• Title/Summary/Keyword: CA1

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A Study on Adsorption Characterics of Metallic Ions by Tannin Immobilized on Chitin and Chitosan (Chitin 및 Chitosan에의 고정화 탄닌의 금속이온 흡착특성에 관한 연구)

  • Kim, Chang-Ho;Chang, Byung-Kwon;Choi, Kyu-Suk
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.204-215
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    • 1993
  • Epoxy-activated chitin was synthesized by the reaction of epichlorohydrin with chitin which was isolated from waste marine sources such as crab shell. Followed by the reaction of epoxy-activated chitin with hexamethylenediamine, the aminohexyl chitin was synthesized. The aminohexyl chitin was subsequently reacted with epichlorohydrin to prepare the epoxy-activated aminohexyl chitin. Finally, the tannin-immobilized chitin (Resin I) was synthsized by the reaction of tannin solution with epoxy-activated aminohexyl chitin. Using silane coupling agent, the tannin-immobilized chitosan(Resin II) was synthesized by the reaction of $\gamma$-glycidoxypropyltrimethoxy silane with chitosan which was prepared by the deacetylation of chitin. Upon the pH variation, adsorptivities of these immobilized tannins to the metal ions such as $Cu^{+2}$, $Ni^{+2}$, $Cr^{+6}$, $Co^{+2}$, $Ca^{+2}$, $Pb^{+2}$, $Ba^{+2}$, and $UO_2{^{+2}}$ ions were determined by batch method. The adsorptivity tendencies of these immobilized tannin to the most of metallic ions were increased with pH. Furthermore, the adsorptivities of Resin(I) and Resin(II) upon the variation of pH, contact time, amount of resin and concentration of metal ion were investigated. As a result, it was found that these immobilized tannin on both chitin and chitosan showed good adsorptivities for uranyl ion.

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A Study on the Assembling Mechanism of the Hairtail, Trichiurus Lepturus, at the Fishing Grounds of the Cheju Strait (제주해협 갈치(Hairtail,Trichiurus lepturus) 자원의 어장형성기구에 관한 연구)

  • Kim, Sag-Hyun;Rho, Hong-Kil
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.34 no.2
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    • pp.117-134
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    • 1998
  • The study on the Assembling Mechanism of the Hairtail, Trichiurus lenpturus, at the Fishing Grounds of the Cheju Strait had been investigated by analyzing the relationship of the oceanographic conditions and the fishing ground of the Hairtail in the Cheju Strait. 1. The fishing grounds of the hairtail at the Cheju Strait are formed at the bottom of a high temperature of the tidal front at the coast. area of northern Cheju Island, the tip of the linguiform is high in salinity at the eastern and western entrances of Cheju Island, low salinity eddy on the surface and its surrounding front, various water masses in the Strait and coastal waters of the South Sea in Korea. 2. The fishing grounds of the Hairtail at the Cheju Strait begins with the sea surface temperature higher than $15^{\circ}C$ and the incoming of low salinity water now from the East China Sea. 3. Estimation of optimum temperature and salinity per season based upon analysis for relationship between temperature of water and salinity of the bottom layer and the catch is : 15.2~$16.4^{\circ}C$, 34.20~34.40${\textperthousand}$ in spring(June); 14.4~ $17.0^{\circ}C$, 33.70~34.30${\textperthousand}$ in summer(July~September); and 15.7~ $18.6^{\circ}C$, 33.70~34.50$\textperthousand$ in autumn(October~December). Hairtail are mostly caught at the Yellow Sea Warm Current and Tsushima Current with temperature over $14.5^{\circ}C$ and salinity over 33.70${\textperthousand}$ at the bottom layers of the Cheju Strait. 4. Considering the relationship between the amount of hairtail catch and the water temperature of bottom layer, when the bottom water being above $14.0^{\circ}C$ flowed into Cheju Strait through the western entrance of the strait in summer, the ca-h appears to have been abundant. In contrast, the catch has been poor when the temperature of such water was recorded to be below $13^{\circ}C$ Therefore, distribution patterns of water at the bottom layer can be used as a forecast index whether the catch of a certain year will be good or poor.

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Quality Characteristics of Brown Rice Dasik Prepared with Pollen Powder (화분 분말을 첨가한 현미다식의 품질 특성)

  • Kim, Ae-Jung;Han, Myung-Ryun;Kim, Myung-Hwan;Lee, Soo-Jeong
    • The Korean Journal of Food And Nutrition
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    • v.23 no.2
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    • pp.212-217
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    • 2010
  • To enhance the quality of traditional Dasik, pollen Dasik containing brown rice flour fortified with 5, 10, 15 and 20% pollen powder were prepared, and their physicochemical properties were evaluated. Pollen Dasik possessed higher amount of mineral such as K and Ca than brown rice Dasik. The L value of pollen Dasik decreased with increasing pollen powder compared to brown rice Dasik, while the b value of pollen Dasik was increased with increasing pollen powder compared to brown rice Dasik(p<0.05). Hardness of pollen Dasik decreased with increasing amounts of pollen compared to the brown rice Dasik(p<0.05). Sensory evaluation on pollen Dasik preparewd with over 10% pollen showed the highest sensery evaluation value in overall preference.

Characteristics and Yield of Jochung Processed by Different Preparation Methods (제조 방법에 따른 쌀 조청의 특성 및 수율)

  • Choi, Yoon-Hee;Baek, Ji-Eun;Park, Shin-Young;Choi, Hye-Sun;Song, Jin
    • The Korean Journal of Food And Nutrition
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    • v.27 no.3
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    • pp.414-420
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    • 2014
  • This study was performed to increase the yield and to reduce the processing times for the preparation to improve the productivity and quality of rice jochung, a traditional food in Korea. In order to evaluate the quality characteristics and yield of jochung, the viscosity, color value, mineral contents and the sensory evaluation were measured. Jochung is prepared from steamed rice (STR), wet-milled rice flour (WRF) and dry-milled rice flour (DRF) by processing methods of rice and reacting times (6 hours or 13 hours) of liquefaction and saccharification. There is commonly added liquefying enzyme for rice liquefaction (0.4%/10 kg rice, at $85{\sim}90^{\circ}C$ for 1 hour or 4 hours) and saccharogenic enzyme with malt (2.5% or 4.5%/10 kg rice, at $56{\sim}60^{\circ}C$ for 5 hours or 9 hours). The inner structural properties of WRF showed the more distinct shape regular structure of uncombined starch particles but the DRF closely maintained particles of rice flour observed by SEM. If processing times for liquefation and saccharification were reduced from 13 hours to 6 hours, the yield of jochungs prepared with WRF increased 8%, the DRF 7%, and the STR 3% respectively and the sensory evaluation as well as color values and overall desirability received high scores. The viscosity, color a and b values of jochung processed with WRF for 6 hours were lower than that processed for 13 hours. The viscosity and color a, b value and Ca content were decreased in the jochung processed with WRF or DRF for 6 hours, but Mg, P and K were increased than that of STR. Jochung processed by 0.4% liquefying enzyme and 2.5% malt with WRF for 6 hours will increase the yield, save manufacturing times and costs and will thereby enable cost-effective techniques.

AtERF11 is a positive regulator for disease resistance against a bacterial pathogen, Pseudomonas syringae, in Arabidopsis thaliana (애기장대 AtERF11 유전자에 의한 Pseudomonas syringae에 대한 병 저항성 유도)

  • Kwon, Tack-Min;Jung, Yun-Hui;Jeong, Soon-Jae;Yi, Young-Byung;Nam, Jae-Sung
    • Journal of Life Science
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    • v.17 no.2 s.82
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    • pp.235-240
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    • 2007
  • AvrRpt2 protein triggers hypersensitive response (HR) and strong disease resistance when it is translocated from a bacterial pathogen Pseudomonas sp. to host plant cells containing a cognate RPS2 resistance protein through Type III Secretion System (TTSS). However, AvrRpt2 protein can function as the effector that suppresses a basal defense and enhances the disease symptom when functional RPS2 resistance protein is absent in the infected plant cells. Using Affymetrix Arabidopsis DNA chip, we found that many genes were specifically regulated by AvrRpt2 protein in the rps2 Arabidopsis mutant. Here, we showed that expression of AtERF11 that is known as a member of B1a subcluster of AP2/ERF transcription factor family was down regulated specifically by AvrRpt2. To determine its function in plant resistance, we also generated the Arabidopsis thaliana transgenic plants constitutively overexpressing AtERF11 under CaMV 355 promoter, which conferred an enhanced resistance against a bacterial pathogen, Pseudomonas syringae pv. tomato DC3000. Thus, these results collectively suggest that AtERF11 plays a role as a positive regulator for disease resistance against biotrophic bacterial pathogen in plant.

Bioactive and Chemical Properties by Silkworm (Bombyx mori L.) Powder Degradation with Kiwifruit, Papaya, Pineapple and Pear Juice (키위, 파파야, 파인애플 및 배 과즙 처리에 의한 누에분말의 이화학적 특성과 생리활성)

  • Cha, Jae-Young;Kim, Yong-Soon;Ahn, Hee-Young;Eom, Kyung-Eun;Heo, Su-Jin;Cho, Young-Su
    • Journal of Life Science
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    • v.20 no.11
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    • pp.1718-1724
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    • 2010
  • Bioactive and chemical properties of silkworm powder (SP) degradation by fruit extract containing the proteolytic enzymes of kiwifruit, papaya, pineapple and pear were investigated. Silkworm powder was incubated with extracts from each fruit at $60^{\circ}C$ for 24 hr. Protein content was slightly higher in the SP treated with fruit extract than that in the control SP. Major minerals were K, Ca, Mg, and Zn. Major fatty acids were linolenic acid, oleic acid, and palmitic acid. When total protein patterns were analyzed by SDS-polyacrylamide gel electrophoresis (PAGE), silkworm protein was strongly degraded by the treatment of fruit extract from pineapple, papaya, and pear, but little silkworm degradation was observed in kiwifruit extract treatment. Fibriolytic activity was only detected in the SP by the fruit extract treatments from papaya and pear. DPPH radical scavenging activity was slightly stronger in the SP treated with fruit extract than that in silkworm powder. However, all these samples exhibiteda relatively low activity compared with the butylated hydroxytoluene (BHT). These results may provide the basic data for understanding the biological activities and chemical characteristics of SP treated with fruit extract for development of functional foods.

Formation of Micron-sized Alginate Microparticles Using Reverse Micelles (역미셀을 이용한 마이크론 수준의 초미세 알긴산 입자 제조)

  • Imm, Jee-Young;Cho, Young-Hee;Han, Dae-Seok;Kim, Seok-Joong
    • Korean Journal of Food Science and Technology
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    • v.35 no.5
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    • pp.835-840
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    • 2003
  • Micron-sized alginate microparticles were formed in the water pools of reverse micelles (RM) composed of hexane/aerosol OT(AOT)/water through the gelation process between sodium alginate and $CaCl_2$. The size of microparticles formed increased as Wo (the molar ratio of water to surfactant) increased from 5 to 10. The microparticles became aggregated at Wo of 15, and stable RM no longer existed at Wo of 20. The characteristics of microparticles prepared at Wo of 5 and 10 showed significant differences in area, maximum diameter, minimum diameter, mean diameter, and perimeter of microparticles (p<0.05). However, there was no difference in appearance and roundness between the microparticles These results indicate that the size of microparticles are affected by Wo, whereas the overall shape of microparticles are not substantially influenced within Wo values used for stable RM formation. The mean diameter of microparticles was about $2{\sim}2.5\;{\mu}m$ and much smaller $(70{\sim}1,000\;times)$ than the reported sue of alginate microparticles formed in an aqueous medium.

The effects of calcium aluminate cement according to particle sizes on calvarial bone defects in rats (백서 두개골 결손부에서 입자 크기에 따른 Calcium aluminate cement의 효과)

  • Shin, Jung-A;Yun, Jeong-Ho;Oh, Seung-Han;Paik, Jeong-Won;Choi, Se-Young;Kim, Chong-Kwan;Choi, Seong-Ho
    • Journal of Periodontal and Implant Science
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    • v.32 no.4
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    • pp.769-779
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    • 2002
  • This present study was carried out to find the effects of calcium aluminate cement($CaO\;{\cdot}\;Al_2O_3$, CAC), which has been developed with bio-compatibility and mechanical properties, in biological environments. Two different particle sizes of CAC - 3.5${\mu}m$ vs. 212${\sim}$250${\mu}m$ which is recommended in periodontal bone grafting procedures-were filled in 8mm calvarial defect in Sprague-Dawley rat. The specimens were examined histologically, especially the bone-cement interface and the response of surrounding tissues. The results are as follows; 1. In the control group, inflammatory cells were observed at 2 weeks. At 8 weeks, periosteum and dura mater were continuously joined together in the defect areas. But in the center of defect area were filled up with the loose connective tissues. 2. In the experimental group l($212{\mu}m{\sim}250{\mu}m$ particle), immature bone was formed and outermost layer was surrounded by osteoid layer at 2 weeks. Osteoblasts were arranged between immature bone and osteoid layer. And, osteoid layer was remained until 8 weeks after surgery. 3. In the experimental group 2, periosteum and dura mater lost its continuity at 2 weeks. Scattering of CAC particles and infiltration of inflammatory cells were observed, which this findings deepened at 8 weeks. The result of this study shows that when calvarial defects in white rats are filled with calcium aluminate cement of 212${\sim}$250${\mu}m$, the materials are to be bio-compatible in growth and healing on surrounding tissues. When further researches are fulfilled, such as direct bone adhesion and bone regeneration ability, it's possible that CAC could be applied to various periodontology fields in the future.

Improvement Method of Sand Ground Using an Environmental Friendly Bio-grouting Material (친환경 바이오그라우팅을 이용한 모래지반 개량 공법)

  • Kim, Dae-Hyeon;Sagong, Myung;Park, Kyung-Ho
    • Journal of the Korean Society for Railway
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    • v.16 no.6
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    • pp.473-481
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    • 2013
  • The purpose of this research is to evaluate the improvements in the strength and injection range of loose ground after injecting $CaCO_3$(created by microorganism reaction). For this purpose, three cases of single-layer (Sand, SP, SW) specimens were made in a 150mm D ${\times}$ 200mm H space and two cases of multi-layer specimens (SW/SP, SP/SW) were made in a 150mm D ${\times}$ 300mm H space. The specimens were made with a relative density of 30% of soft ground and an injection was given over a time of one day. The uniaxial compression strength was measured with a cone penetrometer and the injection range was observed by checking the bulb formation around the injection nozzle. Also, the compositions of the specimens were assessed through XRD analyses. Based on the test results, a compressive strength of 500kPa and 15cm thick cementation were noted due to the cementation of the soil. This implies that there are significant effects of the pore condition and size on bio-grouting technology.

Research on Relation of Nutrients Intake, Health Status, and Bone Mineral Density in Middle-aged Women (장년기 여성의 영양섭취상태, 건강상태와 골밀도와의 관련성에 관한 연구)

  • Kim, Hyeon-Ju
    • Journal of the Korean Dietetic Association
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    • v.9 no.4
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    • pp.307-315
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    • 2003
  • This study was to investigate the relation of nutrients intake, health status, and bone mineral density in middle-aged women. Daily nutrients intake were analyzed by convenient method. The BMD of subjects were measured by Dual Energy X-ray Absorptiometry(DEXA). BMD was measured at the spine(vertebrae L2-L4) and femur(neck, Ward's triangle and trochanter). The nutrients intake of subjects were higher than recommended dietary allowances(RDA) except for calorie, iron, calcium, vitamin B1. Nutrients intake of vitamin A(p<0.05), iron(p<0.01), vitamin $B_2$(p<0.05), niacin(p<0.05), and vitamin C(p<0.05) between $\leq$49 yr group and $\geq$50 yr group. Mean daily intake of calcium was much less than the Korean RDA, 78.5% in $\leq$49 yr group and 77.3% in $\geq$50 yr group. 35.8% of the subjects under 50 years of age($\leq$49 yr group) and 77.4% of the subjects from 50 years up($\geq$50 yr group) were classified as osteopenia or osteoporosis. BMD of L2-L4 were positively correlated with height(p<0.05), weight(p<0.05) and BMI(p<0.05). BMD of femoral neck was positively correlated with BMI(p<0.05), BMD of Ward's triangle was positively correlated with weight(p<0.001). But BMD of L2-L4 and femoral neck were negatively correlated with age(p<0.05), menarche(p<0.05). BMD of Ward's triangle was negatively correlated with age(p<0.001). The BMD of L2-L4 were positively correlated with animal protein(p<0.05), calcium(p<0.05) and iron(p<0.05). The BMD of femoral neck was positively correlated with animal protein(p<0.05). The BMD of Ward's triangle was positively correlated with animal protein(p<0.001) and iron(p<0.001). The above results suggest that it should be difficult to prevent middle-aged women's bone destruction through nutrients intake. Further investigation is necessary to prove the mutual relations between BMD, exercise, and calcium intake. Therefore, middle-aged women will need proper exercise as well as Ca supplementation in order to prevent osteoporosis with aging.

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