• Title/Summary/Keyword: Capacity retention

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The effect of finger play teaching method on the reproduction of children's english words (손유희를 이용한 영어교수법이 유아의 영어 단어 재생에 미치는 효과)

  • Oh, Eun-Soon
    • English Language & Literature Teaching
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    • v.10 no.2
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    • pp.89-111
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    • 2004
  • The purpose of this article is to study the effect of finger play teaching method on the reproduction of children's English words. The hypotheses are as follows: 1) there will be the difference of the reproduction of children's English words between the experimental group(that is taught by finger play teaching method) and the controlled group (that is taught by only oral teaching method). 2) there will be the difference of children's retention capacity of reproducing English words between the experimental group and the controlled group, The researcher made the time series data The measure tool was the check list for reproduction test of children's English words that was made by Run-Soon Oh and J. Eden(2004). The researcher analyzed the data using the Repeated Measures ANOVA and the Analysis of Covariance. The findings of research are as follows: 1) the more the frequency of teaching increases, the more there are the difference of reproducing English words according to frequencies and groups. The reproduction capacity of the experimental group is better than that of the controlled group. A degree of statistical significance is p<.001. 2) The difference of retention capacity of reproducing English words between the experimental group and the controlled group is a statistical significant, p<.05. The experimental group is better than the controlled group.

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SPATIAL AND TEMPORAL INFLUENCES ON SOIL MOISTURE ESTIMATION

  • Kim, Gwang-seob
    • Water Engineering Research
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    • v.3 no.1
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    • pp.31-44
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    • 2002
  • The effect of diurnal cycle, intermittent visit of observation satellite, sensor installation, partial coverage of remote sensing, heterogeneity of soil properties and precipitation to the soil moisture estimation error were analyzed to present the global sampling strategy of soil moisture. Three models, the theoretical soil moisture model, WGR model proposed Waymire of at. (1984) to generate rainfall, and Turning Band Method to generate two dimensional soil porosity, active soil depth and loss coefficient field were used to construct sufficient two-dimensional soil moisture data based on different scenarios. The sampling error is dominated by sampling interval and design scheme. The effect of heterogeneity of soil properties and rainfall to sampling error is smaller than that of temporal gap and spatial gap. Selecting a small sampling interval can dramatically reduce the sampling error generated by other factors such as heterogeneity of rainfall, soil properties, topography, and climatic conditions. If the annual mean of coverage portion is about 90%, the effect of partial coverage to sampling error can be disregarded. The water retention capacity of fields is very important in the sampling error. The smaller the water retention capacity of the field (small soil porosity and thin active soil depth), the greater the sampling error. These results indicate that the sampling error is very sensitive to water retention capacity. Block random installation gets more accurate data than random installation of soil moisture gages. The Walnut Gulch soil moisture data show that the diurnal variation of soil moisture causes sampling error between 1 and 4 % in daily estimation.

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Cycling Performance of Li4Ti5O12 Electrodes in Ionic Liquid-Based Gel Polymer Electrolytes

  • Kim, Jin-Hee;Kang, Yong-Ku;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.33 no.2
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    • pp.608-612
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    • 2012
  • We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

Detergency and Liquid Wetting/Retention Properties of Soiled Polyester/Cotton(65/35) Cloth in Nonionic Surfactant Solutions (비이온계 계면활성제 수용액에서 Polyester/Cotton(65/35) 오염포의 습윤특성과 세척성)

  • Kim, Chun-Hee
    • Textile Coloration and Finishing
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    • v.23 no.2
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    • pp.140-145
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    • 2011
  • The effects of nonionic surfactant solutions of 0.1g/dL on detergency and liquid wetting/retention properties of soiled polyester/cotton(65/35) cloth were studied. Soiled polyester/cotton(65/35) cloth (EMPA 104) and 10 different nonionic surfactants (Span 20, Tween 20, 40, 60, 80, 21, 61, 81, 65, 85) were used in the study. The water retention and liquid retention capacity values of soiled cloth were decreased compared with those of unsoiled cloth. The wetting and water retention of soiled cloth improved with addition of surfactants, whereas water retention ratio(W/H) values didnot change markedly. Generally surfactants with low surface tension and high HLB (Hydrophile-lipophile balance) were more effective in improving the wetting/retention properties of soiled cloth. Nonionic surfactants having high ethylene oxide contents of 20 moles; i.e., Tween 20, 40, 60 & 80, showed better detergency than low ethylene oxide contents of 4 moles; i.e., Tween 21, 61 & 81. As HLB values of surfactants and $cos{\theta}$ of the soiled cloth increase, the detergency values of soiled cloth increased.

Electrochemical Performance of Graphite/Silicon/Carbon Composites as Anode Materials for Lithium-ion Batteries (리튬이온배터리 Graphite/Silicon/Carbon 복합 음극소재의 전기화학적 성능)

  • Jo, Yoon Ji;Lee, Jong Dae
    • Korean Chemical Engineering Research
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    • v.56 no.3
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    • pp.320-326
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    • 2018
  • In this study, Graphite/Silicon/Carbon (G/Si/C) composites were synthesized to improve the electrochemical properties of Graphite as an anode material of lithium ion battery. The prepared G/Si/C composites were analyzed by XRD, TGA and SEM. Also the electrochemical performances of G/Si/C composites as the anode were performed by constant current charge/discharge, rate performance, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DMC:EMC=1:1:1 vol%). Lithium ion battery using G/Si/C electrode showed better characteristics than graphite electrode. It was confirmed that as the silicon content increased, the capacity increased but the capacity retention ratio decreased. Also, it was shown that both the capacity and the rate performances were improved when using the Silicon (${\leq}25{\mu}m$). It is found that in the case of 10 wt% of Silicon (${\leq}25{\mu}m$), G/Si/C composites have the initial discharge capacity of 495 mAh/g, the capacity retention ratio of 89% and the retention rate capability of 80% in 2 C/0.1 C.

Electrochemical Performances of LiMn2O4:Al Synthesized by Solid State Method (고상법으로 합성한 LiMn2O4:Al의 전기화학적 특성)

  • Park, Hye-Jung;Park, Sun-Min;Roh, Gwang-Chul;Han, Cheong-Hwa
    • Journal of the Korean Ceramic Society
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    • v.48 no.6
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    • pp.531-536
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    • 2011
  • Al doped $LiMn_2O_4$ ($LiMn_2O_4:Al$) synthesized by several Al doping process and Solid State method. The Al contents in $Mn_{1-x}Al_xO_2$ for $LiMn_2O_4:Al$ were analyzed 1.7 wt% by EDS. The $LiMn_2O_4:Al$ confirmed cubic spinel structure and approximately 5 ${\mu}m$ particles regardless of three kinds of doping process by solid state method. In the result of electrochemical performances, initial discharge capacity had 115 mAh/g in case of $LiMn_2O_4$ and 111 mAh/g of $LiMn_2O_4:Al$ after 100th cycle at room temperature. But the capacity retention results showed that $LiMn_2O_4$ and $LiMn_2O_4:Al$ were 44% and 69% respectively in the 100th cycle at 60$^{\circ}C$. Therefore we are confirmed that $LiMn_2O_4:Al$ increased the capacity retention about 25% than $LiMn_2O_4$, thus the effect of Al dopping on $LiMn_2O_4$ capacity retention.

The Electrochemical Properties of Sponge Type S@ZIF67/rGO as the Cathode Material for Lithium Sulfur Batteries (리튬 황 전지용 Sponge 형태의 S@ZIF 67/rGO 양극재의 전기화학 특성 분석)

  • Chaelin Seo;Sunghoon Kim;Wook Ahn
    • Journal of the Korean Electrochemical Society
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    • v.27 no.1
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    • pp.47-54
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    • 2024
  • In this study, ZIF67/rGO was used to minimize the battery life degradation due to the insulating properties of sulfur and the elution of lithium polysulfide. ZIF67 wrapped in rGO creates more space within the carbon sponge and can hold a large amount of sulfur. The sulfur@ZIF67/rGO composite was synthesized and prepared as a sponge to enhance the sulfur retention capacity. The result showed a high initial capacity, with a value of about 1093 mAh g-1 and a capacity retention rate of 84% after 100 cycles. The high interaction with sulfur through the complexation of cobalt and carbon confirmed that ZIF67/rGO exhibits high performance as a carrier for sulfur, the anode active material of lithium-sulfur batteries, and the high initial capacity and improved capacity retention rate were confirmed.

Comparative Study on Performances of Composite Anodes of SiO, Si and Graphite for Lithium Rechargeable Batteries

  • Doh, Chil-Hoon;Veluchamy, Angathevar;Lee, Duck-Jun;Lee, Jung-Hoon;Jin, Bong-Soo;Moon, Seong-In;Park, Cheol-Wan;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • v.31 no.5
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    • pp.1257-1261
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    • 2010
  • The electrochemical performances of anode composites comprising elemental silicon (Si), silicon monoxide (SiO), and graphite (C) were investigated. The composite devoid of elemental silicon (SiO:C = 1:1) and its carbon coated composite showed reduced capacity degradation with measured values of 606 and 584 mAh/g at the fiftieth cycle. The capacity retention nature when the composites were cycled followed the order of Si:SiO:C = 3:1:4 < Si:SiO:C = 2:2:4 < SiO:C = 1:1 < SiO:C = 1:1 (carbon coated). A comparison of the capacity retention properties for the composites in terms of the silicon content showed that a reduced silicon content increased the stability of the composite electrodes. Even though the carbon-coated composite delivered low capacity during cycling compared to the other composites, its low capacity degradation made the anode a better choice for lithium ion batteries.

Influence of Electrolyte Composition on Electrochemical Performance of Li-S Cells

  • Kim, Tae Jeong;Jeong, Bo Ock;Koh, Jeong Yoon;Kim, Seok;Jung, Yongju
    • Bulletin of the Korean Chemical Society
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    • v.35 no.5
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    • pp.1299-1304
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    • 2014
  • The electrochemical performance of Li-S cells was investigated in various ternary electrolyte solutions composed of 1,2-dimethoxyethane (DME), tetra(ethylene glycol) dimethyl ether (TGM), and 1,3-dioxolane (DOX). The discharge capacity values and cycle data obtained at each composition were statistically treated with the Minitab program to obtain mixture contour plots, from which the optimal composition of the ternary solvent systems was predicted. The discharge capacities and capacity retention were quite dependent on the electrolyte composition. It was estimated from the contour plots of the capacity at 1.0 C that the discharge capacity sharply increased with a decrease in the TGM content. High capacities greater than 900 mAh/g at 1.0 C were expected for the electrolyte composition with a volume ratio of DME/TGM/DOX = 1/0/1. In contrast, it was predicted from the mixture contour plot of the capacity retention that the cycle performance would significantly increase with an increase in the DME content.

Determination of Water Retention Characteristics of Organic and Inorganic Substrates for Horticulture by European Standard Method (유럽표준배지분석법에 의한 원예용 유기·무기성 배지의 수분보유특성)

  • Kang, Ji-Young;Park, Soon-Nam;Lee, Hyun-Haeng;Kim, Kye-Hoon
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.2
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    • pp.55-58
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    • 2004
  • The objective of this study was to get information about water retention characteristics of horticultural substrates used in Korea determined by European standard method. Water retention curves were prepared at water volume (v/v, %) in relation to -10 cm, -50 cm, -100 cm water pressure head. Water retention curves showed different properties depending upon the type, the place of origin, particle size, and manufacturing processes of substrates. Peat and coir had easily available water content in the range of 30-40% and showed high water holding capacity, water buffering capacity, and aeration for plant growth. However, bark, sawdust and rice hull showed low water holding capacity about below 10%. The easily available water content of perlite and clay ball was low about 0.1-13.8%, whereas that of vermiculite and rockwool granulate was high about 25.9-52.0%. Understanding water retention characteristics of growing substrates is very important in cstablisliing optimum condition for plant growth. Further study on water retention curves for more substrates, mixture and growing media is needed.