• Title/Summary/Keyword: C.G.TECH

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Synthesis and Electrochemical Performance of Li2MnSiO4 for Lithium Ion Battery Prepared by Amorphous Silica Precusor (비정질 실리콘 산화물을 이용한 리튬망간실리콘산화물의 합성 및 전기화학적 특성 평가)

  • Jin, Yun-Ho;Lee, Kun-Jae;Kang, Lee-Seung;Jung, Hang-Chul;Hong, Hyun-Seon
    • Journal of Powder Materials
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    • v.19 no.3
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    • pp.210-214
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    • 2012
  • Mass production-capable $Li_2MnSiO_4$ powder was synthesized for use as cathode material in state-of-the-art lithium-ion batteries. These batteries are main powder sources for high tech-end digital electronic equipments and electric vehicles in the near future and they must possess high specific capacity and durable charge-discharge characteristics. Amorphous silicone was quite superior to crystalline one as starting material to fabricate silicone oxide with high reactivity between precursors of sol-gel type reaction intermediates. The amorphous silicone starting material also has beneficial effect of efficiently controlling secondary phases, most notably $Li_xSiO_x$. Lastly, carbon was coated on $Li_2MnSiO_4$ powders by using sucrose to afford some improved electrical conductivity. The carbon-coated $Li_2MnSiO_4$ cathode material was further characterized using SEM, XRD, and galvanostatic charge/discharge test method for morphological and electrochemical examinations. Coin cell was subject to 1.5-4.8 V at C/20, where 74 mAh/g was observed during primary discharge cycle.

Research of Characterization of Covalently Cross-linked SPEEK/Cs-Substituted MoPA/Ceria 1wt% Composite Membrane for Water Electrolysis (Cs 치환에 따른 수전해용 공유가교 SPEEK/Cs(n)-MoPA/Ceria 1%(n = 1~3) 복합막의 특성 연구)

  • Park, Daeyoung;Hwang, Sungha;Oh, Seunghee;Yoon, Daejin;Kang, Ansoo;Moon, Sangbong;Chung, Janghoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.1
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    • pp.1-10
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    • 2014
  • Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted phophomolybdic acid(Cs-MoPA) with cross-linking agent contents of 0.01mL. In conclusion, CL-SPEEK/$Cs_{(2.5)}$-MoPA/ceria(1%) membrane showed the optimum results such as 0.1095S/cm of proton conductivity at $80^{\circ}C$, 2.906meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 49.73MPa of tensile strength which were better than Nafion 117 membrane.

A Study of Broadband PLC Channel Modeling (광대역 PLC채널의 모델링 분석에 관한 연구)

  • Choi, Y.K.;Park, G.H.;Seo, J.W.;Cha, J.S.;Seo, H.S.;Sin, M.C.
    • Proceedings of the KIEE Conference
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    • 2003.07a
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    • pp.271-273
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    • 2003
  • 최근에 전력선통신(PLC: power line communication)에 관한 연구 및 개발이 활성화되고 있는 가운데, 정부에서는 전력선통신을 위한 전송채널의 주파수허용범위를 기존의 협대역인 450kHz에서 광대역인 30MHz로 확대할 계획이다. 현재, PLC 시스템에서는 대용량정보를 고속으로 전송하기 위한 고속 PLC기술의 개발이 활발히 진행되어지고 있으며, 이러한 통신시스템 기술의 구현을 위해서는 새롭게 확대될 30MHz대역에서의 전력선채널의 분석이 무엇보다도 중요한 해결 과제라고 할 수가 있을 것이다. 전력선은 각종 전기기기와 가전제품 및 사무기기로부터 발생되는 잡음들이 직접 유입되며, 또한 부하가 전력선에 연결되는 시간과 공간에 따라 전송 특성이 수시로 가변하는 특성을 가진다. 이와 같은 열악한 전력선통신채널 환경을 극복하고 통신의 에러극복능력을 향상시키기 위해서는 기존의 협대역 채널모델을 그대로 적용하기에는 부적합한 면이 많으므로, 새롭게 허용될 광대역 주파수를 갖는 전력선 채널에 대한 모델링기법이 요구된다. 따라서, 새롭게 인가될 광대역 채널을 위한 효율적인 전력선통신시스템을 개발하기 위해서는 전력선채널의 리모델링에 근거한 다양하고 실험적인 고찰이 수반되어야 하리라고 판단된다. 그러므로, 본 논문에서는 Mixture 잡음 모델링기법을 이용하여, 부하변동 및 가변적인 잡음 특성을 가진 전력선채널모델을 새롭게 분석하였다. 또한, 새롭게 분석한 전력선채널모델에 관한 수식을 직교 코드에 의한 다중접속 통신 기술인 CDMA 방식에 적용하여 비트 에러율을 유도해 봄으로써 그 유효성을 확인하였다.

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The Preparation and Characteristics of Covalently Cross-Linked SPEEK/Cs-TPA/Ceria Composite Membranes for Water Electrolysis (수전해용 공유가교 SPEEK/Cs-TPA/Ceria 복합막의 제조 및 특성 연구)

  • Song, Minah;Ha, Sungin;Park, Deayong;Ryu, Cheolhwi;Moon, Sangbong;Kang, Ansoo;Chung, Janghoon
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.5
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    • pp.437-447
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    • 2012
  • Ceria ($CeO_2$) was used to scavenge free radicals which attack the membrane in the polymer electrolyte membrane water electrolysis (PEMWE) circumstance and to increase the duration of the membrane. In order to improve the electrochemical, mechanical and electrocatalytic characteristics, engineering plastic of the sulfonated polyether ether ketone (SPEEK) as polymer matrix was prepared in the sulfonation reaction of polyether ether ketone (PEEK) and the organic-inorganic blended composite membranes were prepared by sol-gel casting method with loading the highly dispersed ceria and cesium-substituted tungstophosphoric acid (Cs-TPA) with cross-linking agent contents of 0.01 mL. In conclusion, CL-SPEEK/Cs-TPA/ceria (1%) membrane showed the optimum results such as 0.130 S/cm of proton conductivity at $80^{\circ}C$, 2.324 meq./g-dry-membrane of ion exchange capacity and mechanical characteristics, and 65.03 MPa of tensile strength which were better than Nafion 117 membrane.

A Study on the Cellulose Blend Knit Fabrics using Burn-out Printing Convergence Technology (셀룰로오스 혼방 니트 편포의 착색번아웃 날염복합기술에 관한 연구)

  • Cho, Ho-Hyun;Chung, Myung-Hee;Lee, Jong-Lyel
    • Journal of the Korea Fashion and Costume Design Association
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    • v.16 no.4
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    • pp.229-235
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    • 2014
  • This study conducted a research on burn-out printing convergence technology for cellulose blend knit fabrics. Printing technology, which forms color pattern on the fabric, can be generally classified into four according to printer or printing method, e.g. screen printing, roller printing, rotary printing, digital printing. However, these printing methods are flat in design or pattern, which have limitation to overcome monotonousness of fabric, so that recently burn-out process method, which expresses three-dimensional pattern effect by treating chemical on the surface of fabric as the method to appeal its esthetics to the customers. Particularly, in case of cellulose/polyester composite material, first, it is proceeded in 2 processes, by dyeing cellulose or polyester fabric and burning out cellulose fabric, in this process, due to pollution caused by disperse dye migration, color of polyester fabric part could be discolored, which has high falt risk. This research considered coloring burn-out technique, which simultaneously proceed dyeing and burn-out by reducing dyeing and burn-out process to 1 stage, which were proceeded in 2 stages previously. As the research result, it was confirmed that reasonable depth of roller was 0.04~0.06mm in roller printing process, heat treatment condition of burn-out far-infrared radiation was $185^{\circ}C{\times}30m/min$. Color fastness to washing was confirmed to be 4-5 grade, color fastness to rubbing, 3-4 grade, color fastness to light, 4 grade. Also, it was confirmed that energy reduction effect appeared 38.19%, in case of energy cost per yard compared to the existing production, also, 19.74%, in case of production cost.

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Industrial application of WC-TiAlN nanocomposite films synthesized by cathodic arc ion plating system on PCB drill

  • Lee, Ho. Y.;Kyung. H. Nam;Joo. S. Yoon;Jeon. G. Han;Young. H. Jun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.06a
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    • pp.3-3
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    • 2001
  • Recently TiN, TiAlN, CrN hardcoatings have adapted many industrial application such as die, mold and cutting tools because of good wear resistant and thermal stability. However, in terms of high speed process, general hard coatings have been limited by oxidation and thermal hardness drop. Especially in the case of PCB drill, high speed cutting and without lubricant process condition have not adapted these coatings until now. Therefore more recently, superhard nanocomposite coating which have superhard and good thermal stability have developed. In previous works, WC-TiAlN new nanocomposite film was investigated by cathodic arc ion plating system. Control of AI concentration, WC-TiAlN multi layer composite coating with controlled microstructure was carried out and provides additional enhancement of mechanical properties as well as oxidation resistance at elevated temperature. It is noted that microhardness ofWC-TiA1N multi layer composite coating increased up to 50 Gpa and got thermal stability about $900^{\circ}C$. In this study WC-TiAlN nanocomposite coating was deposited on PCB drill for enhancement of life time. The parameter was A1 concentration and plasma cleaning time for edge sharpness maintaining. The characteristic of WC-TiAlN film formation and wear behaviors are discussed with data from AlES, XRD, EDS and SEM analysis. Through field test, enhancement of life time for PCB drill was measured.

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A New Sweetpotato Cultivar for Use of Bioethanol 'Daeyumi' (바이오에탄올용 고구마 신품종 '대유미')

  • Lee, Joon-Seol;Ahn, Young-Sup;Chung, Mi-Nam;Kim, Hag-Sin;Jeong, Kwang-Ho;Bang, Jin-Ki;Song, Yeon-Sang;Shim, Hyeong-Kwon;Han, Seon-Kyeong;Suh, Sae-Jung
    • Korean Journal of Breeding Science
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    • v.42 no.6
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    • pp.674-678
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    • 2010
  • A new sweetpotato variety, 'Daeyumi', was developed by Bioenergy Crop Research Center, National Institute of Crop Science (NICS), RDA in 2008. This variety was obtained from the cross between 'Jinhongmi' and 'Xusju 18' in 2000. The seedling and line selections were performed from 2001 to 2003, preliminary and advanced yield trials were carried out from 2004 to 2005, and the regional yield trials were conducted at six locations from 2006 to 2008. 'Daeyumi' has cordate leaf, green vine and petiole, elliptic storage root, red skin and yellow flesh color of storage root. This variety is also resistant to Fusarium wilt and nematode. The starch value was 25.9%, ethanol yield was 418 L/Ton, which was 7% higher than that of 'Yulmi' variety, and the total sugar content was 2.47 g/100g, dry weight. 'Daeyumi's initial temperature of starch gelatinization was lower, 76.2$^{\circ}C$, and the retrogradation process was earlier than 'Yulmi'. The average yield of storage root was 27.8 ton/ha in the regional yield trials, which was 36% higher than that of 'Yulmi' variety. Number of storage roots over 50 gram per plant was 3.0, and the average weight of one storage root was 152 gram. This variety can be used for the production of bioethanol and starch processing.

Effects of Combined Chlorine Dioxide Gas Treatment Using Low-Concentration Generating Sticks on the Microbiological Safety and Quality of Paprika during Storage (저농도 서방형 이산화염소 가스 병합처리가 파프리카의 저장 중 미생물 성장과 품질에 미치는 영향)

  • Kang, Ji Hoon;Park, Shin Min;Kim, Hyun Gyu;Son, Hyun Jung;Song, Kyoung Ju;Cho, Miae;Kim, Jong Rak;Lee, Jeong Yong;Song, Kyung Bin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.45 no.4
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    • pp.619-624
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    • 2016
  • Chlorine dioxide ($ClO_2$) gas treatment (75 ppmv, 30 min) has been suggested to improve the microbial safety of postharvest paprika in a previous study. Based on these results, in this study, an additional combined treatment using low-concentration $ClO_2$ gas-generating sticks (3 ppmv) in paprika samples during storage was carried out at $8^{\circ}C$ and 90% relative humidity to further enhance the quality and reduce the decay rate of paprika for the purpose of lengthy storage. After the combined treatment, the initial populations of total aerobic bacteria as well as yeast and molds in the paprika samples decreased by 3.04 and 2.70 log CFU/g, respectively, compared with those of the control samples, and this microbial inactivation was maintained by the low-concentration $ClO_2$ gas-generating sticks during storage. In particular, the decay rate of samples with combined treatment was significantly lower than that of the control. Vitamin C content, hardness, and color quality parameters of paprika samples were not altered by treatment, while weight loss of the samples treated with the combined $ClO_2$ gas was lower than that of the control during storage. These results indicate that the combination of two different $ClO_2$ gas treatments is effective for retaining the quality of paprika during prolonged storage.

Effect of Dietary Probiotics Supplementation Contained with Astaxanthin Produced by Phaffia rhodozyma on the Productivity and Meat Quality of Ducks (Astaxanthin을 생성하는 Phaffia rhodozyma를 포함한 미생물제제의 급여가 오리의 성장과 육질에 미치는 영향)

  • Kim K. S.;Lee J. H.;Shin M. S.;Cho M. S.;Kim Y. P.;Cho S. K.;Kang Y. J.
    • Korean Journal of Poultry Science
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    • v.32 no.2
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    • pp.73-80
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    • 2005
  • This study was carried out to investigate the influence of dietary probiotics supplementation contained with astaxanthin synthesizing microorganism 'Phaffia rhodozyma' on the productivity and meat quality of ducks. Growth performance carried out during 45 days for day-old ducks offered in Joowonori incorporated. A total of 150 day-old ducks(cheribery) of mixed sex(M:F=1:1) were allotted into 5 groups. The basal diets were added with low levels of astaxanthin containing probiotics. We investigated mortality, bodyweight, and feed conversion used by growth performance. 45day-old ducks were butchered and carried out nutrients composition analysis, meat quality test, organoleptic examination, fatty acid analysis, cholesterol analysis, storage test, and astaxanthin concentration analysis. Control showed $3.7\%$ mortality and treatments showed $0\%$ mortality. These results showed improvement of immunity, for influence of dietary probiotics supplementation contained with astaxanthin. The control gained 2.68 kg and treatment gained 2.84 kg. The control was 2.15 and treatment was 1.83 for feed conversion. Treatment was increased feed conversion than control as significantly. The results of meat quality test showed that treatment was tender and taste more than control. The results of nutrients composition analysis showed that treatment was produced low fat and high protein meat. Ducks meat of treatments contained higher unsaturated fatty acid and lower cholesterol than control. The case of carotenoids confirmed that astaxanthin and $\beta-carotein$ were accumulated in duck meat.

Using automated container type culture system Hericium erinaceum mushroom production technology (컨테이너형 버섯식물공장시스템설계 및 노루궁뎅이버섯 생산)

  • Jo, Woo-Sik;Lee, Sung-Hak;Ryu, Song-Yi;Kang, Min-Gu;Kim, Woo-Hyun;Park, Chang-Min;Park, Who-Won
    • Journal of Mushroom
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    • v.14 no.4
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    • pp.249-252
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    • 2016
  • Timing, place, and the high-tech industry to overcome barriers to the introduct of the so-called "smart agriculture". The core factors of precision agriculture, including temperature, humidity, location information, and real summary information, are all significant for ICT controlling technique. The system is a four-season container allowing mushroom product, humidity, illumination, and factors such as carbon dioxide were regulated to create the optimal environment for mushroom cultivation. Hericium erinaceum (also called Lion's Mane Mushroom, Bearded Tooth Mushroom, or Bearded Tooth Fungus) is an edible and medicinal mushroom in the tooth fungus group. During approximately 40 days of incubation, 1.4 kg of oak sawdust was used as the test medium. The humidity, temperature, and $CO_2$ density were maintained at >85-95%, $18-20^{\circ}C$, and 700-1,000 ppm, respectively, in the container type culture system. The time for primordium formation was observed to be 4-7 days. The amount of fruitbody production was 74-95 g per bag. This technique will be used to establish a new community support program, in conjunction with international movement, domestic sales and exports are also planned.