• 한국물환경학회지
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• 제21권3호
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• pp.256-262
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• 2005

The purpose of this study is to investigate the performances of organic removal and methane recovery by using a full scale two-phase anaerobic system. The full scale two-phase anaerobic process was consists of an acidogenic anaerobic baffled reactor (ABR) and a methanognic upflow anaerobic sludge blanket (UASB) reactor. The volumes of acidogenic and methanogenic reactors were designed to $28.3m^3$ and $75.3m^3$. The two-phase anaerobic system represented 60-82% of COD removal efficiency when the influent COD concentration was in the range of 7,150 to 16,270 mg/L after screening (average concentration is 10,280 mg/L). After steady-state, the effluent COD concentration in the methanogenic reactor showed $2,740{\pm}330 mg/L$ by representing average COD removal efficiency was $71.4{\pm}8.1%$ when the operating temperature was in the range of $19-32^{\circ}C$. The effluent SCOD concentration was in the range of 2,000-3,000 mg/L at the steady state while the volatile fatty acid concentration was not detected in the effluent. Meanwhile, the COD removal efficiency in the acidogenic reactor showed less than 5%. The acidogenic reactor played key roles to reduce a shock-loading when periodic shock loading was applied and to acidify influent organics. Due to the high concentration of alkalinity and high pH in the effluent of the methanogenic reactor, over 80% of methane in the biogas was produced consistently. More than 70% of methane was recovered from theoretical methane production of TCOD removed in this research. The produced gas can be directly used as a heat source to increase the reactor temperature.

• 한국환경보건학회지
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• 제19권3호
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• pp.36-40
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• 1993

The objective of this research was to retrofit an on-site sewage treatment system suitable to current situation of Korea to reduce the pollution loading and preserve the invaluable water resources. Operation at the F/M ratio of 0.1 kg. BOD/kg MLSS day showed 87.1% BOD removal efficiency and 84.5% COD removal efficiency, and its effluent concentration was 6.4 mg/l as BOD and 21.7 mg/l as COD. Average removal of total nitrogen showed high removal efficiency of 80%.

• 상하수도학회지
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• 제18권6호
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• pp.778-784
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• 2004

Dyeing wastewater contains recalcitrant organics which can not be easily treated by conventional biological treatment. Therefore it has to be treated by other advanced oxidation process in order to remove COD and Color more efficiently. Fenton oxidation process is one of the most commonly applied processes in removal of COD and color for the dyeing wastewater. However it increase the treatment cost and the production of sludge by the use of the excessive chemical reagent. Ozonation is not suitable in Single treatment process because it is not effective in organics removal compared with Color removal. The purpose of this research in order to evaluate the comparable removal efficiency of COD and color by the combination of advanced oxidation processes for the dyeing wastewater. The sequential treatment processes of Fenton process and ozonation was more effective to remove organics and color than ozonation and Fenton process. The result of Fenton process for the pretreatment presented as the 81% removal of organics whereas ozonation process for the pretreatent presented as the 22.1% removal of organics. The removal of colour was higher as 81.3% for the ozonation as the pretreatment than 77.7% for the Fenton process as the pretreatment.

• 공업화학
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• 제16권5호
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• pp.693-697
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• 2005

제지산업에서 COD 부하 및 난분해성 COD 부하가 높은 생산지종별 발생폐수의 처리방안을 통하여 단위공정의 최적화와 방류수의 수질 안정화에 대해 연구하였다. 그 결과 1차 처리 공정에서는 SS와 더불어 colloid성 물질제거를 통한 COD 제거효율을 향상시키기 위해서 음이온 응집제 및 Alum의 병행사용이 효과적인 것으로 분석되었다. 또한 Fenton 산화법의 병행사용으로 인한 약품의 과량투입은 수질상태에 악영향을 주는 것으로 확인되었기 때문에 최적량인 $FeCl_2$와 $H_2O_2$의 비가 1:1인 농도비 1000 ppm 일 때 COD 제거율이 가장 높다고 판단된다.

• 상하수도학회지
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• 제22권5호
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• pp.497-503
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• 2008

The Oxic-Settling-Anaerobic(OSA) process is a modified activated sludge processes for sludge reduction. It is evaluated that the sludge production in OSA process can decrease to 88% because of biomass decay and kinetic parameter($Y_H$ 0.237mgVSS/mgCOD, $b_H$ $0.195d^{-1}$) in anaerobic reactor, when compared with CAS process. However, it has problems caused by sludge reduction such as increase of nutrient loading. In case that the anoxic condition through the introduction of the intermittent aeration for the enhancement of nitrogen removal ability build up and enough rbCOD is suppled, maximum 88% of nitrogen is removed in the OSA process. If the OSA process optimizing the intermittent aeration cycle is applied to the separate sewage system with high rbCOD fraction, it can be converted to advanced process in terms of the sludge reduction and nitrogen removal, simultaneously.

• Environmental Engineering Research
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• 제24권2호
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• pp.318-323
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• 2019

Paper focuses on comparison between two different orifice plate configurations (plate number 1 and plate number 2) used as cavitating device in the hydrodynamic cavitation reactor for improving pollutant removal efficiencies. Effect of four different parameters such as hydraulic characteristics (in terms of range of flow rates, orifice velocities, cavitation number at different inlet pressures); cavitation number (in range of 5.76-0.35 for plate number 1 and 1.20-0.35 for plate number 2); inlet pressure (2-8 bars) and reaction time (0 to 60 min) in terms of chemical oxygen demand (COD) removal and chlorpyrifos degradation has been studied and compared. Optimum inlet pressure of 5 bars exists for degradation of pollutants for both the plates. It is found that geometry of orifice plate plays important role in removal efficiencies of pollutant. Results obtained confirmed that orifice plate 1 with configuration of 1.5 mm 17 holes; cavitational number of 1.54 performed better with around 60% COD and 98% chlorpyrifos removal as compared to orifice plate 2 having configuration of 2 mm single hole; cavitational number of 0.53 with 40% COD and 96% chlorpyrifos in 2 h duration time.

• 한국환경보건학회지
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• 제24권1호
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• pp.54-61
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• 1998

This study was conducted in order to evaluate the treatment efficiencies of anaerobic packed and fluidized-bed biofilm and to investigate applicability in treating livestock wastewater. Biocarbonate alkalinity(BA) and volatile fatty acid(VFA) were about 3,230-3,270 mg/l, 3,790-3,126 mg/l(as CaCO$_3$) and 224-402 mg/l, 141-387 mg/l(as CH$_3$COOH), and VFA/BA ratio was about 0.069~0.12, 0.045-0.12 in packed and fluidized-bed biofilm. When COD loading rate was 6.0 kg COD/$m^3\cdot$ day in packed and fluidized-bed biofilm, methane gas production were 3.23 l/day and 4.38 l/day, respectively. In the same COD loading rate, methane gas production volumes per kg COD removal were 0.25 m$^3$ CH$_4$/kg COD$_{rm}$ and $0.28 m^3 CH_4/kg COD^{rm}$, respectively. At this time, it could be estimated that fluidized-bed biofilm was more high. In case of HRT 0.94 day(6.0 kg COD/$m^3\cdot$ day) and 11 day(0.5 kg COD/$m^3\cdot$ day), packed-bed biofilm showed 59% and 81% COD removal efficiency, respectively. While fluidized-bed biofilm showed 72% and 85% removal efficiency, respectively. It was showed that fluidized-bed biofilm was more efficient. Packed-bed biofilm was higher than fluidized in treatment efficiencies of organic matters, but required continuous treatment using combined system, because it was very exceeded over an environmental standard solidified from '96 year. In operating fluidized-bed biofilm, if farm house consider high power cost according to high circulation ratio in an economic point of view, it would have an effect that farm house use packed-bed biofilm as combined system in treating livestock wastewater.

• 한국환경과학회지
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• 제18권3호
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• pp.325-331
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• 2009

This study was aimed to behaviour of organics and nitrogen on the upflow anaerobic reactor when a acid fermenter is added. Up flow anaerobic reactor (UAR) reaction will result which operates, COD removal efficiencies of reactor with nitrate loading rate 0.11, 0.66g/L/d were over 77%, but one with 1.0g/L/d was 73.5%. Especially, on NLR 0.11g/L/d, COD removal was 77% and nitrate removal efficiency was 93% simultaneously. The other side upflow anaerobic reactor and acid fermenter (UAR+AF) reaction will result witch operates, COD removal efficiencies of reactor with nitrate loading rate 0.11, 0.66g/L/d were over 85%, but one with 1.0g/L/d was 80%. Especially, on NLR 0.11g/L/d, COD removal was 85% and nitrate removal efficiency was 98% simultaneously. Also, without in reaction condition increase of influent nitrate concentration resulted in the linear decrease of nitrate removal efficiency and nitrate removal efficiency at influent nitrate-nitrogen 800mg/L was 50%. Alkalinity was increased theoretically by denitrification at low nitrate-N concentration, however, it was not increased theoretically at high nitrate-No 40% nitrate-N of UAR was denitrified until 70% height of reactor and 90% nitrate-N of UAR+AF was denitrified until 30% height of reactor Upflow anaerobic reactor was to occur accumulate acid, which TVA/Alkalinity is 0.3$\sim$0.47. Increase of NLR resulted increase of effluent alkalinity and TVA production

• 한국수산과학회지
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• 제32권2호
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• pp.180-185
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• 1999

본 연구에서는 양식장에서 많이 이용되고 있는 회전원판 반응기를 모의 순환 여과식 양어장에 적용하여 인공 양식수 처리 실험을 행하면서 어류의 최적 사육환경을 유지할 수 있는 운전인자를 도출하고자 하였다. 회전원판 반응기는 수리학적 체류시간이 감소하는 부하변동에대해 $5\~6$일 정도의 시간이 흐른 후 정상상태에 도달하였으며 수리학적 체류시간의 증가에 따라 모의 사육조의 암모니아 농도, 회전원판반응기의 암모니아성 질소 제거율 및 제거속도는 증가하였다. 14.6분의 수리학적 체류시간에서 암모니아성 질소의 제거율은 $82.5\%$로 실험조건 중 가장 낮았으나 사육조의 암모니아성 질소농도는 $1.28g/m^3$으로 가장 낮게 나타났다. 모의 사육조의 용존산소는 수리학적 체류시간의 변화와 무관하게 $5.0\~5.3g/m^3$의 범위로 유지되었으며 회전원판 반응기의 원판이 회전할 때 자체적으로 산소가 공급되어 암모니아 둥의 산화와 관련하여 별도의 용존산소 공급은 필요 없는 것으로 나타났다. 알칼리도 소모속도는 수리학적 체류시간의 증가에 따라 선형적으로 증가하였으며 알칼리도 소모속도와 암모니아제거속도의 비는 평균 7.73으로 암모니아성 질소 1 g의 질산화에 7.73g의 알칼리도가 소모되는 것으로 나타났다 회전원판반응기는 원판에 부착된 일부의 타가영양체 미생물에 의해 용존 유기물이 소모되어 COD가 감소되었으며 COD의 제거속도는 수리학적 체류시간의 감소에 따라 선형적으로 증가하여 14.6분의 수리학적 체류시간에서 $5.59\;g/m^3$의 가장 낮은 농도를 보였다.

• KSBB Journal
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• 제14권1호
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• pp.119-123
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• 1999

Polyester 감량폐수의 주성분 중 물리.화학적 처리가 어려운 EG를 생물학적으로 처리하기 위하여 jet-loop reactor를 사용하였다 Jet-loop reactor의 산소전달계수는 air-lift reactor와 비교하여 훨씬 컸다. 합성 polyester 감량폐수를 사용하여 부하율 2.64 $kgCOD_{Mn}/m^3$.day, 3.07$kgCOD_{Cr}/m^3$.day로 처리한 경우 유출수의 농도는 154 $mgCOD_{Mn}/L$, 156$mgCOD_{Mn}/L$이었으며, 이 때 각각 93, 93.9%의 제거율을 나타내었다. $COD_{Mn}$의 비부하 속도가 0.25에서 1.72$kgCOD_{Mn}/kgMLVSS$.day로 증가 함에 따라 비기질제거 속도는 0.25에서 1.60$kgCOD_{Mn}-removed/kgMLVSS$.day로 선형적으로 증가하였다. 그리고, 동력학적 계수 Y는 0.78,$K_d$는 0.1$day^{-1}$, $K_s$는 89mg/L는 k는 0.05$hr^{-1}$이었다. 실제 polyester 감량폐수를 사용하여 부하율 2.64$kgCOD_{Mn}/m^3$.day,5.24$kgCOD_{Cr}/m^3$.day로 처리한 경우 유출수의 농도는 150$kgCOD_{Mn}/L$, 3.6$kgCOD_{Cr}/L$이었으며, 이때 각각 93.2,93%의 제거울을 나타내었다.