• Title/Summary/Keyword: C.E.C

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Decomposition of CO2 with Reduced ferrite by CH4 (CH4로 환원된 페라이트를 이용한 CO2 분해)

  • 신현창;정광덕;주오심;한성환;김종원;최승철
    • Journal of the Korean Ceramic Society
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    • v.39 no.7
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    • pp.657-662
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    • 2002
  • The reduced ferrites, reduced NiF $e_2$ $O_4$ and CuF $e_2$ $O_4$, by C $H_4$ were applied to $CO_2$ decomposition to avoid the greenhouse effects. At the reduction reaction above $700^{\circ}C$, $H_2$ and CO were generated by partial oxidation of C $H_4$ After the reduction reaction up to 80$0^{\circ}C$, the spinel structure ferrites changed to mixture of the oxygen deficient iron oxide (Fe $O_{(1-{\delta})}$(0$\leq$$\delta$$\leq$1)) and the metallic Ni or Cu. The rate and quantity of $CO_2$ decomposition with reduced CuF $e_2$ $O_4$ were larger than those with reduced NiFe $O_4$. The $CO_2$ gas was decomposed by oxidation of the oxygen deficient iron oxide. The metallic Cu and Ni were not oxidized and remained in a metallic state up to 80$0^{\circ}C$. The $CO_2$ decomposition reaction with the reduced ferrite by C $H_4$ gas is excellent process preparing useful gas such as $H_2$and CO and decomposing $CO_2$ gas.

Application of Flory-Treszczanowicz-Benson model and Prigogine-Flory-Patterson theory to Excess Molar Volume of Binary Mixtures of Ethanol with Diisopropyl Ether, Cyclohexane and Alkanes (C6-C9)

  • Kashyap, Pinki;Rani, Manju;Tiwari, Dinesh Pratap;Park, So-Jin
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.257-265
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    • 2020
  • Densities (ρ) for binary mixtures of ethanol (1) + diisopropyl ether (DIPE) or cyclohexane or alkane (C6-C9) (2) were measured at 298.15 K, 308.15 K and 318.15 K. The excess molar volume (VEm) of binary mixtures was calculated using ρ data and correlated with Redlich-Kister polynomial equation. The VEm values for binary mixtures of ethanol (1) + cyclohexane or n-alkane (C6-C9) (2) were positive, whereas for ethanol (1) + DIPE (2) these were negative. The magnitude of VEm values follows the order: cyclohexane > n-nonane > n-octane > n-heptane > n-hexane > DIPE. The VEm values have been interpreted qualitatively and also quantitatively in terms of Flory-Treszczanowicz-Benson (FTB) model and Prigogine-Flory-Patterson (PFP) theory. The values VEm predicted using FTB model agree well with experimental VEm values at all mole fractions. But the PFP theory describes well VEm data in ethanol-rich region (x1 > 0.5) for all binary mixtures and is able to predict the sign of VEm vs x1 curve for ethanol-lean region (x1 < 0.5) except for ethanol (1) + nonane (2) mixtures.

Identification of Potential Corynebacterium ammoniagenes Purine Gene Regulators Using the pur-lacZ Reporter in Escherichia coli

  • HAN , RI-NA;CHO, ICK-HYUN;CHUNG, SUNG-OH;HAN, JONG-KWON;LEE, JIN-HOO;KIM, SOO-KI;CHOI, KANG-YELL
    • Journal of Microbiology and Biotechnology
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    • v.14 no.6
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    • pp.1249-1255
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    • 2004
  • This study has developed Corynebacterium ammoniagenes (c. ammoniagenes) purine gene transcriptional reporters (purF-lacZ and purE-lacZ) that function in Escherichia coli (E. coli) DH5a. After transformation of a C. ammoniagenes gDNA library into E. coli cells harboring either purF-lacZ or purE-lacZ, C. ammoniagenes clones were obtained that repress purF-lacZ and purE-lacZ gene expression. The potential purE and purF regulatory genes are homologous to the genes encoding transcription regulators, the regulatory subunit of RNA polymerase, and genes for purine nucleotide biosynthesis of various bacteria. The C. ammoniagenes purE-lacZ and purF-lacZ reporters were repressed by adenine and guanine within E. coli, indicating similarity in the regulatory mechanism of purine biosynthesis in C. ammoniagenes and E. coli. Gene regulation of pur-lacZ by adenine and guanine was partly abolished in cells expressing potential purine regulatory genes, indicating functionality of the purine gene regulators in repression of purE-lacZ and purF-lacZ. The purE-lacZ and purF-lacZ reporters can be used for the screening of genes involved in the regulation of the de novo synthesis of the purine nucleotides.

Volatile Flavor Components in Various Varieties of Grape(Vitis vinifera L.) (포도의 품종별 휘발성 향기성분 분석)

  • 박은령;김경수
    • Food Science and Preservation
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    • v.7 no.4
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    • pp.366-372
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    • 2000
  • Volatile flavor components in three grape(Vitis vinifera L.) varieties were extracted by SDE(Simultaneous steam distillation and extraction) method using the mixture of n-pentane and diethylether(1:1, v/v) as an extract solvent. Grapes of the following varieties were studies : Blackolympia, Campbell and Delaware. The volatile extracts were analyzed by GC-FID and GC/MS. The totals of 77, 72 and 74 volatile flavor components were identified in Blackolympia, Campbell and Delaware, respectively. (E)-2-Hexenal(20.36%), diethylacetal(18.03%), hexanal and ethyl acetate were contained as the main compounds of Blackolympia. In Campbell, ethyl acetate(30.81%) was relatively more abundant than other compounds and among functional groups, C$\_$6/ aldehydes and alcohols were major constituents of the extract. On the other hand, in Delaware, alcohols was the major constituent group and (E)-2-hexenal(21.07%) and (E)-2-hexena1-ol(19.43%) were the main compounds. All of three grape varieties contained a large amount of hexanal, (E)-2-hexenal, hexanol, (E)-2-hexen-1-ol, thus C$\_$6/-compounds proved to be major volatile components of grape and small amount of terpenols were only detected from Delaware.

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Effects of Density, Temperature, Size, Grain Angle of Wood Materials on Nondestructive Moisture Meters

  • Pang, Sung-Jun;Jeong, Gi Young
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.1
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    • pp.40-50
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    • 2019
  • The aim of this study was to investigate the effects of density, temperature, size, and grain direction on measurement of moisture contents (MC) of wood materials non-destructively. The MC of different sizes of solid wood, glulam, and CLT from larch (larix kaempferi, $560kg/m^3$) and pine (pinus koraiensis, $430kg/m^3$) were measured using the dielectric type and resistance type meters. The specimens were conditioned in the environmental chamber to be equilibrium moisture content (EMC) of 12 % and 19 %. When density setting in dielectric type meter was increased from $400kg/m^3$ to $600kg/m^3$, the MCs of specimen (S-L-100-E) were decreased from 13.4 % to 11.3 %. However, when wood group (WG) setting in resistance type meter was changed from WG1 to WG4, the measured MCs were increased from 9.2 % to 12.3 %. When temperature setting in resistance type meters was changed from 0 to $35^{\circ}C$, the MC was decreased from 17.0 % to 13.0 %. The MCs measured by dielectric type meter for larger specimens (S-L-100-E_11.3 %, G-L-240-E_11.7 % and C-L-120-E_12.8 %) were higher than those of small size specimens (S-L-30-E_8.7 %, G-L-150-E_10.3 %, and C-L-90-E_9.7 %). The MCs measured by resistance type meter for larger specimens (G-L-240-E_11.6 % and C-L-120-E_13.3 %) were also higher than those of small size specimens (G-L-150-E_10.4 %, and C-L-90-E_11.8 %). The resistance type meter was not affected by the grain direction but the dielectric type meter were affected by the grain direction. The MC measured by resistance type meter for G-L-120-E perpendicular to grain direction was 11.5 % and the measured MC parallel to grain direction was 11.3 %. The MC measured by dielectric type meter parallel to grain direction (12.1 %) was higher than that measured perpendicular to grain direction (10.7 %).

Transcriptional Regulation of Escherichia coli serC-aroA Operon : Further Support for cAMP-Dependent Expression

  • Sa, Jae-Hoon;Park, Soo-Sun;Lim, Chang-Jin
    • BMB Reports
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    • v.28 no.1
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    • pp.21-26
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    • 1995
  • The Escherichia coli mixed-function serC-aroA operon encodes biosynthethic enzymes for unrelated pathways leading to the syntheses of serine and aromatic amino acids. It has been proposed that the operon is expressed in a cAMP-dependent manner. In this work experiments were performed to investigate the cAMP-dependent expression of the operon. Exogenous cAMP increased ${\beta}$-galactosidase synthesis in the $cya^+$ and cya strains harboring the serC-aroA-lac fusion plasmid. This enhancement was more dramatic in the $cya^-$ strain grown in a minimal medium. In a dot blot assay the serC-aroA mRNA content increased in a concentration-dependent pattern after the addition of exogenous cAMP. The activity of phosphoserine aminotransferase, encoded by the serC gene, apparently increased in E. coli cells after the addition of cAMP. All results obtained confirmed that the expression of the E. coli serC-aroA operon is positively regulated by cAMP at the level of transcription.

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M.O. Studies of Configuration and Conformation (Part II) Configuration and Conformation of Ketimine isomers

  • Kim, Shi-Choon;Chun, Young-Gu;Lee, Ikchoon
    • Nuclear Engineering and Technology
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    • v.9 no.1
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    • pp.39-44
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    • 1977
  • The configuratior and conformation of N-methyl-C-phenylalkyl-ketimine isomers, Ph-CR=N$CH_3$ (R=H, $CH_3$, $CH_3$CH$_2$), have been studied from extended Huckel molecular orbital calculations. The result shows that the E-configuration of the C=N double bond is favored compared with that of the Z-configuration. The most preferable conformation of the phenyl ring rotamer in N-methyl-C-phenylaldimine and N-methyl-C-phenylmethylketimine are the coplanar forms with regard to the C=N plane, but the conformation of the $CH_3$CH$_2$-rotamer, in N-methyl-C-phenylethyl-ketimine, the gauche form (dihedral angle between C=N and $CH_3$CH$_2$- plane=90$^{\circ}$) is favored.

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Cloning and Sequence Analysis of Hog Cholera Virus(HCV) E2 Gene (돼지 콜레라 바이러스 E2 유전자의 클로닝 및 염기서열분석)

  • 이영기;강신웅;김선원;박성원;이종철;이청호
    • Journal of the Korean Society of Tobacco Science
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    • v.23 no.2
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    • pp.103-108
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    • 2001
  • Hog cholera virus(HCV) was purified from virus infected Bovine kidney cells. From this virus, total protein was analyzed by SDS-PAGE gel electrophoresis and about 55 kDa band of E2 envelope protein was detected. The viral RNA was purified and E2 cDNA was amplified by RT-PCR. E2 cDNA fragment was cloned to PCRII-TOPO cloning vector and named pE2. The analysis of nucleotide sequence showed that this E2 cDNA fragment inserted into pE2 was 1191 nucleotides long and coded 397 amino acids.

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The Chemical Properties and Fertilizer Effect of a Residual By-product of Glutamic Acid Fermentation (구르타민 산발효잔사가공물(酸醱酵殘渣加工物)의 성질(性質)과 비효 -II. 토양(土壤)의 이화학적성질(理化學的性質) 개량효과)

  • Hong, Chong Woon;Jung, Yee Geun;Park, Chon Suh;Kim, Yung Sup
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.4
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    • pp.227-230
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    • 1973
  • To elucidate the effect of the organic carbon compounds included in a separate from glutamic acid fermentation residue (G. A. F. R) on the improvement of the physico-chemical properties of soil, on a soil low in organic matter content, treated with G. A. F. R and compost, observations on the total organic matter, humic acid, fulvic acid, C. E. C. and the development of aggregates were made. From the results of the investigations it was concluded that, the organic carbon compound in the tested G. A. R. F. is more effective than compost in increasing the total organic matter, humic acid, fulvic acid and C. E. C. of soil and in enhancing the development of soil aggregates.

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Contrast Sensitivity as a function of spatial frequency by using polarization (편광을 이용한 눈의 공간주파수-대비민감도 함수 측정기구 설계)

  • Kim, Young-Geun
    • Journal of Korean Ophthalmic Optics Society
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    • v.5 no.1
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    • pp.43-48
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    • 2000
  • It was to adjust the luminance of light by the rotation angle of the polarizes and analyzer. The luminance value Lmax, Lmin of Contrast Sensitivity could be obtained from the rotation angle ${\theta}_m$ of the average luminance($L_m$), the rotation angle(${\theta}_{max}$, ${\theta}_{min}$) of the maximum and the minimum's amplitude. $$L_{max}=I(0)e^{-2at}{\cdot}cos^2{\theta}_m(1+C_s^{-1})$$ $$L_{min}=I(0)e^{-2at}{\cdot}cos^2{\theta}_m(1-C_s^{-1})$$ We obtained the rotation angle(${\theta}_{max}$, ${\theta}_{min}$) of the polarizes and analyzer from the rotation angle ${\theta}_m$ of the average luminance($L_m$) and the Contrast Sensitivity($C_s$). $${\theta}_{max}=cos^{-1}[cos{\theta}_m{\cdot}(1+C_s^{-1})^{1/2}]$$ $${\theta}_{min}=cos^{-1}[cos{\theta}_m{\cdot}(1-C_s^{-1})^{1/2}]$$.

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