• Bulletin of the Korean Chemical Society
• /
• 제32권3호
• /
• pp.863-866
• /
• 2011

The electrode reaction of $Eu^{3+}$ in a LiCl-KCl eutectic melt has been re-examined using cyclic voltammetry (CV). In this work, for the first time, the kinetic details of a $Eu^{3+}/Eu^{2+}$ redox system have been completely elucidated, along with the thermodynamic property, through a curve fitting applied to experimental CV data, which were obtained in a wide scan rate range of 0.5 to 10 V/s. The simulated results showed an excellent fit to all experimental CV data simultaneously, even though the curve fittings were performed within a large dynamic range of initial transfer coefficient values, formal potentials, and standard rate constants. As a result, a proper formal potential, transfer coefficient, and standard rate constant for the $Eu^{3+}/Eu^{2+}$ redox system were successfully extracted using the CV curve fitting.

• Proceedings of the KSME Conference
• /
• 대한기계학회 2000년도 춘계학술대회논문집A
• /
• pp.7-12
• /
• 2000

The automatic turbine startup system provides turbine control based on thermal stress. During the startup, control system monitors and evaluates main components of turbine using damage mechanism and life assessment. In case of valve chest, the temperature of inner/outer wall is measured by thermo-couples and the safety of these values are evaluated by using allowable ${\Delta}T$ limit curve during the startup. Because allowable ${\Delta}T$ limit curve includes life assessment, it is possible to apply this curve to turbine control system. In this paper, low cycle fatigue damage and combined rupture and low cycle fatigue damage criterion proposed for yielding the allowable ${\Delta}T$ limit curve of CV(control valve) chest. To calculate low cycle fatigue damage, the stress analysis of valve chest has peformed using FEM. Automatic turbine startup to assure service life of CV was achieved using allowable ${\Delta}T$ limit curve.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• 제26권1호
• /
• pp.1-6
• /
• 2002

The automatic turbine startup system provides turbine control based on thermal stress. During the startup, control system monitors and evaluates main components of turbine using damage mechanism and life assessment. In case of valve chest, the temperature of inner/outer wall is measured by thermo-couples and the safety of these values are evaluated by using allowable △T limit currie during the startup. Because allowable ΔT limit curve includes life assessment, it is possible to apply this curve to turbine control system. In this paper, low cycle fatigue damage, combined rupture and low cycle fatigue damage criterion were proposed for yielding the allowable ΔTf limit curve of CV(control valve) chest. To calculate low cycle fatigue damage, the stress analysis of valve chest has been performed using FEM. Automatic turbine startup to assure service life of CV was achieved using allowable ΔT limit curve.

• The Journal of Korean Obstetrics and Gynecology
• /
• 제26권3호
• /
• pp.85-92
• /
• 2013

Objectives: The purpose of this study is to find diagnostic points and define the cut off values of hot flashes by using digital infrared thermographic imaging. Methods: Thermographic images of 75 patients with hot flashes (HF, n=35) and non-hot flashes (NHF, n=40) were retrospectively reviewed. We used the temperature difference between Ex-HN3 and CV17, LU4, CV12, CV4 for diagnosing hot flashes. The temperature differences of between two groups were analysed using independent samples t-tests. The cut off values were calculated by received operating characteristic curve analysis. Analyses were undertaken using SPSS version 17.0. and p-value of <0.05 was considered significant. Results: The temperature difference Ex-HN3 and LU4 were the most significantly different between groups (p<0.001). Using receiver operating characteristic curve analysis, the sensitivity, specificity, and area under the curve were 65.7%, 72.5%, 0.729, respectively. The optimum cut off value was defined as $1.00^{\circ}C$. Conclusions: These results suggest that the digital infrared thermographic imaging is a reliable instrument for estimating hot flashes.

• Magazine of the Korean Society of Agricultural Engineers
• /
• 제42권5호
• /
• pp.133-143
• /
• 2000

A large scale field test of prefabricated vertical drains was performed to anayze the effect of parameters of the very soft clay at a test site. compression index and the coefficient of horizontal consolidation obtained by back-analysis of settlement data were compared with those obtained by means of laboratory tests. Hyperbolic method, Asaoka meoth and curve fitting method were used to compute final settlement of coefficient of consolidation. The relationships of settlement measurement(Sm) versus design settlement(St) and the measurement consolidation ratio(Um) versus design consolidation (Ut) were shown as Sm=(1.0~1.1) St , Um=(1.13~1.17) Ut at 1.0m spacing of drain and Sm=(0.7~0.8)St, Um= (0.92~0.99) Ut at 1.5 m spacing of drain, respectively . The relationships of the field compression index(CcField) and virgin compression index(vcc lab) were shown as Ccfield =(1.0~1.2)vcc lab . But it was nearly within the same range when considering the error factor with the determination method of virgin compression index and the prediction back-analysis of the settlement data was larger than the coefficient of vertical consolidation, and the ratio of consolidation coefficient (Ch/Cv) was Ch =(2.4~2.9) Cv , Ch=(3.4~4.2) Cv at 1.0m and 1.5m spacing of drain, respectively.

• Magazine of the Korean Society of Agricultural Engineers
• /
• 제42권4호
• /
• pp.115-123
• /
• 2000

This study compared the degree of consolidation by hyperbolic, curve fitting , Asaoka's and methods using values measured with a theoretical curve in consideration of smear effect and well resistance. The degree of consolidation by the Hyperboilc method was underestimated than the degree of consolidation by Curve fitting. Asaoka's , and Monden's methods. The typical range of the coefficient of horizontal consolidation was Ch=(2-3)Cv in the case considering smear effect and well resistance, and Ch =(0.5-2.1) Cv in the case disregarding smear effect and well resistance. The degree of consolidation obtained by ground settlement monitoring was nearly the same value when the coefficient of smear zone permeability by back analysis was shown to be half that of in-situ and the diameter of the smear zone was shown to be double that of mandrel. By increasing the diameter reduction ratio of the drain, the time of consolidation was delayed. The effect of well resistance showed that the case of a small coefficient of permeability was much more than in the case of a large coefficient of permeability . It was recommended that when designing diameter reduction of a drain, well resistance should be considered.

• Journal of Environmental Health Sciences
• /
• 제35권2호
• /
• pp.130-142
• /
• 2009

This study compared FTIR with XRD method for the analysis of quartz by % recovery, coefficient of variation (CV) and influence of the interference. the results were as the following. 1. In FTIR method, the coefficient of determination ($r^2$) was 0.9998 in a calibration curve of $695\;cm^{-1}$, and the limit of detection was $4.9{\mu}g/sample$. 2. The highest recovery was $799\;cm^{-1}$ (98.2%). 3. The CVpooled of the FTIR method was approximately 10% in three wave numbers. 4. The analysis of qualitative and quantitative for quartz is difficult with mixed cristobalite and iron oxide. 5. In XRD method with rotating sample holder and LynxEye detector, the coefficient of determination was 0.9996 in a calibration curve, and the limit of detection was $5.9{\mu}g/sample$. 6. The recovery and CV pooled were 104.3%, and 11 %, respectively. 7. In muffle furnace ashing, the quartz weight decreased to 34% when the maximum weight of the iron oxide was more than eight times. In conclusion, the accuracy (% recovery) and precision (CV) of FTIR and XRD method for analyzing $\alpha$-quartz were similar. FTIR method was a disadvantage for sample matrix because it indicates possibility of interference. However, XRD method distinguished specific crystalline forms of silica, and the majority of silicate minerals. In addition, XRD method recommend filter dissolution to pretreatment method.

• The Korean Journal of Nuclear Medicine Technology
• /
• 제20권2호
• /
• pp.75-79
• /
• 2016

Purpose The ASAN Medical Center, Nuclear Medicine performs TSH (Thyroid stimulating hormone) and FT4 (Free Thyroxine) tests 8 times per day. Accordingly, 70 ~ 80 kit tubes are consumed every day for the measurements and the time consumed for reagent dispensing averages over 170 seconds, where the TAT (turnaround time) may be effected when the number of test samples is larger than expected. Therefore, the following test was conducted with the purpose to reduce the number of kit tubes consumed, and reduce the time for reagent dispensing. Materials and Methods The test is based on applying the same reagent for tests where the number of samples is 30 or less. The test for TSH was conducted 9 times from July $1^{st}$ 2015 to July $10^{th}$ 2015. The test for FT4 was conducted 4 times from June $18^{th}$ 2015 to June $22^{nd}$, 2015. Standard Solution No.2 (0.153 uU/mL) and No.5 (4.96 uU/mL) was selected as the two-point standards for the TSH test, and Standard Solution No.3 (0.777 ng/dL) and No.4 (2.044 ng/dL) was selected as the two-point standards for the FT4 test. 38 test samples were subject to correlation analysis. Results For TSH, the result of the normal test shows ranges of 0.20 ~ 0.37 uU/mL for Control1, 0.53 ~ 0.71 uU/mL for Control2, and 6.77 ~ 7.94uU/mL for Control3, while the result of two-point calibration curve test shows ranges of 0.18 ~ 0.27 uU/mL for Control1, 0.53 ~ 0.71 uU/mL for Control2, and 7.30 ~ 8.52 uU/mL for Control3. For FT4, the result of the normal test shows ranges of 0.85 ~ 0.94 ng/dL for Control1 and 4.23 ~ 4.57 ng/dL for Control2, while the result of two-point calibration curve test shows ranges of 0.61 ~ 0.75 ng/dL for Control1 and 3.88 ~ 5.71 ng/dL for Control2. For TSH, the CV% of the normal test for Control1, Control2 and Control3 are 10.5, 3.3 and 3.6 respectively, while the CV% of the two-point calibration curve test for Control1 and Control1 are 12.4, 8.2 and 5.1 respectively. The result shows an outstanding correlation of TSH: y = 0.9985x - 0.0459 $R^2=0.9986$. For FT4, the CV% of the normal test for Control1 and Control2 are 0.70 and 0.71 respectively, while the CV% of the two-point calibration curve test for Control1 and Control1 are 8.7 and 16.2 respectively. The result shows an outstanding correlation of FT4: y = 1.2674x - 0.1133 $R^2=0.9824$. Conclusion The two-point calibration curve can be efficiently applied for TSH in cases where the number of test samples is not large, since the number of samples to be re-tested increases when the result is abnormal from the calibration curve. The two-point calibration curve test should not be applied for FT4 where the results do not consistently comply with the quality assessment range. Depending on how the two-point calibration curve is applied, up to 5 test tubes can be conserved per test, and the reduced time for reagent dispensing is anticipated to have a positive effect on the TAT (turnaround time).

• Journal of the Institute of Electronics Engineers of Korea SD
• /
• 제39권1호
• /
• pp.1-11
• /
• 2002

In this paper, new simple method for the calculation of depletion region under complex geometry and general purpose numerical simulator that could handle this were developed and applied in the analysis of SCM with nanoscale tip, which is a promising tool for high resolution dopant profiling. Our simple depletion region seeking algorithm alternatively switches material of elements to align ionized element boundary with contour of zero potential. To prove the validity of our method we examined whether our results satisfy the definition of depletion region and compared those with known values of un junction and MOS structure. By modeling of capacitance based on the shape of depletion region and potential distribution, we could calculate the CV curve and dC/dV curve between silicon substrate and nanoscale SCM tip.

• Journal of Korean Society on Water Environment
• /
• 제27권2호
• /
• pp.228-234
• /
• 2011

The goal of water quality management on stream and watershed is to focus not on discharged loads management but on a water quality management. Discharged loads management is not goal of water quality management but way for perform with total maximum daily loads management. It is necessary to estimate the relation between non-point source with stromwater runoff (NPSSR) and water quality to select a watershed where it is required to manage NPSSR for water quality improvement. To evaluate the effects of NPSSR on stream's water quality, we compare the aspects of water quality in dry and wet seasons using flow duration curve analysis based on flow rate variation data by actual surveying. In this study we attempt to quantify the variation characteristic of water quality and estimate the Inflow characteristic of pollution source with water quality and flow rate monitoring on 10 watersheds. We try to estimate water quality and flow rate by regression analysis and try again regression analysis with each high and low water quality data more than estimations. An analysis of relation between water quality and flow rate of 10 watersheds shows that the water quality of the Nonsan and the Ganggyeong streams had been polluted by NPSSR pollutants. Other eight streams were important point source more than NPSSR. It is wide variation range of $BOD_5$ also high average concentration of $BOD_5$. We have to quantify water quality variation by cv1 in wet season and cv365 in dry season with comparing the estimate of high water quality and low water quality. This method can be used to indicator for water quality variation according to flow rate.