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Shear bond strength of luting cements to fixed superstructure metal surfaces under various seating forces

  • Ozer, Fusun;Pak-Tunc, Elif;Dagli, Nesrin Esen;Ramachandran, Deepika;Sen, Deniz;Blatz, Markus Bernhard
    • The Journal of Advanced Prosthodontics
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    • v.10 no.5
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    • pp.340-346
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    • 2018
  • PURPOSE. In this study, the shear bond strengths (SBS) of luting cements to fixed superstructure metal surfaces under various seating forces were investigated. MATERIALS AND METHODS. Seven different cements [Polycarboxylate (PCC), Glass-Ionomer (GIC), Zinc phospahate (ZPC), Self-adhesive resin (RXU), Resin (C&B), and Temporary cements ((RXT) and (TCS))] were bonded to a total number of 224 square blocks ($5{\times}5{\times}3mm$) made of one pure metal [Titanium (CP Ti) and two metal alloys [Gold-Platinum (Au-Pt) and Cobalt-Chrome (Co-Cr)] under 10 N and 50 N seating forces. SBS values were determined and data were analyzed with 3-way ANOVA. Pairwise comparisons and interactions among groups were analyzed with Tukey's simultaneous confidence intervals. RESULTS. Overall mean scores indicated that Co-Cr showed the highest SBS values ($1.96{\pm}0.4$) (P<.00), while Au-Pt showed the lowest among all metals tested ($1.57{\pm}0.4$) (P<.00). Except for PCC/CP Ti, RXU/CP Ti, and GIC/Au-Pt factor level combinations (P<.00), the cements tested under 10 N seating force showed no significantly higher SBS values when compared to the values of those tested under 50 N seating force (P>.05). The PCC cement showed the highest mean SBS score ($3.59{\pm}0.07$) among all cements tested (P<.00), while the resin-based temporary luting cement RXT showed the lowest ($0.39{\pm}0.07$) (P<.00). CONCLUSION. Polycarboxylate cement provides reliable bonding performance to metal surfaces. Resin-based temporary luting cements can be used when retrievability is needed. GIC is not suitable for permanent cementation of fixed dental prostheses consisting of CP Ti or Au-Pt substructures.

Synthesis and Characterization of Polyphase Waste Form to Immobilize High Level Radioactive Wastes (고준위 방사성 폐기물의 고정화를 위한 다상 고화체 합성)

  • Chae Soo-Chun;Jang Young-Nam;Bae In-Kook;Ryu Kyung-Won
    • Economic and Environmental Geology
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    • v.39 no.2 s.177
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    • pp.173-180
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    • 2006
  • The synthesis of polyphase waste form, which is an immobilization matrix fur the high level radioactive wastes, was performed with the mixed composition of garnet and spinel $(Gd_3Fe_5O_{12}+(Ni_xMn_{1-x})(Fe_yCr_{1-y})_2O_4)$ in the range of 1200 to $1400^{\circ}C$. The phases synthesized from all stoichiometric compositions were garnet, perovskite, and spinel. Especially, garnet was synthesized only in the composition of the highest content of Fe(y=0.9), whereas it was not synthesized in other compositions. This result indicated that the content of Fe was closely related to the formation of garnet. The composition of garnet revealed that the content of Gd was exceeded and that of Fe was depleted. Preferential distribution of elements in the phases can be attributed to the nonstoichiometric composition of garnet.

An experimental study on shear mechanical properties of clay-concrete interface with different roughness of contact surface

  • Yang, Wendong;Wang, Ling;Guo, Jingjing;Chen, Xuguang
    • Geomechanics and Engineering
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    • v.23 no.1
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    • pp.39-50
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    • 2020
  • In order to understand the shear mechanical properties of the interface between clay and structure and better serve the practical engineering projects, it is critical to conduct shear tests on the clay-structure interface. In this work, the direct shear test of clay-concrete slab with different joint roughness coefficient (JRC) of the interface and different normal stress is performed in the laboratory. Our experimental results show that (1) shear strength of the interface between clay and structure is greatly affected by the change of normal stress under the same condition of JRC and shear stress of the interface gradually increases with increasing normal stress; (2) there is a critical value JRCcr in the roughness coefficient of the interface; (3) the relationship between shear strength and normal stress can be described by the Mohr Coulomb failure criterion, and the cohesion and friction angle of the interface under different roughness conditions can be calculated accordingly. We find that there also exists a critical value JRCcr for cohesion and the cohesion of the interface increases first and then decreases as JRC increases. Moreover, the friction angle of the interface fluctuates with the change of JRC and it is always smaller than the internal friction angle of clay used in this experiment; (4) the failure type of the interface of the clay-concrete slab is type I sliding failure and does not change with varying JRC when the normal stress is small enough. When the normal stress increases to a certain extent, the failure type of the interface will gradually change from shear failure to type II sliding failure with the increment of JRC.

Localizations of substance P, CGRP and calcium binding proteins in Korean native goat duodenum (한국재래산양 십이지장의 장관신경계통에 분포하는 Substance P, CGRP 및 칼슘결합단백질 반응세포에 대한 면역조직화학적 연구)

  • Lee, In-se;Lee, Heungshik S.;Song, Seung-hoon;Yoon, Sung-tae;Hwang, In-koo;Kang, Tae-cheon;Won, Moo-ho;Seo, Je-hoon
    • Korean Journal of Veterinary Research
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    • v.39 no.3
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    • pp.435-447
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    • 1999
  • The localization of substance P(SP), calcitonin gene-related peptide(CGRP) and three calcium binding proteins, calbindin D-28k(CB), calretinin(CR) and parvalbumin(PA) was immunohistochemically examined in the myenteric and submucous plexuses of Korean native goat duodenum. In the neurons of myenteric and submucous plexuses of duodenum, immunoreactivities of SP, CGRP and CB were confirmed in both nerve cell bodies and fibers. In contrast, CR immunoreactivity was found only in nerve fibers of myenteric plexuses, while PA immunoreactivity was found only in nerve cell bodies of submucous plexuses. In the inner circular muscle layer, dense SP-like immunoreactive fibers were prominent but only a few CGRP-like immunoreactivities were observed. Most of SP- and CGRP-like immunoreactive neurons of both plexuses colocalized with CB. This result showed that SP and CGRP may have a important role for the movement of small intestine. The colocalizations of CB with SP or CGRP in myenteric and submucous plexuses suggest that CB may serve neuromodulatory role for SP- and CGRP-immunoreacted neurons on the movement of intestinal wall.

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Face detection using fuzzy color classifier and convex-hull (Fuzzy Color Classifier 와 Convex-hull을 사용한 얼굴 검출)

  • Park, Min-Sik;Park, Chang-U;Kim, Won-Ha;Park, Min-Yong
    • Journal of the Institute of Electronics Engineers of Korea SP
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    • v.39 no.2
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    • pp.69-78
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    • 2002
  • This paper addresses a method to automatically detect out a person's face from a given image that consists of a hair and face view of the person and a complex background scene. Out method involves an effective detection algorithm that exploits the spatial distribution characteristics of human skin color via an adaptive fuzzy color classifier (AFCC), The universal skin-color map is derived on the chrominance component of human skin color in Cb, Cr and their corresponding luminance. The desired fuzzy system is applied to decide the skin color regions and those that are not. We use RGB model for extracting the hair color regions because the hair regions often show low brightness and chromaticity estimation of low brightness color is not stable. After some preprocessing, we apply convex-hull to each region. Consequent face detection is made from the relationship between a face's convex-hull and a head's convex-hull. The algorithm using the convex-hull shows better performance than the algorithm using pattern method. The performance of the proposed algorithm is shown by experiment. Experimental results show that the proposed algorithm successfully and efficiently detects the faces without constrained input conditions in color images.

Effect of different tooth preparation designs on the marginal and internal fit discrepancies of cobalt-chromium crowns produced by computer-aided designing and selective laser melting processes

  • Yu, Na;Dai, Hong-Wei;Tan, Fa-Bing;Song, Jin-Lin;Ma, Chao-Yi;Tong, Xue-Lu
    • The Journal of Advanced Prosthodontics
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    • v.13 no.5
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    • pp.333-342
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    • 2021
  • PURPOSE. To evaluate the impact of five different tooth preparation designs on the marginal and internal fit discrepancies of cobalt-chromium (CoCr) crowns produced by computer-aided designing (CAD) and selective laser melting (SLM) processes. MATERIALS AND METHODS. Five preparation data were constructed, after which design crowns were obtained. Actual crowns were fabricated using an SLM process. After the data of actual crowns were obtained with structural light scanning, intaglio surfaces of the design crown and actual crown were virtually superimposed on the preparation. The fit-discrepancies were displayed with colors, while the root means square was calculated and analyzed with one-way analysis of variance (ANOVA), Tukey's test or Kruskal-Wallis test (α = .05). RESULTS. The marginal or internal color-coded images in the five design groups were not identical. The shoulder-lip and sharp line angle groups in the CAD or SLM process had larger marginal or internal fit discrepancies compared to other groups (P < .05). In the CAD process, the mean marginal and internal fit discrepancies were 10.0 to 24.2 ㎛ and 29.6 to 31.4 ㎛, respectively. After the CAD and SLM processes, the mean marginal and internal fit discrepancies were 18.4 to 40.9 ㎛ and 39.1 to 47.1 ㎛, respectively. The SLM process itself resulted in a positive increase of the marginal (6.0 - 16.7 ㎛) and internal (9.0 - 15.7 ㎛) fit discrepancies. CONCLUSION. The CAD and SLM processes affected the fit of CoCr crowns and varied based on the preparation designs. Typically, the shoulder-lip and sharp line angle designs had a more significant effect on crown fit. However, the differences between the design groups were relatively small, especially when compared to fit discrepancies observed clinically.

The Content of Heavy Metals in Herbal Pills Used as General Processed Food and Risk Assessment of Heavy Metal Intakes (유통 환(丸)제품의 중금속 함량 및 위해성 평가)

  • Kim, Sung-Dan;Jung, Sun-Ok;Kim, Bog-Soon;Yun, Eun-Sun;Chang, Min-Su;Park, Young-Ae;Lee, Young-Chul;Chae, Young-Zoo;Kim, Min-Young
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.7
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    • pp.1038-1048
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    • 2010
  • The purpose of this study was to investigate some heavy metals (Pb, Cd, Cr, Cu, Hg) in 52 commercial herbal pills used as general processed food, to identify weekly heavy metal intakes from herbal pills and to evaluate their potential health risks. The samples were digested with a microwave and determinations of heavy metal residues were carried out by inductively coupled plasma mass spectrometry (ICP-MS) and mercury analyzer. The mean values of heavy metal contents for herbal pills used as general processed food were Pb 0.421 (0.032~1.630), Cd 0.157 (0.011~0.515), Cr 1.033 (0.112~9.933), Cu 6.923 (1.333~16.755), Hg 0.010 (0.001~0.088) mg/kg. Lead contents of herba and cadmium of algae, herba were high (ANOVA-test, p<0.05). Levels of cadmium concentrations exceeding WHO reference values (0.3 mg/kg) were observed in 10 samples (4 species). The significant correlation was observed between Pb and Cd (r=0.633, p<0.01). The weekly intakes of Pb, Cd, Cr, Cu, Hg from herbal pills were 1.112 (0.072~5.088), 1.614 (0.029~9.257), 3.000 (0.252~23.690), 0.182 (0.008~1.235), 0.220 (0.000~0.420)%, respectively, as compared with the Provisional Tolerable Weekly Intake (PTWI) established by Joint FAO/WHO Expert Committee for food safety evaluation. Our data suggest regulations limiting heavy metals in herbal pills used as general processed food.

Antimicrobial Drug Resistance and Transferable Resistance Plasmid in Escherichia coli (대장균(大腸菌)의 항균제내성(抗菌劑耐性) 및 전달성(傳達性) Plasmid)

  • Cho, Dong-Taek;Chun, Do-Ki
    • The Journal of the Korean Society for Microbiology
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    • v.17 no.1
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    • pp.21-34
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    • 1982
  • One hundred and twenty-one strains each of Escherichia coli isolated from stools of 60 patients who received various antimicrobial drugs in hospital for more than one week and apparently healthy 60 students who have no history of taking antimicrobial drugs during recent one month, were tested for their resistance to 13 antimicrobial drugs. The frequency of resistance strains was highest to tetracycline with 69.2%, and followed by streptomycin(Sm), sulfisomidine(Su), chloramphenicol(Cm), ampicillin(Ap), and carbenicillin(Cb) in the decreasing order, ranging from 61.2% to 39.3%. Strains resistant to kanamycin(Km), cephaloridine(Cr), and trimethoprim(Tp) occupied about one-fourth of strains, and only four strains were resistant either one or more of nalidixic acid, gentamicin and amikacin, and no strain was resistant to rifampicin. The frequency of resistant strains to Cm, Ap, Km, Cr, and Cb was much higher among patient isolates than student strains, but strains resistant to the other drugs showed almost the same frequencies between patient and student isolates. There was a marked difference in average minimum inhibitory concentrations of between resistant and susceptible strains, suggesting that the resistance to drugs is the plasmid origin. Seventy-six percent of strains were resistant to one to 10 drugs tested, and no much difference was observed between strains from patients and students. However, strains resistant to four or more drugs were much more frequently found among patient isolates than student strains, with the increasing tendency of multiply resistant strains among patient isolates following the increase in the number of resistant drugs. The transfer of drug resistance by conjugation was tested and 98 strains(67.5%) among 145 which were resistant to two or more drugs were found to transfer their drug resistance to E. coli. Among 74 strains resistant to 7 or more drugs, all except one transferred the resistance, and the number of strains with transferable resistance decreased, as the number of resistant drugs decrease. A R plasmid from randomly selected p13 strain was tested for the incompatibility group, and the plasmid was classified into Inc F II. R plasmM DNA bands were identified by polyacrylamide gel electrophoresis.

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A study on Airborne Concentration of Welding Fumes and Metals in Confined Spaces of a Shipyard (모조선소의 밀폐된 작업장에서의 공기중 용접흄 및 중금속 농도에 관한 조사 연구)

  • Kwag, Young-Soon;Paik, Nam-Won
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.7 no.1
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    • pp.113-131
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    • 1997
  • This study was performed to evaluate the exposure levels of worker exposed to welding fume and metals in confined spaces of a shipyard. The airborne concentration of welding fumes and metal elements in confined spaces were compared with those in open working areas. Results of the study were as follows. 1. The geometric mean of welding fume concentration in a confined space was $16.6mg/m^3$, which contained $3.9mg/m^3$ Fe, $1.2mg/m^3$ Mg, $0.8mg/m^3$ Zn, $0.008mg/m^3$ Cu, $0.008mg/m^3$ Pb, $0.005mg/m^3$ Ni, $0.003mg/m^3$ Cr, $0.003mg/m^3$ Cd. The geometric mean of welding fume concentration in open working areas was $5.2mg/m^3$, which contained $1.1mg/m^3$ Fe, $0.3mg/m^3$ Mg, $0.3mg/m^3$ Zn, $0.004mg/m^3$ Cu, $0.008mg/m^3$ Pb, $0.005mg/m^3$ Ni, $0.003mg/m^3$ Cr, $0.0003mg/m^3$ Cd. The geometric mean of welding fume concentration in confined spaces was 3,2 times higher than that in open working areas. The geometric mean concentrations of such metals as Fe, Mg, Zn, or Cu within fume in confined spaces were 2-4 times higher than those in open working areas, while little difference made such metals as Pb, Ni, Cr, Cd. 2. In 32 samples out of a total of 39 samples (82.1%) collected in confined spaces, the concentrations of welding fume exceeded TLV. while so did 19 samples out of 33 samples (57.6%) in open working areas. As for the concentrations of metals in welding flume from confined spaces, Fe exceeded TLV in 14 out of a total of 38 samples (36.8%), Mn exceeded TLV in 23 out of a total of 38 samples (60.5%). As for the concentration of metals in welding fume from open working areas, Fe exceeded TLV in 3 out of a total of 34 samples (8.8%), Mn exceeded TLV in 6 out of a total of 34 samples (17.6%). Considering additive effect among metals, in 31 out of a total of 39 samples (79.5%) collected in confined spaces, the concentrations of welding fume exceeded TLV, while so did 14 out of 38 samples (55.6%) in open working areas. 3. In respect of base metal and welding type the concentration of total welding fume by $CO_2$ gas W./mild steel was the highest, followed by semiauto MMA/mild steel, then followed by TIG or $CO_2$ gas W./stainless steel. ; as for concentration of metal within fume, a decreasing order was Fe, Zn, Mn, and Pb in $CO_2$ gas W./mild steel and semiauto MMA/mild steel, but Fe, Mn, Cr, and Ni in TIG or $CO_2$ gas W./stainless steel. 4. In case of welding base metal covered by paint, contents of Zn within red paint chip and within gray paint chip were 14.0% and 0.08% respectively, which showed a little difference, while the airborne concentrations of Zn within fume during welding base metal covered red paint and gray paint were $1.351mg/m^3$ and $1.018mg/m^3$ respectively, which showed little difference. As for Pb, contents of red paint chip and gray paint chip were 0.14% and 0.08% respectively, and the airborne concentrations within fume during welding base metal covered red paint and gray paint were $0.009mg/m^3$ and $0.007mg/m^3$ respectively, both of which showed little difference.

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Organic Matter and Heavy Metals Pollution Assessment of Surface Sediment from a Fish Farming Area in Tongyoung-Geoje Coast of Korea (통영-거제 연안 어류 양식장 표층 퇴적물 중 유기물 및 중금속 오염 평가)

  • Hwang, Dong-Woon;Hwang, Hyunjin;Lee, Garam;Kim, Sunyoung;Park, Sohyun;Yoon, Sang-Pil
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.27 no.4
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    • pp.510-520
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    • 2021
  • To understand the status of organic matter and heavy metal pollution in surface sediment of a fish farming area, we have measured the concentrations of total organic carbon (TOC), total nitrogen (TN), and heavy metals (As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn) in surface sediments of a fish farming area near Tongyoung-Geoje coast. The mean concentrations of TOC and TN were 22.7 mg/g and 3.4 mg/g, respectively, and were much higher than those in surface sediments of a semi-enclosed bay in the southern coast of Korea. The mean concentrations of As, Cd, Cr, Cu, Fe, Hg, Mn, Pb, and Zn were 10.5 mg/kg, 0.37 mg/kg, 82.9 mg/kg, 127 mg/kg, 4.19%, 0.041 mg/kg, 596 mg/kg, 39.5 mg/kg, and 175 mg/kg, respectively, and the mean concentrations of Cd and Cu were three times higher than those in surface sediments of shellfish farming area in the southeastern coast of Korea. In addition, the concentrations of TOC and corrected Cu exceeded the values of sediment quality guidelines applied in Korea, and pollution load index (PLI) and ecological risk index (ERI) showed that the metal concentrations in the sediments of some fish farming area have a strongly negative ecological impact on benthic organisms, although most metal concentrations did not exceed the sediment quality guidelines. Based on overall assessment results, the surface sediments of fish farming areas in the study region are polluted with organic matter and some heavy metals. Thus, a comprehensive management plan is necessary to improve the sedimentary environments, identify primary contamination sources, and reduce the input of pollution load for organic matter and heavy metals in the sediments of fish farming areas.