• Title/Summary/Keyword: Carbon Dioxide Emissions

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Process Design of Carbon Dioxide Storage in the Marine Geological Structure: I. Comparative Analysis of Thermodynamic Equations of State using Numerical Calculation (이산화탄소 해양지중저장 처리를 위한 공정 설계: I. 수치계산을 통한 열역학 상태방정식의 비교 분석)

  • Huh, Cheol;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.11 no.4
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    • pp.181-190
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    • 2008
  • To response climate change and Kyoto protocol and to reduce greenhouse gas emissions, marine geological storage of $CO_2$ is regarded as one of the most promising option. Marine geological storage of $CO_2$ is to capture $CO_2$ from major point sources(eg. power plant), to transport to the storage sites and to store $CO_2$ into the marine geological structure such as deep sea saline aquifer. To design a reliable $CO_2$ marine geological storage system, it is necessary to perform numerical process simulation using thermodynamic equation of state. The purpose of this paper is to compare and analyse the relevant equations of state including ideal, BWRS, PR, PRBM and SRK equation of state. To evaluate the predictive accuracy of the equation of the state, we compared numerical calculation results with reference experimental data. Ideal and SRK equation of state did not predict the density behavior above $29.85^{\circ}C$, 60 bar. Especially, they showed maximum 100% error in supercritical state. BWRS equation of state did not predict the density behavior between $60{\sim}80\;bar$ and near critical temperature. On the other hand, PR and PRBM equation of state showed good predictive capability in supercritical state. Since the thermodynamic conditions of $CO_2$ reservoir sites correspond to supercritical state(above $31.1^{\circ}C$ and 73.9 bar), we conclude that it is recommended to use PR and PRBM equation of state in designing of $CO_2$ marine geological storage process.

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The Long-term Durability Evaluation of PC Box for Near-surface Transit System manufactured by Microwave Heat curing (마이크로웨이브 발열양생에 의해 제작된 저심도 철도시스템용 PC BOX의 장기내구성 평가)

  • Koh, Tae-Hoon;Yoo, Han-Ju
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.4
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    • pp.766-771
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    • 2016
  • This study examined the long-term durability of PC boxes, which was manufactured by low-carbon eco-friendly concrete using an alternative binder to cement and alternative fine aggregate to sand and microwave heat curing system to reduce the construction cost of a near-surface transit system. Based on the test results, the initial compressive strength of microwave heat cured concrete was higher than that of the steam cured concrete, but those were similar in the long-term age. In addition, there was no significant difference between the two curing conditions in the chemical resistance and the freeze-thawing resistance, and the chloride ion penetration level of the concrete cured by two methods was very low. Therefore, low-carbon eco-friendly concrete and microwave heat curing technology are expected to contribute to the economic construction of a near-surface transit system, and reduce carbon dioxide emissions and environmental impact.

A Study on the Experimental Measurements and Its Recovery for the Rate of Boil-Off Gas from the Storage Tank of the CO2 Transport Ship (CO2 수송선 저장탱크의 BOG 측정 실험 및 회수에 관한 연구)

  • Park, Jin-Woo;Kim, Dong-Sun;Ko, Min-Su;Cho, Jung-Ho
    • Clean Technology
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    • v.20 no.1
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    • pp.1-6
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    • 2014
  • $CO_2$ is generated by the combustion reaction, when getting the energy from fossil fuel. If the carbon dioxide emissions increases more, the global warming problem will become more serious. CCS (carbon capture storage) needs to be developed for the prevention of this. When liquefied $CO_2$ is transported, BOG (boil-off gas) is generated because of several problems. In the study, by injecting liquefied $CO_2$ in two tanks which contains $40m^3$each, the amount of BOG and its composition were measured during 30 days when generating pressure changes and external heat, loading, unloading. In result, 16,040 kg of BOG was generated and the composition has been found out to be 99.95% $CO_2$ and 0.05 % $N_2$. Also, we conducted simulation process for reliquefaction of generated BOG with vapor compression cycle using the PRO/II with PROVISION version 9.2. As a result, the refrigeration cycle of the total circulation flow rate was 42.07 kg/h and the condenser utility consumption was 48.85 kg/h.

Comparison of Carbon Budget between Rice-barley Double Cropping and Rice Mono Cropping Field in Gimje, South Korea (국내 벼-보리 이모작지와 벼 단작지의 탄소수지 비교)

  • Shim, Kyo-Moon;Min, Sung-Hyun;Kim, Yong-Seok;Jung, Myung-Pyo;Choi, In-Tae;Kang, Kee-Kyung
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.18 no.4
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    • pp.337-347
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    • 2016
  • Carbon dioxide ($CO_2$) and methane ($CH_4$) were measured in a rice-barley double cropping and rice mono cropping paddy fields, which are located in the southwestern coast of Korea, over a one-year period. Net ecosystems $CO_2$ exchange (NEE) and ecosystem respiration (Re) were estimated by the eddy covariance (EC) method, and an automatic open/close chamber (AOCC) method was used to measure $CH_4$ fluxes. Environmental factors (solar radiation, air temperature, precipitation etc.) were also measured along with fluxes. After the quality control and gap-filling, the observed fluxes were analyzed. As a result, NEE was -603.0 and $-471.5g\;C\;m^{-2}\;yr^{-1}$ in rice-barley double cropping and rice mono cropping paddy field, respectively. $CH_4$ emissions increased during the course of flooded days and were similar in two cropping paddy field. Accoding to rough results considering only fluxes of $CO_2$ and $CH_4$, it was estimated that the carbon absorbation in rice-barley double cropping paddy field was higher than that in rice mono cropping paddy field by $128.9g\;C\;m^{-2}\;yr^{-1}$.

Estimation of Soil Microbiological Respiration Volume in Forest Ecosystem in the Sobaeksan National Park of Korea (소백산국립공원 산림생태계의 토양미생물호흡량 평가)

  • Lee, Sang-Jin;Lee, Chang-Min;Yang, Seung-Ah;Jung, Hae-Joong;Lee, Jong-Myung;Min, Young-Gi;Kim, Jin-Won;Myung, Hyun-Ho;Park, Hong-Chul
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.26 no.3
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    • pp.19-28
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    • 2023
  • The purpose of this study is to estimate carbon dioxide emissions from soil microbial respiration by forest type of Sobaeksan National Park. As a result of estimating the annual soil microbiological respiration volume by forest type in Sobaeksan National Park, broad-leaved forests, coniferous forest, artificial forests were similar to around 19.5 CO2-ton/ha/yr. In the case of coniferous forests in sub-alpine and grassland near Birobong Peak, 12.2 CO2-ton/ha/yr and 8.1 CO2-ton/ha/yr, respectively, were lower than general forest areas. And as a result of analyzing the changes in soil microbiological respiration rate according to forest type in Sobaeksan National Park, the soil microbiological respiration rate in coniferous forests, broad-leaved forests, artificial forests, and sub-alpine areas was the highest in the July survey in summer and the lowest in November in late autumn. The change in soil microbial respiratory volume according to the measurement time in Sobaeksan National Park was the highest between 12:00 and 16:00, when the soil temperature was generally the highest among the days. It is known that the soil temperature is relatively low and the amount of soil microbial respiration decreases during winter, and the change in respiratory volume over the measurement time during the day was the smallest in November, when the amount of soil microbial respiration was relatively smaller than the May-September survey. However, this study has limitations in revealing the causal relationship of various environmental factors that affect the soil microbial respiration. Therefore, it is suggested that long-term research and investigation of various factors affecting soil respiration are needed to understand the carbon cycle of forest ecosystems.

Development of the Multi-mobility Sharing Service Management System - A Case Study of Kashiwa City, Japan -

  • Kim, Jae-Youl;Tsubouchi, Kota;Yamato, Hiroyuki
    • The Journal of The Korea Institute of Intelligent Transport Systems
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    • v.13 no.1
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    • pp.75-85
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    • 2014
  • Existing car-sharing systems have difficulty meeting the demands of one-way trips and connecting to other sharing systems. Therefore, in this study, a multi-mobility sharing service management system that was able to meet the demands of the one-way and round-way trips and shared diverse transportation modes such as cars (electric car/gasoline car), electric motorcycles and bicycles was developed, and a field study was conducted in Kashiwa-no-ha, Kashiwa City and Nagareyama City, Chiba Prefecture, Japan. As a result of the field test, it was confirmed that this system supplied the one-way demands for 54.9% of total car trips and 43.9% of the user used multiple transportation modes by the common interface. In addition, this system contributed to reduce carbon dioxide emissions by sharing vehicles and using eco-friendly vehicles. The developed sharing system is expected to improve mobility by meeting more various types of traffic demand than existing car sharing systems.

Control of Methane Emission in Ruminants and Industrial Application of Biogas from Livestock Manure in Korea

  • Song, Man-K.;Li, Xiang-Z.;Oh, Young-K.;Lee, Chang-Kyu;Hyun, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.24 no.1
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    • pp.130-136
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    • 2011
  • Methane is known to be one of the major greenhouse gases. On a global scale, livestock farming may contribute 18% of total greenhouse gas emissions. Though methane contribution is less than 2% of all the factors leading to global warming, it plays an important role because it is 21 times more effective than carbon dioxide. Methane emission is a direct result of the fermentation process performed by ruminal microorganisms and, in particular, the archael methanogens. Reducing methane emission would benefit both ruminant production and the environment. Methane generation can be reduced by electron-sink metabolic pathways to dispose of the reducing moieties. An alternative way for methane control in the rumen is to apply inhibitors against methanogens. Generating methane from manure has considerable merit because it appears to offer at least a partial solution to two pressing problems-environmental crisis and energy shortage. An obvious benefit from methane production is the energy value of the gas itself. Control of methane emission by rumen microbes in Korea has mainly been focused on application of various chemicals, such as BES and PMDI, that inhibit the growth and activity of methanogens in the rumen. Alternatives were to apply long-chain polyunsaturated fatty acids and oils with or without organic acids (malate and fumarate). The results for trials with methane reducing agents and the situation of biogas production industries and a typical biogas plant in Korea will be introduced here.

Renewable Energy Production by Heat Pump as Renewable Energy Equipment (신재생에너지 기기로서 히트펌프의 신재생에너지 생산량)

  • Hong, Hiki;Choi, Junyoung;Im, Shin Young
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.29 no.10
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    • pp.551-557
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    • 2017
  • Most European economies, Japan, and many governments have made it a major policy to expand the green business by disseminating heat pump technology, which has a large $CO_2$ reduction effect. The heat pump of all heat sources has been recognized as renewable energy and the policy to encourage has been implemented. In the recently revised Renewable Energy Law, the hydrothermal source (surface sea water) heat pump was newly included in renewable energy. In addition, the scope of application of heat pumps has expanded in the mandatory installation of renewable energy for new buildings, remodeling buildings, and reconstructed buildings based on this law. However application to heat pumps using all natural energy as heat source has been put off. In this revision, the ratio of renewable energy to the total energy produced by the heat pump was fixed at 73%, which depends on coefficient of performance of heat pump. The ratio of renewable energy is $1-1.8/COP_H$, and should be calculated including the coefficient of performance of the heat pump. Using a high efficiency heat pump or a high-temperature heat source increases the coefficient of performance and also reduces $CO_2$ emissions. It is necessary to expand the application of heat pumps as renewable energy equipment and to improve the correct calculation of renewable energy production.

A Study on Greenhouse Gas Emission Characteristics for Regional Governments (A Case Study of Jeonbuk Province) (지자체 온실가스 배출특성 분석연구-전라북도 14개 시·군 사례)

  • Jang, Nam-Jung;An, Jeong-Yi;Kim, Tae-Kyun;Im, Seoung-Hyun;Kim, Deug-Soo
    • Journal of Korean Society for Atmospheric Environment
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    • v.27 no.2
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    • pp.225-237
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    • 2011
  • For each local town (6 cities and 8 counties) affiliated with Jeonbuk provincial government, characteristics of greenhouse gas (GHG) emissions were analyzed and key emission areas were drawn to establish mitigation policies of the regional greenhouse gases. National Institute of Environmental Research (NIER) reported that the total greenhouse gas emission of Jeonbuk was 20.93 million $tCO_2e$ in 2006. The inland area of 5 cities and 1 county (Jeonju, Gunsan, Iksan, Jungeup, Kimje, Wanju) covered 82% of total greenhouse gas emission in Jeonbuk, while the rest local towns of the province, mostly from mountainous areas were responsible for the rest of the total GHG emission. The cities and counties having relatively higher emission in Jeonbuk province were influenced dominantly by the emission from energy and waste sections. Also, agricultural section showed similar tendency except industrial cities such as Gunsan and Jeonju. In the internal portion of city and county, energy section showed the highest portion at the range of 72.1 (Sunchang)~97.0% (Jeonju) and agricultural section was at the range of 1.2% (Jeonju)~26.6 (Sunchang). When the portion of energy section was higher, the lower agricultural section. The emission index was applied to decide the key city and county and the potential city and county with two methodologies in this study. It was required that the key emission areas were drawn to establish regional greenhouse gases mitigation policies.

Combustion Characteristics of Gasoline HCCI Engine with DME as an Ignition Promoter (DME를 착화촉진제로 사용한 가솔린 예혼합 압축 착화 엔진의 연소 특성)

  • Yeom, Ki-Tae;Jang, Jin-Young;Bae, Choong-Sik
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.3
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    • pp.178-185
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    • 2006
  • This paper investigates the steady-state combustion characteristics of the Homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out its benefits in exhaust gas emissions. HCCI combustion is an attractive way to lower carbon dioxide($CO_2$), nitrogen oxides(NOx) emission and to allow higher fuel conversion efficiency. However, HCCI engine has inherent problem of narrow operating range at high load due to high in-cylinder peak pressure and consequent noise. To overcome this problem, the control of combustion start and heat release rate is required. It is difficult to control the start of combustion because HCCI combustion phase is closely linked to chemical reaction during a compression stroke. The combination of VVT and DME direct injection was chosen as the most promising strategy to control the HCCI combustion phase in this study. Regular gasoline was injected at intake port as main fuel, while small amount of DME was also injected directly into the cylinder as an ignition promoter for the control of ignition timing. Different intake valve timings were tested for combustion phase control. Regular gasoline was tested for HCCI operation and emission characteristics with various engine conditions. With HCCI operation, ignition delay and rapid burning angle were successfully controlled by the amount of internal EGR that was determined with VVT. For best IMEP and low HC emission, DME should be injected during early compression stroke. IMEP was mainly affected by the DME injection timing, and quantities of fuel DME and gasoline. HC emission was mainly affected by both the amount of gasoline and the DME injection timing. NOx emission was lower than conventional SI engine at gasoline lean region. However, NOx emission was similar to that in the conventional SI engine at gasoline rich region. CO emission was affected by the amount of gasoline and DME.