• Title/Summary/Keyword: CR39

Search Result 426, Processing Time 0.024 seconds

Corrosion Behavior and Surface Coating of Muffler Materials by Using EB-PVD (전자빔 진공증착기를 이용한 muffler재료의 표면코팅과 내식특성)

  • 최한철
    • Journal of the Korean institute of surface engineering
    • /
    • v.34 no.1
    • /
    • pp.39-48
    • /
    • 2001
  • Fe-Cr-Al alloy has been studied for application in automobile muffler materials due to good corrosion and oxidation resistance. In order to develop the automobile muffler materials, corrosion behaviors of electron beam physical vapor deposition (EB-PVD) coated surface of muffler matericls of muffler materials were investigated using potentiostat. For 0.1M NaCl solution, corrosion potential and pitting potential of Fe-20Cr-10Al was higher than that of Fe-5Cr- 10Al samples. Especially, in the case of Ti and Nb coated samples, pitting potential increased remarkably compared with non-coated samples. For 0.1M $CaCl_2$ solution, Ti-coated Fe-20Cr-10Al showed remarkably improved pitting corrosion resistance in comparison with non-coated Fe-20Cr-10Al and Fe-5Cr-10Al. The number and size of pits were decreased in the case of Ti coated samples in the 0.1M NaCl and 0.1M $CaCl_2$ solution.

  • PDF

A Study on the wear properties of Cr-Zr-N films deposited by closed field unbalance magnetron sputtering (비대칭 마그네트론 스퍼터링 방법으로 제작한 CrZrN 박막의 마모특성 분석)

  • Kim, Jeong-Taek;Lee, Sang-Yul;Han, Jun-Hui
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2007.04a
    • /
    • pp.38-39
    • /
    • 2007
  • Chromium nitrids(Cr-N)박막은 경질박막재료이며 특히 PVD법을 제조한 CrN 박막은 다른 이원계 박막에 비해 높은 내마모성을 갖는다고 알려져 있다. 본 실험에서는 CrN박막에 Zr을 첨가하여 3원계의 CrZrN 박막을 합성하여 박막의 Zr 함량에 따른 표면경도 및 조도를 측정하고 Ball-on-disk type의 마모실험과 습도제어 하에서의 마모실험을 실시하였다. 박막의 Zr 함량이 증가함에 따라 박막의 표면경도가 증가하고 표면조도는 낮아지는 것을 알수 있었고, 그에 따라 마찰계수 값 또한 낮게 측정되었다. 습도제어하에서는 마찰계수 값은 비슷한 경향을 보였으나 습도가 매우 낮은 건조한 환경에서는 박막의 마찰계수 값이 높게 나타나는 경향을 보였다.

  • PDF

Microstructural and Mechanical Properties of CrTiAlN Nanocomposite thin films synthesis by Closed Field Unbalanced Magnetron Sputtering (비대칭 마그네트론을 이용한 CrTiAlN 나노복합 박막의 미세구조와 기계적 특성)

  • Kim, Yeon-Jun;Lee, Ho-Yeong;Byeon, Tae-Jun;Kim, Gap-Seok;Han, Jeon-Geon
    • Proceedings of the Korean Institute of Surface Engineering Conference
    • /
    • 2007.04a
    • /
    • pp.65-66
    • /
    • 2007
  • 비대칭 마그네트론을 이용하여 사원계 CrTiAlN 나노 복합 박막을 합성하였고 합성된 박막의 특성을 분석하였다. CrTiAlN 나노복합 박막의 미세구조는 CrN (111)과 CrN (200)방향으로 성장하였고 기계적 특성은 $30\;{\sim}\;39\;GPa$의 경도 값을 얻었다. 질소 분압이 0.33 Pa에서 가장 높은 경도 값을 얻을 수 있었다.

  • PDF

Application of CR-39 Microfilm for Rapid Discrimination Between Alpha-Particle Sources

  • Dwaikat, Nidal;Al-Karmi, Anan M.
    • Nuclear Engineering and Technology
    • /
    • v.49 no.4
    • /
    • pp.881-885
    • /
    • 2017
  • This work presents a new technique for discriminating between alpha particles of different energy levels. In a first study, two groups of alpha particles emitted from radium-226 and americium-241 sources were successfully separated using a CR-39 microfilm of appropriate thickness. This thickness was adjusted by chemical etching before and after irradiation so that lower-energy particles were stopped within the detector, while higher-energy particles were revealed on the back side of the detector. The number of tracks on the front side of the microfilm represented all alpha particles incident on that side from the two sources. However, the number of tracks on the back side of the microfilm represented only the long-range alpha particles of higher energy that arrived at that side. Therefore, by subtracting the number of tracks on the back side from the number of tracks on the front side, one could easily determine the number of tracks for the short-range alpha particles of lower energy that remained embedded in the microfilm. Discrimination of the two energy levels is thus achieved in a simple, fast, and reliable process.

Effect of Cr Contents on Precipitation Process of Cu-Cr Alloys (크롬동합금의 시효석출거동에 미치는 Cr 첨가량의 영향)

  • Koo, B.H.;Chon, G.B.;Lee, C.G.;Kim, C.J.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.18 no.5
    • /
    • pp.305-311
    • /
    • 2005
  • Effect of Cr contents(Cr: 0.27, 0.45 and 0.65wt.%) on precipitation process has been studied by electrical resistivity measurements, hardness and scanning electron microscope. The first stage of the process consists of the formation of Cr-rich particles, the second stage consists of the competitive growth of these particles. The kinetics of precipitation could be described by Johnson-Mehl-Avrami equation, $f(t)=1-\exp(-kt^n)$. The values of n were found to be in the range from 0.17 to 0.39 at the first stage and from 1.0 to 1.5 at the second stage. The activation energies of Cu-Cr alloys were determined by Cross-Cut method and were 90~136 kJ/mol. The maximum hardness value of $H_RB$ 84 was obtained in Cu-0.65wt.%Cr alloy.

Effective Dose Equivalent due to Inhalation of Indoor Radon-222 Daughters in Korea (한국인의 라돈-222 자핵종 호흡 실효선량당량 평가)

  • Chang, Si-Young;Ha, Chung-Woo;Lee, Byoung-Hun
    • Journal of Radiation Protection and Research
    • /
    • v.16 no.1
    • /
    • pp.1-13
    • /
    • 1991
  • Effective dose equivalents resulting from inhalation of indoor radon-222 daughters at 12 residential areas in Korea were assessed by a simple mathematical lung dosimetry model based on the measurements of long-term averaged radon concentrations at 340 dwellings. The long-term averaged indoor radon-222 concentrations and corresponding eqilibrium equivalent radon $concentration(EEC_{Rn})$ measured by passive time-integrating CR-39 radon cups are in the range of $33.82{\sim}61.42Bq/m^3(median\;:\;48.90Bq/m^3)$ and of $13.53{\sim}24.57Bq/m^3(median\;:\;19.55Bq/m^3)$, respectively. The effective dose equvalent conversion factor for the exposure to unit $EEC_{Rn}$ derived in this study was estimated $1.07{\times}10^{-5}mSv/Bq\;h\;m^{-3}$ for a reference adult and agreed well with those recommended by the ICRP and UNSCEAR. The annual average dose equivalent to the lung $(H_{LUNG})$ from inhalation exposure to measured $EEC_{Rn}$ was estimated to be 20.90 mSv and resulting effective dose $equivalent(H_E)$ was to be 1.25 mSv, which is about 50% of the natural radiation exposure of 2.40 mSv/y to the public reported by the UNSCEAR.

  • PDF

Dosimetry of $^{222}Rn$ Component in Outdoor Natural Background Radiation (자연 방사선량 중 $^{222}Rn$기여 성분 정량 해석)

  • Jun, Jae-Shik;Oh, Hi-Peel;Chae, Ha-Suk;Lee, Byung-Young;Kim, Do-Sung
    • Journal of Radiation Protection and Research
    • /
    • v.14 no.2
    • /
    • pp.10-17
    • /
    • 1989
  • A study for the assessment of dose given by outdoor radon to respiratory system has been carried out by making use of radon-cups containing CR-39 plastic track detectors. Detection efficiencies were determined by irradiation of the radon-cups in a standard radon chamber of known concentration. Thus determined detection factors of CR-39 plastic track detector in bare, open cup and filtered cup geometry are found to be 0.273, 0.0813 and 0.0371 $trmm^{-2}$/(37$Bqm^{-3}{\cdot}d$), respectively, which are chemically etched in 30% NaOH solution of $70^{\circ}C$ for 220 minutes. The outdoor radon concentrations measured at Taejeon(Chungnam National University) from May 1988 to March 1989 are in the range of 27.4 - 135.8 Bq/$m^3$(0.74 - 3.67pCi/l)by open cup and 16.7 - 143.9 Bq/$m^3$(0.45 - 3.89 pCi/l) by filtered cup, which yield overall annual average value of outdoor radon concentration of $70.8Bq/m^3$(1.91 pCi/l). Corresponding effective dose equivalent rate to respiratory system of ICRP standard man is assessed to be 520 nSv /h.

  • PDF

High Temperature Oxidation of NiCoCrAlY-(Ta, Re, Ir) Coatings for Gas Turbines (가스터빈 엔진부품용 NiCoCrAlY-(Ta, Re, Ir) 코팅의 고온산화특성)

  • Choi, J.H.;Lee, D.B.
    • Journal of the Korean institute of surface engineering
    • /
    • v.39 no.3
    • /
    • pp.129-136
    • /
    • 2006
  • The high velocity oxy-fuel sprayed coatings of 38Ni-23Co-20Cr-11Al-3Y-5Ta, 25Ni-34Co-20Cr-11Al-3Y-2Re and 32Ni-34.5Co-22Cr-11Al-0.5Ir (in wt%) were oxidized at 1000 and $1100^{\circ}C$ in air in order to find the alloying effect of Ta, Re and Ir on the oxidation properties of the NiCoCrAlY-base coatings. The primary phase of the coatings was $Ni_3Al$. The oxides formed on the coatings consisted primarily of ${\alpha}-Al_2O_3$, together with some $CoCr_2O_4,\;CoAl_2O_4$, and $Al_5Y_3O_{12}$. Tantalum oxidized to $Ta_2O_5$ and $Ta_2O_{22}$. However, no oxides of Re and Ir were detected by XRD owing to their thermodynamic inertness and/or their small amount.

A Study of Ozonation Characteristics of Bis(2-chloroethyl) Ether (Bis(2-chloroethyl) Ether (BCEE)의 오존산화 특성에 관한 연구)

  • Lee, Cheal-Gyu;Kim, Moon-Chan
    • Applied Chemistry for Engineering
    • /
    • v.21 no.6
    • /
    • pp.610-615
    • /
    • 2010
  • In this study ozonation of bis(2-chloroethyl) ether (BCEE) in aqueous solution was performed in a laboratory scale batch reacter. The ozonation process of BCEE was carried out by bubbling ozone at the bottom of reactor containing the BCEE solution. Ozonation was almost complete after 80 min with an ozone concentration of $50{\pm}10mg/L$. Ozonation treatment efficiencies of BCEE were evaluated in terms of $BOD_5$, $COD_{Cr}$, and TOC. In the ozonation of BCEE a 62.79% decrease of the $COD_{Cr}$ and a 57.25% decrease of the TOC lead to biodegradable by-products ($BOD_5/COD_{Cr}$ = 0.39). The results of this research show that wastewaters containing non-biodegradable compounds, such as BCEE can be successfully treated by ozonation followed by bio-treatment. The pseudo first-order rate constants of the ozonation was $2.00{\times}10^{-4}sec^{-1}$ and the activation energy was $10.02kcal{\cdot}mol^{-1}$ at $30^{\circ}C$.