• 제목/요약/키워드: Carbon/carbon-based materials

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폐수중 항생제의 막기반 제거에 관한 연구: 검토 (Membrane Based Removal of Antibiotics from Wastewater: A Review)

  • 류완키;라즈쿠마 파텔
    • 멤브레인
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    • 제34권2호
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    • pp.96-104
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    • 2024
  • 항생제는 과도한 사용으로 인해 폐수뿐만 아니라 다양한 수원에서 발견되는 새로운 오염 물질 중 하나입니다. 수중 항생제 오염 물질을 처리하기 위한 고도 산화 공정, 생물학적 처리 등 다양한 기술이 있습니다. 이 두 가지 공정은 비효율적이며, 부산물의 생성은 이 공정을 더욱 복잡하게 만듭니다. 오염 물질을 제거하기 위한 또 다른 대안으로 막 기술이 있습니다. 항생제와 내성 유전자의 제거를 개선하기 위해 막 생물 반응기는 NaClO와 탄소 물질로 변형됩니다. 풍부한 반응성 종의 생성은 항생제의 내성 유전자에 대해 활성입니다.

Aging Mechanisms of Lithium-ion Batteries

  • Jangwhan Seok;Wontae Lee;Hyunbeom Lee;Sangbin Park;Chanyou Chung;Sunhyun Hwang;Won-Sub Yoon
    • Journal of Electrochemical Science and Technology
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    • 제15권1호
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    • pp.51-66
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    • 2024
  • Modern society is making numerous efforts to reduce reliance on carbon-based energy systems. A notable solution in this transition is the adoption of lithium-ion batteries (LIBs) as potent energy sources, owing to their high energy and power densities. Driven by growing environmental challenges, the application scope of LIBs has expanded from their initial prevalence in portable electronic devices to include electric vehicles (EVs) and energy storage systems (ESSs). Accordingly, LIBs must exhibit long-lasting cyclability and high energy storage capacities to facilitate prolonged device usage, thereby offering a potential alternative to conventional sources like fossil fuels. Enhancing the durability of LIBs hinges on a comprehensive understanding of the reasons behind their performance decline. Therefore, comprehending the degradation mechanism, which includes detrimental chemical and mechanical phenomena in the components of LIBs, is an essential step in resolving cycle life issues. The LIB systems presently being commercialized and developed predominantly employ graphite anode and layered oxide cathode materials. A significant portion of the degradation process in LIB systems takes place during the electrochemical reactions involving these electrodes. In this review, we explore and organize the aging mechanisms of LIBs, especially those with graphite anodes and layered oxide cathodes.

A critical review of fluoride removal from water by using different types of adsorbents

  • Prashant S. Lingayat;Rampravesh K. Rai
    • Advances in environmental research
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    • 제12권2호
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    • pp.77-93
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    • 2023
  • The water can be contaminated by natural sources or by industrial effluents. One such contaminant is fluoride. Fluoride contamination in the water environment due to natural and artificial activities has been recognized as one of the major problems worldwide. Among the commonly used treatment technologies applied for fluoride removal, the adsorption technique has been explored widely and offers a highly efficient simple and low-cost process for fluoride removal from water. This review paper the recent developments in fluoride removal from surface water by adsorption methods. Studies on fluoride removal from aqueous solutions using various carbon materials are reviewed. Various adsorbents with high fluoride removal capacity have been developed, however, there is still an urgent need to transfer the removal process to an industrial scale. Regeneration studies need to be performed to more extent to recover the adsorbent in field conditions, enhancing the economic feasibility of the process. Based on the review, technical strategies of the adsorption method including the Nano-surface effect, structural memory effect, anti-competitive adsorption and ionic sieve effect can be proposed. The design of adsorbents through these strategies can greatly improve the removal efficiency of fluoride in water and guide the development of new efficient methods for fluoride removal in the future. This paper describes brief discussions on various low-cost adsorbents used for the effective removal of fluoride from water.

The effect of ventilation on reducing the concentration of hazardous substances in the indoor air of a Korean living environment

  • Kim, Hyunjoo;Kim, Jin Seog;Lee, Jongman;Kim, Dalho
    • 분석과학
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    • 제33권1호
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    • pp.49-57
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    • 2020
  • Controlling the quality of indoor air is important in order to maintain a healthy life. In this study, we investigated the correlation between the hazardous substance concentration of indoor air and circulation based on different ventilation methods in the apartment, which is one of the representative housing types in Korea. As target substances, we considered the hazardous substances which are generated during the cooking process and radon gas which is originated from building materials. We measured the concentrations of carbon dioxide and fine particles in relation to type of food and ventilation methods in order to determine the change in the concentration levels of hazardous substances which are generated during the cooking process. On the other hand, we measured the concentration of radon gas before and after letting fresh air into a room through windows in order to determine the change in the concentration level of radon gas which is originated from building materials. The results show that turning on the ventilation fan plays a major role in reducing the concentration levels of hazardous substances in the kitchen, and that it is more effective to turn on the ventilation fan during cooking than after cooking to prevent the diffusion of hazardous materials produced by cooking through the indoor air. Also, the results indicate that letting fresh air into a room through windows more than one time a day is necessary to reduce the concentration level of radon gas in the room to safe concentration range.

Compressive behavior of galvanized steel wire mesh (GSWM) strengthened RC short column of varying shapes

  • Marthong, Comingstarful
    • Structural Monitoring and Maintenance
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    • 제7권3호
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    • pp.215-231
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    • 2020
  • In a reinforced concrete building different shapes of column are adopted depending on the structural orientation and the architectural aspect. When there is an increase in loading due to changes in usage or revision in the design codes these columns need to be strengthened for enhanced performance during their service life. Strengthening materials such as carbon fiber and glass fiber polymer has been successfully used however, due to high cost application other alternative materials need to be explore. Galvanized steel wire mesh (GSWM) is one of the suitable materials locally available. High tensile strength, low weight, corrosion resistance, easy installation, minimum change in dimensions of the sections and cost effectives are the advantages of GSWM. Therefore, in this paper, four different shapes of column such as circular, square, rectangular and L were wrapped with different layers GSWM and jacketed with mortar. All the specimens were tested under axial compression. The objective of the study is to investigate the effectiveness of GSWM as a confining material for strengthening of column having varying shape. Test results shows that the axial strength enhanced with wrapping of GSWM jacket and a circular column presented the highest load carrying capacity and ductility as compared to the others. From the study of 22 column specimens, it is found that axial load is increased upto 20% and 19% when circular and square column are strengthened with one wrap of GSWM respectively, while a rectangular and L column required a wraps of two and three layers respectively in order to achieved the same load capacity as that of a circular column. Based on the present study, it is concluded that GSWM can be effectively used for strengthening of different shapes of concrete columns economically.

더블 PI:PCBM 유전체 층 기반의 초 저전력 CNT 시냅틱 트랜지스터 (Ultra-Low Powered CNT Synaptic Transistor Utilizing Double PI:PCBM Dielectric Layers)

  • 김용훈;조병진
    • 한국재료학회지
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    • 제27권11호
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    • pp.590-596
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    • 2017
  • We demonstrated a CNT synaptic transistor by integrating 6,6-phenyl-C61 butyric acid methyl ester(PCBM) molecules as charge storage molecules in a polyimide(PI) dielectric layer with carbon nanotubes(CNTs) for the transistor channel. Specifically, we fabricated and compared three different kinds of CNT-based synaptic transistors: a control device with $Al_2O_3/PI$, a single PCBM device with $Al_2O_3/PI:PCBM$(0.1 wt%), and a double PCBM device with $Al_2O_3/PI:PCBM$(0.1 wt%)/PI:PCBM(0.05 wt%). Statistically, essential device parameters such as Off and On currents, On/Off ratio, device yield, and long-term retention stability for the three kinds of transistor devices were extracted and compared. Notably, the double PCBM device exhibited the most excellent memory transistor behavior. Pulse response properties with postsynaptic dynamic current were also evaluated. Among all of the testing devices, double PCBM device consumed such low power for stand-by and its peak current ratio was so large that the postsynaptic current was also reliably and repeatedly generated. Postsynaptic hole currents through the CNT channel can be generated by electrons trapped in the PCBM molecules and last for a relatively short time(~ hundreds of msec). Under one certain testing configuration, the electrons trapped in the PCBM can also be preserved in a nonvolatile manner for a long-term period. Its integrated platform with extremely low stand-by power should pave a promising road toward next-generation neuromorphic systems, which would emulate the brain power of 20 W.

Control of Algal Blooms in Eutrophic Water Using Porous Dolomite Granules

  • Huh, Jae-Hoon;Choi, Young-Hoon;Lee, Shin Haeng;Cheong, Sun Hee;Ahn, Ji Whan
    • 한국세라믹학회지
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    • 제54권2호
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    • pp.108-113
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    • 2017
  • The use of aluminum-based coagulants in water pretreatment is being carefully considered because aluminum exposure is a risk factor for the onset of Alzheimer's disease. Lightly burned-dolomite kiln dust (LB-DKD) was evaluated as an alternative coagulant because it contains high levels of the healthful minerals calcium and magnesium. An organic pore forming agent (OPFA) was incorporated to prepare porous granules after OPFA removal through a thermal decomposition process. A spray drying method was used to produce uniform and reproducible spherical granules with low density, since fine dolomite particles have irregular agglomeration behavior in the hydration reaction. The use of fine dolomite powder and different porosity granules led to a visible color change in raw algae (RA) containing water, from dark green to transparent colorlessness. Also, dolomite powders and granules exhibited a mean removal efficiency of 48.3% in total nitrogen (T-N), a gradual increase in the removal efficiency of total phosphorus (T-P) as granule porosity increased. We demonstrate that porous dolomite granules can improve the settling time and water quality in summer seasons for the emergent treatment of excessive algal blooms in eutrophic water.

복합재료의 인증, 동등성 및 수락시험 (Material Qualification, Equivalency, and Acceptance Test for Aerospace Composite Materials)

  • 이호성
    • Composites Research
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    • 제19권2호
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    • pp.1-6
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    • 2006
  • 복합재료를 사용하여 우주항공 부품을 설계할 때 국내는 물론, 미국을 비롯한 우주항공선진국의 감항규정에서 민간과 군용 모두 통계적으로 산출된 값을 사용할 것을 요구하고 있다. 그러나 이 기준을 만족하기 위해서는 방대한 데이터베이스가 필요하여 시험 비용 및 시간이 큰 문제가 되어왔다. 최근 미국 NASA/FAA에서 시험 개수를 줄이면서 동시에 통계적 기준을 만족할 수 있는 새로운 설계허용값 산출방법을 AGATE 프로그램을 통해서 개발하였다. 특히 이미 인증된 재료를 다른 사업에 사용하기 위해서 사용할 수 있는 재료동등성 시험(Material Equivalency Test)은 국내의 사업에 직접 적용할 수 있는 중요한 개념이다. 본 논문에서는 국내에서 사용하고 있는 복합재료의 특성을 공유하여 비용을 절감하고 재료특성을 정확히 관리할 목적으로 재료 동등성 및 수락시험 절차를 설명하고, 예로서 국내에서 개발한 고온용 탄소복합재료의 설계허용값을 산출하였다.

불용성 폴리머가 탄소섬유 보강 Polymer-MDF 시멘트 복합재료의 기계적 특성에 미치는 영향 (The Effects of Insoluble Polymers on Water Stability of Carbon Fiber Reinforced Polymer-MDF Cementitious Composites)

  • 김태진;박춘근
    • Composites Research
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    • 제12권3호
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    • pp.84-90
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    • 1999
  • HAC/PVA계 MDF시멘트 복합재료의 수분안정성 및 기계적 강도향상을 위하여 불용성 폴리머류(폴리우레탄, 페놀, 에폭시수지)와 탄소섬유(길이3mm)를 1-4wt% 보강하였다. 그리고 가압성형법으로 제조한 복합체의 수분침적 기간별 강도특성(수분안정성)과 계면 및 기계적 특성에 영향을 미치는 폴리머와 시멘트의 가교반응에 대하여 SEM 및 TEM 분석을 통하여 관찰하였다. HAC/PVA계 MDF 시멘트 복합체의 섬유함량에 따른 건조 굽힘강도는 섬유함량이 증가할수록 치밀화 구조가 저하되어 비례적으로 감소되었다. 또한 불용성 폴리머류를 사용한 경우에 건조 굽힘강도는 섬유함량이 증가될수록 저하되는 반면, 수분안정성은 크게 향상되었다. 에폭시 수지를 첨가한 경우에 수분안정성이 가장 우수하였으며, 섬유함량 4% 첨가의 경우에 3일 침적강도가 95%, 7일침적시 87%강도를 유지하였다. 이 점은 폴리머와 시멘트의 금속이온이 가교반응을 일으켜 섬유-메트릭스간 계면 부착강도를 크게 개선되었기 때문으로 추정된다. 반면 인장강도 특성은 모든 불용성 폴리머류 첨가 수준에서 섬유 함량이 증가할수록 비례적으로 증가되었으며, 역시 에폭시 수지 첨가의 경우에 강도특성이 가장 우수하였다. 그리고 섬유함량 4% 첨가된 경우에 있어서 인장강도는 섬유함량 0% 대비 약 30~80% 높게 나타났다.

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전과정평가 도입을 통한 농업환경영향 평가 (Environmental Impact Assessment of Agricultural Systems Using the Life Cycle Assessment)

  • 심교문;정지선;소규호;임송택;노기안;김건엽;정현철;이덕배
    • 한국토양비료학회지
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    • 제43권2호
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    • pp.237-241
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    • 2010
  • 전 세계적으로 지구온난화의 원인인 대기 중 온실가스 농도를 감축하는 여러 정책들이 모든 산업을 망라하여 추진되고 있다. 식량안보라는 특수성은 있지만, 농업도 예외는 아니다. 이런 취지에서 최근에 농산물의 전체 생산과정에서 발생하는 탄소배출량을 산정하고, 이를 토대로 탄소배출량이 적은 농산물 생산방식을 도입하고자 하는 요구가 증가하고 있다. LCA 도구를 농업분야의 환경평가에 적용한 해외 연구 사례들을 살펴보면, 스위스는 Ecoinvent가 주축이 되어 농작물, 농업기반시설, 농자재, 농기계 등 농축산 전반에 대한 LCI D/B를 구축하여 제공하고 있고, 우리와 농업시스템이 유사한 일본은 산업연관분석을 이용하여 농업을 위한 Top-down 방식의 LCA 수행 방법론을 개발하였으며, 이를 농작물 생산 방식에 따라 평가하고 농업분야에 대한 영향평가 방법론과 가중치를 개발하였다. 반면에 국내의 LCA를 통한 농업환경영향평가는 출발 단계에 있다. 따라서 농업환경에 있어 주요 인자인 비료 및 농약에 대한 환경영향을 평가하고 이를 위한 국내 비료와 농약의 흐름 모델링, 방법론 개발이 요구되며, 국내 농업 시스템을 반영한 기타 농자재, 농기계 및 농업기반시설에 대한 환경영향평가 역시 수행되어야 한다.