• Title/Summary/Keyword: CO2 capture

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Economic Evaluations for the Carbon Dioxide-involved Production of High-value Chemicals (이산화탄소를 활용한 고부가화합물 제조기술의 경제성 평가연구)

  • Lee, Ji Hyun;Lee, Dong Woog;Gyu, Jang Se;Kwak, No-Sang;Lee, In Young;Jang, Kyung Ryoung;Choi, Jong Shin;Shim, Jae-Goo
    • Korean Chemical Engineering Research
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    • v.52 no.3
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    • pp.347-354
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    • 2014
  • Economic evaluation of the manufacturing technology of high-value chemicals through the carbonation reaction of carbon dioxide contained in the flue gas was performed, and analysis of the IRR (Internal Rate of Return) and whole profit along the production plan of the final product was conducted. Through a carbonation reaction with sodium hydroxide that is generated from electrolysis and by using carbon dioxide in the combustion gas that is generated in the power plant, it is possible to get a high value products such as sodium bicarbonate compound and also to reduce the carbon dioxide emission simultaneously. The IRR (Internal Rate of Return) and NPV (Net Present Value) methods were used for the economic evaluation of the process which could handle carbon dioxide of 100 tons per day in the period of the 20 years of plant operation. The results of economic evaluation showed that the IRR of baseline case of technology was 67.2% and the profit that obtained during the whole operation period (20 years) was 346,922 million won based on NPV value. When considering ETS due to the emissions trading enforcement that will be activated in 2015, the NPV was improved to a 6,000 million won. Based on this results, it could be concluded that this $CO_2$ carbonation technology is an cost-effective technology option for the reduction of greenhouse gas.

Stainless steel 기판에서 제조된 CIGS 박막 태양전지의 ZnO 확산 방지막을 이용한 deep level defect 감소 연구

  • Kim, Jae-Ung;Kim, Hye-Jin;Kim, Gi-Rim;Kim, Jin-Hyeok;Jeong, Chae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.393-393
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    • 2016
  • Cu(In,Ga)Se2 (CIGS) 박막 태양전지는 높은 효율과 낮은 제조비용, 높은 신뢰성으로 인해 박막 태양전지 중 가장 각광받고 있다. 특히 유리기판 대신 가볍고 유연한 철강소재나 플라스틱 소재를 이용하여 발전분야 외에 건물일체형, 수송용, 휴대용등 다양한 분야에 적용이 가능하다. 이러한 유연 기판을 이용한 CIGS 태양전지의 개발을 위해서는 기판의 특성에 따른 다양한 공정개발이 선행되어야 한다. Stainless steel과 같은 철강기판의 경우 Fe, Ni, Cr등의 불순물이 확산되어 흡수층의 특성을 저하시켜 효율을 감소시킨다. 따라서 이러한 철강 기판의 경우 불순물의 확산을 방지하는 확산방지막이 필수적이다. 이러한 유연기판의 특성을 고려하여 본 연구에서는 기존의 두껍고 추가 장비가 요구되는 SiOx나 Al2O3 대신 200nm 이하의 ZnO 박막을 이용하여 확산방지막을 제조하였다. 유연기판으로 STS 430 stainless steel을 이용하였다. 먼저 stainless steel 기판을 이용하여 기판에 의한 흡수층의 특성을 분석하였으며 ZnO 확산 방지막의 유무 및 두께에 따른 흡수층 및 소자의 특성을 분석하였다. 이때 확산 방지막은 기존 TCO 공정에서 사용되는 i-ZnO를 사용하였으며 RF sputter를 이용하여 50~200nm로 두께를 달리하며 특성 비교를 실시하였다. 효율은 확산방지막을 적용하지 않았을 때 약 5.9%에서 확산 방지막 적용시 약 10.7%로 증가하였다. 그 후 기판으로부터 확산되는 불순물의 유입에 의한 결함을 분석하기 위해 DLTS를 이용하여 소자 특성을 분석하였다. 온도는 80~300K으로 가변하며 측정을 실시하였으며 그 후 계산을 통해 activation energy와 capture cross section 값을 구하였다. DLTS 분석 결과 Ni이 CIGS 흡수층으로 확산되어 NiCu anti-site를 형성하여 태양전지의 효율을 감소시키는 것을 확인하였다. 모든 흡수층은 Co-Evaporation 방법을 이용하여 제조하였으며 제조된 흡수층은 SEM, XRF, XRD, GD-OES, PL, Raman등을 이용하여 분석하였으며 그 외 일반적인 방법을 이용하여 Mo, CdS, TCO, Al grid를 제조하였다. AR 코팅은 제외 하였으며 제조된 소자는 솔라 시뮬레이터를 이용하여 효율 특성 분석을 실시하였으며 Q.E. 분석을 실시하였다.

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Investigation on the Applicability of Defocus Blur Variations to Depth Calculation Using Target Sheet Images Captured by a DSLR Camera

  • Seo, Suyoung
    • Journal of the Korean Society of Surveying, Geodesy, Photogrammetry and Cartography
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    • v.38 no.2
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    • pp.109-121
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    • 2020
  • Depth calculation of objects in a scene from images is one of the most studied processes in the fields of image processing, computer vision, and photogrammetry. Conventionally, depth is calculated using a pair of overlapped images captured at different view points. However, there have been studies to calculate depths from a single image. Theoretically, it is known to be possible to calculate depth using the diameter of CoC (Circle of Confusion) caused by defocus under the assumption of a thin lens model. Thus, this study aims to verify the validity of the thin lens model to calculate depth from edge blur amount which corresponds to the radius of CoC. For this study, a commercially available DSLR (Digital Single Lens Reflex) camera was used to capture a set of target sheets which had different edge contrasts. In order to find out the pattern of the variations of edge blur against varying combination of FD (Focusing Distance) and OD (Object Distance), the camera was set to varying FD and target sheet images were captured at varying OD under each FD. Then, the edge blur and edge displacement were estimated from edge slope profiles using a brute-force method. The experimental results show that the pattern of the variations of edge blur observed in the target images was apart from their corresponding theoretical amounts derived under the thin lens assumption but can still be utilized to calculate depth from a single image for the cases similar to the limited conditions experimented under which the tendency between FD and OD is manifest.

Modeling and Simulation of Small and Medium-sized Ships for Fuel Reduction Rate Verification (연료 감소율 검증을 위한 중소형 선박의 모델링 및 시뮬레이션)

  • Kim, Sung-Dong;Kim, Nam-Ho
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.26 no.6
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    • pp.914-921
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    • 2022
  • The International Maritime Organization (IMO) has set a goal of reducing ship's carbon dioxide emissions by 70% and greenhouse gas emissions by 50% by 2050 compared to 2008. Shipowners and shipyards are promoting various R&D activities such as LNG propulsion, ammonia propulsion, electric propulsion, CO2 capture, and shaft generators as a way to satisfy this problem. The dual shaft generator has the advantage that it can be directly applied to an existing ship through remodeling. In this paper, the total fuel reduction rate that can be obtained by applying the shaft generator to the existing ship was verified through simulation. For this purpose, the size of the medium-sized ship was defined, and the governor, diesel engine, propeller, torque switch, generator for shaft generator, propulsion motor for shaft generator, and ship model were modeled and simulated.

Characterization of CO2 Biomineralization Microorganisms and Its Mineralization Capability in Solidified Sludge Cover Soil in Landfill (매립지 복토용 슬러지 고화물내 이산화탄소 생광물화 고정균 분석 및 생광물화능 평가)

  • Ahn, Chang-Min;Bae, Young-Shin;Ham, Jong-Heon;Chun, Seung-Kyu;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.8
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    • pp.598-606
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    • 2013
  • This study was performed to determine whether biomineralization microbes were actively present underneath landfill cover soil producing biocalcification. From this, various types of microbes were observed. Among them, two species were dominantly found; Bacillus megaterium and Alkaliphilus metalliredigens that were known as biominerlization bacteria. With those microbes, $CO_2$ was more highly consumed than without bacteria. In response, the calcium carbonate mineral was produced at 30% (wt) greater than that of the control. At the same time, TG-DTA was successfully used for quantification of $CO_2$ consumed forming calcium carbonate minerals resulting from biocalcification. It was decided that the presence of solidified sewage sludge cake utilized as a cover soil in the landfill could efficiently contribute to possible media adaptably and naturally sequestering $CO_2$ producing from the landfill.

Aquifer Characterization Using Seismic Data on the Aquistore CCS Project, Canada (캐나다 아퀴스토어 탄성파자료를 통한 이산화탄소 지중저장 연구지역 대수층 특성화)

  • Cheong, Snons;Kim, Byoung-Yeop;Shinn, Young Jae;Lee, Ho-Yong;Park, Myung-Ho
    • Economic and Environmental Geology
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    • v.47 no.6
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    • pp.625-633
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    • 2014
  • The Aquistore project is the world's first commercial capture, transportation, utilization and storage project of post-combustion $CO_2$ from a coal-fired thermo electric power plant, and the proposed storage is a saline aquifer at a depth of about 3,500 m. Deep saline aquifer, compared to hydrocarbon reservoir, provides the great volumetric potential for storage of $CO_2$ anywhere in the world, therefore the research results from the project may be exported globally to other sites. Geological $CO_2$ storage characterization for saline aquifer instead of hydrocarbon reservoir needs to estimate the geophysical properties of subsurface geology. This study calculated the geophysical property of water-saturated formation by applying amplitude variation analysis developed from oil and gas exploration. We correlated horizon tops at the well logs to seismic traveltime of 1,815 and 1,857 ms as Winnipeg and Deadwood formations. Gradient analysis from seismic traces showed correlation coefficient of 45 - 81 % on amplitude variation with respect to incident angle. Crossplot of intercept and gradient shows the inverse proportional trend which represents typical water saturated sediments. Product attribute of intercept and gradient described the base of wet sediment. Poisson's ratio change attribute increased at the top of target area satisfying with wet sediment and decreased at the top of basement in a dry rock bed.

Evaluation System of Environmental Safety on Marine Geological Sequestration of Captured Carbon Dioxide (이산화탄소의 해양지중저장과 환경 안전성 평가 방안)

  • Gim, Byeong-Mo;Choi, Tae Seob;Lee, Jung-Suk;Park, Young-Gyu;Kang, Seong-Gil;Jeon, Ei-Chan
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.16 no.1
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    • pp.42-52
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    • 2013
  • Carbon Capture and Storage (CCS) is a mitigation technology essential in tackling global climate change. In Korea, many research projects are aimed to commercialize CCS business around 2020. Public acceptance can be a key factor to affect the successful proceeds of CCS near future. Therefore this paper provides a concise insight into the application of environmental impact assessment and risk assessment procedures to support the sustainable CCS projects. Futhermore, bottlenecks regarding the environmental impacts assessment and related domestic and foreign legislation are revised. Finally, suggestions to overcome these bottlenecks and recommendations for future research are made in conclusion.

Conceptual Design and Hydrodynamic Properties of a Moving Bed Reactor for Intrinsic $CO_2$ Separation Hydrogen Production Process ($CO_2$ 원천분리 수소 제조 공정을 위한 이동층 반응기의 개념 설계 및 수력학적 특성)

  • Park, Dong-Kyoo;Cho, Won-Chul;Seo, Myung-Won;Go, Kang-Seok;Kim, Sang-Done;Kang, Kyoung-Soo;Park, Chu-Sik
    • Clean Technology
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    • v.17 no.1
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    • pp.69-77
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    • 2011
  • The intrinsic $CO_2$ separation and hydrogen production system is a novel concept using oxidation and reduction reactions of oxygen carrier for both $CO_2$ capture and high purity hydrogen production. The process consists of a fuel reactor (FR), a steam reactor (SR) and an air reactor (AR). The natural gas ($CH_4$) is oxidized to $CO_2$ and steam by the oxygen carrier in FR, whereas the steam is reduced to hydrogen by oxidation of the reduced oxygen carrier in SR. The oxygen carrier is fully oxidized by air in AR. In the present study, the chemical looping moving bed reactor having 200 L/h hydrogen production capacity is designed and the hydrodynamic properties were determined. Compared with other reactors, two moving bed reactors (FR, SR) were used to obtain high conversion and selectivity of the oxygen carrier. The desirable solid circulation rates are calculated to be in the range of $20{\sim}100kg/m^2s$ from the conceptual design. The solid circulation rate can be controlled by aeration in a loop-seal. To maintain the gas velocity in the moving beds (FR, SR) at the minimum fluidization velocity is found to be suitable for the stable operation. The solid holdup in moving beds decrease with increasing gas velocity and solid circulation rate.

Development and Evaluation of an Immunochromatographic Assay for Screening Listeria spp. in Pork and Milk

  • Kim, Seong-Hee;Kim, Jin-Young;Han, Woong;Jung, Byeong-Yeal;Chuong, Pham-Due;Joo, Hae-Jin;Ba, Hoa-Van;Son, Won-Geun;Jee, Young-Heun;Yoon, Byoung-Su;Lee, Yong-Soon;Lim, Yoon-Kyu
    • Food Science and Biotechnology
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    • v.16 no.4
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    • pp.515-519
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    • 2007
  • Rapid immunochromatographic assay (ICA) kits were developed using flagella-specific monoclonal antibodies (MAbs) and rabbit polyclonal antibodies for screening Listeria spp. in food. The establishment of different formats, MAb 2B1 as capture antibody and MAb 7A3 or rabbit polyclonal antibodies as detector antibody, was compared. The 2 formats of the ICA kit were shown to have specific reactions with Listeria and no cross-reactivity with any of the non-Listeria including Escherichia coli O157:H7 and Salmonella enteritidis. The detection limits of the ICA kit using the combination of gold-labeled MAb 7A3 and MAb 2B1 showed $1{\times}10^5$ and $1{\times}10^6\;CFU/0.1\;mL$ at 22 and $30^{\circ}C$, respectively. The other format of the ICA kit using the combination of gold-labeled rabbit polyclonal antibodies and MAb 2B1 showed $1{\times}10^6\;CFU/0.1\;mL$ at $22^{\circ}C$ but weak signal at 30 culture. The format utilizing MAb was more sensitive than the one using polyclonal antibodies for capture antibody. Samples contaminated with L. monocytogenes 4b culture (9-10, 5-6, and 1-2 CFU/mL) on pork and pasteurized milk were confirmed as positive results. Current data suggests that this ICA kit is a rapid, simple and effective tool to screen for Listeria spp. in food.

Effective Reduction of Horizontal Error in Laser Scanning Information by Strip-Wise Least Squares Adjustments

  • Lee, Byoung-Kil;Yu, Ki-Yun;Pyeon, Moo-Wook
    • ETRI Journal
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    • v.25 no.2
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    • pp.109-120
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    • 2003
  • Though the airborne laser scanning (ALS) technique is becoming more popular in many applications, horizontal accuracy of points scanned by the ALS is not yet satisfactory when compared with the accuracy achieved for vertical positions. One of the major reasons is the drift that occurs in the inertial measurement unit (IMU) during the scanning. This paper presents an algorithm that adjusts for the error that is introduced mainly by the drift of the IMU that renders systematic differences between strips on the same area. For this, we set up an observation equation for strip-wise adjustments and completed it with tie point and control point coordinates derived from the scanned strips and information from aerial photos. To effectively capture the tie points, we developed a set of procedures that constructs a digital surface model (DSM) with breaklines and then performed feature-based matching on strips resulting in a set of reliable tie points. Solving the observation equations by the least squares method produced a set of affine transformation equations with 6 parameters that we used to transform the strips for adjusting the horizontal error. Experimental results after evaluation of the accuracy showed a root mean squared error (RMSE) of the adjusted strip points of 0.27 m, which is significant considering the RMSE before adjustment was 0.77 m.

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