  • Kim, Tae-Gyung;Park, Bog-Soung;Jung, Yong-Jun
    • Journal of Korean Society on Water Environment
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    • v.33 no.2
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    • pp.211-218
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    • 2017
  • This experiment was carried out with the purpose of testing cadmium adsorption abilities of multi wall carbon nanotube (MWCNT), activated carbon, and synthesized layered double hydroxide (LDH). In the acidic condition, only MWCNT was effective for removing cadmium ion in the aqueous phase while other adsorbents rarely removed it. The MWCNT and cadmium ion adsorption reactions followed pseudo-first order kinetic. When the initial pH value was neutral (pH = 7), cadmium ion was rapidly removed by MWCNT and activated carbon in 4 hr (100% and 99.2%, respectively). Increasing adsorbent dosages affects the pH evolution and cadmium ion removal (0 to 99%). Cytotoxicity test showed that both MWCNT and LDH has low cytotoxic effects on three kind of human cells (A549, HS-294t, and HT-29).

Characteristics of Pt, Pt-Ru and Pt-CeO2 Catalysts Supported on Carbon Nanotubes for Methanol Fuel Cell (탄소 나노튜브에 담지된 Pt, Pt-Ru 및 Pt-CeO2 메탄올 연료전지 촉매의 특성)

  • Hwang, Gui-Sung;Lee, Rhim-Youl
    • Korean Journal of Materials Research
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    • v.21 no.3
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    • pp.138-143
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    • 2011
  • Nanosized Pt, Pt-Ru and Pt-$CeO_2$ electrocatalysts supported on acid-treated carbon nanotube (CNT) were synthesized by microwave-assisted heating of polyol process using $H_2Cl_6Pt{\cdot}6H_2O$, $RuCl_3$, $CeCl_3$ precursors, respectively, and were characterized by XRD and TEM. And then the electrochemical activity of methanol oxidation for catalyst/CNT nanocomposite electrodes was investigated. The microwave assisted polyol process produced the nano-sized crystalline catalysts particles on CNT. The size of Pt supported on CNT was 7~12 nm but it decreased to 3~5 nm in which 10wt% sodium acetate was added as a stabilizer during the polyol process. This fine Pt catalyst particles resulted in a higher current density for Pt/CNT electrode. It was also found that 10 nm size of PtRu alloys were formed by polyol process and the onset potential decreased with Ru addition. Cyclic voltammetry analysis revealed that the $Pt_{75}Ru_{25}/CNT$ electrode had the highest electrochemical activity owing to a higher ratio of the forward to reverse anodic peak current. And the chronoamperemetry test showed that $Pt_{75}Ru_{25}$ catalyst had a good catalyst stability. The activity of Pt was also found to be improved with the addition of $CeO_2$.

Electron Emission Properties of CNT Arrays Grown with MIcro Molding In Capillary (MIMIC) Assisted Process

  • Lim, Han-Eol;Ryu, Je-Hwang;Lim, Joon-Won;Son, Byoung-Taek;Lee, Yi-Sang;Jang, Jin;Park, Kyu-Chang
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1535-1538
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    • 2008
  • Carbon nanotube arrays were fabricated using micro molding in capillary (MIMIC) process. Patterns remained on the surface in the pattern complementary to that present in the mold. CNTs were selectively grown on the MIMIC patterned sites with a triode PECVD. And turn on field for $10\;{\mu}A/cm^2$ electron emission current was $2.2\;V/{\mu}m$ turn on field.

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