Kim, Sangil;Park, Ji Young;Lee, Kyeongmin;Kim, Seung Won
Journal of Korean Society of Occupational and Environmental Hygiene
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v.26
no.1
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pp.38-47
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2016
Objectives: The objective of this study was to determine the exposure levels of forklift operators to diesel engine exhaust(DEE) using black carbon(BC), elemental carbon(EC), and nitrogen dioxide($NO_2$) as indicators. Methods: A total of eight forklift operators in six collection companies were assessed over a period of two months from July to September 2015. BC was measured using a real-time monitor and respirable EC samples were analyzed using the NIOSH method 5040. $NO_2$ samples were collected using a passive badge-type sampler. Results: The geometric mean of BC, EC and $NO_2$ were $3.1-19.1{\mu}g/m^3$, $2.1-23.8{\mu}g/m^3$, and 12.5-166.6 ppb at all companies. When forklifts were operating both outside and inside, BC concentrations increased 2.0-5.6 times. The highest increase was observed when forklifts were operating indoors. The increase in BC concentrations varied by company(company A: 2.0 times, B: 3.2 times, C: 5.6 times, D: 2.1 times, E: 5.1 times, F: 2.6 times). The geometric mean of BC, EC, and $NO_2$ for the forklift operators was $9.6{\mu}g/m^3$, $7.9{\mu}g/m^3$, and 48.9 ppb, respectively. The geometric mean of BC, EC, and $NO_2$ for manufacturing workers was $9.3{\mu}g/m^3$, $0.9{\mu}g/m^3$, and 85.2 ppb, respectively. The mean BC and EC exposure levels for the forklift operators were slightly higher than those for manufacturing workers, but $NO_2$ levels for manufacturing workers were higher than those for the forklift operators(p>0.05). Multiple regression analysis revealed that diesel exhaust emissions standard, forklift weight and forklift manufacturer were the most influential factors in determining worker exposure. Conclusions: In the DEE work environment, workers who perform tasks within the workplace as well as inside forklifts as operators are likely to be exposed to a lack of ventilation. Further study of forklift operators' exposure to DEE indicators should be conducted to include a wider range of occupational and environmental situations, such as collection procedures, seasonal situations, types of fuel used, and number of forklifts.
Kim, Yong-Tae;Lee, Ho-Kil;Kang, Jeong-Ho;Han, Sung-Bin;Chung, Yon-Jong
Journal of Energy Engineering
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v.17
no.4
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pp.227-232
/
2008
Carbon dioxide is considered a major greenhouse gas that contributes to global wanning. $CO_2$ is a major component of the exhaust in the combustion of any hydrocarbon fuel. The regulation for $CO_2$ emission from vehicles has become much more stringent in recent years. These more stringent regulations require vehicle manufacturers to develop alternative fuels that reduce exhaust emissions. This paper evaluated the correlation of $CO_2$ emission and fuel economy in the Gasoline, Diesel, and LPG vehicles according to FTP-75 and NEDC(ECE15+EUDC) driving mode. From this study, we discovered that the decrease rate of $CO_2$ emission is higher for fuels of lower carbon concentration. When the relationship between $CO_2$ emission and fuel consumption rate according to used fuels is expressed as a function, one can find out that they have a high correlation. LPG vehicles produce less $CO_2$ emission than gasoline and diesel vehicles.
Liquefied petroleum gas (LPG) and compressed natural gas (CNG) are often used as fuel for vehicles because they are clean alternative gas fuels. CNG, as a low-carbon fuel, can contribute to the reduction of greenhouse gas emissions. LPG is often used as fuel for taxis because the performance is almost the same as that of gasoline but the price is lower. In the present study, the exhaust gas and the particle number (PN) of particulate matter, which is a recent environmental issue, were compared between LPG and CNG for the same vehicle. A chassis dynamometer was used to conduct the test according to the Federal Test Procedure (FTP)-75 and Worldwide harmonized Light-duty vehicle Test Procedure (WLTC) modes. The PN values of discharged particles having sizes of 5 nm or larger and 23 nm or larger were measured using two condensation particle counters (CPC). The ratio of carbon dioxide was high in the exhaust gas from the LPG vehicle; the ratio of methane was high in the exhaust gas from the CNG vehicle. The PN values of the emitted particles from the two fuels were similar. The PN values of particles having sizes of 23 nm or smaller were high in the high-speed WLTC mode.
Da Hae Lee;Hyeon Myeong Seo;Yun Ha Song;Jaekyoung Lee
Clean Technology
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v.29
no.3
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pp.163-171
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2023
Hydrogen has been gaining a lot of attention as a possible clean energy source that can aid in reaching carbon neutrality. Currently, hydrogen production has relied on the steam reforming of fossil fuels. However, due to the carbon dioxide emissions caused by this process, hydrogen production based on the steam reforming of bio-oil derived from biomass has been proposed as an alternative approach. In order to use this alternative approach efficiently, one of the key issues that must be overcome is that the complexity of bio-oil, which has a large molecular weight and diverse functional groups of hydrocarbons, promotes the catalytic deactivation of nickel-based catalysts. In this review, research efforts to improve nickel-based catalysts for the steam reforming of bio-oil have been discussed in terms of the active phase, support, and promoters. The active phases are involved in activating C-C and C-H bonds of high-molecular-weight hydrocarbons, and noble and transition metals can be utilized. In terms of the support and promoters, the catalytic deactivation of Ni-based catalysts can be inhibited by utilizing reactive lattice oxygen for support or by suppressing the acidity. The development of active and stable Ni-based reforming catalysts plays a critical role in clean hydrogen production based on bio-oils.
Kim, Jinwoo;Jeon, Min-Kyung;Kwon, Tae-Hyuk;Kim, Nam-Ryong
Journal of the Korean Geotechnical Society
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v.40
no.1
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pp.29-37
/
2024
In this study, recycled concrete aggregates (RCA) were treated in a 5-kg-scale prototype reactor with carbon dioxide (CO2) to enhance their material quality and geotechnical performance. The aggregate crushing value (ACV) and California bearing ratio (CBR) were measured on untreated RCAs and CO2-treated RCAs. After CO2 treatment, the ACV decreased from 35.6% to 33.2%, and the CBR increased from 97.5% to 102.4%. The CO2 treatment caused a reduction of fine particle generation and an increase in bearing capacity through carbonation. When CO2 treatment was performed with mechanical agitation, which provided additional enhancement in mechanical quality, the ACV was reduced further to 30.3%, and the CBR increased to 137.7%. If upscaled effectively, the proposed CO2 treatment technique would be an effective method to reduce carbon emissions in construction industries.
Kim, Jae-Kon;Jeon, Cheol-Hwan;Yim, Eui-Soon;Jung, Choong-Sub;Lee, Sang-Bong;Lee, Yun-Je;Kang, Myung-Jin
Journal of the Korean Applied Science and Technology
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v.29
no.3
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pp.450-458
/
2012
In order to reduce the effects of greenhouse gas (GHG) emissions, the South Korean government has announced a special platform of technologies as part of an effort to minimize global climate change. To further this effort, the Korean government has pledged to increase low-carbon and carbon neutral resources for biofuel derived from biomass to replace fossil and to decrease levels of carbon dioxide. In general, second generation biofuel produced form woody biomass is expected to be an effective avenue for reducing fossil fuel consumption and greenhouse gas (GHG) emissions in road transport. It is important that under the new Korean initiative, pilot scale studies evolve practices to produce biomass-to-liquid (BTL) fuel. This study reports the quality characteristics of F-T(Fischer-Tropsch) diesel for production of BTL fuel. Synthetic F-Tdiesel fuel can be used in automotive diesel engines, pure or blended with automotive diesel, due to its similar physical properties to diesel. F-T diesel fuel was synthesized by Fischer-Tropsch (F-T) process with syngas($H_2$/CO), Fe basedcatalyst in low temperature condition($240^{\circ}C$). Synthetic F-T diesel with diesel compositions after distillation process is consisted of $C_{12}{\sim}C_{23+}$ mixture as a kerosine, diesel compositions of n-paraffin and iso-paraffin compounds. Synthetic F-T diesel investigated a very high cetane number, low aromatic composition and sulfur free level compared to automotive diesel. Synthetic F-T diesel also show The wear scar of synthetic F-T diesel show poor lubricity due to low content of sulfur and aromatic compounds compared to automotive diesel.
Journal of the Korea Institute of Building Construction
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v.24
no.2
/
pp.181-191
/
2024
In the realm of cement manufacturing, concerted efforts are underway to mitigate the emission of greenhouse gases. A significant portion, approximately 60%, of these emissions during the cement clinker sintering process is attributed to the decarbonation of limestone, which serves as a fundamental ingredient in cement production. Prompted by these environmental concerns, there is an active pursuit of alternative technologies and admixtures for cement that can substitute for limestone. Concurrently, initiatives are being explored to harness technology within the cement industry for the capture of carbon dioxide from industrial emissions, facilitating its conversion into carbonate minerals via chemical processes. Parallel to these technological advances, economic growth has precipitated a surge in construction activities, culminating in a steady escalation of construction waste, notably waste concrete. This study is anchored in the innovative production of calcium silicate cement clinkers, utilizing finely powdered waste concrete, followed by a thorough analysis of their mineral phases. Through X-ray diffraction(XRD) analysis, it was observed that increasing the substitution level of waste concrete powder and the molar ratio of SiO2 to (CaO+SiO2) leads to a decrease in Belite and γ-Belite, whereas minerals associated with carbonation, such as wollastonite and rankinite, exhibited an upsurge. Furthermore, the formation of gehlenite in cement clinkers, especially at higher substitution levels of waste concrete powder and the aforementioned molar ratio, is attributed to a synthetic reaction with Al2O3 present in the waste concrete powder. Analysis of free-CaO content revealed a decrement with increasing substitution rate of waste concrete powder and the molar ratio of SiO2/(CaO+SiO2). The outcomes of this study substantiate the viability of fabricating calcium silicate cement clinkers employing waste concrete powder.
In Korea, energy policies are actualized through various energy-related plans. Recently, however, as high-ranking plans, which are very vision-oriented, continually set higher sector-by-sector goals, subordinate action plans, which require consistency, encounter distortions in their establishment process. Also, each subordinate action plan reveals limitations in terms of securing flexibility of the plan in responding to uncertainties of the future. These problems pose potential risks such as causing huge social costs. In this regard, with an aim to provide empirical evidence for discussions on improving the procedure for developing and executing Korea's energy plans, this study mainly analyzes the Basic Plan on Electricity Demand and Supply-one of the most important subordinate action plans-in order to explain the problems of the Basic Plan in a logical manner, and potential problems that could occur in the process of sustaining consistency between the Basic Plan and its higher-ranking plans. Further, this paper estimates the scale of social costs caused by those problems assuming realistic conditions. According to the result, in the case of where maximum electric power is estimated to be 7% (15%) less than the actual amount in the Basic Plan on Electricity Demand and Supply, the annual generation cost will rise by 286 billion won and (1.2 trillion won) in 2020. Such social costs are found to occur even when establishing and executing the Basic plan according to the target goal set by its higher-ranking plan, the National Energy Master Plan. In addition, when another higher-ranking GHG reduction master plan requires the electricity sector to reduce emissions by additional 5% in the GHG emissions from the right mix in electricity generation with 'zero' cost of carbon emission, the annual generation cost will rise by approximately 915 billion won in 2020. On the other hand, the analysis finds that since economic feasibility of electric powers in Korea varies significantly depending on their type, Korea is expected to face very small potential social costs caused by uncertainties over the future price of carbon dioxide in the process of establishing the Basic Plan.
This study was conducted to investigate the effects of dietary garlic and may flower powder on $CO_2$ and $CH_4$ emission by Hanwoo cows fed TMR (Total Mixed Ration) based diet. Animals were housed in a hood-type respiration chamber and the environmental temperature was maintained at $20^{\circ}C$. Gases were measured for 24 hours using the multi-detector instrument gas monitoring system (Mamos-300, Australia). The treatments composed of groups with no intake of garlic and may flower powder (Control), with intake of garlic at 0.5% of DM (T1), with intake of garlic at 1% of DM (T2), with intake of may flower at 0.5% of DM (T3), with intake of may flower at 1% of DM (T4), with intake of garlic and may flower at 0.5% of DM (T5) and with intake of garlic and may flower at 1% of DM (T6). The results indicated that $CO_2$ emission in T3 was 53% lower than that of control (p<0.05), and $CH_4$ emissions was 57% lower than control (p<0.05). Also, the hourly pattern of $CO_2$ and $CH_4$ emissions in T3 showed the least difference with all treatments. Gas emissions pattern peaked after 1 hour of feeding and this gap was wider in the afternoon than in the morning hours.
Kim, JongSu;Choi, SeukCheun;Jeong, SooHwa;Mock, ChinSung;Kim, DooBoem
Clean Technology
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v.28
no.2
/
pp.131-137
/
2022
The semiconductor process currently emits various by-products and unused gases. Emissions containing pollutants are generally classified into categories such as organic, acid, alkali, thermal, and cabinet exhaust. They are discharged after treatment in an atmospheric prevention facility suitable for each exhaust type. The main components of organic exhaust are volatile organic compounds (VOC), which is a generic term for oxygen-containing hydrocarbons, sulfur-containing hydrocarbons, and volatile hydrocarbons, while the main components of alkali exhaust include ammonia and tetramethylammonium hydroxide. The purpose of this study was to determine the combustion characteristics and analyze the NOX reduction rate by maintaining a direct combustion and temperature to process organic and alkaline exhaust gases simultaneously. Acetone, isopropyl alcohol (IPA), and propylene glycol methyl ether acetate (PGMEA) were used as VOCs and ammonia was used as an alkali exhaust material. Independent and VOC-ammonia mixture combustion tests were conducted for each material. The combustion tests for the VOCs confirmed that complete combustion occurred at an equivalence ratio of 1.4. In the ammonia combustion test, the NOX concentration decreased at a lower equivalence ratio. In the co-combustion of VOC and ammonia, NO was dominant in the NOX emission while NO2 was detected at approximately 10 ppm. Overall, the concentration of nitrogen oxide decreased due to the activation of the oxidation reaction as the reaction temperature increased. On the other hand, the concentration of carbon dioxide increased. Flameless combustion with an electric heat source achieved successful combustion of VOC and ammonia. This technology is expected to have advantages in cost and compactness compared to existing organic and alkaline treatment systems applied separately.
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