• Title/Summary/Keyword: Carbon 13

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Organic Carbon Distribution and Budget in the Quercus variabilis Forest in the Youngha valley of Worak National Park (월악산 용하계곡 굴참나무림의 유기탄소 분포 및 수지)

  • NamGung, Jeong;Choi, Hyeon-Jin;Han, A-Reum;Mun, Hyeong-Tae
    • Korean Journal of Environmental Biology
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    • v.26 no.3
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    • pp.170-176
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    • 2008
  • Organic carbon distribution and carbon budget of a Quercus variabilis forest in the Youngha valley of Mt. Worak National Park were investigated. Carbon in above and below ground standing biomass, litter layer, and soil organic carbon were measured from 2005 through 2006. For the estimation of carbon budget, soil respiration was measured. The amount of carbon allocated to above- and below-ground biomass was 56.22 and 13.90 ton C ha$^{-1}$. Amount of organic carbon in annual litterfall was 2.33 ton C ha$^{-1}$ yr$^{-1}$. Amount of soil organic carbon within 50 cm soil depth was 119.14 ton C ha$^{-1}$ 50 cm-depth$^{-1}$. Total amount of organic carbon in this Q. variabilis forest was 193.96 ton C ha$^{-1}$. Of these, 61.43% of organic carbon was allocated in the soil. Net increase of organic carbon in above- and below-ground biomass in this Q. variabilis forest was estimated to 7.68 ton C ha$^{-1}$ yr$^{-1}$. The amount of carbon evolved through soil respiration was 6.21 ton C ha$^{-1}$ yr$^{-1}$. Net amount of 1.47 ton C ha$^{-1}$ yr$^{-1}$ was absorbed from the atmosphere by this Q. variabilis forest.

A Comparison Study between Batch and Continuous Process Simulation for the Separation of Carbon-13 Isotope by Cryogenic Distillation (Methane으로부터 13C 동위원소 분리를 위한 회분식 및 연속식 극저온 증류공정모사 비교 연구)

  • Kim, Jong Hwan;Lee, Doug Hyung;Lee, Euy Soo;Park, Sang Jin
    • Korean Chemical Engineering Research
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    • v.45 no.1
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    • pp.57-66
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    • 2007
  • Natural gases generally consist of mainly $^{12}C$ and about 1.1% of $^{13}C$. It is well known that a stable carbon isotope, $^{13}C$, has been widely used for the applications of medical, pharmaceutical, and agricultural tracers. As a result, the development of the separation and concentrating technology of $^{13}C$ can cause of high value-added products and the possibility of the generation of new carbon materials, In general, there are two kinds of approaches to obtain a stable $^{13}C$ isotope by the separation of cryogenic distillation. One is to obtain a concentrated $^{13}CH_4$ isotope from natural gas. Another approach is to get concentrated $^{13}CO$ by distillation followed by a chemical reaction of $CH_4$ and $H_2O$. In this study, rigorous process simulations of the cryogenic distillation have been performed and analyzed for the concentrated separation of $^{13}C$ isotopes from LNG and NG by using commercial process simulator. Due to the very small differences of relative volatilities and separabilities of $^{12}C$ and $^{13}C$, the process design and operation of effective separation and concentration of $^{13}C$ need special strategies and feasibility studies. Utilization of vapor pressure data to acentric factor in SRK equation of state and optimized process conditions have been able to predict for the effective of the separation yield and concentration of $^{13}C$ for the cryogenic distillation. The various operation strategies for both batch and continuous cryogenic distillation are also studied and suggested for the basic design of the process. Development of this study can provide a tool for the effective design and operation of the cryogenic separation of $^{13}C$.

Effectiveness of Electromagnetic Interference Shielding of Carbon Nanofiber/Poly(vinylidene fluoride) Composites as a Function of Beat Treatment Temperature and Time (열처리 온도와 시간에 따른 나노탄소섬유/PVDF 복합재의 전자파 차폐 특성)

  • 김명수;이방원;우원준;안광희
    • Polymer(Korea)
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    • v.25 no.3
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    • pp.367-374
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    • 2001
  • The electromagnetic interference (EMI) shielding effectiveness (SE) of poly(vinylidene fluoride) (PVDF) composites was investigated using carbon nanofiber fillers prepared by catalytic chemical vapor deposition of various carbon-containing gases over Ni and Ni-Cu catalysts. The electrical conductivity of carbon nanofiber which was regarded as the key property of filler for the application of EMI shielding ranged from 4.2 to 22.4 S/cm at a pressure of 10000 psi. The electrical conductivity of carbon nanofiber/PVDF composites ranged from 0.22 to 2.46 S/cm and the EMI SE of those was in the range of 2∼13 dB. The electrical conductivity of carbon nanofibers increased with the increase in heat treatment temperature and time, while the electrical conductivity of the composites increased rapidly at the initial heat treatment and then approached a certain value with the further increase of heat treatment. The SE of the composites showed a maximum at the medium heat treatment and was proportional to the electrical conductivity of the composites. It was concluded that the specific surface area of carbon nanofibers decreased with the continual heat treatment and the specific surface area of filler was an important factor for the SE of the composites.

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Breakthrough behaviour of NBC canister against carbon tetrachloride: a simulant for chemical warfare agents

  • Srivastava, Avanish Kumar;Shah, D.;Mahato, T.H.;Singh, Beer;Saxena, A.;Verma, A.K.;Shrivastava, S.;Roy, A.;Yadav, S.S.;Shrivastava, A.R.
    • Carbon letters
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    • v.13 no.2
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    • pp.109-114
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    • 2012
  • A nuclear, biological, chemical (NBC) canister was indigenously developed using active carbon impregnated with ammoniacal salts of copper (II), chromium (VI) and silver (I), and high efficiency particulate aerosol filter media. The NBC canister was evaluated against carbon tetra chloride ($CCl_4$) vapours, which were used as a simulant for persistent chemical warfare agents under dynamic conditions for testing breakthrough times of canisters of gas masks in the National Approval Test of Respirators. The effects of $CCl_4$ concentration, test flow rate, temperature, and relative humidity (RH) on the breakthrough time of the NBC canister against $CCl_4$ vapour were also studied. The impregnated carbon that filled the NBC canister was characterized for surface area and pore volume by $N_2$ adsorption-desorption isotherm at liquid nitrogen temperature. The study clearly indicated that the NBC canister provides adequate protection against $CCl_4$ vapours. The breakthrough time decreased with the increase of the $CCl_4$ concentration and flow rate. The variation in temperature and RH did not significantly affect the breakthrough behaviour of the NBC canister at high vapour concentration of $CCl_4$, whereas the breakthrough time of the NBC canister was reduced by an increase of RH at low $CCl_4$ vapour concentration.

The Analysis of Wear Phenomena on Added Carbon Content Gas Atmosphere in Ion-Nitriding (이온질화에 있어서 가스중 첨가탄소량에 대한 마모현상 분석)

  • 조규식
    • Tribology and Lubricants
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    • v.13 no.2
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    • pp.96-104
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    • 1997
  • This paper was focused on the wear characteristics of ion-nitrided metal and with ion-nitride processing, which is basically concerned with the effects of carbon content in workpiece and added carbon content gas atmosphere on the best wear performance. Increased carbon content in workpiece increases compound layer thickness, but decreases diffusion layer thickness. On the other hand, a small optimal amount of carbon content in gas atmosphere increase compound layer thickness as well as diffusion layer thickness and hardness. Wear tests show that the compound layer of ion-nitrided metal reduces wear rate when the applied wear load is small. However, as the load becomes large, the existence of compound layer tends to increase wear rate. Compressive residual stress at the compound layer is the largest at the compound layer, and decreases as the depth from the surface increases. It is found in the analysis that under small applied load, the critical depth where voids and cracks may be created and propagated is located at the compound layer, so that the adhesive wear is created and the existence of compound layer reduces the amount of wear. When the load becomes large, the critical depth is located below the compound layer and delamination, which may explained by surface deformation, crack nucleation and propagation, is created and the existence of compound layer increases wear rate. For the compound layer, at added carbon contents of 0 percent and 0.5 at. percent, the $\varepsilon$ monophase is predominant. But at 0.7 at. percent added carbon, the $\varepsilon$ monophase formation tends to be severely inhibited and r' and $Fe_3C$ polyphase formation becomes dominant. This increased hard $\varepsilon$ phase layer was observed to be more beneficial in reducing friction and wear.

Synthesis of Hollow Mesoporous Carbon Nitride Spheres Using Polystyrene Spheres as Template (폴리스티렌 구형입자를 주형으로 이용한 할로우 메조포러스 질화탄소 구형입자의 합성)

  • Park, Sung Soo;Ha, Chang-Sik
    • Journal of Adhesion and Interface
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    • v.15 no.2
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    • pp.63-68
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    • 2014
  • Hollow mesoporous carbon nitride material with sphere shape was synthesized using polystyrene sphere as template and cyanamide as nitrogen and carbon atom sources via thermal treatment process. The process of the silica removal is not necessary because silica as template is not in use for the synthesis of hollow mesoporous carbon nitride material and any solvents are also not in use. The size of polystyrene spheres was about 170 nm. Hollow diameter and wall thickness were 82 nm and 13 nm, respectively, in hollow mesoporous carbon nitride sphere. Surface area, mesopore size and pore volume of hollow mesoporous carbon nitride material was $188m^2g^{-1}$, 3.8 nm and $0.35cm^3g^{-1}$, respectively. The wall in hollow sphere has graphitic structure. Hollow mesoporous carbon nitride material has potential applications in the area of fuel cell, catalysis, photocatalysis, electroemmision device, etc.

Is there a causal effect between agricultural production and carbon dioxide emissions in Ghana?

  • Owusu, Phebe Asantewaa;Asumadu-Sarkodie, Samuel
    • Environmental Engineering Research
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    • v.22 no.1
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    • pp.40-54
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    • 2017
  • According to FAO, "agricultural sectors are particularly exposed to the effects of climate change and increases climate variability". As a result, the study makes an attempt to answer the question: Is there a causal effect between agricultural production and carbon dioxide emissions in Ghana? By employing a time series data spanning from 1960 to 2015 using the Autoregressive Distributed Lag method. There was evidence of a long-run equilibrium relationship running from copra production, corn production, green coffee production, milled rice production, millet production, palm kernel production and sorghum production to carbon dioxide emissions. The short-run equilibrium relationship shows that, a 1% increase in copra and green coffee production will increase carbon dioxide emissions by 0.22% and 0.03%, a 1% increase in millet and sorghum production will decrease carbon dioxide emissions by 0.13% and 0.11% in the short-run while a 31% of future fluctuations in carbon dioxide emissions are due to shocks in corn production. There was bidirectional causality between milled rice production and carbon dioxide emissions, millet production and carbon dioxide emissions and, sorghum production and carbon dioxide emissions; and a unidirectional causality running from corn production to carbon dioxide emissions and carbon dioxide emissions to palm kernel production.

Mechanical Strength Experiment of Carbon/Carbon Composite for Aircraft Brake Disk (탄소/탄소 브레이크 디스크의 기계적 강도 시험에 관한 연구)

  • 유재석;오세희;김천곤;홍창선;윤병일;김광수
    • Composites Research
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    • v.13 no.6
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    • pp.55-62
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    • 2000
  • The strength test was done for the Carbon/Carbon rotor disk which is the critical part of a carbon/carbon brake system in an operating time. The loading fixture was designed for the static strength test of a single carbon/carbon brake disk using finite element analysis. To simulate the real dynamic system in a static condition, the friction surface of the rotor disk was fixed and static load was applied to the rotor slot in the circumferential direction. The described failure mechanism of the brake disk can be described as matrix cracking occurred first at the contact surface of the rotor slot, subsequent delamination from the cracked contact surface, and the final fracture at the notch of the rotor.

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Purification of Water Contaminants Using Activated Carbon Fiber Filter with Phenolic Resin Coated on Glass Fibers as a Precursor

  • Baek, Il-Hyun
    • Carbon letters
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    • v.1 no.2
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    • pp.82-86
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    • 2000
  • The present research was undertaken to evaluate the possibility of water purification filter with activated carbon fibers (ACFs) using a very low cost precursor consisting of phenolic resin coated on glass fibers. The simplified procedure involving coating, curing and activation and a very low cost glass fiber as a raw material were adopted in order to reduce manufacturing cost. The breakthrough curves of the manufactured ACFs and the commercial activated carbon (AC, Calgon F-200) were investigated in the initial concentration range from 19 to 49 ppm for benzene, toluene and ethylbenzene. From breakthrough profiles, the manufactured ACFs had significantly faster adsorption kinetics than the AC. Especially the benzene breakthrough curves, the manufactured ACF (13 g of ACF with 32% of carbon on the glass) was over the limited level (5 ppb) after flowing of 32 l at initial concentration of 15 ppm, while the commercial AC was shown about 3 ppm in initial adsorption.

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Development of a Strain Gauge for Sensing Large Strain (대 변형 감지용 스트레인게이지 개발)

  • Lee, Young Tae;Cho, Seung Woo
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.4
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    • pp.33-36
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    • 2014
  • In this paper, a carbon strain gauge for large strain was developed. The carbon strain gauge was fabricated by forming PCB and antenna pattern using Cu/Ni/Au film and carbon resistor pattern using screen printing process on plastic film substrate. It was possible to develop low-cost disposable strain gauge since the carbon paste was cheap and the fabrication process was simple. The wireless communication type carbon strain gauge was fabricated by integrating signal processing circuit, antenna and power all together on the same substrate as a strain gauge. The wireless communication type carbon strain gauge has a merit of being available immediately at the spot without any particular system.