• 제목/요약/키워드: CO₂

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Na2CO3, K2CO3 및 Li2CO3 첨착활성탄을 이용한CO2 제거 -고정층 반응기에서의 CO2 흡착특성- (Removal CO2 Using Na2CO3, K2CO3 and Li2CO3 Impregnated Activated Carbon -Characteristics of CO2 Adsorption in Fixed Bed Reactor-)

  • 최원준;정종현
    • 한국환경보건학회지
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    • 제34권3호
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    • pp.240-246
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    • 2008
  • The purpose of this study was to gain basic information on the characteristics of $CO_2$ adsorption in relation to $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon in a Fixed Bed Reactor. From the results of this study the following conclusions were made: $Na_2CO_3$, $K_2CO_3$, $Li_2CO_3$-impregnated activated carbon had a longer breakthrough time and more enhanced adsorption capacity than activated carbon alone. When tested with isothermal adsorption and tested for $CO_2$ adsorption the amount of $CO_2$ adsorbed varied with temperature, $CO_2$ inlet concentration, gas flow rate, aspect ratio, etc. Based on the results, when Langmuir, Freundlich and Dubinin-Polanyi adsorption isotherms were used for linear regression of isothermal adsorption data, Langmuir adsorption isotherm was the most suitable. And, the optimum condition for $Na_2CO_3$ and $K_2CO_3$ impregnated activated carbon make-up was 1N and $Li_2CO_3$ was 0.1N. It could be concluded that adsorption capacity was decreased with adsorption temperature and increased gas concentration. When the aspect ratio (L/D) was varied 0.5, 1.0 and 2.0, the significant drop of adsorption amount was observed below 1.0 and breakthrough time was shortened with gas flow rate.

Comparative genetic analyses of Korean bat coronaviruses with SARS-CoV and the newly emerged SARS-CoV-2

  • Na, Eun-Jee;Lee, Sook-Young;Kim, Hak Jun;Oem, Jae-Ku
    • Journal of Veterinary Science
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    • 제22권1호
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    • pp.12.1-12.11
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    • 2021
  • Background: Bats have been considered natural reservoirs for several pathogenic human coronaviruses (CoVs) in the last two decades. Recently, a bat CoV was detected in the Republic of Korea; its entire genome was sequenced and reported to be genetically similar to that of the severe acute respiratory syndrome CoV (SARS-CoV). Objectives: The objective of this study was to compare the genetic sequences of SARS-CoV, SARS-CoV-2, and the two Korean bat CoV strains 16BO133 and B15-21, to estimate the likelihood of an interaction between the Korean bat CoVs and the human angiotensin-converting enzyme 2 (ACE2) receptor. Methods: The phylogenetic analysis was conducted with the maximum-likelihood (ML) method using MEGA 7 software. The Korean bat CoVs receptor binding domain (RBD) of the spike protein was analyzed by comparative homology modeling using the SWISS-MODEL server. The binding energies of the complexes were calculated using PRODIGY and MM/GBGA. Results: Phylogenetic analyses of the entire RNA-dependent RNA polymerase, spike regions, and the complete genome revealed that the Korean CoVs, along with SARS-CoV and SARS-CoV-2, belong to the subgenus Sarbecovirus, within BetaCoVs. However, the two Korean CoVs were distinct from SARS-CoV-2. Specifically, the spike gene of the Korean CoVs, which is involved in host infection, differed from that of SARS-CoV-2, showing only 66.8%-67.0% nucleotide homology and presented deletions within the RBD, particularly within regions critical for cross-species transmission and that mediate interaction with ACE2. Binding free energy calculation revealed that the binding affinity of Korean bat CoV RBD to hACE2 was drastically lower than that of SARS-CoV and SARS-CoV-2. Conclusions: These results suggest that Korean bat CoVs are unlikely to bind to the human ACE2 receptor.

열처리 온도에 따른 Si/Co/GaAs 계의 계면반응 및 상평형에 관한 연구 (The interfacial reactions and phase equilibria of Si/Co/GaAs system)

  • 곽준섭;김화년;백홍구;신동원;박찬경;김창수;노삼규
    • 한국진공학회지
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    • 제4권1호
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    • pp.51-59
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    • 1995
  • (001)방향 GaAs 기판과 Si/Co 박막의 계면반응 및 상평형에 관한 연구를 300-$700^{\circ}C$ 열처리 구간에서 행하였다. 반응에 의한 상전이 과정은 glancing angle X-ray diffraction(GXRD), Auger electron spectroscopy(AES) 및 cross-sectional transmission electron microscopy(GXRD), Auger electron spectroscopy(AES) 및 corss-sectional transmission electron microscopy(XTEM)을 이용하여 분석하였다. Si/Co/GaAs계의 계면반응에서 Co는 $380^{\circ}C$에서 GaAs 기판 및 Si와 반응하여 Co2GaAs과 Co2Si상을 형성하였다. $420^{\circ}C$에서 열처리 후, Co층은 모두 소모되었으며 단면구조는 Si/CoSi/CoGa(CoAs)/Co2GaAs/GaAs으로 전이되었다. $460^{\circ}C$까지 온도를 올려 계속적인 반응을 일으키면 CoGa와 CoAs이 분해되면서 CoSi가 성장하였고, $600^{\circ}C$에서는 Co2GaAs마저 분해되고 CoSi상이 성장하여 GaAs와 계면을 형성하였다. CoSi와 GaAs사이의 계면은 $700^{\circ}C$의 고온까지 안정하였으며 이러한 계면반응 결과는 계산에 의하여 구한 Si-Co-Ga-As 4원계 상태도로부터 이해될 수 있었다.

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Spatial Optical Modulator (SOM);Samsung's Light Modulator for the Next Generation Laser Display

  • Yun, Sang-Kyeong;Song, Jong-Hyeong;Lee, Tae-Won;Yeo, In-Jae;Choi, Yoon-Joon;Lee, Yeong-Gyu;An, Seung-Do;Han, Kyu-Bum;Victor, Yurlov;Park, Heung-Woo;Park, Chang-Su;Kim, Hee-Yeoun;Yang, Jeong-Suong;Cheong, Jong-Pil;Ryu, Seung-Won;Oh, Kwan-Young;Yang, Haeng-Seok;Hong, Yoon-Shik;Hong, Seok-Kee;Yoon, Sang-Kee;Jang, Jae-Wook;Kyoung, Je-Hong;Lim, Ohk-Kun;Kim, Chun-Gi;Lapchuk, Anatoliy;Ihar, Shyshkin;Lee, Seung-Wan;Kim, Sun-Ki;Hwang, Young-Nam;Woo, Ki-Suk;Shin, Seung-Wan;Kang, Jung-Chul;Park, Dong-Hyun
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.551-555
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    • 2006
  • A new type of diffractive spatial optical modulators, named SOM, has been developed by Samsung Electro-Mechanics for projection display and other applications. A laser display in full HD format $(1920{\times}1080)$ was successfully demonstrated by using prototype projection engines having SOM devices, signal processing circuits, and projection optics.

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Co와 Fe+Co혼합미분의 소결치밀화 특성 (Characteristics of Sintering Densification of Co and Fe+Co Fine Powders)

  • 임태환
    • 한국분말재료학회지
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    • 제3권2호
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    • pp.97-103
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    • 1996
  • The densification of the compacts of pure Co, Fe+50%.Co and Fe+25% Co sintered under H$_2$ gas or in vacuum was investigated. The effects of AL, Nb, Ti, and V additions on the densification were also studied. The sintered compact of Co was fully-dense when the density of the compact was lower than $Dg^c$. However, above $Dg^{c}$, it was never fully-dense regardless of sintering atmosphere, temperature, and time. The densification of sintered compacts of Fe-50% Co and Fe-25% Co were always incomplete. While the addition of AL made all compacts fully-dense, the addition of Ti was effective for the compacts of Co and Fe-25% Co. V was effective only for the Fe-25% Co. These results tell us that the particle size of Co powder, the amount of Fe, and the amount of additives forming stable oxides play on important role for the complete densification. Therefore it is desirable to reduce or eliminate the equilibrium pressure of H$_{2}$O or CO in isolated pores to obtain a fully-dense sintered compact.

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CoP 내 지식통합과 CoP 성과 연구: 사회적 자본과 CoP 구성 다양성을 기반으로 (Knowledge Integration and CoP Performance: Based on Social Capital and Diversity in CoP)

  • 이건호;민진영;허동철;이준영;이희석
    • 지식경영연구
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    • 제15권2호
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    • pp.129-145
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    • 2014
  • As a community of practice (CoP) is known to facilitate team learning, it is increasingly important to understand the mechanisms of CoP, thereby enabling organizations to fully utilize it and optimize its benefits. To explain how CoP improves organizational performance, we focus on its effects on social capital and knowledge management activities, and propose a research model suggesting that shared goals and trust in CoP improve its performance through knowledge integration. Our analysis uses structural equation modeling, with field data collected from 372 members of 46 CoPs in three companies; the analysis validates our research model. Our findings also suggest that CoP diversity can strengthen the link between knowledge integration and CoP performance.

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$K_2CO_3$ 수용액 이용 운전조건 변화에 따른 $CO_2$ 포집 특성 시험 (The effect of operating condition on $CO_2$ capture using $K_2CO_3$ solution)

  • 정기진;김진호;이선기;윤성필;김효식;김현진
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2011년도 추계학술대회 초록집
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    • pp.177.1-177.1
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    • 2011
  • 온실가스 감축에 대응하기 위해서 CCS기술이 지구온난화 문제를 해결하는 중요한 기술로 부각되고 있다. $CO_2$ 포집기술 중 습식법에는 대표적으로 아민, 암모니아, $K_2CO_3$와 같은 흡수제를 이용한 연구가 진행되고 있다. 본 연구에서는 $CO_2$ 포집기술 중 하나인 $K_2CO_3$ 수용액을 이용하여 Bench급 $CO_2$ 포집설비에 대한 성능을 파악하기 위한 일환으로 15% $CO_2$를 공급하여 $CO_2$ 포집 안정화 시험을 진행하였다. 압력변화 및 단수 변화를 하여 실험을 진행하였고, 흡수탑 후단의 $CO_2$ 농도를 측정하여 $CO_2$ 포집 성능을 파악하였다.

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Comparison of the Ligating Ability of Anonic Transition Metal Complex $(Mn(CO)_{5}{^-})$, Transition Metal Hydrides $(HCr(CO)_{5}{^-},\;HW(CO)_{5}{^-},\;cis-HW(CO)_{4}P(OMe)_{3}{^-},\;HFe(CO)_{4}{^-},\;trans-\;HFe(CO)_{3}P(OMe)_{3}{^-})$, and Traditional Ligands $(Br^-,\;P(C_{6}H_{5})_{3})\;to\;M(CO)_{5}{^0}$ (M = Cr, W)

  • Park, Yong K;Han, In S;Marcetta Y. Darensbourg
    • Bulletin of the Korean Chemical Society
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    • 제15권6호
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    • pp.436-442
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    • 1994
  • Heterobimetallic complexes have a donor-accepter metal-metal bond in which two electrons from the electron-rich metal moiety are donated to the other electron-deficient one. Based on the competition reactions, Cotton-Kraihanzel force constants, ν(CO)IR band resolution and the relative nucleophilicity comparison of the donor ligands, the following relative ligating ability of the donor ligands toward $M(CO)_5$ (M=Cr, W) is assessed: cis-HW$(CO)_4P(OMe)_3^-$, $HW(CO)_5^-$ > $HCr(CO)_5^-$-$Br^-$ > trans-HFe$(CO)_3P(OMe)_3^-$ > $Mn(CO)_5^-$ > $HFe(CO)_4^-$ > PP$h_3$

CO 합성을 위한 저급석탄-CO2 촉매 가스화 반응 (Low Grade Coal-CO2 Catalytic Gasification Reaction for CO gas Synthesis)

  • 이호용;이종대
    • 한국응용과학기술학회지
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    • 제33권3호
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    • pp.466-473
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    • 2016
  • 본 연구에서는 합성가스 CO를 생산하기 위해 저급 석탄-$CO_2$ 촉매 가스화 실험을 수행하였다. 제조된 CO가스 특성은 키데코 탄과 신화 탄에 KOH, $K_2CO_3$, $Na_2CO_3$ 촉매들의 화학적 활성화 방법을 이용하여 조사되었다. CO 제조공정은 석탄과 화학약품 활성화 비율, 가스 유량, $CO_2$ 전환 반응온도와 같은 실험 변수 분석을 통해 최적화되었다. 제조된 합성 가스는 가스 크로마토그래피(GC)에 의해 분석 되었다. 실험조건 $T=950^{\circ}C$, $CO_2$ 유량 100 cc/min에서, 20 wt% $Na_2CO_3$가 혼합된 키데코 탄에 대해 98.6%, 20 wt% KOH가 혼합된 신화탄에 대한 98.9% $CO_2$ 전환율을 얻었다. 또한, 저급 석탄-촉매 가스화 반응은 동일한 공급 비와 반응 조건에서 97.8%, 98.8%의 CO 선택도를 얻었다.