• Title/Summary/Keyword: Capillary Radius

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Kelvin Equation and Its Role in Nano Systems (켈빈 식과 이의 나노 계에서의 구실)

  • Lim, Kyung-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.23 no.1
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    • pp.54-62
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    • 2006
  • Kelvin equation is revisited, which accounts for important phenomena observed frequently in nano-dispersion systems. They include vapor pressure increase for curved interfaces, nucleation, capillary condensation, Ostwald ripening and so on. The smaller the radius of curvature is, the more significant Kelvin equation becomes. Therefore, its meaning, curvature effect, and importance are examined and discussed.

Prediction of Soil-Water Characteristic Curve and Relative Permeability of Jumunjin Sand Using Pore Network Model (공극 네트워크 모델을 이용한 주문진표준사의 함수특성곡선 및 상대투수율 예측에 관한 연구)

  • Suh, Hyoung Suk;Yun, Tae Sup;Kim, Kwang Yeom
    • Journal of the Korean Geotechnical Society
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    • v.32 no.1
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    • pp.55-62
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    • 2016
  • This study presents the numerical results of soil-water characteristic curve for sandy soil by pore network model. The Jumunjin sand is subjected to the high resolution 3D X-ray computed tomographic imaging and its pore structure is constructed by the web of pore body and pore channel. The channel radius, essential to the computation of capillary pressure, is obtained based on the skeletonization and Euclidean Distance transform. The experimentally obtained soil-water characteristic curve corroborates the numerically estimated one. The pore channel radius defined by minimum radii of pore throat results in the slightly overestimation of air entry value, while the overall evolution of capillary pressure resides in the acceptable range. The relative permeability computed by a series of suggested models runs above that obtained by pore network model at high degree of saturation.

Effects of the Mass of Working Fluid on the Thermal Performance of Heat Pipe with Axial Grooves (그루브형 히트파이프에서 작동유체량이 히트파이프 성능에 미치는 영향)

  • Suh, Jeong-Se;Park, Young-Jun
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.15 no.1
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    • pp.1-8
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    • 2003
  • An analytical and experimental study of the thermal performance of axial heat pipe with axial groove is conducted to determine the optimal mass of working fluid for the maximum heat transport capacity of heat pipe with axial grooves. Generally, the mass of working fluid has been fully charged by considering only a geometrical shape of axial grooves embedded in a heat pipe. When the heat pipe is operated in a steady state, the meniscus re-cession phenomena of working fluid is occurred in the evaporator region. In this work, the optimal mass of working fluid was obtained from the axial variation of capillary pressure, the radius of curvature and wetting angle of meniscus of liquid-vapor interface. Experimental results were also obtained by varying the mass of working fluid within a heat pipe, and presented for the maximum heat transport capacity corresponding to the operating temperature and the elevation of heat pipe. Finally, the analytical results of the optimal mass of working fluid were compared with those of the experimental mass of working fluid.

Effects of the Charging Mass of Working Fluid on the Thermal Performance of Heat Pipe with Axially Grooved Wick

  • Suh, Jeong-Se;Kang, Chang-Ho;Hong, Jung-Kyu
    • International Journal of Air-Conditioning and Refrigeration
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    • v.12 no.2
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    • pp.79-86
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    • 2004
  • An analytical and experimental study has been conducted to determine the optimal charging mass of working fluid for the maximum heat transport capacity of heat pipe with axially grooved wick. When the heat pipe is operated in a steady state, the liquid-vapor meniscus recession of working fluid to the bottom of groove is occurred in the evaporator region. In this work, the optimal charging mass of working fluid was obtained by considering the meniscus recession from the axial variation of capillary pressure, the radius of curvature and wetting angle of meniscus of liquid-vapor interface. Experimental results were also obtained by varying the charging mass of working fluid within a heat pipe, and presented for the trend of maximum heat transport capacity corresponding to the operating temperature and the elevation of heat pipe. Finally, the analytical results of the optimal charging mass of working fluid were compared with those from the experiment, both of which were in good agreement with each other.

Temperature Dependent Self-Diffusion Coefficients of Valinomycin and the Potassium-Valinomycin Complex

  • Kim, Su-Deuk;Lee, Yun-Jung;Joo, Hyun-Hye;Ahn, Sang-Doo
    • Journal of the Korean Magnetic Resonance Society
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    • v.12 no.1
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    • pp.51-59
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    • 2008
  • Convection effect in liquids has been one of the main targets to be overcome in pulsed-field-gradient NMR measurements of self-diffusion coefficients since the temperature gradient along the sample tube generated by the heating and/or cooling process causes the effect, resulting in additional diffusion. It is known that the capillary is the most appropriate tube type for diffusion experiments at variable temperatures since the narrower tube suppresses convection effectively. For evaluating the properties of hydrogen bonding, diffusion coefficients of the $K^+$-complexed and free valinomycin in a micro tube have been determined at various temperatures. From the analysis of the obtained diffusion coefficient values, we could conclude that the intramolecular hydrogen bonding in both of the $K^+$ complexed and free valinomycin in a non-polar solvent is preserved over the observed temperature range, and the temperature dependence of hydrogen bonding is more pronounced in free valinomycin. It is also thought that there is no big change in the radius of the $K^+$-complexed as temperature is varied, and the ratio of overall radius, $r_{complex}/r_{free}$ is slightly decreased as temperature rises.

Feasibility Study on Design of Thrust Bearing for Micro Gas Turbine Generator (초소형 가스 터빈 제너레이터용 스러스트 베어링의 설계 및 타당성에 관한 연구)

  • 이용복;곽현덕;김창호;장건희
    • Tribology and Lubricants
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    • v.17 no.6
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    • pp.467-475
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    • 2001
  • Feasibility study of gas-lubricated bearing in micro gas turbine was performed. Based on Reynolds equation, finite difference method with coupled boundary was developed to analyze bearing characteristics, such as load capacity, mass flow rates and stiffness. By the bearing force and mass flow rates analysis with the variation of supply pressure, bearing clearance and capillary radius, acceptable range of design parameters were suggested in terms of load capacity and stiffness of bearings. Additionally, coupled boundary effect on pressure distribution was investigated and it is stated that coupling could reduce an excitation force due to narrow pressure distribution.

Feasibility Study on Design of Thrust Bearing for Micro Gas Turbine/Generator (초소형 가스 터빈/제너레이터용 스러스트 베어링의 설계 및 타당성에 관한 연구)

  • 곽현덕;이용복;김창호;장건희
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2001.11a
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    • pp.273-281
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    • 2001
  • Feasibility study of gas-lubricated bearing in micro gas turbine was performed. Based on Reynolds equation, finite difference method with coupled boundary was developed to analyze bearing characteristics, such as load-carrying capacity, mass flow rates and stiffness. By the bearing force and mass flow rates analysis with the variation of supply pressure, bearing clearance and capillary radius, acceptable range of design parameters were suggested in terms of load capacity and stiffness of bearings. Additionally, coupled boundary effect on pressure distribution was investigated and it is stated that coupling could reduce all excitation force due to narrow pressure distribution.

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3D-inertia Valve Component for Centrifugal Force-based Micro Fluid Control (원심력기반 3차원 관성밸브 모델링을 통한 정밀 미세유체제어)

  • Kang, Dong Hee;Kim, Na Kyong;Kang, Hyun Wook
    • Journal of the Korean Society of Visualization
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    • v.19 no.1
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    • pp.12-17
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    • 2021
  • A three-dimensional slope valve component is used for controlling micro volume of liquid on a centrifugal force-based microfluidic disk platform, also called a lab-on-a-disk. The modeling factor of the slope valve component is determined to centrifugal force for liquid passing the crest of a slope valve via variation of slope length and angle as well as the radius to start point of slope valve. The centrifugal force is calculated by the equilibrium equation of the capillary and gravitational forces according to the microchannel surface roughness and the liquid volume, respectively. As a result, the slope valve is analyzed by the minimum angular velocity for liquid passing at crest point and the ratio between the length of micro liquid and slope length to obtain the factors for optimal slope angle modeling.

Coherent x-ray scattering to study dynamics in thin films (결맞는 X-선 산란을 이용한 박막의 표면 거동 연구)

  • Kim, Hyun-Jung
    • Journal of the Korean Vacuum Society
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    • v.14 no.3
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    • pp.143-146
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    • 2005
  • A new method of x-ray photon correlation spectroscopy (XPCS) using coherent x-rays is developed recently for probing the dynamics of surface height fluctuations as a function of lateral length scale. This emerging technique applies the principles of dynamic light scattering in the x-ray regime. The short wavelength and slow time scales characteristic of XPCS extend the phase space accessible to scattering studies beyond some restrictions by light and neutron. In this paper, we demonstrate XPCS to study the dynamics of surface fluctuations in thin supported polymer films. We present experimental verification of the theoretical predictions for the wave vector and temperature dependence of the capillary wave relaxation times for the supported polymer films at melt for the film thicknesses thicker than 4 times of the radius of gyration of polymer. We observed a deviation from the conventional capillary wave predictions in thinner films. The analysis will be discussed in terms of surface tension, viscosity and effective interactions with the substrate.

Effect of Curvature Dependency of Surface Tension on the Result of Pore-Volume Distribution Analysis (동공부피 분포의 계산결과에 미치는 표면장력의 곡률 의존도 효과)

  • Cho Chang-Hyun;Ahn Woon-Sun;Chang Seihun
    • Journal of the Korean Chemical Society
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    • v.16 no.6
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    • pp.341-348
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    • 1972
  • The significance of the curvature dependency correction of surface tension is studied in calculating the pore volume distribution of porous adsorbent from nitrogen adsorption isotherm. That is, Kelvin radii are calculated with curvature dependent surface tension values calculated by Chang et al, and then with these Kelvin radii, pore volume distributions of three porous adsorbents, silica alumina (steam deactivated), silica gel (Davidson 59), and silica gel (Mallinc-krodt Standard Luminescent), are calculated. The results are compared with those obtained by the previous method in which surface tension is taken as constant and also with the others. obtained by the modelless method proposed by Brunauer et al. The maximum point of the distribution curve shift to the larger pore radius, when the curvature dependency is considered. Furthermore, the relative pressure at which capillary condensation commences is by far the lower than that accepted previously. This effect becomes significant as the pore radius approaches to the micropore range.

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