• The Bulletin of The Korean Astronomical Society
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• v.38 no.2
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• pp.67.1-67.1
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• 2013

It has been known that HCN is one of ubiquitous high-density gas tracer, and the abundance ratio between HCN and its Isomer, HNC sensitively depends on kinetic temperature in star-forming regions. Here we investigate the molecular abundance ratio toward three different evolutionary phases of massive star formation: Infrared Dark Clouds, High-mass Protostellar Objects and Ultracompact HII Regions. We obtained the abundances of HCN and HNC using optically thin H13CN and HN13C lines observed with the KVN single-dish telescopes and MAMBO 1.2mm and SCUBA $850{\mu}m$ continuum data. According to our results, the ratio of [HCN]/[HNC] increases statistically with the evolutionary stage, indicative of the effect of temperature. We also found a strong anti-correlation between the column density of molecular hydrogen and the HNC abundance.

• Journal of the Korean Chemical Society
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• v.25 no.1
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• pp.7-12
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• 1981

Solvolysis of $p-CH_3, p-H, p-Cl and p-NO_2$-benzenesulfonyl chlorides have heen studied in MeOH-MeCN mixtures. A nonlinear Hammett plot with a ratio order of p-NO_2 > p-CH_3 > p-H > p-Cl was obtained; the reaction was thought to proceed by an S_N1-S_N2 borderline mechanism. In all cases the reactivity was a maximum at 90∼95%(v) methanol, whereas methanol monomer selectivity defined as fi = \frac{k1}{ki}i (k1; observed pseudo-first order rate constant: ki; hypothetical rate constant for MeOH solution having the same polymer structure as in the pure MeOH) was a maximum at 80% methanol with a decreasing order of fi as p-NO_2 > p-Cl > p-H > p-CH_3.$ This was interpreted as the decrease in tightness of transition state; the larger the fi, the tighter is the MeOH attached to the substrate, and hence the more susceptible the substrate becomes to the approaching monomer methanol.

• The Journal of Korean Institute of Communications and Information Sciences
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• v.30 no.6B
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• pp.387-395
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• 2005

In this paper, we propose an end-to-end mobility management and TCP flow control scheme which considers different link characteristics for vertical handover environments. The end-to-end mobility management is performed by using SIP protocol. When a mobile node moves to a new network, it informs its movement of the correspondent node by sending SIP INFO message containing a new IP address which will be used in the new network. And then the corresponding node encapsulates all packets with the new IP address and sends them to the mobile node. in general, RTT of WLAN is shorter than RTT of cdma2000. when the MN moves from WLAN network to cdma2000 network, TCP retransmission timeout will be occurred in spite of non congestion situations. Thus, TCP congestion window size will be decreased and TCP throughput will be also decreased. To prevent this phenomenon, we propose a method using probe packets after handover to estimate a link delay of the new network. We also propose a method using bandwidth ratio of each network to update RTT. It is shown through NS-2 simulations that the proposed schemes can have better performance than the previous works.

• 한국방재학회:학술대회논문집
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• 2008.02a
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• pp.755-758
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• 2008

Currently, the increased run-off and the shortened arrival time are one of the causes of the city environmental disasters in urbanization. Therefore, it is necessary to properly design the hydrologic structures, but it is very difficult to forecast the values necessary to design from the planning stage. Moreover, as the parameter is changed due to the urban development, it is difficult not only to analyze the run-off influences but also to find the related studies and literatures. The purpose of this study is to utilize the results as the important basic data of the hydrologic structures, its proper design and run-off influences through the sensibility analysis of the model parameter variables. In this study, the absolute and relative sensibility analysis method were used to find out the correlation through the sensibility analysis of the topology and hydrology parameters. Especially, in this study, the changes in the run-off amount and volume were calculated according to increase/decrease in CN, the coefficient of discharge, and the empirical formula is prepared and proposed through the regressive analysis among the parameters. In the meantime, the parameter sensibility analysis was performed through the simulation HEC-HMS that is used and available in Korea. From the results of this study, it was found that the run-off amount is increased about by 10% when the CN value is increased by 5% before and after the development through the HEC-HMS simulation and data analysis. As long as there will be additional data collection analysis and result verification, and continuous further studies to find out the parameters proper to the domestic circumstances, it is expected to considerably contribute to the proper design of the hydrologic structures with respect to the ungauged basin.

• Analytical Science and Technology
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• v.11 no.5
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• pp.404-408
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• 1998

Using a reversed-phase high performance liquid chromatography, the separation of 20(S)-, 20(R)-prosapogenin stereo-isomers of ginsenoside-$Rg_2$ and of ginsenoside-$Rg_3$ in ginseng saponins has been carried out with binary solvent system. The optimum conditions for the isomer separation are as following: Nova-$Pak^{(R)}C_{18}$ (Waters, $3.9{\times}150mm$) column, $CH_3CN/CH_3CN$ (100:8, v/v) binary solvent system and the flow rate was 1.7 mL/min. The stereoisomers were separated with change of the mixture ratio of the solvent system, the solvent elution by gradient program, and then detected at 203 nm of UV detector. The simultaneous separation of mixture that were the $Rg_2$, $Rg_3$ isomers was easily performed in nonpolar solvent for $Rg_2$, polar solvent for $Rg_3$ at the same optimum conditions.

• Journal of the Korean Chemical Society
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• v.9 no.2
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• pp.101-105
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• 1965

Spectrophotometric method for the determination of Co(Ⅱ) is developed based on the fact that Co(Ⅱ) forms a stable red complex with 7-nitroso-8-hydroxyquinoline-5-sulfonate at pH 4. 5. The absorbance is measured at 528$m{\mu}$, $25^{\circ}C$. Beer's law is followed in the concentration range of 0. 3 to 6. 0 p.p.m. of Co(Ⅱ) and molar extinction coefficient of the complex was $1.1{\times}10^4$. Of the diverse ions checked, Fe(Ⅱ), Fe(Ⅲ), Cu(Ⅱ), Mn(Ⅱ), Hg(Ⅰ), CN-, EDTA interfere. The composition of the complex is found to be 3:1 ligand to metal species by mole ratio and continuous variation methods.

• Journal of the Korean Chemical Society
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• v.55 no.6
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• pp.940-951
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• 2011

Reaction of 1-methylpyrimidine-(1H,3H,5H)-2,4,6-trione (1-MBA 1) as an unsymmetrical barbituric acid with cyanogen bromide and various aldehydes in the presence of triethylamine and/or pyridine afforded diastereomeric mixtures of new class of heterocyclic stable 5-aryl-1,1'-dimethyl- and 5-aryl-3,1'-dimethyl-1H,1'H-spiro[furo[2,3-d]pyrimidine-6,5'-pyrimidine]2,2',4,4',6'(3H,3'H,5H)-pentaones which are dimeric forms of 1-methyl barbiturate at the range of $0^{\circ}C$ to room temperature. In the reaction of some aldehydes with 1-MBA and BrCN were afforded a mixture of diastereomers. Another two aldehydes such as 4-cyano- and 2-hydroxybenzaldehydes gave exclusively two diastereomers in which binded to the salt of triethylammonium hydrobromide by intermolecular H-bond in ratio of 1:1. 4-Hydroxybenzaldehyde and 2-pyridinecarbaldehyde gave exclusively one diastereomer under the same condition. Aldehydes possessing strong electron-donor were produced exclusively two geometric isomers of Knoevenagel adduct (E- and Z-isomers). The structures of compounds were deduced by $^1H$ NMR, $^{13}C$ NMR and FT-IR spectroscopy. Mechanism of the formation is discussed.

• Korean Journal of Materials Research
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• v.31 no.3
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• pp.162-171
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• 2021

Dry etching of copper thin films is performed using high density plasma of ethylenediamine (EDA)/hexafluoroisopropanol (HFIP)/Ar gas mixture. The etch rates, etch selectivities and etch profiles of the copper thin films are improved by adding HFIP to EDA/Ar gas. As the EDA/HFIP concentration in EDA/HFIP/Ar increases, the etch rate of copper thin films decreases, whereas the etch profile is improved. In the EDA/HFIP/Ar gas mixture, the optimal ratio of EDA to HFIP is investigated. In addition, the etch parameters including ICP source power, dc-bias voltage, process pressure are varied to examine the etch characteristics. Optical emission spectroscopy results show that among all species, [CH], [CN] and [H] are the main species in the EDA/HFIP/Ar plasma. The X-ray photoelectron spectroscopy results indicate the formation of CuCN compound and C-N-H-containing polymers during the etching process, leading to a good etch profile. Finally, anisotropic etch profiles of the copper thin films patterned with 150 nm scale are obtained in EDA/HFIP/Ar gas mixture.

• Journal of the Korean Vacuum Society
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• v.4 no.S2
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• pp.131-138
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• 1995

The broad beam ion sources of hot filament plasma type have widely used for modifications of materials and thin films, and the new type intensive current broad beam metal ion source including reactive gaseous ion beams is needed for preparing the hard coating films such as DLC, $\beta-C_3N_4$ Carbides, Nitrides, Borides etc. Now a electorn beam evaporation(EBE) broad beam metal ion source has been developed for this purpose in our lab. CN film has been formed by the EBE ion source. Study of the CN film shows that it has high hardness(HK=5800kgf/$\textrm {mm}^2$)and good adhesion. This method can widely changes the ratio of C/N atom's concentrations from 0.14 to 0.6 and has high coating rate. The low energy pocket ion source which was specially designed for surface texturing of medical silicon rubber was also developed. It has high efficiency and large uniform working zone. Both nature texturing and mesh masked texturing of silicon rubbers were performed. The biocompatibility was tested by culture of monocytes, and the results showed improved biocompatibility for the treated silicon rubbers. In addition, the TiB2 film synthesized by IBED is being studied recently in our lab. In this paper, the results which include the hardness, thickness of the films and the AES, XRD analysis as well as the tests of the oxidation of high temperature and erosion will be presented.

• Journal of Korean Society on Water Environment
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• v.25 no.3
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• pp.375-385
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• 2009

The estimation of delivery ratio is a essential part of Korean Total Maximum Daily Loads (TMDL) procedure which needs a number of observed stream flow and pollutants data. If observed data were not sufficient, researchers have to find other alternatives. One of them is to make indirect data by using watershed models, such as Soil and Water Assessment Tool (SWAT) and Hydrological Simulation Program - FORTRAN (HSPF) and so on. In this study, indirect daily data was made by using SWAT model. To build the Byongseong-SWAT model accurately, crop cultures are reflected by handling the MGT.file in SWAT model. Especially, mass of manure and schedule of crop culture are inputted through investigating domestic research papers as well as fieldwork. After calibrating SWAT model in comparison with the 22-years flow and pollutants observed outlet data, the delivery ratio of Byongseong watershed is calculated by using daily simulated data during 2004-2007. Empirical equations for delivery ratio through multi-regression analysis are developed by using meteorological and physical factors such as flow, watershed area, stream length, catchment slope, curve number (CN) and subbasin's pollutant discharge loads.