• Title/Summary/Keyword: CNT-

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Hydrothermal Synthesis of Metal-doped BiVO4 Powder and its Thermochromic Properties (금속이 도핑된 BiVO4 분말의 수열 합성 및 이의 열 변색 특성)

  • Wu, Guan Zhu;Son, Dae Hee;Jin, Young Eup;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.26 no.6
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    • pp.681-685
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    • 2015
  • In this study, pure $BiVO_4$ powder and metal-doped $M-BiVO_4$ (M = Mg, Cu) powder, well known as thermochromic materials, were prepared from a mixed aqueous solution of bismuth nitrate ($Bi(NO_3)_3$) and ammonium vanadate ($NH_4VO_3$) in autoclave by hydrothermal method. The crystal structure, microstructure, and thermochromic property of samples were analyzed using FE-SEM, FT-IR, XRD, DSC, UV-Vis-NIR spectroscopy and colorimeter. When heating samples above phase transition temperature, the color of $M-BiVO_4$ (M = Mg, Cu) sample was thermally changed more clearly than that of using only pure $BiVO_4$ sample.

Boiling Heat Transfer Coefficients of Nanofluids Using Carbon Nanotubes (탄소나노튜브를 적용한 나노유체의 비등 열전달계수)

  • Lee, Yo-Han;Jung, Dong-Soo
    • Journal of the Korean Solar Energy Society
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    • v.29 no.5
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    • pp.35-44
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    • 2009
  • In this study, boiling heat transfer coefficients(HTCs) and critical heat flux(CHF) are measured on a smooth square flat copper heater in a pool of pure water with and without carbon nano tubes(CNTs) dispersed at $60^{\circ}C$. Tested aqueous nanofluids are prepared using multi-walled CNTs whose volume concentrations are 0.0001, 0.001, 0.01, and 0.05%. For dispersion of CNTs, polyvinyl pyrrolidone(PVP) is used in distilled water. Pool boiling HTCs are taken from $10kW/m^2$ to critical heat flux for all nanofluids. Test results show that the pool boiling HTCs of the nanofluids are lower than those of pure water in entire nucleate boiling regime. On the other hand, critical heat flux is enhanced greatly showing up to 200% increase at volume concentration of 0.001% CNTs as compared to that of pure water. This is related to the change of surface characteristics by the deposition of CNTs. This deposition makes a thin CNT layer on the surface and the active nucleation sites of heat transfer surface are decreased due to this layer. The thin layer acts as the thermal resistance and also decreases the bubble generation rate resulting in a decrease in pool boiling HTCs. The same layer, however, maintains the nucleate boiling even at very high heat fluxes and reduces the formation of large vapor canopy at near CHF resulting in a significant increase in CHF.

Study on Explosion Behavior of Air-born Rice Bran Dusts according to Ignition Energy (점화에너지 변화에 따른 쌀겨분진의 폭발 거동에 관한 연구)

  • 김정환;김현우;현성호;백동현
    • Fire Science and Engineering
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    • v.13 no.2
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    • pp.26-32
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    • 1999
  • We had investigated combustion pro야$\pi$ies of rice bran dusts. Decomposition of rice bran d dusts with temperature were investigated using DSC and the weight loss according to t temperature using TGA in order to find the thermal hazard of rice bran dusts, and the p properties of dust explosion in variation of their dust with the same particle size. Using H Hartman's dust explosion apparatus which estimate dust explosion by electric ignition after m making dust disperse by compressed air, dust explosion experiments have been conducted by v varying concen$\sigma$ation and size of rice br뻐 dust. According to the results for thermodynamic stability of rice bran dust, there are little change of initiation temperature of heat generation 때d heating value for used particle size. But i initiation temperature of heat generation decreased with high heating rate whereas d decomposition heat increased with particle size. Also, the explosion pressure was increased as t the ignition energy increased and average maximum explosion pressure was 13.5 kgv'cnt for 5 BJ/60 mesh and 1.5 뼈Ie미 dust concentration.

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Processing and Mode 1 Fracture Toughness of Carbon Fiber Composites Reinforced With Carbon Nanotubes (탄소나노튜브로 보강된 탄소섬유복합재의 제조 공정과 모드 1 파괴인성)

  • Kim, Han-Sang
    • Composites Research
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    • v.24 no.5
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    • pp.39-43
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    • 2011
  • For the last twenty years, nanocomposites composed of polymer matrices reinforced with carbon nanotubes (CNTs) have been an active research area. Also, the polymeric nanocomposites reinforced with CNTs are being investigated to be used matrices of carbon fiber composites. Carbon tiber composites have achieved advanced properties in the direction of carbon fibers due to enhanced carbon fiber properties. However, the matrix dominated properties need to be improved further to fully utilize the advanced carbon fiber properties. In particular, delamination is a typical and critical reason for fracture of carbon fiber composites. Mode I fracture toughness test which is also often called double cantilever beam (DCB) test shows the resistance to delamination of carbon fiber composites and this test is performed on carbon fiber composite samples incorporated with carbon nanotubes functionalized with various functional groups. The specimens with mat-like CNT layers showed the increased fracture toughness by 10.6%.

CNT and CNF reinforced carbon fiber hybrid composites by electrophoresis deposition (전기영동법에 의한 탄소나노튜브 및 탄소나노섬유 강화 탄소섬유 하이브리드 복합재료)

  • Choi, O-Young;Lee, Won-Oh;Lee, Sang-Bok;Yi, Jin-Woo;Kim, Jin-Bong;Choe, Hyeon-Seong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.7-12
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    • 2010
  • In order to increase the electrical conductivity and the mechanical properties of carbon fabric composites, multi-walled carbon nanotubes (MWCNTs) and carbon nanofibers (CNFs) were deposited on carbon fabrics by anodic and cathodic electrophoretic deposition (EPD) processes. In the cathodic EPD, carbon nano-particles and nano-sized Cu particles were simultaneously deposited on the carbon fabric, which gave a synergetic effect on the enhancement of properties as well as the degree of deposition. The hybridization of carbon nano-particles and micron-sized carbon fiber significantly improved the through-the-thickness electrical conductivity. In addition, both MWCNTs and CNFs were deposited onto the carbon fabric for multi-scale hybrid composites. Multi-scale deposition improved the through-the-thickness electrical conductivity, compared to the deposition of either MWCNTs or CNFs.

THE EFFECTS OF RADIAL HEAT SINK GEOMETRY AND SURFACE COATINGS ON THE LED COOLING PERFORMANCE FOR HIGH POWER LED LAMP (고출력 LED 램프 용 방사형 히트싱크의 형상 및 표면코팅이 LED 냉각성능에 미치는 영향에 대한 연구)

  • Kim, H.S.;Park, S.H.;Kim, D.;Kim, K.
    • Journal of computational fluids engineering
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    • v.18 no.1
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    • pp.63-68
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    • 2013
  • The purpose of this study is to investigate the cooling performance of radial heat sink used for high power LED lightings by natural convection cooling with surrounding air. Experimental and numerical analyses are carried out together. Parametric studies are performed to compare the effects of geometric parameters in radial heat sink such as the number of fins, fin height, fin length, and thickness of fin base as well as the surface coatings of radial heat sink. In this study, the cooling of 60 W LED lamp is examined with radiative heat transfer considered as well as natural convection. Numerical results show the optimum condition when the number of fin is 40, heat sink height is 120 mm, fin length is 15 mm, and fin base thickness is 3 mm. The difference in temperature of the LED metal PCB is within $1^{\circ}C$ between numerical analyses and experimental results. Also, the CNT coating on the heat sink surface is found to increase the cooling performance significantly.

탄소나노튜브-그래핀 하이브리드 박막을 이용한 투명전극과 전계효과트랜지스터로의 응용

  • Kim, Seong-Ho;Song, U-Seok;Jeong, Min-Uk;Gang, Min-A;Lee, Seon-Suk;Im, Jong-Seon;Hwang, Jin-Ha;Myeong, Seong;An, Gi-Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.177.1-177.1
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    • 2014
  • 단일벽 탄소나노튜브(single-wall carbon nanotube)와 그래핀(graphene)과 같은 저차원 구조의 탄소물질은 우수한 기계적, 전기적, 열적 광학적 특성으로 인해 투명하고 유연한 차세대 전자소자로의 응용(투명전극, 투명트랜지스터, 투명센서 등)을 위한 연구가 활발히 진행되고 있다. 본 연구에서는 단일벽 탄소나노튜브와 단일층 그래핀을 이용한 하이브리드 박막을 제작하여 투명전극(transparent electrode)과 전계효과 트랜지스터(field effect transistors)로의 응용 가능성을 연구하였다. 하이브리드 박막의 제작은 간단한 방법으로 단일벽 탄소나노튜브가 스핀 코팅된 구리 호일 위에 열 화학기상증착법(thermal chemical vapor deposition)을 통해 제작 하였다. 제작 과정 중 탄소나노튜브의 스핀코팅 조건을 최적화하여 하이브리드 박막에서 탄소나노 튜브의 밀도와 정렬을 제어하였으며 하이브리드 박막 제작 후 스핀 코팅 방향에 따른 박막의 저항을 측정하여 단일벽 탄소나노튜브의 코팅 방향에 따라 박막의 저항이 달라지는 모습을 확인할 수 있었다. 하이브리드 박막의 투명전극 특성을 확인 한 결과 $300{\Omega}/sq$의 면저항에 96.4%의 우수한 투과도를 보이는 것을 확인 할 수 있었다. 또한 하이브리드 박막은 CVD 그래핀과 비교하여 향상된 와 on-state current를 보이는 것을 확인 할 수 있었다. 우리는 단일벽 탄소나노튜와 단일층 그래핀으로 이루어진 하이브리드 박막이 앞으로의 투명하고 유연한 소자제작 연구에 있어 새로운 투명 전극 및, 트랜지스터 제작 방법을 제시 할 수 있을 것이다.

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Thermopower Wave in Core-Shell Structures of Carbon Nanotube Chemical Fuels (나노튜브/화학연료의 동축 구조에서 생성되는 열동력 파도를 이용한 전기 에너지 생성)

  • Choi, Wonjoon;Strano, Michael S.
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.6
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    • pp.615-620
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    • 2013
  • There is considerable interest in developing energy sources capable of larger power densities. In our previous works, we proved that by coupling an exothermic chemical reaction with 1D nanostructures, a self-propagating reactive wave can be driven along its length with a concomitant electrical pulse of high specific power, which we identified as a thermopower wave. Herein, we discuss details about many different aspects of a thermopower wave. Different alignment degree in vertically aligned CNT films is evaluated in the reactive wave speed and correlated with its thermal reaction that affects the change in the magnitude of energy generation. The effects of the temperature-dependent properties of chemical fuels and CNTs are evaluated. Furthermore, we explore the convection and radiation portions in this thermal wave as well as the synchronization between the thermal reaction transfer and the oscillation of the electrical signal.

Label-free Femtomolar Detection of Cancer Biomarker by Reduced Graphene Oxide Field-effect Transistor

  • Kim, Duck-Jin;Sohn, Il-Yung;Jung, Jin-Heak;Yoon, Ok-Ja;Lee, N.E.;Park, Joon-Shik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.549-549
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    • 2012
  • Early detection of cancer biomarkers in the blood is of vital importance for reducing the mortality and morbidity in a number of cancers. From this point of view, immunosensors based on nanowire (NW) and carbon nanotube (CNT) field-effect transistors (FETs) that allow the ultra-sensitive, highly specific, and label-free electrical detection of biomarkers received much attention. Nevertheless 1D nano-FET biosensors showed high performance, several challenges remain to be resolved for the uncomplicated, reproducible, low-cost and high-throughput nanofabrication. Recently, two-dimensional (2D) graphene and reduced GO (RGO) nanosheets or films find widespread applications such as clean energy storage and conversion devices, optical detector, field-effect transistors, electromechanical resonators, and chemical & biological sensors. In particular, the graphene- and RGO-FETs devices are very promising for sensing applications because of advantages including large detection area, low noise level in solution, ease of fabrication, and the high sensitivity to ions and biomolecules comparable to 1D nano-FETs. Even though a limited number of biosensor applications including chemical vapor deposition (CVD) grown graphene film for DNA detection, single-layer graphene for protein detection and single-layer graphene or solution-processed RGO film for cell monitoring have been reported, development of facile fabrication methods and full understanding of sensing mechanism are still lacking. Furthermore, there have been no reports on demonstration of ultrasensitive electrical detection of a cancer biomarker using the graphene- or RGO-FET. Here we describe scalable and facile fabrication of reduced graphene oxide FET (RGO-FET) with the capability of label-free, ultrasensitive electrical detection of a cancer biomarker, prostate specific antigen/${\alpha}$ 1-antichymotrypsin (PSA-ACT) complex, in which the ultrathin RGO channel was formed by a uniform self-assembly of two-dimensional RGO nanosheets, and also we will discuss about the immunosensing mechanism.

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Mesoscale Simulation of Polymeric Membranes for Energy and Environmental Application (에너지-환경 분야용 분리막의 Mesoscale Simulation 동향 연구)

  • Park, Chi Hoon;Nam, Sang Yong
    • Membrane Journal
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    • v.27 no.2
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    • pp.121-128
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    • 2017
  • Mesoscale simulation is a type of molecular simulation techniques where groups of atoms are defined as a single bead for calculations, and accordingly, is possible to simulate longer time ($ns{\sim}{\mu}s$) and bigger size ($nm{\sim}{\mu}m$). There are two types of mesoscale simulations : (1) particle-based mesoscale which simulates the system by calculating the movement of the particles themselves and (2) field theory which simulates the system by calculating changes in the chemical potential filed or density field. Mesoscale simulations are powerful tools to study the macroscopic properties of polymers for various applications of energy and environment. In this review, we report the trends and useful information in mesoscale simulation and provide an opportunity for membrane researchers working in the energy-environment field to understand mesoscale simulation techniques.