• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.92-100
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• 2021

In this study, the use of waste food grade aluminium foil and mild steel as a sacrificial electrode in an electrocoagulation system was developed to remove reactive red 111 from wastewater. The effect of different parameters like pH, current density, electrode material, and different electrode configurations was investigated. Optimum operating conditions for maximum COD removal were determined as, 6 mA/㎠ current density and 30 min at 5 pH for aluminium foil and 7 pH for mild steel. Maximum COD reduction obtained at optimum conditions using monopolar 4 electrodes, monopolar 2 electrodes and bipolar electrode configuration were 96.5%, 89.3%, and 90.2% for Mild steel as a sacrificial electrode and 92.1%, 84.2%, and 88.6% for aluminium foil as a sacrificial electrode. The consumption of electrode and energy for both the electrodes of different configurations were calculated and compared. Using batch experimental data, a continuous-flow reactor was developed. Sludge analysis using Fourier Transform Infra-Red Spectroscopy (FTIR) analysis was done. Different adsorption kinetic models and isotherms were developed and it was found that pseudo second-order model and Langmuir isotherm fit best with the experimental data obtained.

• Journal of Korean Society of Water and Wastewater
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• v.28 no.1
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• pp.13-23
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• 2014

A lab-scale Anaerobic Baffled Reactor (ABR) was applied to treat a primary sludge taken from a municipal wastewater treatment plant. In this experiment, acidogenic reaction was promoted by operating the ABR with short hydraulic retention time (HRT) to produce sufficient volatile fatty acids (VFA) instead of production of methane. The performance of ABR on the VFA production and total solids reduction was observed with different operating conditions with 2, 4, 6, and 8 days of HRT. Corresponding organic loading rates were 6.7, 3.4, 2.2, and $1.6kgCOD_{cr}/m^3{\cdot}day$. As HRT increased the removal rate of TCOD was also increased (82.5, 84.2, 96.9, and 95.9 % in average for HRT of 2, 4, 6, and 8 days, respectively) because the settlement of solids was enhanced in the baffle by the decrease of upflow velocity. At HRT of 2 days the average concentration of VFA in the effluent was measured at $1,306{\pm}552$ mgCOD/L corresponding to 107 % increment as compared to the VFA concentration in the influent. However, as HRT increased VFA concentraiotn was decreased to $143{\pm}552$ mgCOD/L at HRT of 8 days. The reduction rates of total solids were 12.2, 26.5, 24.8, and 43.0 % for HRT of 2, 4, 6, and 8 days. As HRT increased the hydrolysis of organic particulate matters in the reactor was enhanced due to the increasing of solids retention time in the baffle zone with low upflow velocity in long HRT condition. Consequently, we found that a primary sludge became a good source of VFA production by the application of ABR process with HRT less than 4 days and the 12-26 % of total solids reduction was expected at these conditions.

• Journal of the Korean Society for Marine Environment & Energy
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• v.6 no.4
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• pp.37-44
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• 2003

In order to evaluate the contribution of MMSTP operation to the improvement of marine water quality of Mokpo harbour and to estimate the change of pollution loads flowing into Mokpo harbour after the operation of Mokpo Municipal Sewage Treatment Plant (MMSTP), the pollution loads flowing into Mokpo harbour from land in dry weather were surveyed and estimated on the bases of the seasonal flow rates and the seasonal water qualities of streams and effluents located around Mokpo harbour from summer, 1997 to spring, 1998 before the operation of MMSTP, and the pollution loads of the inflow and the effluent of MMSTP were also surveyed and estimated from winter, 1998 to spring, 1999 after the operation of MMSTP. The treatment rates of MMSTP were shown to be about 49% in COD, 76% in TSS, 79% in VSS, 3% in T-N, 7% in DIP, 29% In T-P and -32% in DIN. The change rates of pollution loads flowing into the inner harbour of Mokpo due to the operation of MMSTP were shown to be about 56% in COD, 78% in TSS, 84% in VSS, 45% in DIN, 22% in T-N, 34% in T-P and -14% in DIP The contribution rates of MMSTP operation to the reduction of total pollution loads flowing into the entire Mokpo harbour were found to be about 3% in COD, 3% in TSS, 5% in VSS, 1% in DIP, 3% in T-P and -1% in DIN.

• Journal of the Korea Organic Resources Recycling Association
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• v.27 no.2
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• pp.41-49
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• 2019

Livestock manure is a significant source for greenhouse gas (GHG) emission, and a huge amount of GHG emission is generated during its storage. In the present work, lowering temperature was attempted to mitigate methane ($CH_4$) emission from cattle manure (CM) with high solid content. CM was stored for 60 d at $15-35^{\circ}C$ ($5^{\circ}C$ interval). $CH_4$ emission reached $63.6{\pm}3.6kg\;CO_2\;eq./ton\;CM$ at $35^{\circ}C$, which was reduced to $51.6{\pm}1.8$, $24.1{\pm}4.4$, $14.9{\pm}0.5$, and $3.7{\pm}0.1kg\;CO_2\;eq./ton\;CM$ at 30, 25, 20, and $15^{\circ}C$, respectively. After storage, 30% of COD reduction was observed in the CM stored at $35^{\circ}C$, while the COD removal decreased to only 6% at $15^{\circ}C$. It was found that only 3-11% of COD removal was done by anaerobic process, while the rest of COD removal was done by aerobic biological process. Methanobrevibacter and Methanolobus were found to be the dominant species in the CM, and the dominance of Methanolobus psychrophilus increased at lower storage temperature. Specific methanogenic activity test results showed that the inhibition by low temperature was temporal.

• Transactions of the Korean Society of Mechanical Engineers
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• v.19 no.2
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• pp.402-407
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• 1995

The effects of room temperature and strain aging treatment are discussed on the critical condition for the onset of growth of non-propagating cracks on 0.15% C low carbon steel, with special emphasis on the length of the critical non-propagating crack and on the crack opening displacement(COD) at the crack tip. It is found from the experimental analysis that room temperature and strain aging of a fatigue pre-cracked specimen introduced the closure of a crack tip of the pre-crack and the reduction of crack opening displacement at the wake of crack, together with an improvement in crack growth resistance of the microstructure. This may cause an increase in the endurance limit of the specimen, through the enhancement of effective stress for the onset of growth of the critical non-propagating crack.

• Applied Chemistry for Engineering
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• v.33 no.5
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• pp.532-537
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• 2022

The need for obtaining treated wastewater that meets high quality standards for discharge or reuse necessitates the use of highly efficient wastewater treatment techniques. In the present study, experiments have been carried out to reduce the concentration level of biological oxygen demand (BOD), chemical oxygen demand (COD), and total dissolved solids (TDS) from the wastewater sample. Treatment of sample of a real municipal wastewater collected from a sewage treatment plant (STP) was carried out in an electrochemical membrane bioreactor (EMBR). The EMBR was operated continuously for five days, and readings were taken at regular intervals. This paper has experimental results conducted in EMBR that indicate reduction of BOD, COD, and TDS levels of up to 32.25%, 29.25%, and 31.93%, respectively. Further, it was observed that a current of magnitude of 0.00752 mA was generated due to the metabolic activities of bacteria present in municipal wastewater, which gradually decreased day by day due to the decay of bacteria.

• Journal of the Korean Society for Marine Environment & Energy
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• v.4 no.4
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• pp.32-41
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• 2001

We measured the fluxes of COD, TN and 55 in addition to composition and quality of sediment in Komso Bay, West Coast of Korea. The fluxes of TN, SS and COD were measured during flood tide and ebb tide in April and August, 2000. Denitrification rates in the sediments was also measured by direct produced $N_2$ gas technique on April and August from 1999 to 2000 in the same sea area. The composition of the sediments were 0.33~5.67 % of sand, 20.2~25.6 of gravel and 68.7~77.0 % of silt. Ignition loss of the sediments were 6.58~7.50 %. The concentration of hydrogen sulfide in the sediments were 0.028~0.326 mg/gㆍdry and oxidation reduction potential of the sediments were -28~-15 mV Diurnal fluxes of COD, total nitrogen, and suspended solids with tidal current and denitrification rate in the tidal flat have been determined in Komso Bay The diurnal net flux of COD was same in April. While 14.4 ton COD/hr of net influx into the tidal flat was recorded in August. The diurnal net influx of total nitrogen was 0.16 ton N/hr in April and 1.13 ton N/hr in August. The diurnal net influx of suspended solids was 0.05 ton SS/hr in April, and also net influx of suspended solids was 0.29 ton SS/hr in August. The overall purification ability of the tidal flat were estimated 0.00~5.69 g COD/$m^2/day$, 0.06~0.45 g N/m²/day and 0.02~0.12 g SS/$m^2/day$ for COD, TN and SS, respectively. Denitrification rate was 0.009~1.720 m mole ${N_2}/m^2/day$ (average 0.702 m mole ${N_2}/m^2/day$) in April and 0.033~0.133 m mole ${N_2}/m^2/day$ (average 0.077 m mole ${N_2}/m^2/day$) in August, 1999. 0.000~l.909 m mole ${N_2}/m^2/day$ (average 0.756 m mole ${N_2}/m^2/day$) in April, 0.000~1.691 m mole ${N_2}/m^2/day$ (average 0.392 m mole ${N_2}/m^2/day$) in August, 2000. Even with a wide range of denitrification rate depending on the sampling location and studied periods, the average denitrification rate was estimated 0.482 m mole ${N_2}/m^2/day$ in the tidal flat of Komso Bay.

• Journal of Korean Society of Environmental Engineers
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• v.30 no.10
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• pp.975-983
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• 2008

In view of previous investigations that the outermost zone of porous media displays the most vigorous removal of organic contaminant, a novel filtration apparatus of cylinder-shaped porous material (polyester fiber) was applied to the Samcheonji reservoir in Gyeongsan to assess its ability to remove contaminants from reservoir water. The apparent mechanism of purification is that organic pollutant dispersed in the water is collected by the matrix to be degraded by microbes in due course. Data obtained from the experiment appear promising; 19$\sim$27% decrease in COD$_{Cr}$, 37$\sim$43% reduction in COD$_{Mn}$, BOD$_5$ diminution between 67$\sim$81%, 93% decrease in turbidity, and 99% removal of Suspended Solids. The results suggest that this device may be a valuable supplementary means to ameliorate the quality of reservoir water.

• Korean Journal of Ecology and Environment
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• v.51 no.1
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• pp.135-147
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• 2018

In order to investigate the runoff characteristics of nonpoint source pollutants in the Lake Doam watershed, water quality and flow rate were monitored for 38-rainfall events from 2009 to 2016. The EMC values of SS, COD, TN and TP were in the range of 33~2,169, 3.5~56.9, 0.09~7.65 and $0.06{\sim}2.21mg\;L^{-1}$, respectively. As a result of analyzing the effect of rainfall factor on the nonpoint source pollutant load, EMCs of SS, COD and TP showed a statistically significant correlation with rainfall (RA) (p<0.01) and SS showed highly significant correlation with maximum rainfall intensity (MRI, R=0.48). The load ranges of SS, COD, TN and TP were 10.4~11,984.6, 1.1~724.4, 0.6~51.6 and $0.03{\sim}22.85ton\;event^{-1}$, respectively, showing large variation depending on the characteristics of rainfall events. The effect of rainfall on the load was analyzed. SS, COD and TP showed a positive correlation, but TN did not show any significant correlation. The annual load of SS was the highest with $88,645tons\;year^{-1}$ in 2011 when rainfall was the highest with 1,669 mm. The result of impact analysis of nonpoint source pollution reduction project and land-use change on runoff load showed that pollutant load significantly reduced from 2009 to 2014 but SS and TP loads were increased from 2014 to 2016 due to increase in construction area. Therefore, we suggested that nonpoint source pollution abatement plan should be continued to reduce the soil loss and pollutants during rainfall, and countermeasures to reduce nonpoint source pollution due to construction need to be established.

• Journal of environmental and Sanitary engineering
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• v.12 no.3
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• pp.9-17
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• 1997

This research aims to remove nitrogen in the piggery wastewater by combined process with upflow anaerobic sludge blanket (UASB) and biofilm process. For the effective denitrification. anaerobic and anoxic reactors were connected to a reactor. The effluent of aerobix reactor was recycled equally with influent in the upper filter of anaerobic reactor for denitrification and outlet of UBF reactor was connected to the settling tank with $1.5{\;}{\ell}$ capacity and the settling sludge was repeatedly recycled to UASB zone. The organic loading rate of total reactor was operated from 0.4 to $3.1kgCOD/m^{3}/d$ and it was observed that the removal rate of TCOD was 80 to 95 percentage. Ammonia nitrogen was removed over 90 percentage in the less volumetric loading rate than $0.1{\;}kgN/m^{3}/d$. But because of non-limitation of organic materials, it was reduced to 70 percentage in the more volumetric loading rate than $0.6{\;}kgN/m^{3}/d$. But denitrification rate was observed 100 percentage in the all of loading rate. This is caused by the maintenance of optimum temperature, sufficient carbon source, and competition of electron acceptors. The results of COD mass balance at the $1.21{\;}kgCOD/m^{3}/d$ was observed with the 71.7% percentage of influent COD. It was revealed that the most part of organic materials was removed in the aerobic and the anaerobic reactor because 38.4 percentage was conversed into $CH_{4}$ gas and 11 percentage was removed in the aerobic reactor with cell synthesis and metabolism. Besides, 5.7% organics was used to denitrification reaction and 3.7% organics related to sulfate reduction.