• The Journal of Korean Institute of Communications and Information Sciences
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• v.39C no.3
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• pp.291-297
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• 2014

Due to the rapid increase in demand for transportation of human and freight in modern railway systems, the CBTC system has been proposed, which is the solution for improvement of the line capacity that has been limited by the conventional track circuit based train control system. In the CBTC system, higher reliability of the communication system should be guaranteed for the safety of passengers and trains. However, due to the inherent characteristics of the wireless channel environment, performance degradations are inevitable. The diversity techniques can increase the reliability of data transmission using multiple antennas. In this paper, we investigate the performance of the STBC in the railway channel environment. Rician fading model is used for the viaduct scenarios which take important roles in the railway system. Also, considered is the Doppler effect which is an important factor in the mobile communication system. Simulations are performed to analyze the performance of the STBC in various channel environments. Results show that the performance degradation due to the phase error in viaduct scenarios is independent of the diversity order but is affected by the constellation of the modulation.

• Journal of the Korean Electrochemical Society
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• v.11 no.2
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• pp.125-129
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• 2008

Rechargeable lithium-ion polymer batteries have been considered to be next-generation power sources for portable electronic devices and electric vehicles. In this work, we tried to improve the cycling performances of lithium-ion polymer cells by coating aluminum fluoride and acrylonitrile-methyl methacrylate copolymer to the polyethylene separator. It was found that the addition of aluminum fluoride to the surface-modified separator reduced the interfacial resistances and thus the cell exhibited a less capacity fading and better high rate performance. The cell showed an initial discharge capacity of 150 mAh/g and good capacity retention at 0.5 C rate.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.10 no.8
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• pp.1502-1509
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• 2006

In this paper, we proposed reliability and capacity enhancement methods for IEEE 802.15.3 HDR-WPAN (High Data Rate-Wireless Personal Area Network) system which is currently getting an interest in home network technology adopting a MIMO technique. We also analyzed performance or the proposed system through a computer simulation. The HDR-WPAN system using V-BLAST algorithm, transmitting the different signal vector to each other's sub-channel, can get the transmission speed of more than 110Mbps using two Tx/Px antenna without bandwidth expansion in TCM-64QAM mode. Also the proposed system has reliability of 104 at $E_b/N_0=35dB$ under the Rayleigh fading channel in case of two Tx/Rx antenna with MMSE algorithm. The HDR-WPAN system adopting V-BLAST method has its drawback which is very complicated to determine the decision-ordering at the receiver. But, the proposed system enhances the transmission capacity and reliability without extra bandwidth expansion by sending data streams to multiple antennas.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.35 no.5C
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• pp.487-494
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• 2010

This paper presents an OFDM-based dual-hop multi-relay system with best relay selection maximizing the mutual information. For the system either with decode-and-forward (DF) relays or with amplify-and-forward (AF) relays, we derive a lower-bound on the outage probability and the diversity order achievable in frequency selective fading channels and provide the outage capacity from simulation. Performance evaluation shows that both DF and AF provide the same diversity order as in the lower-bound but DF of which the outage probability is much closer to the lower-bound provides a better outage capacity than AF. It is also observed that the SNR gain of DF over AF gets larger as either the number of resolvable multipaths or the number of relay candidates increases, which makes DF relaying more favorable to the OFDM-based multi-relay system.

• The Journal of the Institute of Internet, Broadcasting and Communication
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• v.8 no.5
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• pp.29-34
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• 2008

In this paper, we propose the channel sounding scheme which improves the reliability and performance of communication link and mitigate the fading effect of channel in MTMO-OFDM system having correlation between Tx and Rx antennas. And we estimate the channel propagation characteristics of channels between the transmitter and receiver with CS scheme by measuring the channel propagation characteristics using sounding signal. Multi agent system models can be used to analyze the path of the system within any time frame. Further, using this proposed method, we can increase the channel capacity by simple calculation in receiver and transmitter and allocate the optimal power by channel information in transmitter. Also, the increment of channel capacity using the prorposed method is induced as the number of antenna is increased. So, we can anticipate the performance improvement with the presented scheme in more complicated Tx and Rx antenna system.

• Resources Recycling
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• v.19 no.1
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• pp.27-32
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• 2010

To improve electronic conductivity of cathodic active materials of lithium ion battery, carbonaceous materials is usually added. New mixing method of abrasive milling has been investigated in mixing of graphite and $LiCoO_2$ powders. It would be expected that uniform mixing of graphite reduces capacity fading of cathode of lithium battery. Abrasion milled $LiCoO_2$ composite showed the best electrochemical performance as a cathode material with 1 wt% of graphite content, 300 rpm of milling speed, and 10 min of milling time. The improvement of the electrochemical performances such as cycleability and charge/discharge capacity retention would be mainly attributed to increase of the electronic conductivity and/or prevention of the active materials by uniform dispersion and coating of graphite on $LiCoO_2$.

• Journal of Electrochemical Science and Technology
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• v.13 no.2
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• pp.177-185
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• 2022

Electrochemical properties of LiMn₂O₄ cathode were investigated in three types of Zn-containing electrolytes: lithium-zinc sulfate electrolyte (1M ZnSO₄ / 2M Li₂SO₄), zinc sulfate electrolyte (2MZnSO₄) and lithium-zinc-manganese sulfate electrolyte (1MZnSO₄ / 2MLi₂SO₄ / 0.1MMnSO₄). Cyclic voltammetry measurements demonstrated that LiMn₂O₄ is electrochemically inactive in pure ZnSO₄ electrolyte after initial oxidation. The effect of manganese (II) additive in the zinc-manganese sulfate electrolyte on the electrochemical performance was analyzed. The initial capacity of LiMn₂O₄ is higher in presence of MnSO₄ (140 mAh g^-1 in 1 M ZnSO₄ / 2 M Li₂SO₄ / 0.1 M MnSO₄ and 120 mAh g^-1 in 1 M ZnSO₄ / 2MLi₂SO₄). The capacity increase can be explained by the electrodeposition of MnO_x layer on the electrode surface. Structural characterization of postmortem electrodes with use of XRD and EDX analysis confirmed that partially formed in pure ZnSO₄ electrolyte Zn-containing phase leads to fast capacity fading which is probably related to blocked electroactive sites.

• Journal of the Korean Ceramic Society
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• v.40 no.6
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• pp.507-512
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• 2003

The LiN $i_{l-y}$ $Co_{y}$ $O_2$ samples were synthesized at 80$0^{\circ}C$ and 85$0^{\circ}C$, by the solid-state reaction method, from the various starting materials LiOH, L $i_2$C $O_3$, NiO, NiC $O_3$, $Co_3$ $O_4$, CoC $O_3$, and their electrochemical properties are investigated. The LiN $i_{l-y}$ $Co_{y}$ $O_2$ pre-pared from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ exhibited the $\alpha$-NaFe $O_2$ structure of the rhombohedral system (space group; R3m). As the Co content increased, the lattice parameters a and c decreased. The reason is that the radius of Co ion is smaller than that of Ni ion. The increase in da shows that two-dimensional structure develops better as the Co content increases. The LiN $i_{0.7}$ $Co_{03}$. $O_2$［HOO(800,0.3)] synthesized at 80$0^{\circ}C$from LiOH, NiO, and $Co_3$ $O_4$ exhibited the largest first discharge capacity 162 mAh/g. The size of particles increases roughly as the valve of y increases. The samples with the larger particles have the larger first discharge capacities. The cycling performances of the samples with the first discharge capacity larger than 150 mAh/g were investigated. The LiN $i_{0.9}$ $Co_{0.1}$ $O_2$［COO(850,0.1)］ synthesized at 85$0^{\circ}C$ from L $i_2$C $O_3$, NiO, and $Co_3$ $O_4$ showed an excellent cycling performance. The sample with the larger first discharge capacity will be under the more severe lattice destruction, due to the expansion and contraction of the lattice during intercalation and deintercalation, than the sample with the smaller first discharge capacity. As the first discharge capacity increases, the capacity fading rate thus increases.increases.s.s.s.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.28 no.5
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• pp.191-198
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• 2018

SnSb alloy powders with excess Sn or Sb are fabricated by the high energy ball-milling of pure Sn and Sb powders with different Sn/Sb molar ratios, and then their material properties and lithium electrochemical performances are investigated. It is revealed by X-ray diffraction that SnSb alloys are successfully synthesized, and the powder size is decreased via ball-milling. Charge-discharge test using a coin-cell shows that the best result, in terms of the cyclability and the capacity after 50 cycles, comes from the electrode composed of Sn : Sb = 4 : 6, i.e. the capacity of $580mAh\;g^{-1}$ after 50 cycles. When the electrode is composed of Sn : Sb = 3 : 7, however, the capacity is noticeably decreased by the restrained Sn reaction with Li-ion. The pure SnSb alloy powders (Sn : Sb = 5 : 5) results in the second best performance. In the case of Sn-rich SnSb alloys, the initial capacity is relatively high, but the capacity is quickly fading after 20 cycles.

• Journal of the Korean Electrochemical Society
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• v.7 no.3
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• pp.131-137
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• 2004

Sol-gel method which provides better electrochemical and physiochemical properties compared to the solid-state method was used to synthesize the material of $LiFe_yMn_{2-y}O_4$. Fe was substituted to increase the structural stability so that the effects of the substitution amount and sintering temperature were analyzed. XRD was used for the structural analysis of produced material, which in turn, showed the same cubic spinel structure as $LiMn_2O_4$ despite the substitution of $Fe^{3+}$. During the synthesis of $LiFe_yMn_{2-y}O_4$, as the sintering temperature and the doping amount of Fe(y=0.05, 0.1, 0.2)were increased, grain growth proceeded which in turn, showed a high crystalline and a large grain size, certain morphology with narrow specific surface area and large pore volume distribution was observed. In order to examine the ability for the practical use of the battery, charge-discharge tests were undertaken. When the substitution amount of $Fe^{3+}\;into\;LiMn_2O_4$ increased, the initial discharge capacity showed a tendency to decrease within the region of $3.0\~4.2V$ but when charge-discharge processes were repeated, other capacity maintenance properties turned out to be outstanding. In addition, when the sintering temperature was $800\~850^{\circ}C$, the initial capacity was small but showed very stable cycle performance. According to EVS(electrochemical voltage spectroscopy) test, $LiFe_yMn_{2-y}O_4(y=0,\;0.05,\;0.1,\;0.2)$ showed two plateau region and the typical peaks of manganese spinel structure when the substitution amount of $Fe^{3+}$ increased, the peak value at about 4.15V during the charge-discharge process showed a tendency to decrease. From the previous results, the local distortion due to the biphase within the region near 4.15V during the lithium extraction gave a phase transition to a more suitable single phase. When the transition was derived, the discharge capacity decreased. However the cycle performance showed an outstanding result.