• Title/Summary/Keyword: Ca-형

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Intercalation of Ca-montmorillonite with Decylammonium Ion and n-Alcanol (Decylammonium 이온과 n-Alcanol 분자에 의한 Ca-montmorillonite의 Intercalation)

  • 최진호;김창은;형경우
    • Journal of the Korean Ceramic Society
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    • v.20 no.3
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    • pp.205-210
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    • 1983
  • The determination of charge density and charge distribution in montmorillonite are discussed. The method is based on cation exchange of the inorganic interlayer cations against decylammonium ion and molecular intercalation of n-alcanol. The results obtained from Yougil-bentonite show that charge density of 0.37 per unit formula and cation exchange capacity of 102.5 meq/100g.

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Synthesis and Crystal Structure of Amorphous Calcium Carbonate by Gas-Liquid Reaction of System CaO-$C_2 H_5 OH$-$CO_2$ (CaO-$C_2 H_5 OH$-$CO_2$계의 기.액반응에 의한 비정질 탄산칼슘의 합성 및 결정구조)

  • Im, Jae-Seok;Im, Goeng
    • The Journal of Engineering Research
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    • v.6 no.1
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    • pp.97-109
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    • 2004
  • The synthesis and crystal structure of amorphous calcium carbonate obtained from gas-liquid reaction of CaO-$C_2 H_5 OH$-$CO_2$ system according to change of added amount of calcium oxide by blowing $CO_2$ gas and reaction time using ethanol and ethylene glycol were investigated by electric conductivity, X-ray diffraction, and scanning electron microscope. The powdery or gelatinous phases were prepared by passing $CO_2$ gas at a flow rate of 1$\ell$/min into the suspensions containing 10~40g of CaO in mixing solutions 900ml of $C_2 H_5 OH$- and 100ml of ethylene glycol. By rapid filtration and drying the both phases at $60^{\circ}C$ under reduced pressure, the phases converted to the spherical vaterite and amorphous phase. The stable phase of amorphous calcium carbonate(ACC) was formed in the region pH 7-9 but the formation regions of amorphous phase were remarkably affected by pH in the mother liquor. It seems that a part of ACC changed into chain calcite as an intermediate products. The initial reactants prior to the formation of precipitated calcium carbonate is ACC. And ACC is unstable in the aqueous solution and crystallizes finally to calcite by the through-solution reaction. Especially ACC was produced or gelatinous phase which precipitated from the reaction of CaO-$C_2 H_5 OH$-$CO_2$ system.

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Removal of Cadmium Ion (Cd2+) by Pseudomonas aeruginosa Immobilized in Ca-Alginate Gel Beads in Packed-Bed Column Reactor (충전층 반응기내에서 고정된 Pseudomonas aeruginosa에 의한 Cd2+의 제거)

  • Choi, Kwang Soo;Kim, Chul Kyung
    • Clean Technology
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    • v.8 no.4
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    • pp.217-222
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    • 2002
  • The effects of initial cadmium ion concentrations (50, 100, 200, 300ppm), and feeding velocities (30, 45, 60mL/hr) on the removal ratio of cadmium ion by Pseudomonas aeruginosa ATCC 27853 immobilized in Ca-alginate gel beads in a packed-bed column reactor were investigated at operating temperature $37^{\circ}C$. The removal ratio of cadmium ion with variable initial concentration was decreased in the following order : 50ppm > 100ppm > 200ppm > 300ppm. The optimum removal conditions of cadmium ion by Pseudomonas aeruginosa ATCC 27853 were initial concentration 50ppm, feeding velocity 30mL/hr.

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Study on the Changes in Ca.Mg.K.Na and P Contents of the Platycodon Graucum Nakai by Water Immersion and Boiling (도라지의 Ca.Mg.K.Na.P와 이들의 수침(水浸)과 Boiling에 따른 변화(變化))

  • Lee, Wool-Hyung;Lee, Mahn-Jung
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.3 no.1
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    • pp.35-41
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    • 1974
  • The experiment attempted to detect the loss of mineral substances in the crude herb, especially for the Platycodon graucum Nakai after removal of its acrid flavor. The results obtained are summarized as follows: 1. The quantity of the mineral substance was K Ca P Mg and Na in orders. The above substances were more prevalent in the part of the plant above the ground than the plant below the ground, however Na remained the same in both parts of the plant. 2. As a result of water immersion, in order to clear away the acrid flavor, the one day exudate showed that K was highest in amount and in the others there was no significant difference. There was a slight increase, however, in the amount of Ca K Mg P and Na because of exudation on the 3rd and 5 th days. 3. The amount of the exudate was increased by boiling rather than simple water immersion, but the amount of Ca was decreased.

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Electrical Properies with Ca Contents of the (Sr$_{1-x}.Ca_x)$TiO$_3$Ceramic ((Sr$_{1-x}.Ca_x)$TiO$_3$세라믹의 Ca변화량얘 따른 전기적인 특성)

  • 김진사;정일형;신철기;김충혁;최운식;이준웅
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.318-322
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    • 1997
  • The (Sr$_{l-x}$.Ca$_{x}$)TiO$_3$(0.05$\leq$x$\leq$0.2) ceramics were fabricated to form semiconducting ceramics by sintering at about 1350[$^{\circ}C$] in a reducing atmosphere($N_2$gas). After being fired in a reducing atmosphere, metal oxides, CuO, was painted on the both surface of the specimens to diffuse to the grain boundary. They were annealed at 1100[$^{\circ}C$] for 2 hours and cooled to room temperature. The grain boundary was composed of the continuous insulating layers. The capacitance changes slowly and almost linearly in the temperature region of -30~+85[$^{\circ}C$]. The capacitance characteristics appears a stable value within $\pm$10[%]. The conduction mechanism of the specimens observed in the temperature range of 25~125[$^{\circ}C$], and is divined into three regions haying different mechanism as the current increased: the region I below 230[V/cm] shows the ohmic conduction. The region II can be explained by the Poole-Frenkel emission theory, and the region III is dominated by the tunneling effect.ect.

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A Variable Priority MAC Protocol for QoS Guarantee in Wireless ad hoc Networks (무선 ad hoc 망에서 QoS 보장을 위한 가변 우선순위 MAC 프로토콜)

  • Park, Ha-Young;Kim, Chang-Wook;Han, Jung-Ahn;Kim, Byoung-Gi
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.32 no.7B
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    • pp.463-471
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    • 2007
  • Because of MANET's dynamic characteristic, the hidden node problem can happen. Thus it must use with distributed channel access. In Ad hoc networks, carrier sense multiple access with collision avoidance(CSMA/CA) is one of the most widely used medium access control(MAC) schemes for asynchronous data traffics. However, CSMA/CA could not guarantee the quality of multimedia traffics. CSMA is a contention based protocol. Therefor once a node gets a channel, it can momopolze. Thus the fairness problem with channel starvation will happen. We will propose a new MAC protocol to guarantee QoS for multimedia data in ad hoc networks.

Improving the CO2 Sequestration Capability and Mechanical Properties of CO2 Reactive Cement Paste Using pH Swing Method (pH Swing법을 활용한 이산화탄소 반응경화형 시멘트 경화체의 CO2 고정화 성능 및 기계적 물성 개선)

  • Cho, Seong-Min;Kim, Gyeong-Ryul;Bae, Sung-Chul
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.115-116
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    • 2023
  • This study aims to investigate and improve the carbon dioxide sequestration capability and the mechanical properties of non-hydraulic low calcium silicate cement especially designed for CO2 reaction and ordinary Portland cement subjected to the carbonation curing facilitating pH swing method. Nitric acid (HNO3) was utilized as an liquid for the mixing of cement paste to enhance the initial dissolution of Ca ions from the cements by promoting low pH environment and prevent the direct precipitation of Ca with the anion, owing to the high solubility of Ca(NO3)2 in water. The results presented that the higher the concentration of HNO3, the higher the compressive strength and CO2 sequestration (until 0.1 M). Ca dissolution caused by the harsh acid attack onto the anhydrous cement particle lead to the higher carbonation reaction degree, forming abundant CaCO3 crystals after the reaction. However, cement paste mixed with excessively high concentration of HNO3 presented deterioration due to the too harsh pH environment and abundant NO3- ions which are known to retard the reaction of cement.

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Study on the Radiation Stabilization of Poly(vinyl chloride) ($\Pi$) (PVC의 방사선 안정화에 관한 연구 ($\Pi$))

  • 김기엽
    • Electrical & Electronic Materials
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    • v.5 no.2
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    • pp.244-251
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    • 1992
  • 무독성 혼합안정제 Zn/Ca-stearate의 방사선 안정화 효과를 증진시키기 위해서 oxy-methylene, oxy-ethylene 및 oxy-porpylene 구조의 직쇄형 및 고리형 에테르 화합물을 PVC에 배합하여 방사선조사 하였을 때 PVC의 색차변화를 측정하여 이들 에테르 화합물의 방사선 안정화 효과를 비교 검토하였다. 에테르 화합물에서 oxy-ethylene 구조단위수 4이상인 직쇄형 에테르 또는 고리형 에테르와 oxy-propylene 구조단위수 7인 직쇄형 에테르는 매우 우수한 방사선 안정화 효과를 나타내고 있다. oxy-ethylene 또는 oxy-propylene 구조의 에테르의 방사선 안정화는 Zn/Ca-stearate에서 생성되는 ZnCl$_{2}$와 에테르의 주쇄구조 oxy-ethylene 또는 oxy-propylene의 착체반응에 의한 것으로 추정된다.

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Adaptive CSMA/CA Protocol Using Flag in Aeronautical VHF Communication (플래그를 이용한 항공 VHF 통신환경에서의 적응형 CSMA/CA 프로토콜)

  • Kim, Yong Joong;Park, Yong Tae;Park, Hyo Dal
    • Journal of Advanced Navigation Technology
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    • v.7 no.2
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    • pp.199-205
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    • 2003
  • In this paper, CSMA/CA protocol is modified for aeronautical VHF communication through collision alleviation and the change of retransmission slot selection method in flag used transmission. When collision occurred in the contention period of CSMA/CA process, it is generally waiting for retransmission delay and it has the double size of CW(Contention Window). To solve this problem, this paper modifies the change procedure of original contention window size and reduces the state transition in collision among the whole of it. Also, in this paper we reduces the second collision probability through the station has to enter Backoff mode with increased contention window in the first collision. In the result of simulation, it is verified that it has good property in throughput and delay, So the proposed protocol is suitable for aeronautical VHF communication.

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Development of Technology for Recovering Valuable Metals in Detoxified Waste Asbestos-Containing Waste (무해화된 폐석면에 함유된 유가금속 회수 기술 개발)

  • Kim, Dong Nyeon;Yang, Dong Hyeon;Kim, Seok Chan
    • Applied Chemistry for Engineering
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    • v.31 no.4
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    • pp.438-442
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    • 2020
  • Studies on the recovery conditions and optimization process for valuable metal recovery through chemical treatment from detoxified asbestos-containing waste composed of calcium silicate, larnite, merwinite, and akermanite were conducted. The main components, Si, Ca, and Mg, of detoxified asbestos-containing waste (DACW) were separated and recovered in the form of SiO2, CaSO4, and Mg(OH)2 compounds, respectively. Each separated component was confirmed through X-ray diffraction (XRD) and inductively coupled plasma spectrometer (ICP) analysis. The recovery conditions for each component were first treating them with an acid to separate SiO2 and subsequently with H2SO4 to recover Ca in the form of sulfate, CaSO4. The remaining Mg was recovered by precipitation with Mg(OH)2 under strong basic conditions. This study suggested that it is possible to convert existing treatment process of asbestos waste by landfill through recovering the components into a resource-recycling green technology.