• 한국환경과학회지
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• 제27권9호
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• pp.753-762
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• 2018

The present study set out to investigate the adsorption of Cd(II) ions in an aqueous solution by using Peanut Husk Biochar (PHB). An FT-IR analysis revealed that the PHB contained carboxylic and carbonyl groups, O-H carboxylic acids, and bonded-OH groups, such that it could easily adsorb heavy metals. The adsorption of Cd(II) using PHB proved to be a better fit to the Langmuir isotherm than to the Freundlich isotherm. The maximum Langmuir adsorption capacity was 33.89 mg/g for Cd(II). The negative value of ${\Delta}G^o$ confirm that the process whereby Cd(II) is adsorbed onto PHB is feasible and spontaneous in nature. In addition, the value of ${\Delta}G^o$ increase with the temperature, suggesting that a lower temperature is more favorable to the adsorption process. The negative value of ${\Delta}H^o$ indicates that the adsorption phenomenon is exothermic while the negative value of ${\Delta}S^o$ suggests that the process is enthalpy-driven. As an alternative to commercial activated carbon, PHB could be used as a low-cost and environmentally friendly adsorbent for removing Cd(II) from aqueous solutions.

• 대한화학회지
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• 제18권3호
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• pp.202-209
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• 1974

물 아닌 용매 아세토니트릴에서 구리와 카드뮴의 2,2´-비피리딘(bipy.)과 에틸렌디아민(en.) 착물의 성질의 직류와 교류폴라로그래프로 조사한 결과 각 착물의 전극과정은 아래와 같이 생각된다. $Cu(II)-bipy. \;complex\;{\longrightarrow^{e^-}_{E_{1/2}\risingdotseq+0.1V}}\;Cu(I)-bipy.\;complex\;{\longrightarrow^{e^-}_{E_{1/2}=-0.43V}}\;Cu(Hg)$$Cu(II)-en.\;complex\;{\longrightarrow^{e^-}}\;Cu(I)-en.\;complex\;{times}\;{\longrightarrow^{e^-}_{E_{1/2}=-0.56V}}\;Cu(Hg)$$Cu(II)-bipy. \;complex\;{\longrightarrow^{e^-}_{E_{1/2}=-0.57V}}\;Cu(I)-bipy.\;complex\;{\longrightarrow^{2e^-}_{E_{1/2}=-0.97V}}\;Cd(I)-bipy\;complex$$Cu(II)-en.\;complex\;{\longrightarrow^{e^-}_{E_{1/2}=+0.05V}\;Cu(I)-en.\;complex{\longrightarrow^{e^-}_{E_{1/2}=-0.92V}}\;Cu(Hg)$이상의 모든 파는 학산에만 의존한다. 또 Cu(Ⅰ)-bipy. 착물의 리간드의 수는 2이며, 착물해리상수 $K_d=(1.5{\pm}0.1){\times}10^{-7}$이었다.

• Carbon letters
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• 제26권
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• pp.43-50
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• 2018

In this research, a novel and efficient quinoline thioacetamide functionalized magnetic graphene oxide composite ($GO@Fe_3O_4@QTA$) was synthesized and utilized for dispersive magnetic solid phase preconcentration of Cd(II) and Ni(II) ions in urine and various food samples. A number of diverse methods were employed for characterization of the new nanosorbent. The design of experiments approach and response surface methodology were applied to monitor and find the parameters that affect the extraction performance. After sorption and elution steps, the concentrations of target analytes were measured by employing FAAS. The highest extraction performance was achieved under the following experimental conditions: pH, 5.8; sorption time, 6.0 min; $GO@Fe_3O_4@QTA$ amount, 17 mg; 2.4 mL $1.1mol\;L^{-l}$ $HNO_3$ solution as the eluent and elution time, 13.0 min. The detection limit is 0.02 and $0.2ng\;mL^{-1}$ for Cd(II), and Ni(II) ions, respectively. The accuracy of the new method was investigated by analyzing two certified reference materials (sea food mix, Seronorm LOT NO 2525 urine powder). The interfering study revealed that there are no interferences from commonly occurring ions on the extractability of target ions. Finally, the new method was satisfactorily employed for rapid extraction and determination of target ions in urine and various food samples.

• 한국환경과학회지
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• 제12권7호
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• pp.817-824
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• 2003

Various kinds of zeolites, such as analcime (ANA), cancrinite (CAN), Na-Pl and sodalite octahydrate (SOD) could be synthesized from Hwangto by hydrothermal reaction in a high-pressure vessel. The adsorption characteristics of Cu(II) and Cd(II) by Hwangto and its synthetic zeolites were investigated using the chemical and electrochemical surface parameters of these adsorbents. The heavy metal adsorptivity among the adsorbents decreased in the following sequences: Na-Pl > SOD > ANA > CAN > Hwangto. This sequence was the same with the values of surface site density (Ns) of these adsorbents and was correlated inversely with the values of pHpzc (pH of the point of zero charge) and the va]ues of K$\_$a2/(int) (intrinsic surface deprotonation constant) of the adsorbents for synthetic zeolites, i.e., the adsorbents with higher values of Ns and with lower values of pHpzc and K$\_$a2/(int) for synthetic zeolites showed higher heavy metal adsorptivity. With increasing pH, the heavy metal adsorptivity increased greatly between pHpzc and pH 6 or 7 because of the steep increase of negatively charged sites for synthetic zeolites, but for Hwangto, it increased broadly because of slow increase of negatively charged sites based on its lower surface sites.

• 대한화학회지
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• 제32권1호
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• pp.30-36
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• 1988

에틸렌디아민, 프로필렌디아민 및 디에틸렌트리아민의 구리(II), 카드뮴(II) 및 아연(II) 착이온의 安定度에 미치는 壓力의 影響을 폴라로그래피로 조사하였다. 支持電解質로서는 0.10M의 KN$O_3$ 용액을 쓰고, 킬레이트제의 농도는 0.01M에서 0.1M까지 변화시켰다. 압력이 1기압에서 1,500기압으로 증가함에 따라 금속착이온의 解離常數는 증가하였으며, 단위압력당 증가율은 $Cu(dien)_2^{2+}$의 1.1 ${\times} 10^{-3}$ %에서 Zn(en)$_2^{2+}$의 5.0${\times} 10^{-3}$ % 까지의 값으로 나타났다.

• 한국결정학회지
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• 제12권4호
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• pp.207-211
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• 2001

Cd(SCN)₂{CH/sub 6/H/sub 10/(NH₂)₂}₂(1) 착물을 합성하고 단결성 X-선 회절법으로 구조를 규명하였다. 이 착물은 단사정계, 공간국 P2₁/ space group with a=11.842(2), b=7.926(2), c=11.291(2) Å, β=106.73(3)°V=1014.8(4)Ų, Z=2 로 결정화되었으며, 1775 개의 독립적인 회절반점에 대한 최종 신뢰도 인자 R₁및 ωR₂값은 각각 0.0518 및 0.1315이었다. 착물의 결정 구조는 2개의1,2-Diaminocyclohexane리간드의 질소 원자 xy 평면에서 Cd(II) 금속원자에 chelate 되어 5-membered ring을 형성하며, 2개의 thiocyanate 리간드의 황 원자가 z 축 방향으로 Cd(II) 금속 원자에 트란스 형태로 결합함으로 써 z축 방향으로 약간 늘러진 팔면체 구조의 착물을 형성한다.

• Bulletin of the Korean Chemical Society
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• 제34권7호
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• pp.2191-2194
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• 2013

• 대한약학회:학술대회논문집
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• 대한약학회 2000년도 NEW STRATEGY FOR DRUG DEVELOPMENT IN POST-GENOMIC ERA(대한약학회)
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• pp.161.3-162
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• 2000

• 한국균학회지
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• 제11권4호
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• pp.159-162
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• 1983

The dried carpophores of Sarcodon aspratus were examined for mineral elements and a protein-polysacccharide. Calcium, iron, zinc, magnesium, manganese, copper, lead, cadmium and mercury were detected in that order of contents by atomic absorption spectrometry and automatic mercury analysis. The protein-polysaccharide fraction extracted from the carpophore was found to contain 31.5% protein and 52.8% polysaccharide. The fraction showed no antitumor activity against sarcoma 180 implanted in mice.

• Bulletin of the Korean Chemical Society
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• 제32권9호
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• pp.3255-3260
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• 2011

Two novel binuclear metal-organic coordination complexes $[Cd_2(L)_2(bpy)_2(H_2O)_2]{\cdot}6H_2O$ (1), $[Cd_2(L)_2(phen)_2-(H_2O)_2]{\cdot}2H_2O$ (2) (where L = 2-methylquinoline-3,4-dicarboxylate dianion, bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions and characterized by single crystal Xray diffraction, spectral method (IR), elemental analysis and thermal gravimetric analysis (TGA). Both 1 and 2 consist of two Cd(II) atoms bridged by two monoatomic bridging carboxylate groups from two L ligands, and the second carboxylate group of each L is monodentately coordinated to Cd(II), creating a sevenmembered chelating ring. The coordination at each metal nucleus is completed by a water molecule and a chelating bidentate molecule. The 3D structures of the complexes are stabilized by ${\pi}-{\pi}$ stacking interactions and hydrogen-bonds.