• Title/Summary/Keyword: CO removal

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Effect of Ion Exchange Capacity on Salt Removal Rate in Membrane Capacitive Deionization Process (이온교환용량이 막 결합형 축전식 탈염공정에서 염 제거율에 미치는 영향)

  • Yun, Won Seob;Cheong, Seong Ihl;Rhim, Ji Won
    • Membrane Journal
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    • v.28 no.5
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    • pp.332-339
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    • 2018
  • In order to investigate the effect of ion exchange capacity of ion exchange membranes on the salt removal efficiency in the membrane capacitive deionization process, sulfosuccinic acid (SSA) as the cross linking agent was added to poly(vinyl alcohol)(PVA) and sulfonic acid-co-maleic acid (PSSA_MA) was put into PVA at different concentrations of 10, 50 and 90 wt% relative to PVA. As the content of PSSA_MA increased, the water content and ion exchange capacity increased and the salt removal efficiency was also increased in the membrane capacitive deionization process. The highest salt removal efficiency was 65.5% at 100 mg/L NaCl feed at a flow rate, 15 mL/min and adsorption, 1.4 V/5 min for PSSA_MA 90 wt%.

Particle removal characteristics of high-velocity electrostatic mist eliminator (정전 고속 미스트 엘리미네이터의 포집 효율 특성)

  • Kim, Jin-seon;Kim, Hak-Joon;Han, Bangwoo;Woo, Chang Gyu;Kim, Yong-Jin;Lee, Sangrin;Moon, Sangchul
    • Particle and aerosol research
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    • v.14 no.4
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    • pp.121-133
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    • 2018
  • In this study, we developed a flat-plate type wet electrostatic precipitator that generates stable corona discharge compared to wire type discharge electrode. In order to compare the particle removal efficiency according to the shape of the discharge electrode such as the variation of the horizontal and vertical distance between spiked edges, and the variation of the height of discharge pin support were tested. As a result, when the horizontal distance between spiked edges was increased up to 36 mm, the vertical distance between spiked edges was increased up to 54 mm, and the height of the discharge pin support was increased up to 76 mm, the removal efficiency of PM10 was maintained at approximate 60.0%. Furthermore, the removal efficiency of particles over $5{\mu}m$ was about 80% or more. When the flow rate was 4 m/s, the gap between collection plates was 60 mm, and -14 kV was applied to the discharge electrode. The particle removal efficiency of the flat-plate type electrostatic precipitator was maintained when the horizontal and vertical distance between spiked edges, and the height of the discharge pin support was below a certain level. Those variables may be the important design factors for the shape of the discharge electrode. Therefore, when designing the electrostatic precipitator with multiple channels, the horizontal and vertical distance between spiked edges, and the height of discharge pin support must be selected in consideration of the weight of the discharge electrode and the processing cost.

Surface Analysis and Heavy Metal Adsorption Evaluation of Chemically Modified Biochar Derived from Starfish (Asterina pectinifera) (화학적 개질을 통한 별 불가사리 바이오차 표면 분석 및 중금속 흡착 효율 평가)

  • Jang, Ha Rin;Moon, Deok Hyun
    • Journal of Korean Society on Water Environment
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    • v.38 no.2
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    • pp.82-94
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    • 2022
  • In this study, chemically modified biochar (NSBP500, KSBP500, OSBP500) derived from starfish was utilized to improve the adsorption ability of the SBP500 (Starfish Biochar Pyrolyzed at 500℃) in a solution contaminated with heavy metals. According to the biochar modification performance evaluation batch tests, the removal rate and adsorption amount of NSBP500 increased 1.4 times for Cu, 1.5 times for Cd, and 1.2 times for Zn as compared to the control sample SBP500. In addition, the removal rate and adsorption amount of KSBP500 increased 2 times for Cu, 1.8 times for Cd, and 1.2 times for Zn. The removal rate and adsorption amount of OSBP500 increased 5.8 times for Cu. The FT-IR analysis confirmed the changes in the generation and movement of new functional groups after adsorption. SEM analysis confirmed Cu in KSBP500 was in the form of Cu(OH)2 and resembled the structure of nanowires. The Cd in KSBP500 was densely covered in cubic form of Cd(OH)2. Lead(Pb) was in the form of Pb3(OH)2(CO3)2 in a hexagonal atomic layer structure in NSBP500. In addition, it was observed that Zn was randomly covered with Zn5(CO3)2(OH)6 pieces which resembled plates in KSBP500. Therefore, this study confirmed that biochar removal efficiency was improved through a chemical modification treatment. Accordingly, adsorption and precipitation were found to be the complex mechanisms behind the improved removal efficiency in the biochar. This was accomplished by electrostatic interactions between the biochar and heavy metals and ion exchange with Ca2+.

Pretreatment Process for Performance Improvement of SIES at Kori Unit 2 in Korea

  • Lee, Sang-Jin;Yang, Ho-Yeon;Shin, Sang-Woon;Song, Myung-Jae
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2004.02a
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    • pp.12-27
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    • 2004
  • Pretreatment process consisted of submerged hollow-fiber microfiltration(HMF) membrane and spiral-wound nanofiltration(SNF) membrane has been developed by NETEC, KHNP for the purpose of improving the impurities of liquid radioactive waste before entering Selective Ion Exchange System(SIES). The lab-scale combined system was installed at Kori NPP #2 nuclear power plant and demonstration tests using actual liquid radioactive waste were carried out to verify the performance of the combined system. The submerged HMF membrane was adopted for removal of suspended solid in liquid radioactive waste and the SNF membrane was used for removal of particulate radioisotope such as, Ag-l10m and oily waste because ion exchange resin can not remove particulate radioisotopes. The liquid waste in Waste Holdup Tank (WHT) was processed with HMF and SNF membrane, and SIES. The initial SS concentration and total activity of actual waste were 38,000ppb and $1.534{\times}10_{-3}{\mu}Ci/cc$, respectively. The SS concentration and total activity of permeate were 30ppb and lower than LLD(Lower Limit of Detection), respectively.

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Rejection of DNA, Protein-DNA Complexes and Chromatin by Hollow Fiber Membranes

  • Higuchi, Akon;Hara, Mariko;Sato, Tetsuo;Ishikawa, Gen;Nakano, Hiroo;Satoh, Sakae
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.18-21
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    • 1996
  • Virus and DNA removal in bio-drug manufacturing processes has received a great deal of attention in recent years. Removing of a virus using a membrane process is a promising method, because inactivated virus can be removed from the bio-drug and the process can be used as an additional and security inactivation after the method of general heat-inactivation of the virus in the bio-drug. The FDA and the biopharmaceutical industry have recently announced strict guidelines for impurities of virus and DNA contamination. The regulatory guidelines on residual amounts of DNA in mammalian cell culture products require DNA contamination of less than 100 pg/dose. Therefore, permeation and rejection of DNA through the porous membranes have become important in the application of DNA removal in bio-drug manufacturing using membrane technology. In this study, the permeation of DNA and chromatin through regenerated cellulose hollow fibers that have a mean pore diameter of 15 nm was investigated.

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A Study on a Development of the Grinding Robot to Remove Welding-bid of Working Pieces (취부용 피스(piece)제거 및 사상 작업 자동화장비 개발에 관한 연구)

  • Noh, Hyo-Won;Kim, Ki-Jung;Leem, Rae-Soo;Kim, Ho-Kyoung
    • Special Issue of the Society of Naval Architects of Korea
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    • 2008.09a
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    • pp.136-143
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    • 2008
  • This paper presents the application of a robot which aims at grinding automatically welding-bead remained in the removal job of working pieces for shipbuilding. In specific, the investigation on this application is composed of two parts; one topic is on the development of a robot platform vertically movable on a steel plate of hull, while the other topic is of the development of a grinding tool mechanism in order to remove welding-beads by using a diamond wheel installed on a servo cylinder (which can result in high working pressure on the grinding wheel). Besides, the development of a vision system for tracking welding-beads as well as recognizing welding surfaces is added for the convenience of this robot application to the removal of welding-beads remained in the working pieces for shipbuilding.

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A Study on the Removal Reaction Characteristics of Sulfur Dioxide (대기오염 물질인 $SO_2$ 제거반응 특성 연구)

  • 강순국;정명규
    • Journal of Environmental Science International
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    • v.4 no.1
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    • pp.41-52
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    • 1995
  • The effects of reaction temperature, SO2 and CO2 concentration in an air gas stream, particle sizes of limestone on the reactivity and capacity of SO2 removal have been determined in a thermogravimetric analyser(TGA). The apparent reaction order of sulfation reaction of pre-calcined lime(CaO) with respect to SO2 is found to be close to unity. The apparent activation energies are found to be 17,000 kcal/kmol for sulfation of pre-calcined lime and 19,500 kcal/kmol for direct sulfation of limestone(CaCO3). The initial sulfation reaction rate of pre-calcined lime increases with increasing temperature, whereas the sulfur capture capacity exhibits a maximum value at 90$0^{\circ}C$. In direct sulfation of limestone, sulfation reactivity and sulfur capature capacity of sorbent increase with increasing temperature and decreasing CO2 concentration in a gas bulk stream. The main pare of pre-calcined lime is shifted to the larger pore sizes and pore volume decreases with increasing sulfation time and temperature. The surface area of lime decreases with increasing calcination temperature under an air atmosphere, whereas is yearly constant under a CO2(5, 10%) atmosphere in a gas stream.

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Effect of Anionic Polymer on Particle Size Distribution in PAC Coagulation Process for Phosphorus Removal (PAC를 이용한 인제거 공정에서 음이온계 고분자 첨가가 입도 분포에 미치는 영향)

  • Kim, Sunghong;Lee, Dongwoo;Kim, Donghan;Kim, Dooil
    • Journal of Korean Society on Water Environment
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    • v.29 no.2
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    • pp.170-175
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    • 2013
  • Achieving very low phosphorus levels in treated wastewater will require the installation of additional treatment. Phosphorus removal experiments by chemical coagulation were carried out for the effluent of wastewater treatment plant in this study. TP (total phosphorus) or phosphate were highly related to the addition of PAC (poly aluminium chloride) which is one of the inorganic coagulants. But, organic polymer did not significantly affect the phosphorus removal efficiency. Polymer affected the flocculation of particle especially particle matter less than 10 micrometer so, the number of micro particles was decreased by polymer dose. Chlorination would not affect on chemical coagulation process and TP and turbidity could be effectively removed by the co-addition of PAC and polymer.

Characteristics of One- & Two-Stage Biofiltration System : Removal of Volatile Organic Compounds

  • Jeong, Gwi-Taek;Lee, Gwang-Yeon;Lee, Kyoung-Min;Cha, Jin-Myeong;Ryu, Hwa-Won;Park, Don-Hee
    • 한국생물공학회:학술대회논문집
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    • 2005.10a
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    • pp.281-286
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    • 2005
  • Biofiltration is a biological process which is considered to be one of the more successful examples of biotechnological applications to environmental engineering, and is most commonly used in the removal of odoriferous compounds. In this study, we have attempted to assess the efficiency with which both single and complex odoriferous compounds could be removed, using one- or two-stage biofiltration systems. The complex gas removal scheme was applied with a 200 ppm inlet concentration of ethanol, 70 ppm of acetaldehyde, and 70 ppm of toluene with EBCT for 45 seconds in a one- or two-stage biofiltration system. The removal yield of toluene was determined to be lower than that of the other gases in the one-stage biofilter. Otherwise, the complex gases were sufficiently eliminated by the two-stage biofiltration system.

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Removal of Gaseous Elemental Mercury Using Reactive Species Produced by Dielectric Barrier Discharge (저온 플라즈마 반응에 의해 생성된 반응활성종을 이용한 원소상 수은의 제거)

  • Jeong, Ju-Young;Jurng, Jong-Soo
    • Journal of Environmental Science International
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    • v.15 no.5
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    • pp.479-484
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    • 2006
  • Removal of elemental mercury $(Hg^0)$ with the reactive species produced from dielectric barrier discharge (DBD) was studied. We investigated the effect of operating parameters such as the applied voltage, residence time, initial concentration and co-existence of other pollutants. The removal of $(Hg^0)$ was significantly promoted by an increase in the applied voltage of the DBD reactor system. It is important to note that at the same input power, the removal efficiency of $(Hg^0)$ was much higher than that of NO gas. These results imply that if the DBD system is used as a NOx treatment facility, it is capable of removing $(Hg^0)$ simultaneously with NOx.