• Title/Summary/Keyword: C-H activation

Search Result 1,315, Processing Time 0.031 seconds

Equilibrium and Hydriding Characteristics of Metal Hydride Chemical-Treated and Compacted in Pellet (화성처리 및 성형화에 따른 금속수소화물의 평형특성 및 수소흡장거동)

  • Park, C.K.;Cho, T.H.
    • Transactions of the Korean hydrogen and new energy society
    • /
    • v.5 no.1
    • /
    • pp.9-17
    • /
    • 1994
  • Activation behavior, hydriding rate and disintegration were studied for a compact in pellet form and hydrogen storage alloy particles treated with newly developed inorganic solution. Cylindrical disc of 12.95mm diameter and of 7.1mm thickness was prepared by compressing(8ton) a mixture of $MmNi_{4.5}Al_{0.47}$ and PTFE. Chemical treatment of particles with 1mol of solution was performed at room temperature for several hours until the pH of solution did not change. Chemical treatment made much accelerated activation without any incubation period which generally exists in the untreated alloys and the hydriding reaction rate after full activation also was improved.

  • PDF

Magneto-resistances of the coated conductors fabricated on the tilted single crystalline Ni substrates and RABiTS

  • Yoo, J.;Kim, H.;Jung, K.;Oh, S.;Youm, D.
    • 한국초전도학회:학술대회논문집
    • /
    • v.10
    • /
    • pp.132-135
    • /
    • 2000
  • Magneto-resistances of the YBa$_2$Cu$_3$O$_{7-{\delta}}$ based coated conductors fabricated on the tilted single crystalline Ni substrates and RABiTS (rolling assisted bi-axially textured substrate) were measured under various magnetic fields. The activation energies of vortices were estimated from them by fitting equation of p = p$_o$ exp(-U(H,T)/k$_B$T). When currents flew in the rolling direction for the case of the tilted single crystalline YBCO on the RATS, the activation energies were similar to those of c-axis normal YBCO films on the SrTiO$_3$ single crystal substrates [5] and were slightly larger than those of the RABiTS coated conductors. On the contrary, for the currents flowing in the transverse direction, the magnetoresistances show double transitions in the temperature with much smaller activation energies.

  • PDF

Corrosion Characteristics and Surface Morphologies of TiN and ZrN Film on the Abutment Screw by Arc-ion Coating(II) (어버트먼트 나사에 아-크 이온도금된 TiN과 ZrN피막의 부식특성과 표면 형상 (II))

  • Jeong, Y.H.;Kwag, D.M.;Chung, C.H.;Kim, W.G.;Choe, H.C.
    • Corrosion Science and Technology
    • /
    • v.10 no.6
    • /
    • pp.212-217
    • /
    • 2011
  • In this study, corrosion characteristics of TiN and ZrN film on the abutment screw by arc-ion plating were investigated using a potentiodynamic anodic polarization test in deaerated 0.9% NaCl solution at $36.5{\pm}1^{\circ}C$. The surface morphologies of the coating layers before and after corrosion test were investigated by a field-emission scanning electron microscope (FE-SEM) and a energy dispersive x-ray spectroscopy (EDS). The surfaces of the TiN and ZrN coated abutment screws showed the smooth surfaces without mechanical defects like scratches which can be formed during the manufacturing process, compared with those of the non-coated abutment screw. The corrosion and passive current densities of TiN and ZrN coated abutment screws were lower than those of the non-coated abutment screw.

Mast Cell Increase and Stem Cell Factor Receptor (c-kit) Expression in Helicobacter pylori-infected Gastritis (Helicobacter pylori 감염 위염에서의 비만세포 증가와 Stem Cell Factor Receptor (c-kit)의 발현)

  • Jekal, Seung-Joo
    • Korean Journal of Clinical Laboratory Science
    • /
    • v.37 no.1
    • /
    • pp.41-46
    • /
    • 2005
  • It is known that mast cells (MCs) are increased in H. pylori-infected gastritis and its increase is mediated by stem cell factor (c-kit ligand). To determine the mechanism of mast cell recruitment and activation by stem cell factor, weinvestigated the expression of stem cell factor receptor (c-kit) in H. pylori-positive and -negative gastric mucosa. Biopsy specimens from 16 H. pylori-negative and 20 positive subjects were examined. H. pylori infection in gastric mucosa was examined by the Warthin-Starry method. MC and c-kit were identified by immunohistochemisty, using a monoclonal antihuman MC tryptase antibody and a polyclonal anti-human c-kit antibody. Densities of MC and c-kit positive cell were measured by a computerized image analysis system. MCs were detected in the lamina propria of both H. pylori-positive and -negative gastric mucosa. Densities of MC and c-kit positive cell were significantly greater in H. pylori-positive than -negative subjects. c-kit was located on the surface of MCs. These results indicate that stem cell factors may be one of the factors involved in mast cell increase and that they activate mast cells by binding with c-kit.

  • PDF

Transition Metal-Catalyzed Ortho-Functionalization in Organic Synthesis

  • Park, Young-Jun;Jun, Chul-ho
    • Bulletin of the Korean Chemical Society
    • /
    • v.26 no.6
    • /
    • pp.871-877
    • /
    • 2005
  • Recent progress in the filed of transition-metal mediated C-H bond activation has had a great influence on organic synthesis. Among such transition-metal catalyzed reactions, ortho-functionalization via the chelationassisted strategy has been paid great attentions as one of the powerful methodologies for converting aromatic compounds into ones that are more functionalized at the exclusively ortho-position. In this context, various transition metal-catalyzed ortho-functionalizations such as alkylation, alkenylation, silylation and carbonylation are described briefly and their prospects are suggested.

The Physical Characteristics and Preparation of $Mg_2SiO_4(La.Ho)$ Thermoluminescent Phosphor ($Mg_2SiO_4(La.Ho)$열형광체의 제작과 물리적 특성)

  • Noh, Kyung-Suk;Song, Jae-Heung;Koo, Hyo-Geun;Lee, Deog-Kyu
    • Journal of radiological science and technology
    • /
    • v.20 no.1
    • /
    • pp.65-69
    • /
    • 1997
  • [ $Mg_2SiO_4(La.Ho)$ ] thermoluminescent phosphor was made by putting the $MgCl_2.6H_2O$ and $SiO_2$ and by doping the rare earth element of $LaCl_3.7H_2O$ and $HoCl_3$. The heating rate is $10^{\circ}C/sec$ for the thermoluminescent phosphor. Two peaks are found in the measured $Mg_2SiO_4(La.Ho)$ Tl glow curve at $152^{\circ}C$ and $205^{\circ}C$ when the heating rate is $5^{\circ}C/sec$. The peak value at $205^{\circ}C$ is the most sensitive to X-ray among the glow peaks. The activation energy of the main peak has been estimated by the peak shape method. The estimated activation energies for Ho and La are $0.52{\sim}1.77\;eV$ respectively.

  • PDF

Growth of Interfacial Reaction Layer by the Isothermal Heat Treatment of Cast-Bonded Fe-C-(Si)/Nb/Fe-C-(Si) (Nb/Fe-C-(Si) 주조접합재에서 등온열처리시 계면반응층의 성장에 관한 연구)

  • Jung, B.H.;Kim, M.G.;Jeong, S.H.;Park, H.I.;Ahn, Y.S.;Lee, S.Y.
    • Journal of the Korean Society for Heat Treatment
    • /
    • v.16 no.5
    • /
    • pp.260-266
    • /
    • 2003
  • In order to study the interfacial reaction between Nb thin sheet and Fe-C-(Si) alloy with different Chemical compositions, they were cast-bonded. The growth of carbide layer formed at the interface after isothermal heat treatment at 1173K, 1223K, 1273K and 1323K for various times was investigated. The carbide formed at the interface was NbC and the thickness of NbC layer was increased linearly in proportional to the heat treating time. Therefore, It was found that the growth of NbC layer was controlled by the interfacial reaction. The growth rate constant of NbC layer was slightly increased with increase of carbon content when the silicon content is similar in the cast irons. However, as silicon content increases with no great difference in carbon content, the growth of NbC layer was greatly retarded. The calculated activation energy for the growth of NbC layer was varied in the range of 447.4~549.3 kJ/moI with the compositions of cast irons.

Reaction kinetic of crystal growth in NaX zeolite (NaX 제올라이트 결정성장의 반응속도)

  • 하종필;송종택;김익진
    • Journal of the Korean Crystal Growth and Crystal Technology
    • /
    • v.11 no.1
    • /
    • pp.14-19
    • /
    • 2001
  • The crystal size was determined as a function of reaction temperature, during the crystallization process of NaX zeolite. The measured rate constants for linear growth were as 0.0441$\mu\textrm{m}$/h at $80^{\circ}C$, 0.0595$\mu\textrm{m}$/h at $90^{\circ}C$ and 0.0972$\mu\textrm{m}$/h at $100^{\circ}C$, respectively. The activation energy calculated from the relation between the linear growth rate an the reaction temperature was 43.243kJ/mol. The reaction of crystal growth were revealed as 20 days at $80^{\circ}C$, 16 days at $90^{\circ}C$ and 9 days at $100^{\circ}C$, respectively. Both the final product crystal size an the crystallization time were decreased with increasing reaction temperature.

  • PDF