Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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Crystal Structures and Thermal Properties of Two Binuclear Cd(II) Supramolecular Complexes Based on Quinolinecarboxylate Ligand

  • Hao, Hu-Jun (College of Chemistry and Ecological Engineering, Guangxi University for Nationalities) ;
  • Yin, Xian-Hong (College of Chemistry and Ecological Engineering, Guangxi University for Nationalities) ;
  • Lin, Cui-Wu (College of Chemistry and Chemical Engineering, Guangxi University) ;
  • Wei, Shui-Qiang (College of Chemistry and Chemical Engineering, Guangxi University)
  • Received : 2011.05.06
  • Accepted : 2011.07.16
  • Published : 2011.09.20
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Abstract

Two novel binuclear metal-organic coordination complexes $[Cd_2(L)_2(bpy)_2(H_2O)_2]{\cdot}6H_2O$ (1), $[Cd_2(L)_2(phen)_2-(H_2O)_2]{\cdot}2H_2O$ (2) (where L = 2-methylquinoline-3,4-dicarboxylate dianion, bpy = 2,2'-bipyridine, phen = 1,10-phenanthroline) have been synthesized under hydrothermal conditions and characterized by single crystal Xray diffraction, spectral method (IR), elemental analysis and thermal gravimetric analysis (TGA). Both 1 and 2 consist of two Cd(II) atoms bridged by two monoatomic bridging carboxylate groups from two L ligands, and the second carboxylate group of each L is monodentately coordinated to Cd(II), creating a sevenmembered chelating ring. The coordination at each metal nucleus is completed by a water molecule and a chelating bidentate molecule. The 3D structures of the complexes are stabilized by ${\pi}-{\pi}$ stacking interactions and hydrogen-bonds.

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