• Title/Summary/Keyword: CN Method

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X-ray crystal structure of two-dimensional bimetallic host clathrate with 2-aminoethanol, [Cd{NH2CH2CH2OH}2Ni(CN)4]·3C6H5NH2·H2O

  • Kim, Chong-Hyeak;Moon, Hyoung-Sil;Lee, Sueg-Geun
    • Analytical Science and Technology
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    • v.21 no.6
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    • pp.562-568
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    • 2008
  • A novel two-dimensional cadmium(II)-nickel(II) bimetallic host clathrate, $[Cd{NH_2CH_2CH_2OH}_2Ni(CN)_4]{\cdot}3C_6H_5NH_2{\cdot}H_2O$, 1, has been synthesized and structurally characterized by X-ray single crystallographic method. The clathrate 1 crystallizes in the monoclinic system, space group $P2_1/c$ with a = 14.370(3), b = 7.728(1), c = 28.172(4) ${\AA}$, ${\beta}=97.58(1)^{\circ}$, V = 3101.1(9) ${\AA}^3$, Z = 4. The host framework of the clathrate 1 is built of the cyanide bridges between octahedral Cd(II) atom and square planar Ni(II) atom. The octahedral Cd atoms ligated by two 2-aminoethanol molecules and four cyanide ligands bridged with square planar Ni atoms. The Ni atoms bridges to four Cd atoms via cyanides is made up of puckered quadrangles of composition $\{CdNi(CN)_2\}_2$, all edges are shared. This cyanide bridges form an infinite two-dimensional host networks stacking along b axis. 2-Aminoethanol ligands bond to Cd atom through N atom as a monodentate ligand in the axial position and four cyanides take an equatorial plane with all in trans-configurations. The aniline guest molecules and water molecules are located in between the host layer sheets, respectively.

Flood Runoff Computation for Mountainous Small Basins using HEC-HMS Model (HEC-HMS 모델을 이용한 산지 소하천유역의 홍수유출량 산정)

  • Chang, In-Soo
    • Journal of the Korean Society of Industry Convergence
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    • v.7 no.3
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    • pp.281-288
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    • 2004
  • The objective of this study is to propose a methodology of the flood runoff analysis in steep mountainous basins and the analysis basin is the Jasa valley basin in Chungju city Analyzing the spatial pattern of the rainfall in 1994. 6 30~7.1, the seasonal rainy front was tied up in the whole central district, and the rainfall center was moving from the northern Chungbuk province to the northern Kyongbuk province and caused heavy storm. Analyzing the temporal pattern with the Huff method, the 52.5% of the rainfall was concentrated on the 3rd quartile. Rainfall frequency analysis is accomplished by five distribution types; 2-parameter Lognomal, 3-parameter Lognomal, Pearson Type III, Log-Pearson Type III and Extremal Type I distribution Rainfall-runoff analysis in Jasa valley basin was made using HEC-HMS model. Jasa valley basin was divided into 3 sub-basins and the analysis point was 3 points{A, B and C point) With the rainfall data measured by the 10 minutes, the flood runoff also was calculated by as many minutes. SCS CN model, Clark UH model and Muskingum routing model in HEC-HMS model were used to simulate the runoff volume using selected rainfall event.

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A Basic Study on Green Building Certification in China (중국의 녹색건축인증 현황에 대한 기초조사 연구)

  • Kim, Jae-Young;Liu, Zhi-Hong;Lee, Jong-Kuk
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.16 no.1
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    • pp.12-19
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    • 2017
  • This study investigates and analyzes the current status of green building certification (ESGB) in China, which is experiencing serious environmental pollution due to rapid economic development as an international pending issue for green growth, It is a basic research. This will be used as a resource to contribute to the reduction of carbon emissions in the future construction sector. The research method is to investigate the status of green building certification and the types of facilities in the whole of China, and to examine the evaluation criteria and items of ESGB 2014 and analyze the differences with ESGB 2006. Most of the research methods are based on the literature review and refer to the website of China Green Building Evaluation and the data of China Urban Science Institute.

Photocatalytic Degradation of Rhodamine B Using Carbon-Doped Carbon Nitride under Visible Light

  • Wang, Zhong-Li;Zhang, Zai-Teng;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.30 no.6
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    • pp.279-284
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    • 2020
  • In this work, a carbon-doped carbon nitride photocatalyst is successfully synthesized through a simple centrifugal spinning method after heat treatment. The morphology and properties of the prepared photo catalyst are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectrophotometer (UV-vis), and specific surface area. The results show that the band gap of the prepared sample, g-CN-10 is 2.1 eV, is significantly lower than that of pure carbon nitride, 2.7 eV. As the amount of cotton candy increased, the absorption capacity of the prepared catalyst for visible light is significantly enhanced. In addition, the degradation efficiency of Rhodamine B (RhB) by sample g-CN-10 is 98.8 % over 2 h, which is twice that value of pure carbon nitride. The enhancement of photocatalytic ability is attributed to the increase of specific surface area after the carbon doping modifies carbon nitride. A possible photocatalytic degradation mechanism of carbon-doped carbon nitride is also suggested.

Purification and Characterization of Antioxidant Substance from the Stem Bark of Rhus verniciflua (옻나무 껍질에서 항산화물질의 정제와 특성)

  • Kim, Jung-Bae
    • The Korean Journal of Food And Nutrition
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    • v.14 no.6
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    • pp.527-531
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    • 2001
  • In order to isolate antioxidant substances from Rhus verniciflua (RV) , the dried stem bark was extracted with water. The crude water extracts was purified by using HPLC method with a DEAE (anionic type) , CN and ODS column. The purified compound remained stable at pH 3.0∼6.0. but unstable above pH 6.5. It was stable at 100$^{\circ}C$ for 4 hours, but still had about 80% of residual activity after treatment at 100$^{\circ}C$ for 5 hours. In antimicrobial test, no inhibition was observed against Gram-positive and negative bacteria. This compound was stronger than that of commercial antioxidant showed that DPPH test, such as BHT, BHC at the same concentration (20 $\mu\textrm{g}$/ml) .

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Estimation of Movement Amount of River Floating Debris Based on Effective Rainfall and Flow Rate (유효강우량과 유량에 따른 하천 부유쓰레기 이동량 산출)

  • Jang, Seon-Woong;Yoon, Hong-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.12 no.1
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    • pp.237-242
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    • 2017
  • Along with effluence of non-point pollution source, continuous precipitation due to rainy season or localized heavy rain can also be a good reason for increase of flow rate. And if the water level is going up due to the increase, floating debris around rivers and streams will move because of increased flow velocity. However, currently, there are no studies which perform quantitative calculation on movement of floating debris by analyzing amount of rainfall and flow rate in both domestic and abroad. Thus, the present study calculated amount of movement of floating debris based on moving route monitoring results according to changes of effective rainfall and flow rate that are obtained by using SCS-CN method.

Application of Detention and Infiltration-based Retention Hybrid Design Technique to Oncheon Stream (유수지 및 침투기반 저류지 복합설계기법의 온천천 유역 적용)

  • Choi, Chi Hyun;Kim, Eungseock;Kim, Jin Kwan;Kim, Sangdan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2B
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    • pp.99-108
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    • 2011
  • In this study a hybrid design scheme for the purpose of designing infiltration-based retentions and a detention is applied to reproduce urban hydrologic regime to natural hydrologic regime. The proposed method is based on the NRCS-CN stormwater estimation technique, and applied to determine the size for stormwater control facilities on the Oncheon stream as an example. Urban area, corresponding to less than 70 m height of the Oncheon stream basin area is targeted. The results indicate that the proposed scheme is very useful to reproduce its undeveloped flow-duration curve.

A Conceptual Soil Water Model of Catchment Water Balance: Which Hydrologic Components are Needed to Calibrate the Model? (유역 물수지 모의를 위한 개념적인 토양수분모형: 모형 보정에 필요한 수문성분 분석)

  • Choi, Daegyu;Yang, Jeong-Seok;Chung, Gunhui;Kim, Sangdan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.3B
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    • pp.211-220
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    • 2011
  • In this study a conceptual soil water model is proposed to simulate water balance at catchment scale. The model is based on the sequential separation of daily precipitation into surface runoff, wetting, vaporization, and percolation. The proposed model is calibrated by using three observation sets: empirically estimated annual vaporization, monthly wetting estimated by NRCS-CN method, and both of them. The model performance is evaluated to understand which hydrologic components for calibrating the model are needed. It is shown that both of annual vaporization and monthly wetting are indispensable hydrologic components to simulate reasonably precipitation partitioning.

Effects of coating material and cutting parameters on the surface roughness and cutting forces in dry turning of AISI 52100 steel

  • Keblouti, Ouahid;Boulanouar, Lakhdar;Azizi, Mohamed Walid;Yallese, Mohamed Athmane
    • Structural Engineering and Mechanics
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    • v.61 no.4
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    • pp.519-526
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    • 2017
  • In the present paper, the effects of cutting parameters and coating material on the performances of cutting tools in turning of AISI 52100 steel are discussed experimentally. A comparative study was carried out between uncoated and coated (with TiCN-TiN coating layer) cermet tools. The substrate composition and the geometry of the inserts compared were the same. A mathematical model was developed based on the Response Surface Methodology (RSM). ANOVA method was used to quantify the effect of cutting parameters on the machining surface quality and the cutting forces. The results show that feed rate has the most effect on surface quality. However, cutting depth has the significant effect on the cutting force components. The effect of coating layers on the surface quality was also studied. A lower surface roughness was observed when using PVD (TiCN-TiN) coated insert. A second order regression model was developed and a good accuracy was obtained with correlation coefficients in the range of 95% to 97%.

A Study on the Estimation of Regional Groundwater Recharge Ratio (지역단위 지하수 자연함양율 산정방법 연구)

  • 최병수;안중기
    • Journal of the Korean Society of Groundwater Environment
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    • v.5 no.2
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    • pp.57-65
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    • 1998
  • Recently, many researchers have studied on the estimation of groundwater storage and its usable amount in Korea. Those studies were, however, mostly on the groundwater recharge amount over the nation or for the large extent of areas. On the other hand, it has been also needed to study on the regional recharge rate for the planning of groundwater management or for the assessment of groundwater development impacts. In this paper, two practical methods for the estimation of regional groundwater recharge have been studied and proposed, which are $\circled1$ the estimation of the groundwater recharge due to the SCS-CN infiltration method, and $\circled2$ the estimation of groundwater recharge ratio by analyzing groundwater level hydrographs.

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