• Journal of the Korean Wood Science and Technology
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• 제33권3호통권131호
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• pp.53-63
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• 2005

본 연구는 바다목장사업 소재로서 방부처리 목재의 사용 가능성에 대한 기초자료를 얻고자 실시하였다. CCA, CCFZ, ACQ 처리재 내 포함된 유해 중금속의 해수에 대한 용탈 안전성을 평가하기 위해 각각 2% 및 3% 방부제 수용액으로 처리한 목재를 증류수, 자연해수 및 인공적으로 염도를 조절한 인공해수에 41일간 폭로하여 기간 별 각 성분의 용탈량을 측정하였다. 바닷물에서 CCA 처리재의 구리 및 크롬의 용탈은 거의 일어나지 않았으며, 다소 많은 비소의 용탈이 있었으나 증류수에서의 용탈에 비해 적은 양을 나타내었다. CCFZ는 증류수에서 크롬과 아연의 용탈량이 매우 높았으나 바닷물에서는 훨씬 적은 용탈량을 나타내었다. 방부제 흡수량 및 인공해수의 염분 농도에 따른 용탈량에는 큰 차이가 없었다. ACQ 처리재는 CCA 및 CCFZ 처리재에 비해 많은 구리 용탈을 나타내었으며 용탈 매체에 따른 차이는 나타나지 않았다.

• Journal of the Korean Wood Science and Technology
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• 제29권1호
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• pp.52-59
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• 2001

본 연구는 양생방법과 양생온도에 따른 소나무, 낙엽송, 북양가문비나무 변재부에서 CCA와 CCFZ의 정착특성을 조사하기 위하여 수행되었다. 방부제 유효성분의 정착 정도는 6가크롬의 3가크롬으로 환원율에 의해 결정하였으며, 연구결과를 토대로 수종, 방부제, 양생방법, 양생온도의 조합별 적정 양생기간을 예측하였다. 양생방법에 관계없이 양생온도가 높을수록 방부제 유효성분들의 정착이 크게 가속되었으며, 건조양생에 비하여 비건조양생시 정착이 빨리 진행되었다. 수종간의 양생속도는 양생방법과 방부제의 종류에 관계없이 전반적으로 소나무>낙엽송>북양가문비나무 순으로 빨랐고, 소나무를 대상으로 비교한 방부제간의 정착속도는 CCA 2호>CCA 3호>CCFZ의 순이었다. 양생방법에 관계없이 양생온도와 양생 소요기간간의 상관이 매우 우수하여 처리재 양생장소의 대기온도에 의해 수종과 방부제의 조합별 적정 양생기간을 거의 완벽하게 예측할 수 있었다.

• Journal of the Korean Wood Science and Technology
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• 제30권2호
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• pp.151-157
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• 2002

갈색부후균 Tyromyces palustris를 이용하여 CCA, CCFZ처리 목재에서 구리를 제거하였다. 균에 의한 구리의 제거효율을 높이기 위한 전처리 방법으로서 증기압처리와 수산처리를 검토하였으며, 적정 배양 방법을 찾기 위하여 진탕배양, 고체배양, 정치배양에서 구리 제거율을 비교하였다. 전처리 방법에서, 증기압 처리만으로는 효과적인 구리제거가 불가능하였으며, 수산처리는 구리제거율은 낮았으나 수산처리 후 균처리를 하면 제거율이 향상되었다. 배양 방법에서는 정치 배양의 구리 제거효율이 높게 나타났다. 대량 배양을 위한 공기부양식 생물반응기에 의한 구리의 제거율은 7일 배양 이후 61%의 제거율을 보였다. T. palustris에 의한 구리제거기작을 탐색하기 위하여 배양액 중에 생성된 물질을 LC/Mass 분석 결과 T. palustris에서 분비되어진 수산과 방부처리 목재 중의 구리가 결합된 수산구리 착염체의 형성이 배양액 중에 존재함이 확인됨으로 균체 외 수산의 작용이 처리재의 구리제거에 크게 관여함이 밝혀졌다.

• Journal of the Korean Wood Science and Technology
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• 제23권3호
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• pp.66-72
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• 1995

The rate of fixation of the components were evaluated in CCA-Type B and CCFZ-treated radiata pine sapwood by quantitative analysis of solution expressed from the treated wood. The leaching characteristics of radiata pine blocks treated with CCA-Type B and CCFZ were also evaluated by the AWPA standard leaching test. Both fixation and leaching charactersistics of CCA-Type B were compared with CCA-Type C treated wood samples. The rate of CCA-Type B fixation was a little faster than that of CCFZ. However, significant amounts of arsenic was unfixed in the CCA-Type B treated samples and consequently leached. These significant quantities of arsenic liberated from the CCA-Type B treated wood during service may pose some environmental concerns. Arsenic was no longer detectable from CCA-Type C treated samples when fixation was complete, even though the fixation of CCA-Type C was slower in some degree than CCA-Type B. In summary, it could be said that CCFZ was much safer preservative than CCA-Type B by the criterion based on the relative hazard assessed by absolute amount of unfixed element present in the treated wood. Also the decision that CCA preservative has to move from Type B to Type C should be made sooner or later for continuous use of CCA preservative in the future.

• Journal of the Korean Wood Science and Technology
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• 제31권6호
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• pp.55-59
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• 2003

The fixation and leaching characteristics of chromated copper arsenate (CCA Type C) and chromium- copper-fluoride-zinc (CCFZ) in domestic softwood (Japanese red pine, Korean pine, and Japanese larch) sapwood were investigated using the expressate method to follow chromium fixation and the American Wood-Preservers' Association (AWPA) leaching procedure to determine leaching properties after fixation. The rates of fixation were affected by preservative types; CCA was fixed much faster than CCFZ for all species evaluated. There were definite differences in the fixation rates of different species, with Korean pine requiring shorter to fix than the other species evaluated. Chromium fixation was greatly enhanced by elevated temperatures, and fixation time can be estimated according to fixation temperatures applied. The percentage of arsenic and zinc leached from domestic softwoods was relatively high compared to chromium and copper, indicating that there is still a relatively high unfixed arsenic and zinc components after complete chromium fixation in CCA-and CCFZ-treated samples, respectively.

• Journal of the Korean Wood Science and Technology
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• 제24권4호
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• pp.93-99
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• 1996

In order to investigate the extent of fixation of new water-borne preservatives in blocks of pinus densiflora sapwoods the streaming potential through the column with preservative treated wood was measured at various conditions. The rates of leachability of ingredients in the treated wood were estimated by the measurement of electric conductivity of the solution with the leached components. The solution was also analyzed by Atomic absorption spectrophotometer (AA). As a results, the experimental data indicated that the fixation of CCB, CCFZ and ACQ in wood were relatively unstable. The fixation rates of CCB, CCFZ were improved by increasing heat and drying time. The amounts of the leached ingredients were apparently higher in CCB and CCFZ than in CCA, while the rate of leaching of ACQ was not changed at various drying temperature.

• Journal of the Korean Wood Science and Technology
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• 제23권4호
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• pp.60-66
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• 1995

The treatability of Japanese larch heartwood was assessed by pressure treatment of non-incised dimension material with CCA or CCFZ. The effectiveness of incising(conventional, high density, and needle incising) for improving CCA treatability on refractory Japanese larch heartwood was also investigated. Preservative retention and penetration were somewhat greater with CCFZ treatment, although those was generally poor in both preservatives. The retention gradients for both CCA and CCFZ-treated stock were essentially the same shape. Treatment of non-incised material with CCA acheived the recommended treatability for using treated wood at the regions of hazard class H2 in the Japanese Agricultural Standards. However, Japanese larch heartwood would require incising as a pretreatment for enhancing treatability, if CCA-treated larch is intended to be used at the regions of hazard class H3 and H4. As expected, incising resulted in a considerable improvement of preservative treatability, particularly penetration, and the effect of incising on the improvement of treatability was excellent at the sequence of needle incising, high density incising, and conventional incising. Among incising techniques investigated in this study, high density and needle incising enhanced CCA treatability beyond the point where it did meet a minimum requirements specified by the Japanese Agricultural Standards for using CCA-treated Japanese larch at the regions of hazard class H3 and even H4.

• Journal of the Korean Wood Science and Technology
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• 제23권4호
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• pp.33-38
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• 1995

The rates of fixation of CCA-Type B and CCFZ in blocks of radiata pine sapwood were compared at various temperatures and conditioning methods (drying and nondrying conditioning). Also the time required to proper fixation of preservative components in the treated wood was estimated. Fixation was monitored by the rates of depletion of free hexavalent chromium in the cell lumens in the teated blocks. The rate of preservative fixation in wood was highly temperature dependent. The fixation rate was considerably accelerated by means of heating and complete fixation of hexavalent chromium was achieved within about 12 hours by heating at $60^{\circ}C$. The moisture content of treated wood during fixation apparently played an important role in the fixation process. The fixation rate of treated wood conditioned in nondrying conditions was much more faster than that of treated wood conditioned in drying conditions. particularly when the moisture content of treated wood was below fiber saturation point. Time required to full fixation could be predicted successfully using the fixation temperatures applied since the correlation between the fixation temperature and the fixation time was excellent. regardless of conditioning methods.

• Journal of the Korean Wood Science and Technology
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• 제32권2호
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• pp.1-8
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• 2004

갈색부후균 Tyromyces palustris를 이용하여 CCA처리 목재와 CCFZ처리 목재에서 중금속을 제거하였다. 전처리 방법으로써 증기압처리와 수산처리가 검토되었다. 수산 전처리에 의한 균처리의 제거율 상승 영향과 일정 균체량에 대한 방부처리재의 폭로양의 차이에 따른 처리율의 변화정도를 검토하였다. 배양방법을 달리하여 방부처리재의 유효성분 제거량을 비교하고 생물반응기를 이용하여 중금속 제거를 실시하였다. 크롬과 비소는 수산의 농도가 증가할수록 제거율이 증가하였으나 구리는 농도의 증가에 따른 제거율이 크게 향상되지 않았다. T. palustris는 균체량 287 mg으로 크롬과 비소는 시료무게 3 g까지 60% 이상의 제거율을 나타냈고 구리는 50% 이상의 제거율을 나타내었다. 진탕배양에서는 크롬, 구리, 비소의 제거율이 60% 이상의 제거율을 보였으며, 정치배양에서는 구리의 제거율이 진탕배양보다 높게 나타났다. 생물반응기 적용 시 7일 배양이후 제거율은 크롬 72%, 구리 61%, 비소는 59%이었다.

• Journal of the Korean Wood Science and Technology
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• 제28권4호
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• pp.61-71
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• 2000

The effect of the treatment with CCFZ, FR-4, and PEG400 from butt end on the dimensional stability and bending properties was examined. Three softwood species such as red pine, Korean white pine and Japanese larch and three hardwood species such as poplar, alder and oak were investigated in this research. Shrinkage of red pine, Korean white pine, poplar, and alder treated with PEG400 decreased. However, there was no significant decrease of shrinkage in Japanese larch and oak. The decrease of shrinkage when moisture content changed from about 20% to 10% was larger than that at any other phase. In regard to the effect of treatment on bending properties, bending MOE and MOR of all specimens treated with PEG400 decreased significantly. Especially in the case of red pine, poplar, and alder treated with PEG400, bending MOR reduced 9%, 14%, and 12%, respectively. Reductions of MOR of the hardwood was also much larger than that of the softwood. However, in all species, treatment with CCFZ and FR-4 did not affect the change of bending MOE and MOR significantly. Comparing the large specimen which also included heartwood with the small specimen which included only treated sapwood, there was a difference in the change of bending MOE and MOR between them. The large specimens of Korean white pine, alder and Poplar, which had a relatively low proportion of sapwood(18~22%), showed the decrease of MOR by 11~13% more than that of small specimens, while red pine, Japanese larch and oak, which had a relatively high proportion of sapwood(35~40%), showed little decrease. It means that bending MOE and MOR of structural wood treated from butt end should be considered in terms of sapwood proportion as well as effect of treated chemicals.