• Title/Summary/Keyword: CL Data

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Silver Ores and Fluid Inclusions of the Cheolam Silver Deposits (철암은광상(鐵岩銀鑛床)의 광석(鑛石)과 유체포유물(流體包有物))

  • Park, Hee-In;Woo, Young-Kyun;Bae, Young Boo
    • Economic and Environmental Geology
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    • v.20 no.1
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    • pp.1-18
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    • 1987
  • The Cheolam silver deposits are emplaced along the fractures in breccia dike and the Hongjesa granite. Breccia dike contains fragments of late Cretaceous acidic volcanic rocks and other fragments of various rocks distributed in the mine area. Therefore it is presumed that the mineralization was taken place in later than late Cretaceous time. Mineral paragenesis is complicated by multiple episodes of fracturing. Six distinct depositional stages can be recognized: stage I, deposition of base metal sulfides; stage II, deposition of base metal sulfides and silver minerals; stage III, deposition of carbonates; stage IV, deposition of silver minerals and base metal sulfides; stage V, deposition of silver minerals; stage VI, deposition of barren quartz. Silver minerals from the deposits are native silver, acanthite, pyrargyrite, argentian tetrahedrite, stephanite, polybasite, pearceite, allargentum, antimonial silver and electrum. Fluid inclusion studies ware carried out for stage I, II, IV and VI quartz and stage III calcite. Homogenization temperatures for each stage are as follows: stage I, from $225^{\circ}$ to $360^{\circ}C$; stage II, from $145^{\circ}$ to $220^{\circ}C$; stage III, from $175^{\circ}$ to $240^{\circ}C$; stage IV, from $130^{\circ}$ to $185^{\circ}C$; stage VI, from $120^{\circ}$ to $145^{\circ}C$. Salinities of ore fluids were in the range of 4 and 10 wt.% equivalent NaCl over stage I and stage VI. Ore mineralogical data of each stage indicate that temperatures are within the range of homogenization temperature of fluid inclusions and sulfur fugacities declined steadily from $10^{-9.7}atm$. to $10^{-18.7}atm$. through stage I into stage V.

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Hydrochemical Characteristics of Groundwater in an Area Affected by Pig Carcass Burial: Leakage Detection (돼지사체 매몰지역 지하수의 수지구화학 특성: 침출수 누출 판단)

  • Oh, Junseop;Kim, Ho-rim;Lee, Jeong-Ho;Kim, Kyoung-ho;Choi, Kwang-jun;Kim, Hyeon-Koo;Yun, Seong-Taek
    • Journal of Soil and Groundwater Environment
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    • v.23 no.1
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    • pp.30-40
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    • 2018
  • To evaluate potential impacts of shallow groundwater by the leachate from buried carcass, we investigated hydrochemical characteristics of both leachate and shallow groundwater from monitoring wells and surrounding shallow groundwater wells in an area potentially affected by pig carcass burial. The hydrochemical survey was conducted before and after the relocation of a burial pit. The leachate samples and the groundwater affected by leachate showed the hydrochemistry of $Ca-HCO_3$ type with high $NH_4{^+}$ concentrations, while unaffected groundwater was mostly the $Ca(Na)-Cl+NO_3$ type due to pervasive impacts from agrochemicals. The results of factor analysis on hydrochemical data showed the followings: 1) contamination of groundwater from agro-livestock farming and livestock burial are coexisting in the study area, 2) among ionic species, $HCO_3{^-}$, $NH_4{^+}$, $NO_3{^-}$ and Mn are very useful to differentiate the groundwater contamination from leachate, and 3) groundwater contamination by leachate has been recognized around the monitoring wells even after the relocation of a burial pit, likely due to residual contaminants in surrounding soils. Therefore, it is suggested that continued monitoring of groundwater contamination should be conducted after the relocation of carcass burial pits.

Effectiveness of Calcium Nitrite in Retarding Corrosion of Steel in Concrete

  • Abosrra, L.;Youseffi, M.;Ashour, A.F.
    • International Journal of Concrete Structures and Materials
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    • v.5 no.1
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    • pp.65-73
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    • 2011
  • Corrosion of steel bars embedded in concrete admixed with 0%, 2% and 4% calcium nitrite (CN), having compressive strengths of 20 and 46 MPa was investigated. Reinforced concrete specimens were immersed in 3% NaCl solutions for 1, 7 and 15 days where 0.4A external current was applied to accelerate the chemical reactions. Corrosion rate was measured by retrieving electrochemical data via potentiodynamic polarization technique. Pull-out tests of reinforced concrete specimens were then conducted to assess the corroded steel-concrete bond characteristics. Experimental results showed that corrosion rate of steel bars and steel-concrete bond strength were dependent on concrete strength, amount of CN added and accelerated corrosion period. As concrete strength increased from 20 to 46 MPa, corrosion rate of embedded steel decreased. The addition of 2% CN to concrete of 20 MPa was not effective in retarding corrosion of steel at long time of exposure. However, the combination of higher strength concrete and 2% or 4% CN appear to be a desirable approach to reduce the effect of chloride-induced corrosion of steel reinforcement. After 1 day of corrosion acceleration, specimens without CN showed higher bond strength in both concrete mixes than those with CN. After 7 and 15 days of exposure, the higher concentration of CN, the higher bond strength in both concrete mixes achieved, except for the concrete specimen of 20 MPa compressive strength with 2% CN that recorded the highest deterioration in bond strength at 15 days of exposure.

Impact of Air Convection on H3PO4-Activated Biomass for Sequestration of Cu (II) and Cd (II) Ions

  • Girgis, Badie S.;Elkady, Ahmed A.;Attia, Amina A.;Fathy, Nady A.;Abdel Wahhab, M. A.
    • Carbon letters
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    • v.10 no.2
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    • pp.114-122
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    • 2009
  • Crushed, depitted peach stones were impregnated activated with 50% $H_3PO_4$ followed by pyrolysis at $500^{\circ}C$. Two activated carbons were produced, one under its own evolved gases during pyrolysis, and the second conducted with air flow throughout the carbonization stage. Physicochemical properties were investigated by several procedures; carbon yield, ash content, elemental chemical analysis, TG/DTG and FTIR spectra. Porosity characteristics were determined by the conventional $N_2$ adsorption at 77 K, and data analyzed to get the major texture parameters of surface area and pore volume. Highly developed activated carbons were obtained, essentially microporous, with slight effect of air on the porous structure. Oxygen was observed to be markedly incorporated in the carbon matrix during the air treatment process. Cation exchange capacity towards Cu (II) and Cd (II) was tested in batch single ion experimental mode, which proved to be slow and a function of carbon dose, time and initial ion concentration. Copper was up taken more favorably than cadmium, under same conditions, and adsorption of both cations was remarkably enhanced as a consequence of the air treatment procedure. Sequestration of the metal ions was explained on basis of the combined effect of the oxygen functional groups and the phosphorous-containing compounds; both contributing to the total surface acidity character.

A Study on The Evalution of Influencing Factors in THM Analysis (THM 분석에 있어서의 영향인자에 관한 연구)

  • 남상호;이운기
    • Journal of Environmental Health Sciences
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    • v.18 no.2
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    • pp.82-91
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    • 1992
  • The examination of the pollutants originated from domestic sewage, industrial and agricutural activities the existences of some toxic heavy metals, organic matters and pathogenic microorganisms. A recent report of WHO brought out that such pollutants are in existence with above roughly 2,000 kinds of chemical substances and amongst them about 750 chemicals have been indentified by drinking water. And above 600 kinds of them are organic pollutants and in addition these include carcinogenic mutagenic and poisonous substances. This is not intended to embody a study of broad confined to various approaches on organic materials, and therefore will be THM produced on injection of chlorine at water filtration plant. To specify the relations between THM and factors having an effect upon THM such as TOC, Cl$_{2}$, Temperature, pH and reaction time, first of all the recovery ratio for analytical methods of THM (Head sapce, purge and trap, Liquid/ Liquid Extraction methods) was investigated. Provided that by using it,the correction coefficients are obtained, the accuracy of data might be able to be enhanced through analysis.The result of the experiments are given in the followings. 1) Among three kinds of analytical methods, recovery rate was higher in order of purge and trap Liquid/Liquid Extraction, Head space. There is no great difference in recovery rate among three methods. 2) The higher the concentration of TOC, the more the amount of THM. 3) The higher the reaction temperature, the more the amount of THM. 4) The longer the reaction time, the more the amount of THM. 5) The higher the pH, the more the amount of THM. 6) The higher the concectration of chlorine, the more the amount of THM.

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Effect of Job Insecurity on Job related Depression and Anxiety: Large- and Small-sized Company Employees (근로자의 직업불안정성이 직업 관련 우울감 및 불안감에 미치는 영향: 대규모와 소규모 사업장 근로자를 중심으로)

  • Ha, Yeongmi;Park, Hyunju
    • Korean Journal of Occupational Health Nursing
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    • v.25 no.4
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    • pp.329-339
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    • 2016
  • Purpose: The purpose of this study was to investigate the influences of job insecurity on job related depression and anxiety in large- and small-sized company employees. Methods: Data of the third Korean Working Condition Survey in 2011 were used. Subjects were 2,050 large-sized company employees and 18,924 small-sized company workers. $x^2$ test and multiple logistic regression using SAS 9.2 were conducted. Results: Large- and small-sized company employees showed significant differences in terms of demographic, health-related, and job-related characteristics. From the bivariate analysis, gender, income, self-rated health, occupation, working hours per week, job-related stress, workplace violence, and job insecurity were significantly related to job-related depression/anxiety in large-sized company employees. From the multivariate analysis, higher income (AOR: 0.22, 95%CI: 0.07~0.71), better health perception (AOR: 0.05, 95%CL: 0.01~0.18), 40 or more working hours per week (AOR: 0.20, 95%CI: 0.05~0.79) showed lower risk for job-related depression/anxiety. From the bivariate and multivariate analysis, better health perception (AOR: 0.32, 95%CI: 0.20~0.53), higher job-related stress (AOR: 2.57, 95%CI: 1.68~3.93, workplace violence experience (AOR: 4.26; 95%CI: 2.88~6.30), and job insecurity experience (AOR: 1.90, 95%CI: 1.18~3.05) were significantly related to job-related depression/anxiety in small-sized company employees. Conclusion: Results of this study suggest that job insecurity experience was significantly related to job-related depression/anxiety in small-sized company employees but not in large-sized company employees. Therefore, small-sized company workers who have experienced feeling of job insecurity are vulnerable population in terms of job-related depression/anxiety.

Home Health Resource Utilization Measures Using a Case-Mix Adjustor Model (가정간호 환자구성모델을 적용한 자원이용량 비교 분석)

  • You Sun-Ju;Chang Hyun-Sook
    • Journal of Korean Academy of Nursing
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    • v.35 no.5
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    • pp.774-786
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    • 2005
  • Purpose: The purpose of this study was to measure home health resource utilization using a Case-Mix Adjustor Model developed in the U.S. Method: The subjects of this study were 484 patients who had received home health care more than 4 visits during a 60-day episode at 31 home health care institutions. Data on the 484 patients had to be merged onto a. 60-day payment segment. Based on the results, the researcher classified home health resource groups (HHRG). Result: The subjects were classified into 34 HHRGs in Korea. Home health resource utilization according to clinical severity was in order of Minimum (C0) < 'Low (Cl) < 'Moderate (C2) < 'High (C3), according to dependency in daily activities was in order of Minimum (F0) < 'High (F3) < 'Medium (F2) < 'Low (Fl) < 'Maximum (F4). Resource utilization by HHRGs was the highest 564,735 won in group C0F0S2 (clinical severity minimum, dependency in daily activity minimum, service utilization moderate), and the lowest 97,000 won in group C2F3S1, so the former was 5.82 times higher than the latter. Conclusion: Resource utilization in home health care has become an issue of concern due to rising costs for home health care. The results suggest the need for more analytical attention on the utilization and expenditures for home care using a Case-Mix Adjustor Model.

Mode of Action on EcoRI Restriction Endonuclease: EcoRI and EcoRI Variant N199H have Active Monomeric Forms

  • Kim, Jae-Jong;Koh, Suk-Hoon;Kim, Joong-Su;Lee, Dae-Sil
    • BMB Reports
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    • v.31 no.2
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    • pp.149-155
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    • 1998
  • The N199H variant of the EcoRI endonuclease has about twice the catalytic activity of the wild-type. A comparison of their biochemical characteristics, using synthetic oligonucleotides 5'-dAAAACTTAAGAAAAAAAAAAA-3' (KA) and 5'-dTTTTTGAATTCTTTTTTTTTT-3' (KT), helps to define the cleavage reaction pathway of these enzymes. Both EcoRI and EcoRI variant N199H were found to cleave singlestranded KA or KT about three times faster than the double-stranded forms, although the KT oligonucleotide was more susceptible. Using the ssDNA substrate in kinetic analyses, lower $K_m$ values were obtained for the N199H variant than for the wild-type at low (50 mM), as well as high (200 mM), sodium chloride concentrations. This difference between the endonucleases is attributed to a grealter accessibility for tbe substrate by the variant, and also a higher affinity for the DNA backbone. It also appears that the relative activities of the two enzymes, particularly at high ionic strength, are proportional to their populations in the monomeric enzyme form. That is, according to gel filtration data, half of the N199H molecules exist as monomers in 200 mM NaCl, whereas those of the wild-type are mainly dimeric. Consequently, the Asp199 residue of the EcoRI endonuclease may be implicated in the protein-protein interaction leading to dimerization, as well as in coupling to DNA substrates. In summary, it is proposed that active monomeric endonuclease molecules, derived from the dimeric enzyme, recognize and form a complex with a single stranded form of the DNA substrate, which then undergoes nucleophilic substitution and cleavage.

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Effect of Additives on the Characteristics of Amorphous Nano Boron Powder Fabricated by Self-Propagating High Temperature Synthesis (자전연소합성법을 이용한 비정질 나노 붕소 분말 특성에미치는 첨가제의 영향)

  • Joo, Sin Hyong;Nersisyan, Hayk H.;Lee, Tae Hyuk;Cho, Young Hee;Kim, Hong Moule;Lee, Huk Hee;Lee, Jong Hyeon
    • Korean Journal of Materials Research
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    • v.25 no.12
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    • pp.659-665
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    • 2015
  • The self-propagating high temperature synthesis approach was applied to synthesize amorphous boron nano-powders in argon atmospheres. For this purpose, we investigated the characteristics of a thermally induced combustion wave in the $B_2O_3+{\alpha}Mg$ system(${\alpha}=1.0-8.0$) in an argon atmospheres. In this study, the exothermic nature of the $B_2O_3-Mg$ reaction was investigated using thermodynamic calculations. Experimental study was conducted based on the calculation data and the SHS products consisting of crystalline boron and other compounds were obtained starting with a different initial molar ratio of Mg. It was found that the $B_2O_3$ and Mg reaction system produced a high combustion temperature with a rapid combustion reaction. In order to regulate the combustion reaction, NaCl, $Na_2B_4O_7$ and $H_3BO_3$ additives were investigated as diluents. In an experimental study, it was found that all diluents effectively stabilized the reaction regime. The final product of the $B_2O_3+{\alpha}Mg$ system with 0.5 mole $Na_2B_4O_7$ was identified to be amorphous boron nano-powders(< 100 nm).

A New Salt-Tolerant Thermostable Cellulase from a Marine Bacillus sp. Strain

  • dos Santos, Yago Queiroz;de Veras, Bruno Oliveira;de Franca, Anderson Felipe Jacome;Gorlach-Lira, Krystyna;Velasques, Jannaina;Migliolo, Ludovico;dos Santos, Elizeu Antunes
    • Journal of Microbiology and Biotechnology
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    • v.28 no.7
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    • pp.1078-1085
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    • 2018
  • A salt-tolerant cellulase secreted by a marine Bacillus sp. SR22 strain with wide resistance to temperature and pH was purified and characterized. Its approximate mass was 37 kDa. The endoglucanase, named as Bc22Cel, was purified by ammonium sulfate precipitation, gel filtration chromatography, and extraction from the gel after non-reducing sodium dodecyl sufate-polyacrylamide gel electrophoresis. The optimal pH value and temperature of Bc22Cel were 6.5 and $60^{\circ}C$, respectively. The purified Bc22Cel showed a considerable halophilic property, being able to maintain more than 70% of residual activity even when pre-incubated with 1.5 M NaCl for 1 h. Kinetic analysis of the purified enzyme showed the $K_m$ and $V_{max}$ to be 0.704 mg/ml and $29.85{\mu}mol{\cdot}ml^{-1}{\cdot}min^{-1}$, respectively. Taken together, the present data indicate Bc22Cel as a potential and useful candidate for industrial applications, such as the bioconversion of sugarcane bagasse to its derivatives.