• Journal of the Korean Chemical Society
• /
• v.33 no.6
• /
• pp.582-587
• /
• 1989

Rates for aquation of $[Cr(NH_3)_5(DMF)]^{3+}$ ion in aqueous acidic solution have been measured by spectrophotometric method at various temperatures and pressures. The volume of activation for the aquation is small negative and lies in the limited range -2.76 ∼ -3.65 $cm^3mol^{-1}$. The entropy and compressibility coefficient of activation are small negative values. From the results of thermodynamic activation parameters, it can be inferred that the aquation of $[Cr(NH_3)_5(DMF)]^{3+}$ ion proceeds through an associative interchange($I_a$) mechanism.

• Journal of the Society of Disaster Information
• /
• v.19 no.2
• /
• pp.280-291
• /
• 2023

Purpose: As fire accidents happen at the production and storage sites of superabsorbent polymers for convenience of daily life, an experimental study was conducted to secure basic data to establish practical preventive measures against them. Method: The sample container (20cm width × 20cm length) was made into a rectangular cuboid with the heights of 3cm, 5cm, 7cm, and 14cm, respectively, to allow access to the infinite flat plane. The front and back of the container were covered with a 300-mesh stainless steel mesh for one-dimensional heat transfer. The sample container was placed in the center of the thermostatic bath, which was heated to a predetermined temperature by setting the thermostat program in advance, and it was determined to be 'ignited' when the central temperature of the sample rose by more than 20℃ above the set temperature, and "unignited" when it was maintained at an approximate value of the set temperature. Result: The critical autoignition temperature was calculated to be 217.5℃ when the height of the sample container was 3 cm, 212.5℃ when it was 5 cm, 202.5℃ when it was 7cm, and 187.5℃ when it was 14cm. The ignition induction time to reach the maximum temperature was 34hours for 3cm, 76hours for 5cm, 143hours for 7cm, and 318hours for 14cm. Conclusion: ① As the size of the container increased, the autoignition temperature decreased and the induction time to reach the maximum temperature increased. ② An apparent activation energy was calculated to be 44.92kcal/mol, with a correlation of 96.93%.

• Journal of the Korean Chemical Society
• /
• v.34 no.2
• /
• pp.117-122
• /
• 1990

The rate constants for the aquation of $trans-[CoETECl_2]^+ \;and \;cis-{\beta}-[CoTETCl_2]^+$ and the isomerization of $trans-[CoETEClOH_2]^{2+}$ were measured by spectrophotometric method under various temperature and pressure conditions. For the aquations of $trans-[CoETECl_2]^+ \;and\; cis-{\beta}-[CoTETCl_2]^+$, the activation entropies are 4.0 eu and 5.3 eu respectively and the activation volumes are $-5.8 cm^3mol-1\; and\; -6.6 cm^3mol^{-1}$ at 40$^{\circ}C$, respectively. From these data the dissociative mechanism involving trigonal bipyramid-type intermediate is proposed for the acquation reaction. For the isomerization of $trans-[CoETEClOH_2]^{2+}\; to\; cis-{\beta}-[CoETEClOH_2]^{2+}$ the activation entropy is 9.5 eu and the activation volume is $8.4 cm^3mol^{-1}(30^{\circ}C$. The mechanism of isomerization may be considered as the dissociative mechanism with $H_2O$-dissociation.

• Journal of the Korea Institute of Building Construction
• /
• v.6 no.4 s.22
• /
• pp.99-102
• /
• 2006

Although constructions are getting diverse, larger in size, and higher-storied, we witness that CM technologies are not coping with such a growing trend. In particular, CM, one of vulnerable areas, shall continue to be given priority hereafter. The research has been conducted with a strong focus on total design and supervision offices already specializing in CM projects, in order to prepare for the future activated CM markets. Authors have sought to find mistakes in the process of being in control of CM works and create measures to boost CM through case-study, documentary research, and interviews with experts. It excludes theoretical research, as many data are already accumulated domestic and abroad.

• Proceedings of the Korean Institute Of Construction Engineering and Management
• /
• autumn
• /
• pp.296-299
• /
• 2002

Construction Management tends to create a formal procurement resulted from recent legislative procedures system in domestic construction industry. However, the fact that construction Manager(CMr) has been chosen, in practice, under a poor circumstance in selecting and discriminating specialty requires the more optimal procedures. Therefore, in this research, we analyze the existing shortcomings. the various procedures, influence factors, and the criteria to be considered in selecting and evaluating CMr. Also. this study suggests the improved method based on the facts above. To accomplish the construction project successfully, it is one of the advanced schemes to choose an adequate CMr needed to the project through the precision in the formation and application of the procedure as well as the suggested criterion in selecting CM.

• Proceedings of the Korean Institute Of Construction Engineering and Management
• /
• 2007.11a
• /
• pp.289-294
• /
• 2007

It has been 10 years Since December 1996 when CM method was institutionalized by Construction Industry Fundamental law. Even though construction market has been in stagnant of business activities till now, CM in Korea started to be activated by the introduction of CM method i.n public construction. In the end of 2005, the number of CM order's contract is 6.7 times , an amount of CM order's money is 9.2 times more than operation plan of CM system announced in 2001. Therefore, CM market has been dramatically growing. However, it is judged that the shortage of faith in CM project and necessity of CM method are not recognized and study on a owner who affects successful settlement of CM has not been performed. When considering those points, in introduction and practical use of CM, CM is suggested to the field which is necessary for a client through the task performance level research and analysis of a owner who act a important role to activate Construction Management. As result of studying pre-existing papers to i.nvestigate of owner's capability level, the task function of a client is classified into 10 types and a public opinion poll was performed based on the 10 types of function.

• Construction Engineering and Management
• /
• v.15 no.2
• /
• pp.37-41
• /
• 2014

• Proceedings of the Korean Vacuum Society Conference
• /
• 1999.07a
• /
• pp.60-60
• /
• 1999

단결정 다이아몬드의 열전도도는 약 22W/cm.K로 열전도도가 가장 큰 물질로 알려져 있으며, 비저항은 10$\Omega$.cm 이상의 높은 값을 갖는다. 대부분 열전도도가 큰 것으로 알려진 물질들은 Cu, Ag 등과 같이 전자의 흐름에 의하여 열이 전도되기 때문에 큰 전기전도도를 함께 갖는 것일 일반적이다, 그러나, 다이아몬드는 빠른 phonon의 이동에 의하여 열전도가 이루어지므로 전기적으로 절연 특성을 갖으면서도 큰 열전도가 가능하다. 단결정 다이아몬드는 고방열 절연체로서 이상적인 물질 특성을 보여준다. 전기절연성을 갖는 열전도층으로 다이아몬드를 이용하기 위해서는 저가로 제조가 용이한 화학기상증착법을 이용하여야 한다. 화학기상증착법으로 제조된 다결정 다이아몬드 박막의 열전도도는 약 21W/cm.K로 여전히 매우 높은 값을 갖는 것으로 알려져 있지만, 비저항 값은 인위적으로 도핑을 전혀 하지 않은 상태에서도 106$\Omega$.cm 정도의 낮은 값을 갖는다. 전혀 도핑을 하지 않았음에도 전도성을 갖는 특이한 특성을 다결정 다이아몬드가 보여 주고 있으므로 이에 대한 연구는 주로 전기 전도성을 갖는 특이한 특성을 다결정 다이아몬드가 보여주고 있으므로 이에 대한 연구는 주로 전기전도성의 원인을 규명하는데 집중되고 있다. 아직 명확한 전도 기구는 제안되고 있지 못하지만 전도성의 원인은 수소와 관련이 있고 전도는 표면을 통하여 이루어진다는 것이다. 산(acid)을 이용하여 다결정 다이아몬드 박막을 세척하면 전기 전도성이 사라지고 높은 저항값을 갖는 박막을 얻게 되는데 박막을 세척하는 공정은 박막의 표면만을 변호시키므로 표면에 있던 전기전도층이 용액 처리를 통하여 제거되므로 전도성이 사라진다고 생각하는 것이다. 그러나, 본 연구에서는 두께가 두꺼울수록 저항값이 증가하는 것이 관찰되었고 기존의 측정방식인 수평적인 저항 측정법에 대하여 수직적 방향으로 저항을 측정하면 저항값이 1/2 정도 작게 측정되었다. 다결정 다이아몬드에서 표면을 통하여 전류가 흐른다면 박막의 두께에 따른 변화가 나타나지 않아야 하고 수직적인 전류 측정법이 오히려 더 큰 저항을 보여주어야 한다. 기존의 표면 전도 모델로는 설명되지 못하는 현상들이 관찰되었고 정확한 전기 전도 경로를 확인하기 위하여 전해 도금법으로 금속들이 석출되는 모습을 관찰하였다. 이 방법을 통하여 다결정 다이아몬드에서 전류는 결정입계를 통하여 전도됨을 알 수 있었다. 온도에 따른 다결정 다이아몬드의 전기전도도 변화를 관찰하였고 이로부터 활성화 에너지 값을 구할 수 있었다. 다결정 다이아몬드의 전도도는 온도에 따라서 0.049eV와 0.979eV의 두 개의 활성화 에너지를 갖는 구간으로 나뉘어졌다. 이로부터 다결정 다이아몬드에는 활성화 에너지 값이 다른 두 종류의 defect level이 형성되는 것으로 추정할 수 있고 이 낮은 defect level에 의하여 전도성을 갖는 것으로 생각된다.

• Journal of the Korean Vacuum Society
• /
• v.13 no.3
• /
• pp.109-113
• /
• 2004

Zn diffusions in InP have been studied by electrochemical capacitance voltage. The InP layer was grown by metal organic chemical vapor deposition, and $Zn_3P_2$ thin film was deposited on the epitaxial substrates. The samples annealed in a rapid thermal annealing. It is demonstrated that surface hole concentration as high as $1\times10^{19}\textrm{cm}^{-3}$ can be achieved. When the Zn diffusion was carried at $550^{\circ}C$ and 5-20 min., the diffusion depth of hole concentration moves from 1.51$\mu\textrm{m}$ to 3.23 $\mu\textrm{m}$, and the diffusion coeffcient of Zn is $5.4\times10^{-11}\textrm{cm}^2$/sec. After activation, the concentration is two orders higher than that of untreated sample at 0.30 $\mu\textrm{m}$ depth. As the annealing time is increase, the hole concentration remains almost constant, except deep depth. It means that excess Zn interstitials exist in the doped region is rapidly diffusion into the undoped region and convert into substitutional When the thickness of $SiO_2$ thin film is above 1,000$\AA$, the hole concentration becomes stable distribution.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.35 no.6
• /
• pp.1357-1366
• /
• 2015

This study (II) aims to draw up the future-oriented construction policy recommendations based on the outcomes as a result of a broad research and conducting questionnaire surveys on the arguable issues raised by construction engineers for roads and bridges in the course of previous study (I) implementation. As for the question of "The term 'Construction Management (CM)' which currently is defined in two (2) ways", 45% of respondents have answered that two (2) different types of CM should be unified into one (1) CM type as is the case in most advanced countries. About the question of "The ways to educate the CM professionals", many respondents have preferred to acquire CM professional certificate after receiving education for a certain period of time from private CM training institutions. As for the question of The revised draft that the ICEC grade of special engineers for design, construction and quality control areas shall be "more than 78 points from a more than 75 points by the original draft." 52% of respondents preferred to maintain the original draft. About the question of "The reason why the CM system has not been working well yet." 62% of respondents have answered that the staff members who are in charge of handling public project procurements are concerned about the fact that their roles (or activities) might be deprived as a result of CM adoption. In order for the CM system to be activated, based on the notion that the construction projects must be out soured, the reshuffle of the headquarter organization of Ministry of Land, Infrastructure and Transportation (MLIT) should be preceded.