• Journal of the Korean Electrochemical Society
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• v.11 no.2
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• pp.105-108
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• 2008

In the recent years, increasing interests are being focused on the rational functionalization of the CNTs by some creative methods. However, the considerable toxicity of CNT is still a controversialissue and limits its biological application. To improve the biocompatibility of CNT, in this work we prepared CNT-$TiO_2$ nanocomposites with CNT and organic titanium precursors. Our observations demonstratethat the modified interface could accelerate the heterogeneous electron transfer rates and thusenhance the relevant detection sensitivity, suggesting its potential application as the new strategy for the development of the biocompatible and multi-signal responsive biosensors for the early diagnosis of cancers.

• Korean Chemical Engineering Research
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• v.55 no.5
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• pp.646-651
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• 2017

Size and shape of carbon nanotube (CNT) agglomerates in the dilute phase of a bubbling fluidized bed ($0.15m\;i.d{\times}2.6m\;high$) have been determined by the laser sheet technique. Axial solid holdup distribution of the CNT particles showed S curve with dense phase and dilute phase in bubbling fluidization regime. Heywood diameter and Feret diameter of the CNT agglomerates in the dilute phase of bubbling fluidized bed increased with increasing gas velocity. The CNT particle number in the agglomerates increased with increasing of gas velocity. Aspect ratio increased and circularity, roundness and solidity decreased with increasing of gas velocity. A possible mechanism of agglomerates formation was proposed based on the obtained information.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.18.1-18.1
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• 2011

Some applications of carbon nanotubes (CNTs) as field emitters, such as x-ray tubes and microwave amplifiers, require high current emission from a small emitter area. To emit the high current density, CNT emitters should be optimally fabricated in terms of material properties and morphological aspects including high crystallinity, aspect ratio, distribution density, height uniformity, adhesion on a substrate, low outgassing rate during electron emission in vacuum, etc. In particular, adhesion of emitters on the substrate is one of the most important parameters to be secured for high current field emission from CNTs. So, we attempted a novel approach to improve the adhesion of CNT emitters by incorporating metal oxide layers between CNT emitters. In our previous study, CNT emitters were fabricated on a metal mesh by filtrating the aqueous suspensions containing both highly crystalline thin multiwalled CNTs and thick entangled multiwalled CNTs. However, the adhesion of CNT film was not enough to produce a high emission current for an extended period of time even after adopting the metal mesh as a fixing substrate of the CNT film. While a high current was emitted, some part of the film was shown to delaminate. In order to strengthen the CNT networks, cobalt-nickel oxides were incorporated into the film. After coating the oxide layer, the CNT tips seemed to be more strongly adhered on the CNT bush. Without the oxide layer, the field emission voltage-current curve moved fast to a high voltage side as increasing the number of voltage sweeps. With the cobalt-nickel oxide incorporated, however, the curve does not move after the second voltage sweep. Such improvement of emission properties seemed to be attributed to stronger adhesion of the CNT film which was imparted by the cobalt-nickel oxide layer between CNT networks. Observed after field emission for an extended period of time, the CNT film with the oxide layer showed less damage on the surface caused by high current emission.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.150-150
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• 2010

Carbon nanotubes have drawn attention as one of the most promising emitter materials ever known not only due to their nanometer-scale radius of curvature at tip and extremely high aspect ratios but also due to their strong mechanical strength, excellent thermal conductivity, good chemical stability, etc. Some applications of CNTs as emitters, such as X-ray tubes and microwave amplifiers, require high current emission over a small emitter area. The field emission for high current density often damages CNT emitters by Joule heating, field evaporation, or electrostatic interaction. In order to endure the high current density emission, CNT emitters should be optimally fabricated in terms of material properties and morphological aspects: highly crystalline CNT materials, low gas emission during electron emission in vacuum, optimal emitter distribution density, optimal aspect ratio of emitters, uniform emitter height, strong emitter adhesion onto a substrate, etc. We attempted a novel approach to fabricate CNT emitters to meet some of requirements described above, including highly crystalline CNT materials, low gas emission, and strong emitter adhesion. In this study, CNT emitters were fabricated by filtrating an aqueous suspension of highly crystalline thin multiwalled CNTs (Hanwha Nanotech Inc.) through a metal mesh. The metal mesh served as a support and fixture frame of CNT emitters. When 5 ml of the CNT suspension was engaged in filtration through a 400 mesh, the CNT layers were formed to be as thick as the mesh at the mesh openings. The CNT emitter sample of $1{\times}1\;cm^2$ in size was characteristic of the turn-on electrical field of 2.7 V/${\mu}m$ and the current density of 14.5 mA at 5.8 V/${\mu}m$ without noticeable deterioration of emitters. This study seems to provide a novel fabrication route to simply produce small-size CNT emitters for high current emission with reliability.

• Journal of the Korea Concrete Institute
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• v.28 no.1
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• pp.67-74
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• 2016

With several different dosages of multi-walled CNTs which was 0.1, 0.3, and 0.5% of the weight of binder, the fluidity in fresh CNT cement composites, as well as the strength and strength development with age of the hardened composites were investigated in this experimental study. The experimental results from flow test indicated that the increase in the dosage of CNTs badly impacted on the workability of fresh composites, and the results from rheological measurements presented the decrease in plastic viscosity and the increase in yield stress according to the amount of CNTs. In addition, the thixotrophy in the flow curve obtained from the rheology test was observed more noticeably in the composites with higher dosage of CNTs. With the experiments on the strength properties, the improvement of both compressive and tensile strengths with the increase of CNTs dosage could be obtained. Moreover, early strength development by adding CNTs was found when it was compared with plain cementious matrix without CNT.

• Journal of the Microelectronics and Packaging Society
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• v.20 no.4
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• pp.17-23
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• 2013

As a basic research to develop stretchable electronic packaging technology, CNT-Ag composite pads were formed on top of Cu/Sn chip bumps and flip-chip bonded using anisotropic conductive adhesive. Average contact resistances of the flip-chip joints were measured with respect to bonding pressure and presence of the CNT-Ag composite pads. When Cu/Sn chip bumps with CNT-Ag composite pads were flip-chip bonded to substrate Cu pads at 25MPa or 50 MPa, contact resistance was too high to measure. The specimen processed by flip-chip bonding the Cu/Sn chip bumps with CNT-Ag composite pads to the substrate Cu pads exhibited an average contact resistance of $213m{\Omega}$. On the other hand, the flip-chip specimens processed by bonding Cu/Sn chip bumps without CNT-Ag composite pads to substrate Cu pads at 25MPa, 50MPa, and 100MPa exhibited average contact resistances of $370m{\Omega}$, $372m{\Omega}$, and $112m{\Omega}$, respectively.

• Composites Research
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• v.24 no.5
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• pp.17-22
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• 2011

Recently transparent electrodes using carbon nanotube (CNT) have been studied actively to replace conventional ITO. In this work, CNT or ITO coated poly(ethylene terephthalate) (PET) were prepared by controlling the surfaces since the cohesion degree depends upon drying conditions. As transparent electrode application, 3 drying temperatures were set as 20, 80, and $120^{\circ}C$ to produce the change of surface properties. Interfacial durability and electrical properties of prepared transparent electrodes were evaluated by electrical resistance measurement. Surface change with changing drying temperature was observed by FE-SEM, whereas the transparency change was measured by UV-spectroscopy. The electronic properties of nanoparticle coated surface were evaluated using cyclic voltametry method upon the surface change with controlled drying temperature. Durability of CNT coated surfaces was better than ITO coated ease. As drying temperature increased, better coated surface was prepared due to improved cohesion among nanoparticles, which resulted in increased electrical properties.

• Composites Research
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• v.33 no.1
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• pp.1-6
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• 2020

Dispersion and electrical resistance (ER) properties of polyurethane (PU) type topcoat were evaluated using carbon nanotube (CNT) with different CNT weight fraction. CNT was dispersed in PU type topcoat using ultra sonication dispersion method. CNT/PU topcoat was coated on carbon fiber reinforced epoxy composite (CFRC) surface using gravity feed spraying method. Static contact angles of CFRC and CNT/PU topcoat were performed using 4 types of solvents to calculate the work of adhesion between CNT/PU topcoat and CFRC surface. Surface resistance of CNT added PU topcoat was measured to determine CNT dispersion. Adhesion property between CNT/PU topcoat and CFRC was determined via cross hatch cutting test based on ASTM D3359. The optimized condition of CNT weight fraction was found.

• Composites Research
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• v.25 no.3
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• pp.76-81
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• 2012

Atmospheric pressure plasma treatment on carbon nanotube (CNT) surfaces was performed to modify reinforcement effect and interfacial adhesion of carbon fiber reinforced CNT-phenolic composites. The surface changes occurring on CNT treated with plasma were analyzed by using Fourier transform infrared spectroscope (FT-IR). The significant improvement of wettability on CNT was confirmed by static contact angle test after plasma treatment. Such plasma treatment resulted in a decrease in the advancing contact angle from $118^{\circ}$ to $60^{\circ}$. The interfacial adhesion between carbon fiber and CNT-phenolic composites increased by plasma treatment based on apparent modulus test results during quasi-static tensile strength. Furthermore, the proposed database offers valuable knowledge for evaluating interfacial shear strength (IFSS).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.06a
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• pp.154-154
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• 2008

Although the screen printing technology using photosensitive carbon nanotube (CNT) paste has many advantages such as low cost, simple process, uniform emission, and capability of mass production, the CNT paste needs to be improved further in CNT dispersion, printability, adhesion, electrical conductivity, population of CNT emitters, etc. Ball milling has been frequently employed to prepare the CNT paste as ball milling can mix its ingredients very well and easily cut the long, entangled CNTs. This study carried out a parametric approach to fabricating the CNT paste in terms of low-energy ball milling and a paste composition. Field emission properties of the CNT paste was characterized with CNT dispersion and electrical conductivity which were measured by a UV-Vis spectrophotometer and a 4-point probe method, respectively. Main variables in formulating the CNT paste include a length of milling time, and amounts of CNTs and conductive inorganic fillers. In particular, we varied not only the contents of conductive fillers but also used two different sizes of filler particles of ${\mu}m$ and nm ranges. Among many variations of conductive fillers, the best field emission characteristics occurred at the 5 wt% fillers with the mixing ratio of 3:1 for ${\mu}m$-and nm-sizes. The amount and size of fillers has a great effect on the morphology, processing stability, and field emission characteristics of CNT emitter dots. The addition a small amount of nm-size fillers considerably improved the field emission characteristics of the photosensitive CNT paste.